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REFERENCE PACKET
Includes:
Equations & Constants
Periodic Table
Common Oxidation Numbers
Compound Naming Flowchart
Writing Compound Formulas Chart
Elements to Memorize
Polyatomic Ions to Memorize
Electronegativity Values
Solubility Rules
Graphing Guidelines
PRE-AP CHEMISTRY EQUATIONS AND CONSTANTS
ATOMIC STRUCTURE ΔHrxn np ΔHf o (products) nr ΔHf o (reactants)
hc OTHER FORMULAS
E h c λν E
λ m
D
Atomic Mass fraction abundancemass of isotope V
isotopes
accepted value experimental value
BEHAVIOR OF GASES % error (100)
accepted value
Ptotal = P1 + P2 + P3 + …
experimental yield
% yield (100)
PV = nRT theoretical yield
DRT m EQUILIBRIUM
MM n
P MM
For reaction aA + bB ↔ cC + dD:
P1 V1 P2 V2
n1 T1 n2 T2 K eq
C c D d
Rate = k[A]x[B]y
A a B b
SOLUTIONS
CONSTANTS AND CONVERSIONS
moles of solute (n)
Molarity (M) Avogadro’s Number = 6.022 x 1023 particles per mole
liter of solution
h = Planck’s Constant = 6.63 x 10‒34 J·s
V1M1 = V2M2
c = Speed of Light = 3.0 x 108 m/s
Kw = [H+][OH–] = 1 x 10‒14 (at 25°C)
STP = 0 °C and 1 atm
pH = – log [H+]
0°C = 273 K
pOH = – log [OH–]
Volume of Ideal Gas at STP = 22.4 L/mol
[H+] = 10 – pH
1 atm = 760 mm Hg = 760 torr = 101.33 kPa = 14.7 psi
[OH–] = 10 – pOH
ΔH = moles x ΔHfus ΔH = moles x ΔHvap 1000 calories (cal) = 1 Calorie (Cal) = 1 kilocalorie (kcal)
Electronegativity Values
H He
2.1 0
Li Be B C N O F Ne
1.0 1.5 2.0 2.5 3.0 3.5 4.0 0
Na Mg Al Si P S Cl Ar
0.9 1.2 1.5 1.8 2.1 2.5 3.0 0
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
0.8 1.0 1.3 1.5 1.6 1.6 1.5 1.8 1.8 1.8 1.9 1.6 1.6 1.8 2.0 2.4 2.8 0
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
0.8 1.3 1.2 1.4 1.6 1.8 1.9 2.2 2.2 2.2 1.9 1.7 1.7 1.8 1.9 2.1 2.5 0
Cs Ba •La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
0.7 0.9 1.1 1.3 1.5 1.7 1.9 2.2 2.2 2.2 2.4 1.9 1.8 1.8 1.9 2.0 2.2 0
Fr Ra §Ac
0.7 0.9 1.1
POLYATOMIC IONS TO MEMORIZE!
YOU MUST MEMORIZE NAME, FORMULA, AND CHARGE!
Polyatomic ions are groups of elements that, when bonded together, have a charge… meaning
electrons are either lost or gained. Polyatomic ions are very important in many of our units this
year! Therefore, it is very important that you learn them, and LEARN THEM WELL!!!
OTHERS:
MnO4—1 permanganate
C2H3O2—1 acetate
HCO3—1 hydrogen carbonate (bicarbonate)
CrO4—2 chromate
Cr2O7—2 dichromate
OH—1 hydroxide
CN—1 cyanide
NH4+1 (note positive charge) ammonium
NOTE: The charge can be shown either before or after the number… both are correct. Also, if a
charge is either +1 or –1, you may show just the sign (+ or –). The 1 is not required to be shown.
Solubility of Common Ionic Compounds in Water
SOLUBLE COMPOUNDS (aq) EXCEPTIONS (s)
All Group 1 salts None
All ammonium (NH4+1) salts None
All NO3−1, ClO3−1, ClO4−1, and C2H3O2−1 salts None
All Cl−1, Br−1, I−1 salts Ag , Hg2 (mercury (I)), Pb+2
+1 +2
All F−1 salts Mg+2 Ca+2, Sr+2, Ba+2, Pb+2
All salts of SO4−2 Ca+2, Sr+2, Ba+2, Pb+2, Ag+1, Hg2+2
INSOLUBLE COMPOUNDS (s) EXCEPTIONS (aq)
All salts of OH−1 Group I, NH4+1, Ba+2, Sr+2, Ca+2
All other monatomic and polyatomic anions Group I and NH4+1