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You are on page 1of 23

2018

ADVANCE

RT – 5

PAPER – 2

Time: 3 Hours Maximum Marks: 237

Marking Scheme

Section I - +5, -2

Section II - +3, 0

Section III - +3, -1

Section IV - +8 (+2, +2, +2, +2), 0

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2

CHEMISTRY

TEST-II

PART-I

Atomic number: Co = 27, Pt = 78 ; RH = 109677 cm–1 ; Velocity of light, C = 3 × 108 m sec–1

SECTION–I

Single Correct Choice Type

This section contains 6 multiple choice questions. Each question has four choices (A), (B),

(C) and (D) for its answer, out of which ONLY ONE is correct.

1. 0.5 g of a polybasic Acid HxA (all the hydrogens are acidic) of molecular mass 120 requires

0.5 g of NaOH for complete neutralization. The number of replaceable hydrogen atoms in

the acid and the atomic mass of A would be:

(A) 1, 19 (B) 2, 118 (C) 3, 117 (D) 4, 115

2. You are given 1 litre of 0.1 M NaCl and 2 litre of 0.2M BaCl2 solutions in the laboratory.

Both electrolytes are strong. Using only these two solutions what maximum volume of

solution having [Cl–] = 0.34 M exactly can you prepare?

(A) 2.5 litre (B) 2.4 litre (C) 2.3 litre (D) None of these

3. The correct order of E2/SN2 ratio for products of the following halide is -

Ph

(P) CH3–CH–C–CH3 (Q) CH3–CH–CH–CH3

I Ph I

(R) CH3–CH2–I (S) CH3–CH2–CH–CH3

I

(A) (R) < (S) < (Q) < (P) (B) (R) < (Q) < (S) < (P)

(C) (P) < (R) < (S) < (Q) (D) (Q) < (P) < (R) < (S)

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4. Predict the product (major) in the following reaction:

CH3 CH3

NaNO2+HCl

CH–C–CH2–NH2 A

CH3

CH3

CH3 CH3

(A) CH3–CH–C–CH2–CH3 (B) CH3–CH–CH2–C–OH

CH3 OH CH3 CH3

CH3 CH3

CH3

(C) CH–C–CH2OH (D) CH3–CH–C–CH2–CH3

CH3

CH3 CH3 Cl

(i) HNO2

5. P

(ii) ∆

OH NH2

The P is

O

NH2

6. An element undergoes a reaction as shown X + 2e − → X 2− , energy released =

30·87 eV/atom. If the energy released, is used to dissociate 4g of H2 molecules, equally into

H+ and H* where H* is excited state of H atoms where the electron travels in orbit whose

circumference equal to four times its de-Broglie's wavelength. Determine the minimum

number of moles of X that would be required.

Given: IE of H = 13·6 eV/atom, bond energy of H2 = 4·526 eV/molecule

(A) 1 (B) 2 (C) 3 (D) 4

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SECTION–II

Integer Type

This section contains FIVE questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

7. During some reaction CrO 24− ion is formed from Cr2+ ion. CrO 24− so produced is then

reduced to Cr3+. If we started with 2 mole of Cr2+ , then how many equivalents of Cr3+ were

produced?

8. A centre of symmetry is equivalent to x-fold alternating axis of symmetry. What is the value

of x?

9. α-Amino acids (like α-hydroxy acid) on heating gives piperazine (cyclic amide). How

many isomers are produced when (±) CH3−CH−COOH is heated?

NH2

OH

Me Br

Me Me

(A) (B)

(Minor product)

If (C) contains a carbonyl group in it, then how many methyl group(s) is/are attached to its

cyclic ring?

11. Given below is the list of oxides of some of the elements, determine how many oxides are

amphoteric in nature?

Al2O3, N2O, CO, B2O3, P4O10, BeO, ZnO,

CaO, NO2, Sb2O3, SO3, Cl2O7, Na2O

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SECTION–III

Paragraph Type

This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice

questions have to be answered. Each of these question has four choices (A), (B), (C) and (D)

out of which ONLY ONE is correct.

Aryl halides undergo nucleophilic substitution reactions only in extreme conditions. Except

for certain industrial processes where very severe conditions are feasible, one does not ordinarily

prepare phenols (ArOH) , ethers (ArOR ), amines (ArNH2 ) or nitrites (ArCN) by nucleophilic

attack on aryl halides. The presence of electron withdrawing groups like − NO 2 ,−CF3 at ortho or

para position to the halogen atom makes the aryl halides more susceptible to nucleophilic attack.

The reaction of unactivated and deactivated aryl halides with strong bases or at high temperature

proceed via the benzyne intermediate.

OCH3

I. Me3CO–K+

12. Product. The predominant product is

II. D2O

Cl

OCH3 OCH3 OCH3 OCH3

OD D

(A) (B) (C) (D)

OD D D OD

D OD

F Mg, ether

13. Product.

Br

The predominant product is

MgF F F

(A) (B) (C) (D)

Br MgBr

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Cl KNH2

14. + (A).

liq. NH3

C 6 H5

(A) (B)

1,2-Diols are oxidized to ketone and/or aldehydes by periodic acid (HIO4). Periodic acid

reacts with the diol to form a cyclic intermediate. The reaction takes place because iodine is in

+7 oxidation state so it readily accepts electrons. When the intermediate breaks down the bond

between the two carbons bonded to the –OH group breaks.

CH3 CH3

HIO4

CH3–C–CH–CH3 CH3–C–CH–CH3 + H2O

OH OH O O

I

O O

OH

CH3 CH3

HIO3 C=O + C=O

+ CH3 H

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15. An alkene is treated with OsO4 followed by aq. NaHSO3. When the resulting diol is treated

with HIO4, the only product obtained is an unsubstituted monocyclic ketone with molecular

formula C6H10O. The structure of alkene is

(A) (B)

OH OH

(A) (B)

OH OH

(CH3)3C (CH3)3C

OH OH

(C) (D)

OH OH

(CH3)3C

HIO4

17. (A) HCHO + HCOOH. Compounds (A) and (B) respectively are:

(2 mole) 2 mole 1 mole

HI

(B)

(Excess)

CHO

CH2OH & CH2 –I

(A) CHOH & CH2 = CH–CHO (B)

CH2OH CH2 –I

CH2OH

CH2OH CH3 CH2OH CH2–I

(C) CHOH & CH–I (D) CHOH & CH–I

CH3

CH2OH CH2OH CH2–I

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SECTION–IV

Matrix Type

This section contains 2 questions. Each question has four statements (A, B, C and D) given in

Column I and five statements (p, q, r, s and t) in Column II. Any given statement in

Column I can have correct matching with one or more statement(s) given in Column II. For

example, if for a given question, statement B matches with the statements given in q and r,

then for that particular question, against statement B, darken the bubbles corresponding to

q and r in the ORS.

Column –I (Reaction) Column -II

CH3 (p) Product gives positive Br2 water test

Cr O2Cl2 H3O+

(A) (CH3CO)2O

OH

(B) CH3CHO reagent test

CH–CH3 solution test

(C) + P

Ph Ph Ph

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19. For a first order reaction A Product. [Ao is initial conc. of A]

(r)

k

(D) Amount of reactant left after 4 half lives 1

(s)

k

(t) 1.44 × t1/2

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PHYSICS

PART-II

SECTION – I

Single Correct Choice Type

This Section contains 6 multiple choice questions. Each question has four choices (A), (B),

(C) and (D) out of which ONLY ONE is correct.

end of a slope as shown in the figure. A block of mass m h

is released from the slope from height h. It slides till the l

end of the carriage (The friction between the body and M

the slope and also friction between carriage and smooth

horizontal floor is negligible) Coefficient of friction

between block and carriage is µ. Find expression for

minimum h in the given options.

M m m m

(A) µ1 + l (B) 2µ1 + l (C) µ 2 + l (D) µ1 + l

m M M M

process in which PVx = constant. The graph shown

represents the variation of molar heat capacity of such a C'

gas with respect to x. The values of C' and x',

respectively, are given by (3/2)R

x

x'

5 5 5 5 7 7 7 7

(A) R, (B) R, (C) R, (D) R,

2 2 2 3 2 2 2 5

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22. In the arrangement shown, the small spherical object of mass m is at rest on a smooth floor

R

at x = − and is connected to a spring of force constant k. At t = 0, it is given a velocity

2

R k

V= iˆ . The speed of the image of this object in the stationary concave mirror at t =

4 m

3π m

is

4 k

x=0

R

−

2

k k R

(A) 2 R (B) R (C) km (D) zero

m m 4

23. In the circuit shown initially the switch is connected to 1 and after attaining steady state, it

is broken (say at t = 0). Then at the moment when the charge on the capacitor is numerically

LCE 2

equal to , the current through the inductor is

2R 2

R

1

E L C

E E 1 E 2E

(A) (B) (C) (D)

R 2R 2 R R

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24. Two light waves of same frequency, same velocity but different amplitudes from two

seperate sources, travel along the same path in the same direction, then for points on the line

(position x) and for time t the intensity

(A) is constant over x and t (B) is constant over x but varies with t

(C) varies with x but constant over t (D) varies with both x and t

r0

shown. A vertical force P is applied on the upper surface

of the body downward. If the compressive stress at all

the cross-section is constant then variation of radius with

altitude y measured from the upper surface is given by

[g = acceleration due to gravity]

ground

2P ρgyπr02

(A) r = r0 ln 2 (B) r = r0 exp

y ρπr0 g 2P

ρgPy

(C) r = r0 + 2 y (D) r = r0 exp 2

πr0

SECTION – II

Integer Type

This section contains FIVE questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be

bubbled.

with velocity vb. Initial velocity of the particle is vm directed

along y-axis. Coefficient of friction between particle and vb

belt is µ. The particle touches the belt at the origin of a fixed Belt

coordinate system and remains on the belt. Determine the

product of inverse of coordinates (x, y) of the point where vm x

1

sliding stops. [vm = 1 ms–1, vb = 2 ms–2, µ = ] m

2 2

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27. Two balls of equal density and radii r and R = 2r, are placed with the centre of the larger

one directly above the middle of a cart of mass M = 6 kg and length L = 2m. The mass of

the smaller ball is m = 1 kg. The balls are made to roll, without slipping, in such a way that

the larger ball rests on the cart and a straight line connecting their centres remains at a

constant angle φ = 60° to the horizontal. The cart is pulled by a horizontal force in the

direction shown in figure. If the time is t which elapses before the balls fall off the cart then

find (t + 0.45) in seconds.

m

M F

28. A neutron with an energy of 4.6 MeV collides with protons and is retarded. Assume that

upon each collision the neutron is deflected by 45°. If the number of collisions is (20 + x)

which will reduce its energy to 0.23 eV then find x.

29. In the figure, CDEF is a fixed conducting smooth frame in a vertical plane. A conducting

uniform rod GH of mass m = 3 kg can move vertically and smoothly without losing contact

with the frame. GH always remains horizontal. It is given velocity u = 30ms–1 upwards and

released. Taking the acceleration due to gravity as g and assuming that no resistance is

present other than R = 1Ω, find out time taken by rod to reach the highest point. (Given B =

1T, g = 10 m/s2, l = 1m, ln (2) = 0.7)

C l F

u

G ⊗B H

D E

R=1Ω

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30. Three identically charged, small spheres each of mass m are suspended from a common

point by insulated light strings each of length l. The spheres are always on vertices of an

equilateral triangle of length of the side x(<<l). Calculate the rate dq/dt in ampere with

which charge on each sphere increases if length of the sides of the equilateral triangle

dx a

increases slowly according to the law = , where a = 104 m3/2.s–1, m = 12 kg, l = 1m.

dt x

SECTION − III

Paragraph Type

This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice questions

have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of

which ONLY ONE is correct.

A cylindrical vessel contains a diatomic gas. It is closed with a light piston. Initially the

piston is at height L0. The temperature of the gas initially is T0.

L0

31. The mean rotational K.E. of a molecule in the final state after the gas is compressed to half

its initial volume adiabatically. (41 / 5 ≅ 1.32) [k = Boltzmann const.] is

(A) 1.32 kT0 (B) kT0

kT0

(C) 2.64 kT0 (D)

1.32

32. The mean rotational K.E. of a molecule in the final state after the gas is compressed to half

its initial volume isothermally [41 / 5 ≅ 1.32] is

(A) 1.32 kT0 (B) kT0

kT0

(C) 2.64 kT0 (D)

1.32

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33. Assume that the gas is suddenly compressed to half its initial volume and then allowed to

cool to the initial temperature T0. In the cooling process the change in internal energy of the

gas is

(A) –0.32 nRT0 (B) +0.32 nRT0

(C) –0.64 nRT0 (D) +0.64 nRT0

In a photoelectric effect experiment a point source of light of power 40 W emits mono-

energetic photons of wavelength λ1 that can just emit photoelectrons from an isolated

metallic sphere of radius r = 1 cm, placed at a distance of 1m from the light source. Now,

three other separate sources of wavelength λ2, λ3 and λ4 light emitting same number of

photons as that of green light are brought near the source of green light.

Assume one photoelectron is emitted out of every 106 incident photons on sphere.

(Take λ2 = 4136 Å, λ3 = 5000 Å, λ4 = 7200 Å, λ1 = 4963 Å, hc = 12408 eV Å)

(A) 2.5 × 109 (B) 2.5 × 108

(C) 2.5 × 107 (D) 2.5 × 106

(A) 0.7 V (B) 0.5 V

(C) 0.6 V (D) 0.8 V

36. The time after which the emission of photoelectron will stop is

(A) 1.39 × 10–6 s (B) 1.39 s

–3

(C) 1.39 × 10 s (D) 1.39 × 10–1 s

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SECTION − IV

Matrix Type

This section contains 2 questions. Each question has four statements (A, B, C and D) given

in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in

Column I can have correct matching with one or more statement(s) given in Column II.

For example, if for a given question, statement B matches with the statements given in q and

r, then for that particular question, against statement B, darken the bubbles corresponding to

q and r in the ORS.

Column I Column II

(A) The fringe width for red colour as compared to that for (p) Half

voilet colour is approximately (ln YDSE)

(B) The distance between the slits is halved and the distance (q) One-fourth

between the slit and the screen is doubled, then fringe width

will become (ln YDSE)

(C) lf the distance of a point from a point source of light is (r) Double

doubled then the intensity will become

(D) Light from a lamp is falling normally on a small surface. lf (s) Three times

the surface is tilted to 60° from this position, then the (t) Four times

intensity of the surface will become

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38. A uniform but time varying magnetic field B(t) exists in a cylindrical region of radius a and

is directed into the plane of the paper, as shown in figure. Magnetic field decreases at

constant rate inside the region. If r is the distance from axis of cylindrical region then match

the items in column-I with those in column-II

A 2

3

B(t)

B 1

4

a

Column I Column II

(t) Increases as r2

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MATHEMATICS

PART - III

SECTION - I

Single Correct Choice Type

This Section contains 6 multiple choice questions. Each question has four choices (A), (B),

(C) and (D) out of which ONLY ONE is correct.

39.

(A) 1 (B) 2

1

(C) (D) none of these

2

(A) 13 (B) 6

(C) 4 (D) 1

( x 3 + x + 1)

41. The value of ∫ e x dx is

(1 + x 2 ) 3 / 2

xe x x 2e x

(A) +C (B) +C

(1 + x 2 )1/ 2 (1 + x 2 )1/ 2

ex

(C) +C (D) None of these

(1 + x 2 )1 / 2

is

1

(A) 1 (B)

2

3

(C) (D) 2

2

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π

43. If f ′′(x) > 0, ∀ x ∈ R, f ′(3) = 0 and g(x) = f (tan2 x –2 tan x + 4), 0 < x < , then g (x) is

2

increasing in

π π π

(A) 0, (B) ,

4 6 3

π

(C) 0, (D) none of these

3

44. If foci of hyperbola lie on y = x and one of the asymptote is y = 2x, then equation of the

hyperbola, given that it passes through (3, 4), is

5

(A) x2 – y2 – xy + 5 = 0 (B) 2x2 – 2y2 + 5xy + 5 = 0

2

(C) 2x2 + 2y2 – 5xy + 10 = 0 (D) none of these

SECTION–II

Integer Type

This section contains FIVE questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

p

45. If four vectors are equally inclined to each other at an angle θ and cos θ = − then

q

p + q = _______.

46. A line L1 with direction ratios (–3, 2, 4) passes through the point A(7, 6, 2) and a line L2

with direction ratios (2, 1, 3) passes through the point B(5, 3, 4). A line L3 with direction

ratios (2, –2, –1) intersects L1 and L2 at C and D. Find CD.

x

47. Let f(x) = ∫ {( a − 1)(t 2 + t + 1) 2 − (a + 1)(t 4 + t 2 + 1)}dt . Then the total no. of integral value

0

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48. The lengths of two perpendicular focal chords of the parabola y2 = 4(x + 1), are p and q.

pq

Then the value of is

p+q

49. A box has 2 white, 4 black and 6 green balls. Person A, draws a ball from it. Then from the

remaining balls person B draws two balls which are found to be green. The probability that

p

A has drawn a black ball is (p and q are co-prime), p, q ∈ I + then p + q =

q

SECTION–III

Paragraph Type

This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice

questions have to be answered. Each of these question has four choices (A), (B), (C) and (D)

out of which ONLY ONE is correct.

A sphere is the locus of a point in space such that its distance from a fixed point in space is

constant. The fixed point is called the centre and the constant distance is called the radius of the

sphere. In Cartesian system, the equation of the sphere, with centre at (–g, –f, –h) is

x 2 + y 2 + z 2 + 2 gx + 2 fy + 2hz + c = 0 and its radius is f 2 + g 2 + h2 − c

In vector form the equation | r − 0 | = a represent a sphere with centre 0 and radius a.

50. Equation of the sphere having centre at (3, 6, –4) and touching the plane

r .( 2iˆ − 2 ˆj − kˆ) = 10 , is ( x − 3) 2 + ( y − 6) 2 + ( z + 4) 2 = k 2 , where k is equal to

(A) 3 (B) 4

(C) 6 (D) 17

51. Radius of the circular section of the sphere | r | = 8 cut off by the plane r .(iˆ + 2 ˆj + 2kˆ ) = 15 is

(A) 39 (B) 29

(C) 59 (D) 7

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52. Radius of the circular section of sphere x 2 + y 2 + z 2 = 25 cut off by the sphere

x 2 + y 2 + z 2 − 4 x − 4 y − 4 z − 13 = 0 is

(A) 5 (B) 22

(C) 24 (D) none of these

f : R → R, f ( x) is a differentiable function such that all its successive derivatives exist.

f '( x) can be zero at discrete points only and f ( x) f " ( x) ≤ 0∀x ∈ R .

Now answer the following questions based on the above comprehension:

(A) f (a + h) f " (a − h) < 0 (B) f (a + h) f " (a − h) > 0

(C) f ' (a + h) f " (a − h) < 0 (D) nothing can be said

(A) f " ( γ ) = 0 for at least one γ ∈ (α, β) (B) f "' ( γ ) = 0 for at least one γ ∈ (α, β)

(C) f "" ( γ ) = 0 for at least one γ ∈ (α, β) (D) f ""' ( γ ) = 0 for at least one γ ∈ (α, β)

(A) no real root (B) one

(C) two (D) three

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22

SECTION–IV

Matrix Type

This section contains 2 questions. Each question has four statements (A, B, C and D) given in

Column I and five statements (p, q, r, s and t) in Column II. Any given statement in

Column I can have correct matching with one or more statement(s) given in Column II. For

example, if for a given question, statement B matches with the statements given in q and r,

then for that particular question, against statement B, darken the bubbles corresponding to

q and r in the ORS.

56.

Column I Column II

(A) −1

lim cosec sin x (p) – π/2

x →π / 2

k (q) 0

(B) lim tan −1 ,k ∈ R

x →0 x2

tan(π cos 2 x ) (r) π/2

(C) lim

x →0 2x 2

(D) lim

x → −∞ 2x + 3

(t) π

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23

57.

Column I Column II

(A) If the point (a, a) lies between the lines |x + y| = 6 then [|a|] can (p) 1

be equal to, ([.] represents the integral part)

(B) Number of circle touching both the axes and the line x + y = 4. (q) 2

(C) A point can be located in the x-y plane in such a way that two (r) 3

tangents drawn from it to the parabola y 2 = 4ax are normals to

the parabola x 2

= 4 y , then possible values of a can be

(D) If normals are drawn at four points with eccentric angles (s) 4

x2 y2

θ1 , θ 2 , θ 3 and θ4 on the ellipse 2 + 2 = 1 , passes through a

a b

fixed point and value of θ1 + θ 2 + θ 3 + θ 4 = nπ then n may be

(t) 5

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