ELV con Ley de Raoult

Modificada

FIPGNP - UNI
Punto de Burbuja
xi = zi
sat
Calcular Pi
Calcular γ i
P = ∑ xiγ i Pi sat

y = xiγ i Pi sat
/P
 yi = zi
Punto de rocío γi =1
sat
Calcular Pi
P0 = 1/ ∑ yi / γ i Pi sat

mientras error > e min

xi = yi P0 / γ i Pi sat

Calcular γ i
P = 1/ ∑ yi / γ i Pi sat

error = P − P0
P0 = P
fin
 xi = zi
sat
Calcular Ti
Temperatura de T 0 = ∑ xiTi sat

burbuja mientras error > e min

Calcular γ i
Calcular Pi sat aT 0
P1sat = PP1sat / ∑ xiγ i Pi sat
sat sat
Calcular T 1comoT 1 aP 1

error = T − T 0
T0 =T
fin
yi = xiγ i Pi sat
/P
 yi = zi
Calcular Ti sat

Temperatura de T 0 = ∑ yiTi sat

rocío γi =1
mientras error > e min
Calcular Pi sat aT 0
xi = yi P / γ i Pi sat
Calcular γ i
P1sat = PP1sat ∑ yi / γ i Pi sat
sat sat
Calcular T comoT 1 aP 1

error = T − T 0
T0 =T
fin
 Calcular Pi sat
V0 = 0
γi =1
ELV
Calcular K i = γ i Pi sat / P
mientras error > e min
zi
xi =
⎡⎣1 + V 0 ( γ i K i − 1) ⎤⎦
Calcular γ i
Calcular K i = γ i Pi sat / P
F (V 0 )
V =V0− Newton Raphson
F ' (V 0 )
error = V − V 0
V0 =V
fin