INSTITUT TEKNOLOGI DEL

Jl Sisingamangaraja, Tobasamosir -22381, Sumatera Utara

telp +62632331234, fax +626323311116, www.del.ac.id
TERMODINAMIKA KIMIA
PR 2

 Kerjakan soal-soal berikut pada kertas A4 dengan baik dan benar!

 PR dikerjakan individual dan dikumpulkan paling lambat hari Selasa (22 Maret 2016)
pukul 08.00 melalui ketua kelas.

1. Water at 28C flows in a straight horizontal pipe in which there is no exchange of

either heat or work with surroundings. Its velocity is 14 m/s in a pipe with an
internal diameter of 2.5 cm until it flows into a section where the pipe diameter
abruptly increases. What is the temperature change of the water if the
downstream diameter is 3.8 cm? If it is 7.5?

2. One kilogram of air is heated reversibly at constat pressure from an initial state
of 300 K and 1 bar until its volume triples. Calculate W, Q, U, and H for the
process. Assume for air that ⁄ and

3. An ideal gas initially at 600 K and 10 bar undergoes a four-step mechanically

reversible cycle in a closed system. In step 1-2, pressure decreases isothermally
to 3 bar; in step 2-3, pressure decreases at constant volume to 2 bar; in step 3-4,
volume decreases at constant pressure; and in step 4-1, the gas returns
adiabatically to its initial state. Take ( ⁄ ) and ( ⁄ ) .
a. Sketch the cycle on a PV diagram
b. Determine both T and P for states 1, 2, 3, and 4
c. Calculate W, Q, U, and H for each step of the cycle

4. Calculate Z and V for ethane at 50C and 15 bar by the following equations:
a. Gas ideal equation
b. The truncated virial equation : with the following
experimental values of virial coefficients :

c. The truncated virial equation : , with a value of B from the

generalized Pitzer correlation : ̂
d. The Riedlich/Kwong equation.

5. For steady flow through a heat exchanger at approximately atmospheric

pressure, what is the final temperature,
a. When heat in the amount of 800 kJ is added to 10 mol of ethylene initially at
200 C?
b. When heat in the amount of 2500 kJ is added to 15 mol of 1-butane initially at
260 C?

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 INSTITUT TEKNOLOGI DEL
Jl Sisingamangaraja, Tobasamosir -22381, Sumatera Utara
telp +62632331234, fax +626323311116, www.del.ac.id
TERMODINAMIKA KIMIA
PR 2

6. A fuel consisting of 75 mol-% methane and 25 mol-% ethane enters a furnace

with 80% excess air at 30C. If kJ per kg mole of fuel is transferred as
heat to boiler tubes, at what temperature does the fuel gas leave the furnace?
Assumption complete combustion of the fuel.

-Selamat mengerjakan-

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