UNIFAC: VOLUMEN

Y AREA Alcano Alqueno Aromatico

SUPERFICIAL

GRUPO PRINCIPAL 1 2 3

CH2=CH

CH=CH

CH2=C

CH=C

ACH
C=C
CH3

CH2

CH

C
GRUPO SECUNDARIO 1 2 3 4 5 6 7 8 70 9
VOLUMEN R 0.9011 0.6744 0.4469 0.2195 1.3454 1.1167 1.1173 0.8886 0.6605 0.5313
AREA SUPERFICIAL Q 0.8480 0.5400 0.2280 0.0000 1.1760 0.8670 0.9880 0.6760 0.4850 0.4000
SUSTANCIAS
SELECCIONADAS
1,2-Dimethoxyethane 2
2,2,4-Trimethylpentane 5 1 1 1
Acetaldehyde 1
Acetic Acid 1
Acetone 1
Acetonitrile
Aniline 5
Benzaldehyde 5
Benzene 6
Benzyl Alcohol 5
Bromobenzene 5
Butane 2 2
Chlorobenzene 5
Chloroform
Diethylamine 2 1
Diisopropylamine 4 1
Dimethyl Sulfoxide
Dimethylamine 1
Ethyl Acetate 1 1
Ethyl Alcohol 1 1
Ethyl Ether 2 1
Ethyl Formate 1 1
Ethylamine 1
Ethylene Glycol
Formic Acid
Isobutane 3 1
Isobutyl Alcohol 2 1 1
Isopropyl Acetate 2 1
Isopropyl Alcohol 2 1
Methanol
Methyl Acetate 1
Methyl Ethyl Ketone 1 1
Methyl Formate 1
Methyl Isobutyl Ketone 2 1 1
 Methyl tert-Butyl Ether 3 1
Methylamine
Methylene Chloride
N,N-Dimethyl Formamide
n-Butyl Acetate 1 3
n-Butyl Alcohol 1 3
n-Butyl Chloride 1 2
n-Butylamine 1 2
n-Heptane 2 5
n-Hexane 2 4
n-Pentane 2 3
n-Propyl Acetate 1 2
n-Propyl Alcohol 1 2
o-Dichlorobenzene 4
o-Xylene 4
Piperidine 4
Propane 2 1
Pyridine
sec-Butyl Alcohol 2 1 1
tert-Butyl Alcohol 3 1
Tetrahydrofuran 3
Toluene 5
Triethylamine 3 2
Trimethylamine 2
Water
 Aldehido
Aromatico Alcohol Cetona Ester

3 4 5 6 7 8 9 10 11 12

CH3COO

CH2COO
CH3OH

CH3CO

CH2CO
ACCH3

ACCH2

HCOO
ACOH
ACCH

CHO
H2O
OH
AC

10 11 12 13 14 15 16 17 18 19 20 21 22 23
0.3652 1.2663 1.0396 0.8121 1.0000 1.4311 0.9200 0.8952 1.6724 1.4457 0.9980 1.9031 1.6764 1.2420
0.1200 0.9680 0.6600 0.3480 1.2000 1.4320 1.4000 0.6800 1.4880 1.1800 0.9480 1.7280 1.4200 1.1880

1 1

1 1
1

1
1

1
1
1
1
1
1
1
1
 1
1

1
1

1
1

1
 Aniline
Ether Amine, 1st Amine, 2nd Amine, 3rd Pyridine

13 14 15 16 17 18

CH3NH2

CH2NH2

CHNH2

CH3NH

CH2NH

ACNH2
FCH2O

C5H5N
CHNH
CH3O

CH2O

CH3N

CH2N
CH-O

24 25 26 27 28 29 30 31 32 33 34 35 36 37
1.1450 0.9183 0.6908 0.9183 1.5959 1.3692 1.1417 1.4337 1.2070 0.9795 1.1865 0.9597 1.0600 2.9993
1.0880 0.7800 0.4680 1.1000 1.5440 1.2360 0.9240 1.2440 0.9360 0.6240 0.9400 0.6320 0.8160 2.1130

1
1

1
1
1

1
1
Pyridine Nitrile Acid Chloride Dichloride Other Chloride

18 19 20 21 22 23

HCOOH

CH2Cl2
CH3CN

CH2CN
C5H4N

C5H3N

COOH

CHCl2

CHCl3
CH2Cl

CHCl

CCl2

CCl3
CCl
38 39 40 41 42 43 44 45 46 47 48 49 50 51
2.8332 2.6670 1.8701 1.6434 1.3013 1.5280 1.4654 1.2380 1.0060 2.2564 2.0606 1.8016 2.8700 2.6401
1.8330 1.5530 1.7240 1.4160 1.2240 1.5320 1.2640 0.9520 0.7240 1.9880 1.6840 1.4480 2.4100 2.1840

1
 1

1
 Ethanediol
Disulfide

Furfural

bromo
iodo
Other Chloride Nitro Thiol alkyne

24 25 26 27 28 29 30 31 32 33 34

(CH2OH)2
CH3NO2

CH2NO2

furfural
CHNO2

ACNO2

CH3SH

CH2SH

CH=-C
ACCl
CCl4

CS2

Br
I
52 53 54 55 56 57 58 59 60 61 62 63 64 65
3.3900 1.1562 2.0086 1.7818 1.5544 1.4199 2.5070 1.8770 1.6510 3.1680 2.4088 1.2640 0.9492 1.2929
2.9100 0.8440 1.8680 1.5600 1.2480 1.1040 1.6500 1.6760 1.3680 2.4810 2.2480 0.9920 0.8320 1.0880

1
2
 Trichloroethylene
Dimetilsulfoxyde

Fluorobenzene
Acrylonitrile

Formamide

Flexy Ester
alkyne Fluorides Silane

34 35 36 37 38 39 40 41 42
Cl-(C=C)

DMF-1

DMF-2
DMSO

ACRY
C=-C

COO

SiH3

SiH2
ACF

CF3

CF2

SiH
CF
66 67 68 69 71 72 73 74 75 76 77 78 79 80
1.0613 2.8266 2.3144 0.7910 0.6948 3.0856 2.6322 1.4060 1.0105 0.6150 1.3800 1.6035 1.4443 1.2851
0.7840 2.4720 2.0520 0.7240 0.5240 2.7360 2.1200 1.3800 0.9200 0.4600 1.2000 1.2630 1.0060 0.7490

1
1
 Methylpyrrolidone
Silane Siloxane Chlorofluorocarbons A

42 43 44 45

HCClF2
HCCl2F

CONH2
CCl2F2
HCClF
SiH2O

CClF2

CClF3
CCl3F

CCl2F
SiHO

NMP
SiO
Si

81 82 83 84 85 86 87 88 89 90 91 92 93 94
1.0470 1.4838 1.3030 1.1044 3.9810 3.0356 2.2287 2.4060 1.6493 1.8174 1.9670 2.1721 2.6243 1.4515
0.4100 1.0620 0.7640 0.4660 3.2000 2.6440 1.9160 2.1160 1.4160 1.6480 1.8280 2.1000 2.3760 1.2480
 Glycol Ethers
Amides Sulfides

46 47 48 49 50

CONCH3CH2
CON(CH3)2

CON(CH2)2

Morpholine
CONHCH3

CONHCH2

C2H5O2

C2H4O2

C4H4S

C4H3S

C4H2S
CH3S

CH2S

CHS
95 96 97 98 99 100 101 102 103 104 105 106 107 108
2.1905 1.9637 2.8589 2.6322 2.4054 2.1226 1.8952 1.6130 1.3863 1.1589 3.4740 2.8569 2.6908 2.5247
1.7960 1.4880 2.4280 2.1200 1.8120 1.9040 1.5920 1.3680 1.0600 0.7480 2.7960 2.1400 1.8600 1.5800