Вы находитесь на странице: 1из 1

Resistivity of

Pyrophoric bulk Powder


( Spontaneo (Ω) / Electrical
usly ignite Dust conductivity Dust or
Molecular Melting Boiling Solubility at or below Vapour Flash point Auto Ignition NFPA LD - 50 LC 50 Handling restriction (Air sensitivity, Burning Explosion of liquid Shock liquid MIE
Sr. No Name of Chemical CAS No formula State Point 0C Point 0C in water 54.40C ) Sp. Gravity density (0C) Temp 0C Explosive Limit % TLV - ppm HFR (mg/Kg) (mg/l) Eco Toxicity pH storage stability etc.) Class MIT (O C) Class ( pS/m ) sensitivity (mj) Product of combustion Incompatibility Reactivity

ORAL
(LD50): Toluene forms explosive reaction with
Acute: 636 Acute: (LC50): 313 mg/l 48 1,3-dichloro-5,5-dimethyl-2,4- Incompatible with strong oxidizers, silver perchlorate,
hours [Daphnia
mg/kg 49000 (daphnia)]. 17 mg/l 24 imidazolididione; dinitrogen tetraoxide; sodium difluoride, Tetranitromethane, Uranium
[Rat]. mg/m 4 hours [Fish (Blue Gill)]. concentrated nitric Hexafluoride. Frozen
DERMAL hours 13 mg/l 96 hours [Fish acid, sulfuric acid + nitric acid; N2O4; Bromine Trifluoride reacts violently with Toluene at -80 deg.
(Blue Gill)]. 56 mg/l 24
(LD50): [Rat]. hours [Fish (Fathead AgClO4; BrF3; Uranium hexafluoride; C. Reacts chemically with nitrogen oxides, or halogens to
Acute: 440 ppm minnow)]. 34 mg/l 96 sulfur dichloride. Also forms an form
hours [Fish (Fathead
C6-H5-CH3 14100 24 hours minnow)]. 56.8 ppm explosive mixture Reactive with nitrotoluene, nitrobenzene, and nitrophenol and
1 Toulene 108-88-3 or C7-H8 Liquid -95°C 110.6°C not soluble No 0.8636 3.1 4.4444 480 LOWER: 1.1% UPPER: 7.1% 50 230 mg/kg [Mouse]. any hours NA with tetranitromethane NA NA NA NA NA 0.24 Gasious Carbon Products oxidizing agents halogenated products, respectively.

Freshwater
Algae: EC50 1000
mg/L 72 h
Freshwater Fish :
LD50 Oral : LC50 >961
>3100 mg/L/96h
mg/kg (Rat) (Pimephales
LD50 promelas)
Dermal : Microtox: EC50 >
>2000 >31 10000 mg/L 17 h Strong oxidizing
mg/kg mg/L/4h Water Flea: EC50 Keep away from heat and sources of agents, strong acids,
2 tert-Butanol 75-65-0 C4 H10 O Liquid 25 - 25.5 83 °C 238 ppm No 0.78 2.6 Liquid 490 °C 2.4 - 8.0 100 230 (Rabbit) (Rat) 933 mg/L 48 h 7 ignition. NA NA NA NA NA NA Co, Co2 alkali metals Stable

Derminal >
2,000
mg/kg LC50 (fish) - 94
(rabbit) mg/L 96H
Oral LD50 > > 4.13 EC50 (Aq
122836-35- Light-tan 2,689 mg/l (4 Invertebrate) -
3 SULFENTRAZONE 5 powder 123°C NA 780 mg/L No 1.21 NA NA NA NA 200 ppm 200 mg/kg (rat) h) (rat) 60 mg/L 48H NA NA NA NA NA NA NA NA NA NA NA

Air
Sensitive Sensitive to light.Do not store
above 20°C
Anydrous Sodium Hypochlorite is very
explosive. Primary amines and calcium
hypochlorite or sodium hypochlorite
react
to form normal chloroamines, which
are explosive. Interaction of
ethyleneimine with sodium (or other) Decomposed by carbon dioxide from air. Slowly decomposes
hypochlorite gives on contact with air. Unstable in air unless mixed with sodium
the explosive N-chloro cmpd. Removal hydroxide. Incompatible with ammonium acetate,
of formic acid from industrial waste ammonium carbonate, ammonium nitrate, ammonium
streams with sodium hypochlorite soln oxalate, and
becomes ammonium phosphate. Decompostion of sodium
explosive at 55 deg C. Several hypochlorite takes place within a few seconds with these
explosions involving methanol and salts. Also
sodium hypochlorite were attributed to incompatible with primary amines, phenyl acetonitrile,
formation of methyl ethyleneimine, methanol, acidified benzyl cyanide, formic
hypochlorite, especially in presence of acid,
acid or other esterification catalyst. Use urea, nitro compounds, methylscellulose, celloluse, aziridine,
of sodium hypochlorite soln to destroy ether, ammonia. Mixing this product with chemicals (e.g.
acidified Slightly reactive to ammonia, acids, detergents, etc.) or organic matter (e.g.
benzyl cyanide residues caused a reactive with reducing urine, feces, etc.) will release chlorine gas. Chloramine gas
violent explosion, thought to have agents, combustible may be
Sodium 7681-52-9 Oral (LD50): been due to formation of nitrogen materials, organic evolved when ammonia and bleach are mixed. Decomposed
Hypochlorite, 12% 1310-73-2 Soluble in 1 PPM as 5800 mg/kg trichloride. (Sodium materials, metals, by hot water. Sensitive to light. Exposure to light accelerates
4 (NaOH + water) 7732-18-5 NaClO Liquid -3°C 100°C water No 1.19-1.20 0.62 Nap Nap Nap Cl2 300 [Mouse]. Nap Na 12 hypochlorite) Nap Nap Nap Nap Nap Nap Nap acids. decompositon.

LD50 oral = Harmful to Avoid contact with skin and eyes. Avoid
1500 mg/kg aquatic contact with clothing. Remove and
( Rat ) organisms, may wash
LD50 cause long-term contaminated clothing before re-use.
Dermal > adverse effects Avoid breathing vapors or mists. Do not
Powder Soluble in 2000 mg/kg in the aquatic
Possibly ingest. Wash
5 Sodium isocyanate 917-61-3 C N Na O Solid 550 °C Nap water No 1.9 Nap Nap NA NA NA 200 ( Rat ) NA environment
hazardous short NA thoroughly after handlin NA NA NA NA NA NA NOX compunds Acids
Reactive with NA
oral toxicity term oxidizing agents,
(LD50): degradation metals, acids. Slightly
Salt of Soluble in 1870 mg/kg products are not Mositure reactive reactive to reactive Reacts with water to evolve heat. Incompatible with KCO,
6 Potassium carbonate, 584-08-7 K2CO3 Tartar 891°C Nap water No 2.29 Nap Nap Nap NA NA 201 [Rat]. NA likely NA Don't store above 25 C Nap Nap Nap Nap Nap Nap NA with moisture chlorine trifluoride, calcium oxide, and magnesium.

toxicity
(LD50): 80 carbon oxides (CO, CO2),
0.44 mg/kg Possibly Store under cool and well ventilated nitrogen oxides (NO,
7 Phenylhydrazine 100-63-0 C6H8N2 Liquid 19.35 238°C NA No 1.1 3.7 89°C 174°C NA (mg/m3) 320 [Rabbit]. NA hazardous NA area NAp NAp NAp NAp NA NA NO2...). NA

Oral toxicity
(LD50):
2800 mg/kg
[Rat]. Acute
dermal
toxicity
(LD50): carbon oxides (CO, CO2),
N,N- HCON(CH3) Soluble in 4720 mg/kg Possibly nitrogen oxides (NO, incompatibles such as
8 Dimethylformamide 68-12-2 2 Liquid -61°C 153°C water No 0.95 2.51 57.7 445° 2.2-15.2 30 (mg/m3 120 [Rabbit]. 9400 hazardous NA Nap Nap Nap Nap Nap Nap NA NO2...). oxidizing agents, acids Stable

Protect cylinders from physical


Chlorodifluorometha damage; do not drag, roll, slide or
ne Liquefied 1.21 g/cm³ 220000 No Ecological drop, store < 52 C
9 (R22) 75-45-6 gas -157 °C -40.7 °C No (at 20 °C) 3 NA 632 - 635 NA 1000 ppm 201 NA ppm/4h damage NA Molecule is Stable NA NA NA NA NA NA Cl2, F2 Compounds NA NA
DCPT 111992-16- C1H7Cl2F2
10 6 N3O Dry & Dark area for storage Halogen chemical
-34.05 146.5 VERY TOXIC TO
11 Chlorine 7782-50-5 Cl2 gas -101 °C °C 8620 mg/l No 2.7 kg/m³ 2.5 Na NA NA 0.5 400 Na ppm/4h AQUATIC LIFE NA Nap Nap Nap Nap Nap Nap Nap Nap Nap

Acute oral
toxicity
(LD50):
3310 mg/kg
[Rat]. Acute
dermal
toxicity (LC50): Reactive with
(LD50): 5620 oxidizing agents,
Soluble in 1060 mg/kg 1 hours (LC50): 423 mg/l reducing agents, Reacts with metals to produce flammable hydrogen gas
12 Acetic acid 64-19-7 C2-H4-O2 Liquid 16.6 118.1 water No 1.049 2.07 39 463 4-19.9% 10 320 [Rabbit] [Mouse] 24 hours [Fish 2 NA NA NA NA NA NA NA NA metals, acids, alkalis. Highly corrosive to SS 304

ORAL
(LD50): Highly reactive with
Acute: 661 metals, acids, alkalis.
mg/kg Reactive with
[Rat.] oxidizing agents,
DERMAL combustible
(LD50): (LC50): materials, organic
Acute: 3540 Acute: materials. Possible Human Cancirogen (Clss- 2B)
Soluble in mg/kg 13300 Possibly In presence of H2SO4, Teratogenic : creates Effect on Reproductive effects and Birth
13 Acetaldehyde 75-07-0 CH3CHO liquid -123.5°C 21°C water No 0.78 1.52 -38° 175°C LOWER: 4% UPPER: 55% 25 342 [Rabbit] ppm hazardous NA Stable Nap Nap Nap Nap Nap NA carbon oxides (CO, CO2). polymerized violently deffects

Carbon monoxide,
Derminal>2 carbon dioxide, nitrous
00mg/kg oxides,
5-Amino 111992-18- Oral hydrogen chloride, and
14 (DCAPT) 8 solid 146 Na not soluble no NA NA NAp NA Nap Nap NA >500mg/Kg NA Na NA NA NA NA NA NA NA NA hydrogen fluoride. NA NA

Incompatible with
acetaldehyde,
ammonium
peroxodisulfate,
chloroformamidinum,
chloric acid,
ammonium nitrate,
dinitorgen tetroxide,
nitryl fluoride,
polystyrene, sodium
oral toxicity acetylide, potassium
(LD50): dichromate,
30000 peroxyformic acid,
mg/kg sulfuric acid, sodium
15 Iron 7439-89-6 Fe solid 1535 3000 in soluble No 7.86 NA NA NA NA NA 121 [Rat]. NA NA NA NA NA NA NA NA NA NA NA carbide NA

ORAL
(LD50):
Decomp Acute: 1650
osition mg/kg
temperat [Rat.]. 1300
ure: Soluble in mg/kg Possibly oxidizing agents,
16 Ammonium chloride 12125-02-9 NH4Cl solid 338°C 520°C water no 1.53 Na Na Na NA 10 mg/m3 200 [Mouse]. NAp hazardous 5.5 No NA NA NA NA NA NA Cl2, NOX acids, alkalis NA

Oral (LD50):
5628 mg/kg
[Rat]. Acute
dermal
toxicity
(LD50): Ecotoxicity in
15800 64000 4 water (LC50):
Soluble in mg/kg hours 29400 mg/l 96 oxidizing agents,
17 Methyl alcohol 67-56-1 CH3OH Liquid -97.8°C 64.5°C water no 0.7915 1.11 12 464 6-36.5 200 130 [Rabbit [Rat]. hours NA NA Nap Nap Nap Nap Nap NA COX metals, acids. NA

Derminal> Carbon monoxide,


200 mg/kg carbon dioxide, nitrous
Oral : 50- oxides,
111992-17- C10H6Cl2F 103°C - 500 mg/Kg hydrogen chloride, and
18 FMC 97273 (5-Nitro) 7 2N4O3 solid 104°C NA not soluble No NA NA NA NA NA NA NA (rat) NA NA NA NA NA NA NA NA NA NA hydrogen fluoride NA NA

Soluble in 67 Nitrogen oxides. Acrid


19 Nitric Acid, 98% 7697-37-2 HNO3 Liquid NA 83.9 °C water No 1.51 NA NA NA NA 2 300 NA ppm/4h NA <1 NA NA NA Nap Nap NA NA vapors. Corrosive vapors

Alkali, metal alkaline,


compound alkaline
earth metals, bases,
acids, metal alloys
7 °C Attacks many metals,
( 101%); producing hydrogen
-10 °C Rat: 375 (highly flammable)
(103,5%), LD50: 2140 mg/m3 may form explosive
24 °C mg/kg (male/fe mixtures with air.
20 Oleum 8014-95-7 ySO3.H2O Liquid (107%) 150 °C Miscible No 1.94 NA NA NA NA 0.2 mg/m3 male NA NA NA NA NA NA NA sulfur oxides. Alkali Highly water reactive

ORAL
(LD50):
Acute: 670
mg/kg [Rat Acute:
DERMAL 1414.2
(LD50): ppm 4
Acute: 2800 hour(s) Possibly
21 1,2-Dichloroethane 107-06-2 C2H4CL2 liquid -35.3°C 83.5 NA no 1.23 3.42 13°C 413°C 6.2-15.6 40 230 mg/kg [Rat]. hazardous NA Normal NA NA NA NA NA NA COX compounds NA Stable

LD50 Oral -
Rat - male
and female
- > 5,000
22 Iron(II,III) oxide 1317-61-9 Fe3O4 Solid 1,538 NA NA No NA NA NA NA NA NA NA mg/kg NA NA NA NA NA NA NA NA NA NA NA NA NA

Incompatible with the


following materials:
potassium chlorate,
potassium
perchlorate,
potassium
permanganate,
sodium,
lithium, bases, organic
material, halogens,
metal acetylides,
oxides and hydrides,
metals as non
powders(yields
hydrogen
gas), metal
compounds, metals as
powders, strong
oxidizing and reducing
agents. Concentrated
solutions react
oral LD violently with Reactive with oxidizing agents, combustible materials,
Soluble in 502140 510 water, spattering and organic materials, metals,alkalis.
23 Sulfuric Acid, 40% 7664-93-9 H2SO4 Liquid 10.36°C 195 water No 1.3 2.01 NA NA NA 1 mg/M3 302 mg/kg mg/m3 NA <1 NA NA NA NA NA NA NA NA liberating heat Slightly Explosive in presence of Haet, of oxidizing materials

Calcium phosphide and hydrochloric acid undergo very


energetic reaction. It reacts with oxidizers
Reactive with alkalis. releasing chlorine gas. Incompatible with, alkali metals,
Slightly reactive to carbides, borides, metal oxides, vinyl acetate, acetylides,
Oral (LD50): (LC50): reactive with oxidizing sulphides,
Hydrochloric Acid, Soluble in 900 mg/kg 1108 Possibly agents, organic phosphides, cyanides, carbonates. Reacts with most metals
24 30% MSDS 7647-01-0 HCl Liquid NA 100 water No 1.03 0.62 NA NA NA 7 Mg/m3 201 [Rabbit]. ppm, hazardous Acididc Genrates Fumes NA NA NA NA NA NA NA materials, Metals to produce flammable Hydrogen gas

vigorous/explosive reaction with ethanol: barium


perchlorate, bromine pentafluoride, calcium
hypochlorite, chloryl perchlorate, chromium trioxide,
chromyl chloride, dioxygen difluoride, disulfuryl difluoride,
fluorine nitrate,
hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl
perchlorate, perchloric acid permanganic acid,
peroxodisulfuric
acid, potassium dioxide, potassium perchlorate, potassium
permanganate, ruthenium(VIII) oxide, silver perchlorate,
silver
peroxide, uranium hexafluoride, uranyl perchlorate. Ethanol
reacts violently/expodes with the following compounds:
acetyl
bromide (evolves hydrogen bromide) acetyl chloride,
aluminum, sesquibromide ethylate, ammonium hydroxide &
silver
oxide, chlorate, chromic anhydride, cyanuric acid + water,
dichloromethane + sulfuric acid + nitrate (or) nitrite,
hydrogen
peroxide + sulfuric acid, iodine + methanol + mercuric oxide,
manganese perchlorate + 2,2-dimethoxy propane,
perchlorates,
permanganates + sulfuric acid, potassium superoxide,
potassium tert-butoxide, silver & nitric acid, silver
perchlorate, sodium
hydrazide, sulfuric acid + sodium dichromate,
tetrachlorisilane + water. Ethanol is also incompatible with
Oral; Dose: Acute: platinium, and
1400 mg/kg 20000 sodium. No really safe conditions exist under which ethyl
Skin; Dose: ppm 8 oxidizing agents, alcohol and chlorine oxides can be handled. Reacts
soluble in 20000 hours Possibly acids, alkalis, vigorously with
25 Ethyl Alcohol 64-17-5 CH3CH2OH Liquid -114.1 78.5 water No 0.8 1.54 18.5 363 3.3-19 % 1000 230 mg/kg [Rat]. hazardous Neutral absorbs moiture NA NA NA NA NA NA COX moisture. acetyl chloride

ORAL
(LD50):
Oral (LD50):
Acute: 4090 1200
891 mg/kg These products are
mg/kg
Acute mg/m3 2
[Rat]. carbon oxidesfumes
(CO, when
CO2).
Soluble in [Rat]. hours Possibly Emits Na2O is heated Reactive with Sodium Carbonate is decomposed by acids with
26 Sodium carbonate 497-19-8 Na2CO3 Solid 851°C NA water No 2.5 NA NA NA NA 201 dermal [Mouse hazardous 11.5 Hygroscopic NA NA NA NA NA NA When
heatedPyridine
to decompositon oxidizing agents, acids effervescence. Reacts
toxicity (LC50): to decomposition,
Soluble in (LD50): 28500 Possibly cyanide fumes are Reactive with Reacts violently with chlorosulfonic acid, chromic acid,
27 Pyridine 110-86-1 C5H5N Liquid -42°C 115.3°C water no 0.982 0.982 20 482°C 1.8-12.4 5 330 1000 mg/kg mg/m3 hazardous NA Stable NA NA NA NA NA NA released oxidizing agents, acids maleic anhydride, nitric acid, fuming sulfuric acid

Вам также может понравиться