1. Like electron atomic nucleus also---- about on its own axis.

a. rotate b. spin c. revolve d. all these.

2. If the rate equation of a reaction 2A + B ® Product, Rate = k [A] 2 [B] and A is
present in large excess then order of reaction is:
a. 1 b. 2 c. 3 d. None of these
3. The compound used for the absorption of water in combustion analysis is
a. Magnesium per chlorate b. sodium carbonate
c. sodium thiosulphate d. potassium hydroxide
4. The number and natural abundance of isotopes of an elements are determine by --
-- spectroscopy
a. NMR b. IR c. Mass d. UV/Vis
5. The number of peaks in the NMR spectrum of toluene are
a. 3 b. 4 c. 1 d. 2
6. The conversion of carbonate urea is:
a. slow and exothermic b. fast and exothermic
c. slow and endothermic d. fast and endothermic
7. Which of the followings is correct?
a. Acetophenone is an ether
b. Diastase is an enzyme
c. Cycloheptane is an aromatic compound
d .all of the above
8. Which one is organic in nature?
a. KCN b. NH4CNO c. CaC2 d. Bucky ball
9. The highest electrical conductivity of the following aqueous solutions is of
a.0.1 M acetic acid b. 0.1 M chloroacetic acid
c. 0.1 M fluoroacetic acid
d. 0.1 M difluoroacetic acid
10. Hydrogen gas is not liberated when the following metal is added to dil. HCl.
a) Mg b) Sn c) Ag d) Zn
11. The cathode in lead storage battery is made of:
(a) Lead (b) Lead oxide
(c) Lead hydroxide (d) None of them
12. CH3CHO and C6H5CH2CHO can be distinguished chemically by
a) Tollen's reagent test b) Fehling solution test
c) Benedict test d) Iodoform test
13. The correct order of decreasing acid strength of trichloroacetic acid (A),
trifluoroacetic acid (B), acetic acid (C) and formic acid (D) is
a) A > B > C > D b) A > C > B > D
c) B > A > D > C d) B > D > C > A
14. For making distinction between 2-pentanone and 3-pentanone the reagent to be
employed is
a) K2Cr2O7/H2SO4 b) Zn-Hg/HCl
c) SeO2 d) Iodine/NaOH
15. Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and
conc. HCl is called
a) Cope reduction b) Dow reduction
c) Wolff-Kishner reduction
d) Clemmensen reduction
16. 501.85 oC is equal to _____ K
a) 775 K b) 7.75 K c) 77.5 K d) None
17. Hybridization of C2 and C3 of H3C – CH = C = CH – CH3
a) Sp, Sp3 b) Sp2, Sp c) Sp2, Sp2 d) Sp, Sp
18. Which one is correct for evaporation:
a) Require no Ea b) Require no catalyst
c) Endothermic process d) Physical Process e) All
19. Which one is not electromagnetic radiation:
a) x-rays b) UV-rays c) Cathod rays d) IR rays
20. Which of the following of will have the same number of molecules at STP?
a. 280 cm3 of CO2 and 280 cm3 of N2O
b. b.11.2 dm3 of O2 and 32 g of O2
c. 44g of CO2 and 11.2 dm3 of CO
d. d. 28g of N2 and 5.6 dm3 of oxygen
21. Absolute temperature of He gas is proportional to
a. translational kinetic energy
b. rotational kinetic energy
c. vibrational kinetic energy d. potential energy
22. Most ideal gas at room temperature is:
a) CO2 b) NH3 c) SO2 d) N2
23. The number of molecules in 100 mL of 0.02 N H2SO4 is
a) 6.02×1022 b) 6.02×1021
20
c) 6.02×10 d) 6.02×1018
24. Which one is most stable covalent hydride:
a) HF b) HCl c) HBr d) HI
25. Which is both oxidizing as well as reducing agent
a. NO b. HCl c. Both (a) & (b) d. None
26. Ethanol is much more soluble in water than ethyl ethanuate which one of the
following statement correctly account for this
a. ethanol is polar molecule but ethyl ethanoate is non–polar
b. ethanol is non polar molecule but ethyl ethanoate is polar
c. a hydrogen bond is formed between H–atom of the OH group in ethanol and
O–atom of water molecule
d. a hydrogen bond is formed between the H–atom of the OH group in ethanol
and hydrogen of the water molecule
27. Why the boiling point of methane is greater than that of Neon : a) a molecule of
methane has a greater mass
b) a molecule of methane has more electrons than a molecule of Neon
c) The molecules of methane have stronger intermolecular forces than those of
Neon
d) the molecule of methane is polar but that of Neon is not
28. Which one is the unit of surface tension
a) N/m b) J/m2 c) Both (a) & (b) d) None
29. Particles involves in an ordinary chemical reaction is:
a) Electron b) Proton c) Neutron d) Positron
30. The energy of an electron in the exited state n = 4 in hydrogen atom is:
(a) – 13.6 eV (b) – 3.4 eV (c) –0.85 eV (d) – 1.5 eV
31. The number of carbon atoms in 18 gram of glucose are (C6H12O6):
a. 6 × NA b. 0.3 × NA c. 0.6 × NA d. NA
32. If actual yield is 5/7 times of T. yield then the percentage yield is:
a. 61.0% b. 66.6% c. 71.0% d. 75.0%
33. For liquefaction of gases, which of the following method is more effective?
a. Lindes method b. Claud’s method
c. Both have same effect d. Cannot predict
34. Which one has lowest temperature
(a) Troposphere (b) Stratosphere
(c) Mesosphere (d) Thermosphere
35. Number of carbonate ions produced when 25 gram of CaCO3 is dissolved in
water:
a. NA b. 1.5 NA c. 2.0 NA d. 0.25 NA
36. Total number of orbitals in M shell of an atom:
a.2 b. 3 c. 6 d. 9
37. 32 gram of SO2 , 8gram of O2 and 16 gram of CH4 are enclosed in container at
760 mm Hg & 273 k, ratio in volume of these gases:
a. 1 : 1 : 2 b. 1 : 2 : 4 c. 2 : 1 : 4 d . 2 : 1 : 3
38. Which of the following is the viscosity of water at 25 oC
a. 10–1 kg m–1s–1 b. 10–2 kg m–1s–1
c. 10–3 kg m–1s–1 d. 1 poise
39. Which of the following is not helpful in more product formation for the following
general equation?
2A(g) + 3B(g) → 2C(g) +D(g) + Heat
a. Increasing temperature b. increasing conc. of D
c. Increasing pressure d. Decreasing conc. Of B
40. Photochemical reaction are of:
a. Zero order b. First order c. 2nd order d. 3rd order
41. Equal mass of O2, CH4, & SO2 is enclosed in container, what is the mole fraction
of O2
a. 1/7 b. 2/7 c. 0.5 d. 1/3 .
42. Two electrodes A & B having standard reduction potential 3.5 volts & 1.5 volt
respectively. The maximum cell potential can be obtained from the cell is:
a. 5.0 volt b .– 2.0 volt c. 1.5 volt d. 2.0 volt
2
43. What is the bond order of N 2
(a) 1 (b) 2 (c) 3 (d) 4
44. Which one is not state function:
a) Work b) Heat c) Internal energy d) both a) & b)
45. Complexes with bidentate ligands are
a. ligands b. Chelates c. Complexes d. None
46. As the principal quantum No. increase the energy difference b/w adjacent energy
level:
a. decrease b. Increase
c. Remain fluctuating d. Remain same
47. Which electronic arrangement is that of a metallic element a. 2 , 1 b. 2 , 4 c.
2,5 d.2,7
48. Which of the following is least inert
a. Helium b. Neone c. Argon d. Xenon
49. Which of the following molecule is linear
a.H2O b. NO2 c. NO 2 d. ClO 2
50. Value of the standard reduction potential for strong reducing agents is:
(a) Large negative value (b) Zero
(c) Large positive value (d) negligibly small
51. Most stable hydride is of:
a. Fluorine b. Bismuth c. Thallium d. Lead.
52. Which process of ester will give carboxylic acid
a. Hydration b. Hydrolysis
c. Oxidation d. Reduction
53. On passing 0.1 Faraday of electricity through AlCl3, the amount of aluminum
metal deposited on cathode is (At mass of Al is 27
a.0.27 g b. 0.81 g c. 0.9 g d. 13.5 g
54. Given the reaction :
Pb (s) + Cu2+ (aq) → Pb2+ (aq) + Cu (s)
What is the reducing agent:
a. Pb2+ aq b. Cu2+ aq c. Pb (s) d. Cu (s)
55. Ca2+ ion is isoelectronic with
a. Mg2+ b. Na+ c. Ar d. Kr
56. Which one is the example of complex hydride?
a.PH3 b. NaH c. AlCl3 d.NaBH4
57. The super oxide are formed by the elements:
a. K, Rb, Cs b. K, Na, Cs, c. K, Li, Na d .None
58. Urea is also called:
a. Carbamide b. Carbonyl diamine c. Diamino Methonal d. All
59. In galvanic cell:
a. Al does not releases electrons and changes to Al+3 b. Al releases and change to
Al+3 ion
c. Both of the above d. None
60. The general formula (RCO)2O represents:
(a) An ether (b) Ketone
(c) An ester (d) An acid unhydride