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PII: S0959-6526(16)30061-0
DOI: 10.1016/j.jclepro.2016.02.143
Reference: JCLP 6850
Please cite this article as: Nikbin IM, Rahimi R S, Allahyari H, Fallah F, Feasibility study of waste Poly
Ethylene Terephthalate (PET) particles as aggregate replacement for acid erosion of sustainable
structural normal and lightweight concrete, Journal of Cleaner Production (2016), doi: 10.1016/
j.jclepro.2016.02.143.
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6 Department of Civil Engineering, Islamic Azad University Rasht Branch, Iran
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9 Saman Rahimi R*
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10 Department of Civil Engineering, Islamic Azad University Rasht Branch, Iran
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13 Hamed Allahyari
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17 Farhad Fallah
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18 Faculty of Civil Engineering, Science and Research Branch Islamic Azad University of Sirjan, Sirjan, Iran
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22 *Corresponding author.
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30 Abstract
31 Using PET as a raw material to produce bottles or containers is very common that after usage leads to a
32 challenging environment protection issue. A large amount of consumed PET become waste and require
33 vast areas of land for storage since several tons of that cannot be fully recycled at once. Concerning this
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34 issue, there is a potential to recycle wastes such as waste PET to produce concrete and to prevent the
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35 direct contact of plastics with the environment due to a longer service life of concrete. In this study, the
36 resistance of normal PET concrete (NPC) and lightweight PET concrete (LWPC) against sulfuric acid
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37 erosion was investigated. Percentages of 5, 10 and 15 of waste PET particles substitute for fine natural
38 aggregate in both NPC and LWPC mixtures. After curing and then immersing specimens in 5% sulfuric
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39 acid solution, in intervals of 15, 30 and 60 days, crushing load, mass measuring, and ultrasonic wave
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40 velocity tests were conducted on them. According to the results, not only LWPC did erode less than NPC,
41 but also their crushing load reduction, mass loss, and ultrasonic wave velocity reduction rate was lower
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42 than the NPC specimens. Furthermore, the lightweight concrete without PET (LWC) showed a lesser
43 reduction rate, compared to normal concrete (NC). Reusing waste PET in concrete consumes large
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44 amounts of it, which compensates for its disposal issues, protects natural resources, decreases the dead
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45 load of buildings due to its low unit weight, and in this study led to improving acid resistance of both
46 types of concrete.
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47 Keywords: Waste Polyethylene Terephthalate (PET); Waste management; Sulfuric acid attack;
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54 1. Introduction
55 PET is one of the widespread used plastics in the packaging industry due to its lightweight and
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56 easiness of handling and storage (Rahmani et al., 2013). Since the beverage consumption increased,
57 producing PET bottles increased particularly in the USA, Canada, and Western Europe (Choi et al., 2005;
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58 Reis and Carneiro, 2012). In some Asian countries such as China, India, and Korea, a rise in the
59 production of PET has dramatically become an environmental menace (Choi et al., 2002; Kim et al.,
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60 2010).
61 During the last few decades, the generation, recycling, composting, and disposal of solid wastes have
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altered fundamentally. Total solid waste generation according to last reports was 251 million tons in the
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63 USA (U S Environmental Protection, 2010) and 10.37 million tons in Iran (Nabizadeh et al., 2008). Yet,
64 84% of the waste is buried, and only 6% is recycled, and 10% is composed in Iran (Nabizadeh et al.,
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65 2008). In the case of the USA, these values are 53.8%, 34.5%, and 11.7% in terms of burying, recycling,
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66 and composting (U S Environmental Protection, 2010). Figure 1 shows the breakdown of solid wastes
67 generated, by material. According to the figure, the total amount of waste plastic generated in the USA
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68 was 12.7% and in Iran was 8%. According to NOPCOR (NAPCOR (National Association for PET
69 Container), 2014), the total weight of PET bottles and jars available in the USA for recycling in 2014 was
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70 2.65 million tons and the total amount, by weight, of postconsumer PET bottles collected for recycling
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71 was 0.82 million tons, so the recycling rate of PET was 31%, including both whole bottles and dirty
72 flakes. Moreover, the utilisation rate of PET (the amount of clean flakes produced from post-consumer
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73 bottles plus clean flakes exported, to total bottles available for recycling) was 21.6%. PET can be
74 recovered and recycled again and again by thorough washing and re-melting for use in new PET products,
75 or by chemically breaking down the PET into its constituent raw materials, which are then purified and
76 converted into new PET. PET can be recycled into new PET containers, carpet, clothing, protective
77 packaging, industrial strapping, automotive parts, construction materials, even the felt for tennis balls, and
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78 tennis ball canisters (“Recycling | PETRA: Information on the Use, Benefits & Safety of PET Plastic.,”
79 2016). Any PET that is unsuitable for recycling because it is too dirty or contaminated (the difference
80 between recycling rate and utilisation rate) to be properly cleaned can be safely and efficiently burned as
81 an energy source.
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82 Although it is possible to benefit from the produced heat during incineration, the combustion of some
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83 kinds of wastes like PET may produce poisonous gasses. In addition, there are active campaigns against
84 waste incineration, causing air pollution and consequent acid rain, and Greenpeace actively acted on these
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85 problems (Frigione, 2010). On the other side, the decline of wastes greatly benefits the natural
86 environment with certain economic advantages since waste materials stand for a big loss of resources that
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87 could be recovered, recycled or appointed to other uses (Frigione, 2010; Sadrmomtazi et al., 2015;
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88 Sharma and Bansal, 2015).
89 Furthermore, the concrete industry is one of the largest consumers of natural resources. It is estimated that
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90 the worldwide consumption of concrete is almost 10 thousand million tons per a year. If one assumes that
91 concrete is 70% aggregates and uses 300 kg/m3 of cement then nearly 1.2 thousand million tons of cement
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92 and 7.5 thousand million tons of aggregates are consumed annually by the industry (Bogas et al., 2015).
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93 In this sense, the sustainability criteria are emphasised and applied to concrete due to their most
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94 widely usage in building materials and some factors, such as versatility, ease of raw materials
95 obtainment, low cost, ease of fabrication, high mechanical strength, impermeability to water, and
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96 high durability (Güneyisi et al., 2004; Khaloo et al., 2008; Sadrmomtazi et al., 2015).
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97 Therefore, using PET particles instead of a proportion of aggregate can improve some characteristics of
98 concrete due to their satisfactory abrasion behaviour (Janfeshan Araghi et al., 2015), high toughness
99 (Rahmani et al., 2013), low thermal conductivity (Fraternali et al., 2011), high ductility (Janfeshan Araghi
100 et al., 2015), and high heat capacity (“Plastics, Polymers & Resins | DuPont USA,” 2016).
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101 Utilising waste materials in concrete is of particular interest due to the fact that the usable lifespan of
102 concrete is far greater than its non-usable life span. Moreover, the lifespan of usable plastics is much
103 lower than their waste service life on the earth. Therefore, the inclusion of waste products in concrete can
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105 In recent decades, many pieces of research have been conducted on using different types of waste
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106 materials in concrete. Table 1 lists some of these researches that replaced different constituents of
107 concrete with various types of waste materials (Sharma and Bansal, 2015).
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108 Researchers indicated that mortars made of PET could be utilised in aggressive environments due to their
109 low water absorption. In addition, it could provide high erosion resistant concrete (Ge et al., 2013). Some
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researchers, Won et al. and Singh et al. (Singh et al., 2004; Won et al., 2010), illustrated that using PET in
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111 concrete leads to increase in ductility and decrease in plastic shrinkage cracks, which improves concrete
112 durability. Moreover, Akçaözog˘lu et al. (Akçaözoğlu et al., 2010) indicated that utilising PET in concrete
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113 contributes to improvement in permeability and resistance to carbonation and leads to decrease in weight,
114 which provides worthy advantages in structures designing. Even then, it could suffer from some minor
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115 disadvantages, a decrease in compressive and tensile strength (Albano et al., 2009; Choi et al., 2009).
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116 One of the most crucial problems in the design and construction of structural elements is the considerable
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117 amount of weight of dead-load. Structural lightweight concrete has been used successfully for structural
118 purposes for many years. This type of concrete has a lower density compared to normal weight concrete
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119 and differs from normal weight concrete by using lightweight aggregates. The main application of
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120 structural lightweight concrete is to decrease the dead load and consequently reduce the dynamic loads of
121 concrete structures such as high-rise buildings, long-span bridges and marine structures, allowing the
122 structural designer to reduce the areas of sectional members, and the construction cost can be saved when
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124 In recent decades, the durability of concrete has been standing out in structures designing. Although
125 considrable worthy progress in recognising of erosion processes has achieved, there have been limits on
127 The main issue about the durability of concrete structures is to face acidic environments, which affects
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128 performance, lifetime, and cost of vital infrastructures maintaining. Previous studies have shown that
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129 existent acids in underground water, chemical sewage or acids produced by oxidation of sulfur
130 compounds in backfills could attack concrete substructures (Alani and Faramarzi, 2014; Hobbs and
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131 Taylor, 2000). Additionally, many concrete structures, especially in industrial areas, are affected by
132 erosion resulted by acid rain (Fan et al., 2010). Spoiling sewages leads to several problems, including
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133 pollution of soils and underground water, reduction of ability in wastewater transfer and excessive ground
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134 settlement cave-in (Chang et al., 2005). Furthermore, providing high-quality sewage infrastructures needs
135 too much expenditure on high-quality concrete. For example, only in the US, the costs of controlling and
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136 maintaining in Germany is even more than investing in new wastewater infrastructures. Moreover, costs
137 of sewer controlling and maintening caused by biogenic sulfuric acid attack have estimated about 100
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138 thousand million US dollars (O’Connell et al., 2012). In 1945, Parker (Parker, 1945) associated this
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139 subject with chemical-microbial interaction in sewage and mentioned that effects of sulfuric acid on
140 concrete are more destructive than sulfate attack. Because in this situation, there are dissolution effects
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141 resulted by hydrogen ions besides of sulfate ions attack. Sulfuric acid reacts with existent calcium
142 hydroxide (CH) in concrete and produces gypsum, and then gypsum formation leads to approximately
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143 double volume expansion of concrete. Even now, some researchers have mentioned this reaction plays a
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144 secondary part in erosion procedure. The reactions between gypsum and calcium aluminate hydrate
145 (C3A) and formation of ettringite cause more destruction due to their greater expansion in volume than
146 initial compounds (Monteny et al., 2001). These compounds cause inner pressure to increase, which leads
147 to the formation of cracks (Monteny et al., 2001). While the erosion is continuing, the cracked surface
148 becomes white and soft, and the eroded concrete loses its mechanical strength. Gradually, with increasing
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149 the number of cracks, the concrete begins spalling and finally ruins (Lee et al., 2008; Schmidt et al., 2009;
150 Skalny et al., 2003). The findings of conducted studies are not scientifically used in typical constructions
151 yet. On the other side, the erosion of water and wastewater infrastructures has been one of the most
152 problems during recent decades. However, there are many attitudes about a proper design of structures
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153 against aggressive environment during their service life (Neville, 2004; Wells and Melchers, 2015;
154 Yamanaka, 2002). Some of these studies, on the one hand, illustrate improvements in concrete properties
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155 by utilising various admixtures and innovative materials compounds and at last introduce a modern
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156 concrete; on the other hand, prevent growing sulfuric acid producing bacteria (Bassuoni and Nehdi,
157 2007). So far many pieces of research were conducted on effects of cement type, water to cement ratio
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158 (W/C), admixtures and types of aggregates on the improvement in normal concrete and mortar resistance
159 to sulfuric acid attack (Bassuoni and Nehdi, 2007; Chang et al., 2005; Lotfy et al., 2016; Roy et al., 2001;
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160 Thomas and Gupta, 2016; Yuan et al., 2015).
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161 Due to insufficient studies about the deterioration of PET concrete exposed to sulfuric acid, in this
162 research effects of various percentages of PET particles on LWPC and NPC exposed to sulfuric acid
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167 In order to make concrete specimens, an amount of natural fine aggregate, normal-weight coarse
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168 aggregate (gravel), and light expanded clay aggregate (LECA) produced in Leca factory (Saveh, Iran)
169 with 740 kg/m3 of dry compacted density were mixed. Table.2 shows the characteristics of aggregates.
170 The sieve analysis conducted for aggregates was based on ASTM standard (ASTM C33 / C33M, 2013;
171 ASTM C330 / C330M - 14 Standard Specification for Lightweight Aggregates for Structural Concrete,
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172 2014), and the results are given in Table 3. The cement utilised in this study is Portland cement type II,
174 The PET particles, rinsed and grinded by means of industrial machines, were provided from waste dirty
175 PET bottles and utilised as fine aggregate in concrete. The PET particles used in this study had the
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176 maximum size of 7mm (as shown in Figure 2) and the estimated unit weight of 464 Kg/m3 with a specific
gravity of 1.11 gr/cm3. Moreover, their flexural modulus of elasticity, tensile modulus of elasticity and
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178 maximum tensile strength were 2.5 GPa, 2.9 GPa and 60 MPa. Table 3 shows the sieve analysis results.
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179 The percentages of concrete components and concrete mixtures (ACI Committee 211, 1991) are given in
180 Table 4. First, a half of the sands and gravel and total of LECA were mixed. Afterwards, the PET
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particles were added to the mixture and properly mixed with the existing materials, and then 20% of the
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182 existing water was added to saturate the aggregates. After that, remained cement and sand were added
183 into the mixture, and finally, the remained water was poured. Moreover, by increasing in the proportion of
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184 PET particles, the mix time increased. All the physical and mechanical characteristics of specimens
185 containing 5, 10 and 15 volumetric percent of substituted PET were compared with control specimens
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186 (NC and LWC). In the case of NPC and LWPC, the numbers 5, 10, and 15 stand for the percentage of
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190 There is not a strict method to measure the resistance of concrete in acidic environments, but ASTM C267
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191 (“ASTM C267 - 01(2012) Standard Test Methods for Chemical Resistance of Mortars, Grouts, and
192 Monolithic Surfacings and Polymer Concretes,” 2012) presented general guidelines for mortars or grouts
193 and polymer concretes. All the samples were cured at 20 °C and 95% RH for 28 days. Afterwards, three
194 samples of each mixture were tested in order to compare the results and give an exact definition of
195 analysis about the specimens in the sulfuric acid solution. The remained samples were divided into two
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196 equal groups, one of them was kept in curing container and the other one was transferred to 5% sulfuric
197 acid solution (PH≈1) to simulate sewage environments in laboratory accelerated test. Three specimens of
198 each mixture immersed in sulfuric acid solution and three specimens cured in water were extracted after
199 15, 30, and 60 days and rinsed three times with tap water, and after putting them at room temperature for
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200 30 minutes, their dimensions were measured and crushing load test, mass change measuring, and
201 ultrasonic wave velocity test were conducted. The mass variation of specimens in the form of a
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202 percentage of their initial mass used as an indicator to evaluate the deterioration of concrete subjected to
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203 the sulfuric acid solution. Equation 1 presents the cumulative mass loss (MLj) for each specimen.
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M j − Mi)
205 ML j = ( ) ×100 (1)
Mi
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206 Where:
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208 Mi = the primary mass of specimen before exposure to sulfuric acid (kg).
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210 The mass variation is a simple and traditional measuring factor in acidic attack test and can depend on the
211 size of specimens and cement type. In addition, it could be significantly under the effect of the behaviour
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212 of reactions products and decomposition of cement paste on specimens. Therefore, in this paper crushing
213 load bearing capacity for cubic specimens in the size of 10×10×10 cm was considered as an effective
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214 measure of concrete resistance to sulfuric acid attack. Measuring the dimensions of specimens was
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215 accompanied by many problems after the acidic attack because the dimensions could become irregular
216 with exposed aggregate. In order to eliminate these problems, the load bearing capacity of specimens was
217 applied as a factor to mention the maximum load recorded within the compressive test (Chang et al.,
218 2005). The compressive load, before and after the acidic attack is called crushing load and this measuring
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219 method is called crushing load test (Chang et al., 2005). To estimate the decrease in the crushing load
220 value compared to reference value before subjecting to sulfuric acid, Equation 2 was employed.
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fc j − fc28
∆fc j = ( ) × 100 (2)
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222
fc28
223
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224 Where:
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226 fc28 = the primary crushing of specimen after a 28-day curing (kg).
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228 To measure ultrasonic wave velocity (“ASTM C597 - 09 Standard Test Method for Pulse Velocity
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229 Through Concrete,” 2009), an ultrasonic non-destructive electronic machine (PUNDIT MODEL
230 PC1,012) was used which its accuracy was 0.1 µs. A transducer with the vibration frequency of 52 kHz
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231 and accuracy of ±1% for travel time and ±2% for distance was also utilised. Nine measurements were
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232 performed for three cubic specimens of each design in various ages, and the minimum time among them
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234
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236 Fan et al. (Fan et al., 2010) presented Equation 3 to estimate the crushing load of concrete specimens
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f cr , j
238 Dcc = (3)
f cn , j
239 Where:
240 Dcc = relative strength deterioration ratio of crushing load for deteriorated concrete specimen.
241 fcr,j = the axial crushing load of concrete exposed to the acid solution during j days.
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242 fcn,j = the axial crushing load of control specimens cured in the water during j days.
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244 As shown in Figure 3, increasing in immersion time in the sulfuric acid solution causes Dcc ratio to
245 decrease in both types of concrete, although Dcc variations versus time are decreased by increasing the
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246 percentage of PET particles. In the other words, by increasing PET particles, less crushing load reduction
247 for specimens attacked by sulfuric acid is seen. The least values among them are associated with
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248 LWPC15 and NPC15, illustrating positive effects of substituting PET particles on the concrete resistance
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249 to erosion.
250 After plotting the difference between the crushing load of immersed specimens and their initial crushing
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251 load, after a 28-day curing, versus their immersion time in Figure 4, it can be expressed that relative
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252 changes in crushing loads begin decreasing from primary ages. The specimens containing 15 percent of
253 PET indicated lower reduction than the other ones (after 60 days immersion), especially in regard to
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254 LWPC. This lower reduction can be attributed to their higher ability to retain their healthy core and
255 integrity against acid attack. The crushing load reduction rate for specimens consisted of 5%, 10% and
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256 15% of PET particles was reduced after approximately halftime of immersion.
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257 Figure 5 represents the relation between ultrasonic wave velocity and immersion time of specimens in the
258 sulfuric acid. According to this figure, ultrasonic wave velocity related to specimens containing PET
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259 particles was lower than control specimens at initial ages. By passing time of immersing, the ultrasonic
260 wave velocity of all specimens began reducing, and after nearly 20 days reached each other. For control
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261 specimens, the reduction of ultrasonic wave velocity tended to continue, but specimens containing PET
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262 particles almost got a constant value. By increasing immersion time, erosion products are produced in
263 concrete, and due to higher porosity and lower integrity of concrete after exposure, ultrasonic wave
264 velocity reduces. The ultrasonic velocity of specimens containing 15% of PET particles was less than the
265 other ones in both types of concrete. This is because of higher capacity of concrete containing more PET
266 particles to resist the internal pressure caused by expansion of cement paste during the reaction to the
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267 sulfuric acid. This resistance could be related to more porosity of PET concrete as accommodation for
268 reaction products and the flexibility of PET particles. Therefore, it might be expressed that specimens
269 containing more PET particles have higher ultrasonic wave velocity after 60-days immersion, indicating
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271 Figure 6 plots mass of immersed specimens versus immersion time. As observed, specimens containing
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272 PET particles had less mass compared with control specimens at initial ages. After a 60-day immersion,
273 the specimens containing more PET particles retained more mass in terms of NPC and LWPC, which
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274 indicates their higher resistance to sulfuric acid attack. It should be noted that lower mass of concretes
275 containing more PET particles during initial days is due to the lower unit weight of PET particles
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276 compared to normal aggregates.
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277 Figure 7 represents the mass loss of specimens containing various percentages of PET particles attacked
278 by sulfuric acid. LWPC showed less mass reduction than NPC specimens. However, LWC indicated more
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279 mass loss compared to NPC10 and NPC15. Concerning this figure, by increasing the PET percentage in
280 both types of concretes, the resistance to sulfuric acid increased, and the LWPC15 as well as NPC15 had
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282 The relation between 28-day crushing load of specimens and their mass loss after immersing in sulfuric
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283 acid solution is shown in Figure 8. The graph is divided into four quarters that the intersection of them is
284 a point with values of the 28-day crushing load and the 60-day mass loss of control specimen attacked by
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286 -Points on the up and left quarter of graph have higher crushing load and lower mass loss than control
288 -Points on the down and left quarter of graph have lower crushing load and mass loss than control
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290 -Points on the up and right quarter of graph have higher crushing load and mass loss than control concrete
291 (OD).
292 -Points on the down and right quarter of graph have lower crushing load and higher mass loss (OWP).
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293 Hewayde et al. (Hewayde et al., 2007) mentioned that the factors of compressive strength improvement
294 necessarily do not contribute to enhancing the concrete resistance to sulfuric acid attack. According to
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295 designer’s goal, a concrete with high durability and medium strength could be produced to use in some
296 circumstances. As shown in Figure 8, the points resulted by crushing load and mass loss tests on two
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297 types of LWPC and NPC containing various percentages of PET particles are located on the down and
298 left quarter of graph (OD). In the other words, by increasing the percentage of PET particles, the mass
299
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loss and crushing load of specimens affected by sulfuric acid was decreased, while the resistance to
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300 erosion increased, especially regarding LWPC. It is important to note that crushing load could be
301 increased by adding supplementary cementitious materials in order to use the advantages of these types of
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302 concrete. In the other words, if the goal of design is to increase concrete durability and have the least
304 Figure 9 shows the relation between the mass loss of specimens and the loss of their crushing load during
305 a 60-day immersion in sulfuric acid solution. It is observed that both crushing load and mass were
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306 decreased, and the analysis of regression coefficients, shown in these graphs, illustrate a linear equation
308 Regarding the best-fit line for specimens, the higher coefficients of the equations, the higher decrease for
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309 crushing loads in comparison to mass loss. It is observed that the regression coefficient is increased by
310 substituting PET particles in both types of concretes, which shows a lesser mass loss for specimens
311 containing more PET particles within a specific range of crushing load. Although LWC and LWPC5 have
312 a lesser coefficient compared to NC and NPC5, this coefficient is higher for LWPC10 and LWPC15.
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313 In this study, specimens containing 15% of PET particles had the highest equation coefficient in the case
314 of both types of concretes, and LWPC15 had the highest coefficient compared to all specimens. As a
315 consequence, the specimens containing higher percentage of PET particles have higher durability,
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317 As seen in Figure 10, the crushing load variation of LWPC is obviously lower than NPC in all
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318 percentages of PET substitution, and this variation is higher at the end of 60-days immersion. Not only
319 LWPC specimens did erode less than NPC specimens, but also their crushing loads reduction rates were
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320 lower than the NPC specimens. Moreover, LWC showed less crushing load reduction than NC.
321 Figure 11 shows ultrasonic wave velocity variation versus the time of immersion in sulfuric acid. From
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the initial days of immersion, LWPC specimens had marked variations compared to NPC specimens, and
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323 LWPC15 had the highest one. In addition, LWC had lower ultrasonic velocity variation compared to both
325 As seen in Figure 12, substituting PET particles in both types of concrete led to a decrease in the mass
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326 change of specimens. Furthermore, LWPC specimens had less mass change than NPC specimens and
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327 showed higher resistance to sulfuric acid. Both LWPC and NPC showed lower mass change compared
328 with NC due to the positive effect of substituting PET particles on the concrete resistance to sulfuric acid,
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330
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332 PET waste reflects a serious environmental issue that is in urgent need of being addressed by the
333 scientific community. Experiments were conducted to investigate the feasibility of PET in NPC
334 and LWPC as a partial substitution for natural fine aggregate and present an interesting approach
335 for recycling of this type of waste material in the civil engineering area. In this study, the influence
336 of sulfuric acid attack on the two types of NPC and LWPC consisted of various percentages of PET
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337 particles (5, 10, and 15) as a substitute for aggregate was investigated by using crushing load, mass
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340 - According to the mass measuring test, specimens containing more percentage of PET particles had a
341 lesser mass loss. It could be concluded the specimens consisted of 15% of PET particles had better
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342 resistance to sulfuric acid in two types of concrete and the least mass loss in LWPC15 occurred.
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343 - The LWPC specimens had less mass change compared to the NPC specimens, which shows more
344 resistance of LWPC specimens to sulfuric acid attack than the NPC specimens. Both NPC and LWPC
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345 also showed lower mass change than the NC specimens. This matter mentions positive effects of adding
346 PET particles in concrete against acid erosion, especially in the case of LWPC.
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347 - Regarding the crushing load test, the crushing load changes were decreased by substituting more PET
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348 particles in both NPC and LWPC. Additionally, samples included higher percentage of PET particles,
349 more retain their load-bearing capacity against sulfuric acid attack. This retention was more for LWPC
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351 - The crushing load of LWPC specimens was obviously lower than NPC specimens in all percentages of
352 PET substitution. Moreover, not only LWPC specimens did erode less than NPC specimens, but also their
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353 crushing load reduction rate was lower than the NPC specimens. Furthermore, the LWC specimens
355 - Regarding ultrasonic wave velocity test, the loss of ultrasonic wave velocity of specimens containing
356 more percentages of PET particles decreased. It might be due to the higher capacity of concrete
357 containing PET particles to resist the internal pressure caused by expansion of cement paste and retain
358 more integrity during the reaction to sulfuric acid, which could be related to its more porosity as
359 accommodation for reaction products and the flexibility of PET particles. This reduction was the lowest
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361 - From the initial days of immersion, the LWPC specimens indicated lower values of ultrasonic wave
362 velocity loss compared to the NPC specimens, and this value were the lowest for LWPC15. In addition,
363 the LWC specimens had lower ultrasonic wave velocity reduction than both NC and NPC.
364 - In the case of crushing load and mass measuring variations results, the coefficient of equation in the
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365 relation between mass and crushing load variations increased by substituting more PET particles in both
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366 LWPC and NPC specimens. Increas in the coefficient of the equation shows the changes in mass is lower
367 than crushing load. Although LWC and LWPC5 had lower coefficient than NC and NPC5, this
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368 coefficient was higher for LWPC10 and LWPC15. In this study, specimens consisted of 15% of PET
369 particles had the highest equation coefficient for both LWPC and NPC. LWPC15 had the highest
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370 coefficient compared to all specimens, which shows the specimens containing higher percentage of PET
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371 particles have higher durability against erosion, especially in the case of LWPC.
372 - Clearly, substituting PET particles for fine aggregate into the concrete contributes to higher durability
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373 against sulfuric acid attack. Although substituting PET for fine aggregate leads to a decrease in some
374 mechanical properties, it can be utilised for encapsulating waste materials and producing ecologically safe
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375 concrete. The outcomes of the present work illustrate quite encouraging results and open a new approach
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376 to recycle PET wastes in concrete leading to produce a high-quality concrete for using in certain civil
377 engineering applications. Nonetheless, future studies such as evaluation of acid resistance of concrete
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378 containing waste PET along with other waste plastics, feasibility study of resistant concrete containing
379 PET and pozzolanic materials against acid attack, and investigating the resistance of other types of
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380 concrete such as self-compacting concrete against sulfuric acid attack, should clarify which treatments
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381 can optimise concrete performance with the lowest environmental impact.
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391 References
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392 ACI Committee 211, 1991. ACI 211.1-91: Standard Practice for Selecting Proportions for Normal,
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393 Heavyweight, and Mass Concrete (Reapproved 2009).
395 Akçaözoğlu, S., Atiş, C.D., Akçaözoğlu, K., 2010. An investigation on the use of shredded waste PET
397 doi:10.1016/j.wasman.2009.09.033
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398 Alani, A.M., Faramarzi, A., 2014. An evolutionary approach to modelling concrete degradation due to
399 sulphuric acid attack. Appl. Soft Comput. J. 24, 985–993. doi:10.1016/j.asoc.2014.08.044
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400 Albano, C., Camacho, N., Hernández, M., Matheus, A., Gutiérrez, A., 2009. Influence of content and
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Tables Caption.
Table 2. The characteristics of the fine (sand) and course (gravel) aggregates.
Table 3. Sieve analysis for aggregates. (a) Sand, (b) Gravel, (c) LECA, (d) PET particles
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Table 4. Concrete mixture proportion.
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Tables.
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Grinded PET particles with a maximum size of 7mm,
Replaced Natural aggregate with PET
Araghi et al., 2015 estimated unit weight was 464 kg/m3 and specific gravity of
particles by 5%, 10%, and 15%.
PET particles was 1.11 g/ cm3
3 distinct types of plastic particles used shredded fine flaky 5%, 10% and 15% replaced natural
Saikia and Brito,
plastic particles (PF), Shredded coarse flaky plastic particles aggregate with each type (PF, PF, PC)
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2014
(PC), heat treated pellet-shaped spherical/cylindrical (PP) of plastic particles
Rahmani et al., Replaced sand with PET particles by
Grinded PET particles with a maximum size of 7mm
2013 5%, 10% and 15%
Used as plastic fibers in concrete.
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Bhogayata et al., Metalized polythene waste bags with an average size of 1
Added 0.5, 1.0, or 1.5 % of the volume
2013 mm x 2 mm.
of concrete
Replaced the fine aggregates in the
Ramadevi and
PET bottles used as fiber concrete with 1, 2, 4, and 6% of the
Manju, 2013
PET bottle fibers
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Addition of polyethylene fibers at
Non-recyclable plastic waste used as a macro fiber of 60
Bhogayata et al., different proportions (from 0.3%, 0.6%,
mm × 3 mm and shredded fiber (size considered as very
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2012 and 0.9% to 1.2% of the volume of
fine random palettes)
concrete)
Added fiber from 0 to 6% in the
Malagavei, 2011 HDPE used as fiber
concrete mix
Addition of fiber with the 0.5% volume
Prahallada and
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Plastic fiber obtained from cutting waste plastic pots fraction based on distinct aspect ratios
parkash, 2013
of 30, 50, 70, 90, and 110
Suganthy et al., Sand replaced with 25, 50, 75, or 100%
Pulverized plastic used in the form of granules of 1 mm size
2013 of plastic granules
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PET aggregates
Saikia and Brito, Replaced natural aggregates with the
Recycled PET aggregates
2013 plastic aggregate at 5, 10, and 15%
Replacement of 0, 5, 10, 15 percent
Rai et al., 2012 Plastic flakes as a fine aggregate
sand
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Table 2. The characteristics of the fine (sand) and course (gravel) aggregates.
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Specific gravity (g/cm3) 2.51 2.75
Unit weight (kg/m3) 1,581.3 1,728.9
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Moisture content (%) 0.2 0.4
Moisture of saturated surface dry (%) 0.5 0.7
Fines modulus (FM) - 2.82
Sand equivalent value (SE) (%) - 80
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a)
Percentage passing
Sieve size (mm) ASTM limits (%)
throw the sieve (%)
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4.75 100 100
2.63 81.98 80-100
1.18 63.66 50-85
0.60 45.15 25-60
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0.30 23.31 9-30
0.15 4.12 2-10
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Percentage passing
Sieve size (mm) ASTM limits (%)
throw the sieve (%)
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12.5 63.92 45-70
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4.75 0.55 0-9
2.36 0.27 0-5
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Percentage passing
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4.75 12.5
2.36 67.5
1.18 15
0.600 2.5
0.300 1.5
0.150 1
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Component 0 % PET %5 PET %10 PET %15 PET
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Cement 379.63 427.1 379.63 427.1 379.63 427.1 379.63 427.1
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Gravel 976.05 342 976.05 342 976.05 342 976.05 342
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LECA - 203 - 203 - 203 - 203
- Figure 3 Deterioration ratio of crushing load: a) LWC and LWPC, b) NC and NPC.
- Figure 4 Relative changes of crushing loads after immersion in 5% sulfuric acid solution: a) LWC
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- Figure 5 Ultrasonic wave velocity of specimens versus immersion time in 5% sulfuric acid
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solution: a) LWC and LWPC, b) NC and NPC.
- Figure 6 Mass of specimens attacked by 5% sulfuric acid solution: a) LWC and LWPC, b) NC
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and NPC.
- Figure 7 Mass changes of specimens attacked by 5% sulfuric acid solution: a) LWC and LWPC,
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b) NC and NPC.
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- Figure 8 Relation between mass loss and 28-day crushing load: OBP, overall better performance;
- Figure 9 Relations between mass loss of concrete specimens and loss of their crushing load
during 60 days of immersion in 5% sulfuric acid solution: a) NC and LWC, b) NPC5 and
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- Figure 10 Comparative relation between crushing load changes versus acid immersion time.
- Figure 11 Comparative relation between ultrasonic wave velocity changes versus acid immersion
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- Figure 12 Comparative relation between mass changes of specimens versus acid immersion time.
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Figure 3 Deterioration ratio of crushing load: a) LWC and LWPC, b) NC and NPC.
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Figure 4 Relative changes of crushing loads after immersion in 5% sulfuric acid solution: a) LWC and
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Figure 5 Ultrasonic wave velocity of specimens versus immersion time in 5% sulfuric acid solution: a)
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Figure 6 Mass of specimens attacked by 5% sulfuric acid solution: a) LWC and LWPC, b) NC and NPC.
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Figure 7 Mass changes of specimens attacked by 5% sulfuric acid solution: a) LWC and LWPC, b) NC
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Figure 8 Relation between mass loss and 28-day crushing load: OBP, overall better performance; OWP,
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Figure 9 Relations between mass loss of concrete specimens and loss of their crushing load during 60
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LWPC10, c) NPC15 and LWPC15.
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Figure 10 Comparative relation between crushing load changes versus acid immersion time.
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Figure 11 Comparative relation between ultrasonic wave velocity changes versus acid immersion time.
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Figure 12 Comparative relation between mass changes of specimens versus acid immersion time.
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