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1. Introduction
Process and plant technology, which can be classified as a part of thermo-process technologies, spans a wide arch
covering the different materials with temperatures from low to very high temperatures. Figure 1 shows by trend the
energy consumption and process temperatures for the most important fields of the extractive industry and the basic
primary industry. The maxima are in the temperature range of up to 400 °C and from 900 °C to 1500 °C. The
industry sectors chemistry, textile, and sugar are to be found in the lower temperature range. Typically, the energy
intensive branches, such as non-ferrous metals, iron and steel, glass, refractories and ceramics, are to be found in the
temperature range T 600 °C. All these industry sectors need the exact adjustment of the necessary process
parameters (e. g. temperature, time and atmosphere) for the thermal treatment of the materials in order to achieve a
production of goods with high quality properties.
Fig. 1. Energy consumption and process temperatures for industrial sectors, acc. to [1].
For the generalized term Thermo-process Technology, the definition can be: „Process- and plant-technology for
the thermo-chemical and the thermo-physical treatment of materials in such a way, that the perfect product quality
will be reached by the targeted adjustment and control of loads temperature and the process atmosphere under
economical boundary conditions” [2].
The main topics at present of the “Industrial Furnace” community are shown in Figure 2 and separated in
• Technology,
• Environment and
• Society.
With the previous definition of the generalized term Thermo-process Technology one present topic is the
processing of new materials and the competition between different materials for the same application (e. g.
automotive industry). The example is dealing with high strength steels vs. high strength aluminum alloys as well as
carbon fibers, Figure 3. For automotive applications this competition is driven by the philosophy of light weight
construction as a challenge between modern high strength steels, the press hardening technology and high strength
aluminum flat products from the 6xxx group, which are driven in US by the Ford light weight concept and the
decision of Ford to use this Al group for the F 150 model. On the other hand BMW starts with the application of
carbon fibers in the purely electricity driven I3 model and the hybrid I8 model. These trends are highly connected
with improved and new furnace technologies concerning heating (higher temperatures, process window for press
hardening steels) and cooling (faster controlled cooling with higher specifications related to microstructure and
flatness of strips and save operation for wide, thin strips) and completely different furnaces for the production of
carbon fibers.
Fig. 3. Light weight construction - materials design: new high strength steels, Al-alloys and C-fiber-composites.
2.1 Steel
2.1.1 High strength steels
The portfolio of high strength steels with the characteristic data concerning elongation and tensile strength is
shown in Figure 4. Soft steel grades are annealed after cold rolling in bell-type furnaces with a 100 % H2-
atmosphere [3]. The heat treatment processing of high strength austenitic manganese steels is characterized by the
embrittling intergranular carbides in manganese steels formed during slow cooling or reheating through the 400 to
800 °C range. They are removed by solution annealing above 1000 °C followed by rapid quenching. The kinetics of
carbide formation follows the typical C-curve of an isothermal transformation diagram, with the fastest growth
(carbide nose) occurring at 600 to 650 °C [4].
How are 3rd Gen AHSS (Advanced High Strength Steels) produced? The process of making HF1050 steel grade
involves a number of steps. In a nutshell [6]:
• Casting of the HF steel (slab)
• Hot rolling and cold rolling to fine tune its properties (coil)
• Continuously annealing in a process that provides the precise control needed to obtain the final
microstructure of the grade
• Optional: electro-galvanization
• Optional: additional treatment to remove hydrogen and eliminate brittleness before delivery to the customer
The production of the new high strength steel grades requires modern continuous casting technologies, strong
tandem rolling mills for cold rolling and annealing lines which allows very high heating temperatures and ultra-fast
controlled cooling. For existing continuous annealing lines a revamping of the existing cooling sections, Figure 5, is
Herbert Pfeifer / Energy Procedia 120 (2017) 28–40 31
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necessary considering the hard conditions concerning the height and homogeneity of the heat transfer coefficient of
nozzle fields, the interaction of flow and strip and at least the flatness and quality of the strip.
The requirement of fast resp. ultra-fast cooling ( T 100 K/s) in continuous annealing lines for the processing of
steel strips needs further research activities in cooling technologies based on gas, water or mist (water/gas) cooling.
The comparison of different cooling technologies is shown in Figure 6. Raick [8] noted a specific cooling rate of 80
K/(s.mm) for N2-rich gas and 100 K/(s.mm) for H2-rich cooling gas. Actually values of 150 K/(s.mm) are
communicated for the cooling with N2-rich gases [7] for steels up to 980 MPa (TRIP and DP) with the advantage of
saving alloying and operational costs. With ultra-fast water cooling systems more than 1000 K/(s.mm) is possible for
UHSS up to 1500 MPa (MS).
32 Herbert Pfeifer / Energy Procedia 120 (2017) 28–40
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For H2-based systems 200 K/(s.mm) [9] are published. The high heat transfer coefficient and the homogeneity of
the heat transfer coefficient must be considered and additionally the tendency of fast shrinking of the strip, which is
a source to produce strip buckles, the vibration of the strip from the fluid structure interaction of fluid flow and strip
and at least the surface scratches from the contact of the strip with the nozzle system, which in the worst case results
in a strip fracture. The advanced potential of hydrogen with the low density and the high thermal conductivity
compared to nitrogen has the potential of a cooling gradient T 200 K/(mm.s) but needs all safety requirements of
a combustible fluid. The published results are [9]:
• Up to 200 K/(mm.s) cooling rate in the quench
• Homogenous cooling over the width of the strip
• Good flatness
• Controllable quenche (for steel grades UHSS/AHSS; AHSS of the next generation)
• 580 up to 1700 MPa tensile strength
The H2-technology is a proved technology in the field of ferritic and austenitic stainless steel strips with a bright
annealed surface finish (surface type 2B, 2R) in vertical annealing lines (BAL: Bright Annealing Line) with a muffle
separating the oxygen containing combustion atmosphere from the very pure hydrogen atmosphere with dew point
in the range of -70 °C.
A first vertical continuous annealing plant with hydrogen technology for carbon steels is installed at HyCal Corp.
(USA) for steel grades up to 100 % martensitic (MS steel grades), dual phase, TRIP and complex phase steels [10].
The highest temperature in the furnace is 980 °C, which is approx. 100 K higher than in conventional continuous
annealing lines, realized with 155 single ended radiant tubes. Various controlled cooling rates can be realized with
the H2-quench with quality issues as clean strip and good flatness.
Fig. 6. Arrangement of operating rapid cooling systems and their most important characteristics [8].
For the increase of the fundamental knowledge some test stands are installed at the Department of Industrial
Furnaces at RWTH Aachen University for the investigation of the local heat transfer (HT) of real nozzle systems,
Figure 7a/b, the fluid structure interaction of gas flow from nozzle systems with the strip for horizontal and vertical
installations, Figure 7c, and also in a separate unit for H2-cooling. On one hand side the results of this experiments
are used in the design period for the layout of the plant and in the operating period for the optimization of the
cooling sections, for example of changing demands during the life cycle of an annealing line concerning new steel
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grades, decreasing strip thickness and increasing strip width and at least increasing of productivity (higher line
speeds). On the other hand side the results are used for the verification of numerical simulation concerning the local
heat transfer coefficient, fluid flow pattern between nozzle system and strip (FSI: Fluid Structure Interaction),
Figure 7d, strip deformation resulting from thermal and mechanical stress, strip vibration and transient deformation
with different process parameters as specific strip tension, strip width and thickness, type of nozzle system and flow
parameters.
The development of new materials with improved technologies and the relevant process and plant technology,
either for steel, aluminum or carbon fibers has the risk of technology innovations and management decisions
concerning the different realization of light-weight philosophies as shown in Figure 3. Two examples are the
development of the press hardening technology from steels with a cheap alloying concept and the announcement of
Ford to use 6xxx Aluminum grades for the light-weight construction of the Ford F150.
Fig. 7. Test stands for heat transfer of complex nozzle systems and fluid strip interaction with exemplary results at RWTH Aachen University.
2.2 Aluminum
The announcement of Ford to use 6xxx high strength Aluminum grades for the light-weight construction of the
Ford F150, Figure 8. The Al 6xxx series contain 0.5 to 1 % silicon and 0.4 to 1 % magnesium approximately in the
proportions required for formulation of magnesium silicide (Mg2Si). Although not as strong as most 2xxx and 7xxx
alloys, 6xxx alloys have good formability, weldability, machinability, and corrosion resistance, with medium
strength. The demand for the Ford F150 is announced of > 275,000,000 kg/yr, [11]. This results in an increasing of
the rolling and heat treatment capacities of the global players in Aluminum production. The investment was in the
range of 3 to 4 billion € in USA and Europe in the last years.
Heat treatment to increase strength of aluminum alloys is a three-step process:
Solution heat treatment: dissolution of soluble phases
Quenching: development of supersaturation
Age hardening: precipitation of solute atoms either at room temperature (natural aging) or elevated
temperature (artificial aging or precipitation heat treatment).
Industrial requirements for the cooling technology of continuous annealing lines for Al 6xxx alloys for strips are
Water-quench (controllable): Cooling rates T 25 to 100 K/s
Temperature range: T = 480 to 250 °C
Strip thickness: 0.5 to 5 mm
Homogeneous cooling over strip width and length
Flatness
Process parameters / model based
The technical challenges are also focused on intensive, homogeneous cooling strategies for flexible continuous
heat treatment lines, e. g. water quenches. The complex relations between cooling, thermal stress in the strip and
deformation (flatness) after the quench can be investigated by using experimental and numerical simulations,
Figure 9. The presented cooling rate is in the range of 60 K/s, Figure 9a.
With the resulting temperature distribution the Mises stress and the related strip deformation was calculated and
verified with measured data from quench experiments.
The investigation of the basic heat transfer principles of the water quench [13] and the interaction of gaseous
fluid and strip [14] are covered by different research and development projects of the German Federal Ministry of
Economic Affairs and Energy and research institutes in a pre-competitive manner considering the problems of the
industry by involving the stakeholders in so called “project work meetings”.
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Fig. 9. Combined experimental (cooling rate a) and strip deformation d)) and numerical investigation of a water quench.
Fig. 10. Carbon fiber thermal production line with oxidation/stabilization and high temperature carbonization furnaces, acc. to [16, 17].
The annual production capacities of small- and large-tow carbon fibers was approx. 110 000 t/yr in 2014 [17].
This capacity is small compared to the production of steel and aluminum for automotive applications. The
apportionment of the capacity is 20 % to air plane applications, 15 % customers and 65 % for industry. For
automotive applications the large-tow carbon fibers (lower costs, higher productivity and medium mechanical
properties) are preferred.
A final resume for the application of steel, aluminum and CFRP for automotive parts indicates a potential
compared to standard steel grades of 5 to 15 % of high strength steels, 40 to 50 % of aluminum and 55 to 75 % for
CFRP, Figure 11. On the other hand the specific costs of parts are higher. Finally the advantages are in the lower
specific CO2-emissions over the life cycle of the car.
Fig. 11. Comparison of specific weight and cost per part for an automotive structure element [18].
3 Environment
The CO2-emissions reduction target of 40 % of Germany from 1990 to 2020 seems to be failed from the
viewpoint of the actual situation. Furthermore the target for 2050 (-80 to -95 %) is extremely ambitious. For the
steelmaking technology the philosophy of the “Energiewende Philosophy” is described in the study
“Treibhausgasneutrales Deutschland im Jahr 2050” [19] as:
“For the use of renewable energies and renewable electricity it’s necessary to change in many branches of the
industry the processes fundamentally and to use suitable plant technologies. For examples the authors of the study
acts on the assumption that the Blast Furnace - Basic Oxygen process route for the primary steelmaking not further
Herbert Pfeifer / Energy Procedia 120 (2017) 28–40 37
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exists in the future. For it the electric arc furnace based on steel scrap and direct reduced iron (DRI) will be massive
strengthen. As energy source for the direct reduction of ore only renewable methane will be used and the reheating
furnaces for the hot rolling mills will be heated exclusively with renewable electricity.”
This philosophy is driven by the idea of electrification of industry with renewable electricity. Generally the
economic decision weather fuel or electrical heating of midsize and large industrial furnaces depends from the local
situation of energy prices and the available technical solutions.
The idea of 100 % furnaces heated with renewable electricity for the hot rolling mills of steel plant, which are
classified in hot rolling mills for flat and long products, will be checked by a technical comparison of both
principles. The yearly production of rolled steel was 43 Mio. t in 2000 and 40.4 Mio. t in 2015 in Germany. The
semi-final products after hot rolling are hot rolled strip and long products as wire and steel rods. The products from
the continuous casting process (slabs, billets and blooms) are reheated in walking beam furnaces, pusher type
furnaces and rotary hearth furnaces on the hot rolling temperature which is in the range of 1060 to 1260 °C [20]. For
the production of long products for civil engineering (e. g. rolled wire) and high quality automotive and construction
steels (e. g. steel grades for further heat treatment - hardening, nitriding, roller ball steels) usually pusher or walking
beam furnaces are used to supply the hot rolling mills. The productivity is linked with that of the rolling mill, which
means, that the furnace is usually not operating with the nominal productivity (lower efficiency compared to
nominal productivity). Figure 12 shows an exemplary Sankey diagram of the specific energies for a pusher type
furnace of a hot strip rolling mill. The specific energy consumption is approx. 1.25 GJ/t from coke oven and natural
gas. The utilization ratio of energy (averaged thermal efficiency) is 65 % and represents the state of the art. Also the
noted air preheating temperature is a typical value for air preheating with central recuperators. The use of the off-gas
enthalpy for the steam production depends from the consumers of steam and the available infrastructure. The cost
effectiveness for using the excess off-gas for steam production (supporting the available steam system, heating of
pickling lines etc.) or the generation of electricity by steam turbines or ORC-systems is not given in any cases yet.
The wall and cooling water losses in the exemplary case are approx. 13 %.
The principle question is, if a technical solution of an electric heated furnace for this application is possible. If
generally fuel based and electric solutions for the same task are available, which is not the case for this type of
furnace and application, the decision for the technology depends from the local relation of costs for fuel to
electricity. For the feasibility study of a resistance heated reheating furnace for a hot rolling mill a ferritic Fe-Cr-Al
resistance heating material is necessary, because the application temperature is up to 1300 °C and it can also applied
in an oxidizing atmosphere as air. Figure 13 shows that the recommended surface load decreases with increasing
furnace temperature.
38 AuthorHerbert
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Fig. 13. Maximum recommended surface loads for ferritic Fe-Cr-Al resistance heating materials and radiant tubes, acc. to [22].
Typical temperatures for the last zone of reheating furnaces are in the range of 1200 to 1300 °C. The maximum
specific surface load for this temperature range is approx. 3 W/cm² (30 kW/m²). This value is comparable to the
maximum surface load of metallic radiant tubes and half of the value for ceramic radiant tubes.
The approximatively calculation of the electricity used for the electrification of the reheating furnaces in the
German steel plants is 11 TWhel/yr and the comparison with the electricity from wind or photovoltaic (PV) shows,
that 12.5 % of the electricity from the wind or 28.2 % for the PV is necessary for this step in steelmaking industry,
Table 1. Additional electricity is e. g. necessary for the annealing of cold rolled strip (approx. 4.5 TWh el/yr) and
numerous other applications. The total consumption of electricity in the steel industry was 22.4 TWh el in 2014. A
rough estimation results in a doubling up to 45 TWhel/yr based on todays data. This more than actually installed PV
in Germany and half of the wind power.
Table 1. Scenario for the replacement existing fuel based technology with electric heated furnaces.
In a last step it is checked, if the available space is sufficient for the installation of the resistance heaters. The
check is based on the data for a 180 t/h (cold charging) pusher-type furnace for the reheating of billet for a hot
rolling wire mill, Table 2. For the installed thermal power of 78.7 MW (7700 m³ NG/h) an equivalent electric power
of 60 MW is necessary considering a thermal efficiency of th,g 0.65 for the gas heated furnace and an thermal
efficiency of th,el 0.80 for the electrically heated furnace.
The furnace temperature is in the range of 1000 to 1250 °C. Acc. to Figure 13 the permissible surface load of the
resistance heating elements is 60 to 35 kW/m². For the estimated power of P = 60 MW is the necessary area
A = 60,000 kW/47.5 kW/m² 1250 m². For the upper furnace only a roof surface of 290 m² an 80 m² for the side are
Herbert Pfeifer / Energy Procedia 120 (2017) 28–40 39
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available. This simple estimation demonstrates that the available surface in the upper surface (370 m²) is not high
enough compared to the required surface area of approx. 625 m².
Additionally to the problem of space there are another other critical issues:
The resistance heating from the lower side is not possible, since scale is build up in the furnace and a part
of it drops down on the bottom.
The life time of the resistance elements must be checked for long periods with high oxygen in the furnace
atmosphere and especially other components, e. g. from casting powders.
The amount and type of scale resulting from the high O2-content in the furnace atmosphere is relevant for
the yield of the process and for the behavior of scale in the descaling units after the furnace and in front of
the rolling mill.
Energy management of the furnace in a complex, on renewable energies based electrical power supply.
Table 2. Basic data of the pusher-type furnace of BSW (Badische Stahlwerke), Kehl (Germany), acc. to [24].
furnaces are running in limit ranges concerning temperatures for the available technical principles and furnace
design materials for HSS and CFRP and the cooling mechanisms (gas cooling with H 2, water/air mist cooling).
Based on the future environmental targets an electrification of industrial furnaces is under discussion. A first
check for reheating furnaces in the steel industry shows the amount of electric energy used for this task in
comparison with the available energy produced from wind and solar power plants in Germany.
A rough estimation results in a doubling of electricity up to 45 TWh el/yr based on actual data for the German
steel industry. This more than actually installed PV in Germany and half of the wind power.
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Essen, 2012
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