2.4.1 Introduction While sometimes it is appropriate to bake flour mixed with nothing but water, such as when one is hurrying out of Egypt with a pharoah in hot pursuit, baked goods are generally improved by the judicious addition of other ingredients. Whether the base is bran flour or corn flour, transforming the flour into muffins requires throwing in a pinch of this or that. So it is for alloys. Whether the base metal is iron or aluminum, it is rarely used in its pure form. Small amounts (often less than 1%) of other elements, which are sometimes called hardeners, are required to attain more useful properties. One of the properties of critical interest for structural metals is their strength. Unalloyed aluminum has an ultimate tensile strength of about 13 kips/ in.2 (ksi) [90 MPa]. This value can be increased by more than 30 ksi [200 MPa], however, by adding a dash of zinc, then throwing in a pinch or two of copper and magnesium and just a smidgen of chromium. Putting this recipe in the oven and heating it at the prescribed temperature and duration can bring the strength up to more than 80 ksi [550 MPa]. Variations on the ingredients and heating instructions can yield alloys to meet almost any engineering appetite. Aluminum alloys are divided into two categories: wrought alloys, those that are worked to shape, and cast alloys, those that are poured in a molten state into a mold that determines their shape. The Aluminum Association maintains an internationally recognized designation system for each category, described in ANSI H35.1, Alloy and Temper Designation Systems for Aluminum (42). The wrought alloy designation system is discussed in the next section and the cast alloy system in Section 3.1.4. While strength and other properties of both wrought and cast products are dependent on their ingredients, or the selective addition of alloying elements, further variations on these properties can be achieved by tempering. Tempering refers to the alteration of the mechanical properties of a metal by means of either a mechanical or thermal treatment. Temper can be produced in wrought products by the strain-hardening that results from cold working. Thermal treatments may be used to obtain temper in cast products, as well as in those wrought alloys identified as heat-treatable. Conversely, the wrought alloys that can only be strengthened by cold work are designated non-heat-treatable. 2.4.2 Wrought Alloys The Aluminum Association�s designation system for aluminum alloys was introduced in 1954. Under this system, a four-digit number is assigned to each alloy registered with the Association. The first number of the alloy designates the primary alloying element, which produces a group of alloys with similar properties. The Association sequentially assigns the last two digits.