VII.

OBSERVATION RESULT

No. Procedure Observation Result Hyphotesis / Reaction Conclusion

1. The compound that formed in
experiment I and II are cis
potassium bis dioxalato diaquo
chromate(III). It is proven by dark
green when it is reacted with
ammonium solution. the percent
result are in experiment I(70.645%)
and II(43.7876%).
1. Preparation of isomer trans of potassium bisoxalatodiaquochromate(III)

No. Activity Observation Reaction

Oxalate acid H2C2O4·2H2O(s)

1 White crystal
dehydrate
H2C2O4·2H2O(s) +
Oxalate acid H2O(l) →
2 White crystal coagulate
dehydrate + aquadest H2C2O4·2H2O(s)

3 Potassium dichromate Orange crystal K2Cr2O7(s)

Potassium dichromate K2Cr2O7(s) + H2O(l) →

4 Orange crystal coagulate K2Cr2O7(s)
+ aquadest

Oxalate acid 7H2C2O4·2H2O(s) +

dehydrate solution + Blackish brown + bubble K2Cr2O7(s) →
5 2K[Cr(C2O4)2(H2O)2](s)
potassium dichromate gas
solution + 6CO2(g) + 7H2O(l)

7H2C2O4·2H2O(s) +
After the second K2Cr2O7(s) →
Blackish brown + bubble
6 mixing solution is 2K[Cr(C2O4)2(H2O)2](s)
gas
vapour + 6CO2(g) + 7H2O(l)

Residue:
Filtrate: blackish brown 2K[Cr(C2O4)2(H2O)2](s)
7 Crystal after filtered Residue: blackish brown
(s) filtrate: 7H2O(l)

After washed with -

8 Blackish brown
distilled water
After washed with -
9 Blackish brown
ethanol
Weight I: 1.8720 gram
After drying (temp:
Weight II: 1.8235 gram Percent result= 70.645%
10 40℃), weight is
Weight III: 1.8235 gram
constant
Weight IV: 1.6902 gram
Testing the isomer 7H2C2O4·2H2O(s) +
purity: K2Cr2O7(s) →
11 Green 2K[Cr(C2O4)2(H2O)2](s)
Filter paper + crystal
+ ammonium solution + 6CO2(g) + 7H2O(l)
2. Preparation of isomer trans of potassium bisoxalatodiaquochromate(III)

No. Activity Observation Reaction

Oxalate acid dehydrate H2C2O4·2H2O(s)

1 White crystal
powder
Potassium dichromate K2Cr2O7(s)
2 Orange crystal
powder
H2C2O4·2H2O(s) +
Oxalate acid dehydrate K2Cr2O7(s) →
3 powder + potassium Orange-white crystal H2C2O4·2H2O(s) +
dichromate powder K2Cr2O7(s)

Oxalate acid dehydrate 7H2C2O4·2H2O(s) +

powder + potassium K2Cr2O7(s) →
4 Blackish green pasta 2K[Cr(C2O4)2(H2O)2](s) +
dichromate powder +
aquadest drop by drop 6CO2(g) + 7H2O(l)

Stirring until 7H2C2O4·2H2O(s) +

After the solution is K2Cr2O7(s) →
precipitation is
5 mixing + ethanol + 2K[Cr(C2O4)2(H2O)2](s) +
forming:
stirring 6CO2(g) + 7H2O(l)
1 minute
7H2C2O4·2H2O(s) +
After decantation K2Cr2O7(s) →
6 Dark green crystal 2K[Cr(C2O4)2(H2O)2](s) +
process + ethanol again
6CO2(g) + 7H2O(l)

7H2C2O4·2H2O(s) +
Filtrate: dark green K2Cr2O7(s) →
7 Crystal after filtered 2K[Cr(C2O4)2(H2O)2](s) +
Residue: dark green
6CO2(g) + 7H2O(l)

I = 1.2808 gram
After drying (temp: II = 1.2673 gram
8 40℃), weight is Percent result= 43.7876 %
III = 1.2673 gram
constant
IV = 1.2342 gram

Testing the isomer 7H2C2O4·2H2O(s) +

purity: K2Cr2O7(s) →
9 Dark green 2K[Cr(C2O4)2(H2O)2](s) +
Filter paper + crystal +
ammonium solution 6CO2(g) + 7H2O(l)
 CALCULATION

Trans
Known: Mass of H2C2O4.2H2O = 3 gram
Mass of K2Cr2O7 = 1 gram
Mr of H2C2O4.2H2O = 126g/mole
Mr of K2Cr2O7 = 294 g/mole
3 gram
Mole of H2C2O4.2H2O = 126 g/mole = 0.0238 mole
1 𝑔𝑟𝑎𝑚
Mole of K2Cr2O7 = = 0.0034 mole
294 𝑔/𝑚𝑜𝑙𝑒

Reaction:
7H2C2O4.2H2O(s) + K2Cr2O7(s) → 2K[Cr(C2O4)2(H2O)2](s) + 6CO2(g) + 7H2O(l)
m: 0.0238 mole 0.0034 mole - -
r: 0.0238 mole 0.0034 mole 0.0068 mole 0.0204mole 0.0238mole
s: - - 0.0068 mole 0.0204mole 0.0238mole

Theoritical mass:
2K[Cr(C2O4)2(H2O)2] = 0.0068 mole x 303 g/mole
= 2.0604 gram
Experimental mass: I = 1.8720 gram
II = 1.8235 gram
III = 1.8235 gram
IV = 1.6902 gram
Mass of filter paper: 0.3467 gram
1.5253 gram + 1.4768 gram + 1.4768 gram + 1.3435 gram
𝑥̅ 𝑜𝑓 𝑚𝑎𝑠𝑠 =
4
= 1.4556 gram

1.4556 gram
% yield = x 100%
2.0604 𝑔𝑟𝑎𝑚

= 70.645%
Cis
Known: Mass of H2C2O4.2H2O = 3 gram
Mass of K2Cr2O7 = 1 gram
Mr of H2C2O4.2H2O = 126g/mole
Mr of K2Cr2O7 = 294 g/mole
3 𝑔𝑟𝑎𝑚
Mole of H2C2O4.2H2O = 126 𝑔/𝑚𝑜𝑙𝑒 = 0.0238 mole
1 𝑔𝑟𝑎𝑚
Mole of K2Cr2O7 = = 0.0034 mole
294 𝑔/𝑚𝑜𝑙𝑒

Reaction:
7H2C2O4.2H2O(s) + K2Cr2O7(s) → 2K[Cr(C2O4)2(H2O)2](s) + 6CO2(g) + 7H2O(l)
m: 0.0238 mole 0.0034 mole - -
r: 0.0238 mole 0.0034 mole 0.0068 mole 0.0204mole 0.0238mole
s: - - 0.0068 mole 0.0204mole 0.0238mole

Theoritical mass:
2K[Cr(C2O4)2(H2O)2] = 0.0068 mole x 303 g/mole
= 2.0604 gram
Experimental mass: I = 1.2808 gram
II = 1.2673 gram
III = 1.2673 gram
IV = 1.2342 gram
Mass of filter paper: 0.3602 gram
0.9206 gram + 0.9071 gram + 0.9071 gram + 0.8074 gram
𝑥̅ 𝑜𝑓 𝑚𝑎𝑠𝑠 =
4
= 0.9022 gram

0.9022 gram
% yield = x 100%
2.0604 𝑔𝑟𝑎𝑚

= 43.7876 %