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Article history: The purpose of this work is to evaluate the effects of size and shape of recycled polyethylene terephthal-
Received 23 June 2012 ate (PET) aggregate on the fresh and hardened properties, including abrasion resistance, of concrete. 5%,
Received in revised form 11 November 2013 10% and 15% in volume of natural aggregate in the concrete mixes were replaced by an equal volume of
Accepted 12 November 2013
three differently shaped and sized PET-aggregates. The results indicate that the slump of fresh concrete
Available online 5 December 2013
increases slightly with the incorporation of pellet-shaped PET-aggregate. Flakier plastic aggregate sharply
decreases the slump of the fresh concrete and it further decreases if the content and size of this type of
Keywords:
PET-aggregate increase. The compressive strength, tensile splitting strength, modulus of elasticity and
PET bottle waste
Recycling
flexural strength of concrete deteriorate due to the incorporation of PET-aggregate and the deterioration
Concrete of these properties intensifies with increasing content of this aggregate. Differences in size, shape and
Aggregate texture of PET-aggregates change the water to cement ratio as well as the slump of fresh concrete mixes,
Mechanical properties which ultimately change the mechanical behaviour. Flaky PET-aggregates bridge the two separated con-
Abrasion resistance crete pieces and therefore prevent concrete from breaking apart after failure. The abrasion resistance of
concrete mixes containing various types of PET-aggregate is better than that of the reference concrete.
The abrasion resistance of concrete with incorporation of various types and contents of PET-aggregates
can be related to its compressive strength.
Ó 2013 Elsevier Ltd. All rights reserved.
0950-0618/$ - see front matter Ó 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.conbuildmat.2013.11.049
N. Saikia, J. de Brito / Construction and Building Materials 52 (2014) 236–244 237
calorific value of plastic waste can be used for incineration or other Sieve size (mm) Cumulative amount passed (%)
high temperature processes, but its combustion produces danger- PC PF PP
ous gases that could be harmful to human health. Although some
16.0 100.00 100.00 100.00
alternatives, apart from landfilling, are feasible, recycling waste 11.2 99.96 100.00 100.00
plastic to produce new materials such as concrete seems to be 8.0 97.69 100.00 100.00
one of the best ways to dispose of waste plastics, because of its eco- 5.6 49.24 100.00 100.00
nomic and ecological advantages. 4.0 20.59 99.99 99.46
2.0 0.89 45.65 7.93
Plastic waste has to be mechanically separated and processed in
1.0 0.02 0.94 0.04
order to produce plastic-based aggregate. A life cycle analysis of 0.5 0.00 0.01 0.02
mixed household plastics shows that mechanical recycling pro- 0.25 0.00 0.00 0.00
vides a higher net positive environmental impact than the recovery 0.125 0.00 0.00 0.00
of energy or land-filling [3–5]. There is significant potential for the 0.063 0.00 0.00 0.00
Residue 0.00 0.00 0.00
use of plastic waste as aggregate in concrete preparation. The incor-
poration of plastics in concrete can significantly improve some
properties of concrete as plastic has high toughness, good abrasion reference concrete containing normal density NA only, and they
behaviour, low thermal conductivity and high heat capacity [6–8]. further decrease with increasing PA content in concrete [26,27].
Different types of plastic waste such as polyethylene tere- However, it has been claimed that the incorporation of shredded
phthalate (PET) bottles [9–16], polyvinyl chloride (PVC) pipes PET-aggregate up to a certain level does not influence the compres-
[17], high density polyethylene (HDPE) [18], thermosetting plastics sive and flexural strengths of cement mortar [14]. The properties of
[19], mixed plastic waste [20,21], expanded polystyrene foam concrete containing PA as lightweight aggregate are similar or even
(EPS) [22], polyurethane foam [23,24], polycarbonate [12], and better than those of concrete containing some other commonly
glass reinforced plastic (GRP) [25] have all been used as aggregate, used natural lightweight aggregates [27]. The decrease in bond
filler or fibre in the preparation of cement mortar/concrete after strength between PA and cement paste and the inhibition of ce-
mechanical treatment. ment hydration due to the hydrophobic nature of plastic are the
There are two schools of thought on the workability behaviour reasons indicated in several studies for the poor mechanical prop-
of concrete containing plastic aggregate (PA) [26]): (1) the incorpo- erties of concrete containing plastic [26,27]. Curing conditions also
ration of PA decreases the slump of fresh concrete because of its have an effect on the mechanical and durability properties of con-
sharp edges and angular particle shape; (2) concrete mixes con- crete with plastic [15,16]. Coating plastics with slag and sand pow-
taining PA have more free water as PA neither absorbs water nor ders and treating plastic chemically can improve the mechanical
adds any to the concrete mix and this increases slump. PA is signif- performance of concrete by improving the interaction between ce-
icantly lighter than natural aggregate (NA) and therefore the incor- ment paste and PA [18,28,29]. The use of granulated blast furnace
poration of PA decreases the fresh and dry densities of the resulting slag (GBFS) or fly ash as mineral admixtures can also improve the
concrete [26]. This property can be useful in the development of mechanical behaviour of concrete [10,19].
light-weight concrete or other cement composites. Concrete containing PA can stop or divert the propagation of
The strength properties and modulus of elasticity of concrete microcracks and improve concrete toughness, which is of great
containing various types of PA are always lower than those of a practical significance [12,21]. The incorporation of plastic pieces
Fig. 1. PET-aggregate types used in this work: (A) PC; (B) PF; (C) PP.
238 N. Saikia, J. de Brito / Construction and Building Materials 52 (2014) 236–244
Table 2 100
Experimental methods used to determine various aggregate properties.
90
Properties Standard used 80
Table 3
Properties of various types of aggregate.
Property Results
Coarse NA Fine NA PC PF PP
Apparent density (kg/m3) 2670 2612 1340 1340 1360
Dry density (kg/m3) 2627 2602 1330 1320 1360
SSD basis (kg/m3) 2606 2643 1350 1350 1360
Water absorption (% dry basis, 24 h) 0.63 0.20 0.18 0.25 0.10
Bulk density (kg/m3) 1418 1441 351 555 827
Shape index (%) 11.5 – – – –
Weight loss (%) in Los-Angeles abrasion test 27.2 – nd – –
Table 4
Concrete mixes composition.
Concrete mixes Cement (kg/m3) Water (kg/m3) Natural aggregate (kg/m3) Plastic aggregate (kg/m3)
Coarse Fine PC PF PP
Ref 350 185.5 996.4 802.7 – – –
PC5 350 213.5 920.4 788.4 45.9 – –
PC10 350 227.5 844.5 774.1 91.7 – –
PC15 350 259.0 768.5 759.8 137.5 – –
PF5 350 199.5 996.4 713.3 – 45.9 –
PF10 350 210.0 996.4 624.0 – 91.7 –
PF15 350 224 996.4 534.6 – 137.5 –
PP5 350 185.5 996.4 713.3 – – 45.9
PP10 350 182 996.4 624.0 – – 91.7
PP15 350 182 996.4 534.6 – – 137.5
The abrasion resistance was determined according to the DIN 52108 standard
Table 5 method using a Bohme apparatus. For this, 100 100 100 mm3 cubic specimens
Experimental methods used to determine various fresh were initially cast by the normal procedure adopted in this study. After an initial
and hardened concrete properties. 56 days of curing in a wet chamber, 71 71 50 mm3 test specimens were pre-
pared by sawing the cubic specimens. The samples were returned to the wet cham-
Targeted properties Method
ber for 91 days; then they were dried in a ventilated oven at 110 ± 5 °C until
Fresh concrete constant mass. Before determining the abrasion behaviour, the thickness of the
Slump test NP EN 12350-2 specimens was measured at nine locations. The weight of the specimens was also
Density NP EN 12350-6 measured using a digital scale. Then a given quantity of abrasive powder was evenly
Hardened concrete spread on the clean grinding path of the disc of the abrasion-testing device. Each
Compressive strength NP EN 12390-3 specimen was then fixed to a holding device under a calibrated weight; after 4 cy-
Splitting tensile strength NP EN 12390-6 cles of a pre-determined number of rotations, the dimensions of the specimen were
Flexural strength NP EN 12390-5 measured at nine locations, as was its weight. The results presented here are the
Modulus of elasticity LNEC E397 average of three specimens.
Abrasion resistance DIN 52108
Table 6
Fresh concrete properties.
Properties Ref PC PF PP
5 10 15 5 10 15 5 10 15
W/C (%) 0.53 0.61 0.65 0.74 0.57 0.60 0.64 0.53 0.52 0.52
Slump (mm) 127 120 120 – 122 122 120 122 122 132
Density (kg/m3) 2387 2326 2277 2233 2336 2290 2243 2347 2297 2254
240 N. Saikia, J. de Brito / Construction and Building Materials 52 (2014) 236–244
are segregated, possibly due to the higher W/C ratio. For PC, an-
30
other explanation may be its flaky nature. Remarkably, fresh con-
25 crete mixes containing PC at all substitution levels and the one
20 with 15% PF reach a stage where they look like the reference con-
crete mix with the required slump range. Even though they exhibit
15
a very low slump value. The density of fresh concrete declines as
PC
10 the content of PET-aggregate increases. This trend is self-explana-
PF
5 tory since there is a clear gap between the density of natural aggre-
PP 7-day gate and that of PET-aggregate (Table 6).
0
0 5 10 15
Amount of NA substituted by plastic aggregate (%) 3.2. Hardened concrete properties
crete with 5%, 10% and 15% PC they are respectively 73%, 52%
40 and 35%.
The higher strength of concrete containing PP is attributed to its
30 water to cement (W/C) ratio, which is lower than that of concrete
with the other two types of PET-aggregate. Despite the higher W/C
20
of concrete with 5% PF than that of concrete with 5% PP, the com-
pressive strength of the first is almost the same as that of the sec-
PC
ond. This is due to the differences in the shape of these two types of
10 PF
PET-aggregate. The surfaces of PF are rough whereas those of PP
PP 91-day
are very smooth. Binding between PF and cement paste is therefore
0
0 5 10 15 better than binding between PP and cement paste. Another possi-
Amount of NA substituted by plastic aggregate (%) ble factor is the different particle size distribution of these two
types of PET-aggregate. The particle size distribution of PF almost
Fig. 3. Compressive strength of concrete versus incorporation of PET-aggregate to matches that of natural fine aggregate, while almost all the parti-
replace NA at different ages. cles of PP fall within a narrow size range, i.e. they are almost iden-
tical in size. So replacing NA with PP changes the grading curve,
4 which possibly hinders any potential improvement of the com-
Splitting tensile strength (MPa)
Fig. 5. Concrete specimens containing PP after failure in the tensile splitting strength test.
Fig. 8. Cracked concrete specimens after the flexural strength test: (A) reference; (B) PC.
6
Ref 10%
5% 15%
0
PP PF PC
(A) Depth of wear
50
Ref 10%
40 5% 15%
Weight loss (g)
30
20
10
0
PP PF PC
Fig. 9. Cracking in a concrete beam containing PC after flexural failure.
(B) Weight loss
bridge effect of PP fibres on cracks and a diversion effect of PP Fig. 10. Depth of wear and weight loss of concrete with various percentages of
replacement of NA with PET-aggregate after the abrasion resistance test.
fibres on separated paste blocks [34]. The larger the content of
PP fibres, the stronger the effects. In addition, friction work is con-
sumed when PP fibres are pulled out from concrete [34]. Concrete plastic, particularly PC, can improve the relative flexural strength
with high compressive strength normally has high abrasion resis- of concrete as it can arrest, bypass and bridge the cracks produced
tance [37–40]. A small improvement in concrete’s abrasion resis- by mechanical means. As these properties are also responsible for
tance is observed if its compressive strength exceeds a critical the improvement of abrasion resistance [34], the abrasion resis-
value, around 40 MPa [41]. Compression testing measures the bulk tance of concrete containing PET-aggregate also improves. The
strength of concrete, while an abrasion test measures the quality of increasing content of PET-aggregate (PP at all substitution levels
the surface. As aggregate has a marked effect on the surface prop- and for PC and PF up to the 10% level) further improves the abra-
erties of concrete, the quality and type of aggregate have a signif- sion resistance because the improvement caused by its addition
icant effect on the abrasion resistance. The paste/aggregate bond is more pronounced than the loss due to the compressive strength
and aggregate hardness also affect abrasion resistance [41]. evolution.
In this case the improvement of abrasion resistance observed The highest abrasion resistance is observed for concrete with
because of the incorporation of PET-aggregate is probably attribut- 15% PP. Concrete containing PP at this substitution level is proba-
able to the characteristics of PET-aggregate. Plastic has high tough- bly very resistant, thanks to the specific properties of PP such as
ness and good abrasion behaviour [6]. The results also show that better toughness and abrasion behaviour than NA and to the
N. Saikia, J. de Brito / Construction and Building Materials 52 (2014) 236–244 243
1. The nearly spherical and smooth-surface textured PET- The authors are grateful to Leonel Silva, Diogo Serpa, Pedro
aggregate (PP) lowers the W/C ratio and this increases the Pereira, Luís Evangelista and Fernando Rodrigues for their assis-
slump value of the concrete mix. The angular and non-uni- tance with the experimental work. The financial assistance of the
form PET-aggregates (fine PF and coarse PC) with sharper ICIST Research Institute, IST, Technical University of Lisbon and
edges increase the water requirement of concrete and con- of the FCT (Foundation for Science and Technology), Portugal, is
versely lower the slump value of concrete mixes. The parti- also gratefully acknowledged.
cle size distribution of these PET-aggregates further
increases the water requirement of concrete mixes.
2. There is a reduction in the density of fresh concrete as the References
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