Академический Документы
Профессиональный Документы
Культура Документы
S. Shanthakumar
Research Scholar, Dept. of Civil Engineering, Indian Institute of Technology Bombay, Mumbai, India
D. N. Singh
Dept. of Civil Engineering, Indian Institute of Technology Bombay, Mumbai, India
R. C. Phadke
General Manager, CHEMITHON Engineers Pvt. Ltd., Mumbai, India
ABSTRACT: Electrostatic precipitation is a well established technique to control the emission of particulate
matter (fly ash or dust particles) from coal-fired thermal power stations. Flue gas conditioning, FGC, is a
technique that involves addition of chemical agents to the flue gas in order to increase the collection efficiency of
the Electrostatic Precipitators, ESPs. Several efforts have already been made by earlier researchers to
characterize the fly ash from hoppers, to ascertain its suitability for various engineering applications. However,
how characteristics of the fly ash inside the ESP, from one location to another, change has not yet been
investigated in details. Such investigations would help in understanding the influence of flue gas conditioning on
functioning of ESPs. With this in view, attempts were made to characterize the fly ash collected at various
locations of the ESP unit of a power plant (viz., hopper, bottom portion, collection plate and Induced Draft (ID)
fan). The study brings out the influence of flue gas conditioning on overall characteristics of the fly ash.
1 Introduction
The population explosion and industrial growth are two traits of present day society, which require more electricity
generated form the coal-fired thermal power stations. However, the combustion of coal results in production of an
enormous quantity of the ash, which essentially constitutes of bottom- and fly-ash. The fly ash particles that are in
the form of suspension in the flue gas, which comes out of the power stations, contribute to an increased
suspended particulate matter, SPM. Hence, reduction in emission levels of the SPM becomes essential for
safeguarding the environment.
Electrostatic precipitation is a well established technique that employs application of electric field to separate out
the suspended particles (fly ash or dust) from the flue gas, which comes out of thermal power stations by
collecting it in hoppers (Navarrete et al., 1997; Parker, 1997; Kim and Lee, 1999; Bottner, 2003; Ray, 2004a;
Hanne et al., 2006). Previous studies reveal that the collection efficiency of the ash can be enhanced by resorting
to the flue gas conditioning, FGC, which deals with addition of different types of chemical additives (viz., sulphur
trioxide, ammonia, salts of sodium) and sprinkling of water to the flue gas, which alters the resistivity of the fly ash
and hence results in increased collection efficiency (Cheremisinoff, 1977; Brown et al., 1978; Harker and
Pimparkar, 1988; ACRL, 1998; Alvarez et al., 2000; Ray, 2004b). With ever growing emphasis on the utilization of
the fly ash, mainly in the cement and concrete, ceramic and electronic industries, researchers have conducted
several studies on characterization of the fly ash from hoppers (Joshi and Lohtia, 1997; Bayat 1998; Foner et al.
1999; Sear, 2001; Kiattikomal et al. 2001; Singh and Kolay, 2002; Pandian, 2004; Moreno et al. 2005; Das and
Yudhbir, 2006; Vassilev and Vassileva, 2007). However, how these characteristics of the fly ash get influenced
due to the flue gas conditioning, has not yet been investigated in details.
With this in view, an attempt has been made in this study to characterize the fly ash collected at various locations
in the Electrostatic precipitator (ESP) unit of a power plant in India. These locations correspond to hopper, bottom
portion, collection plate and Induced Draft (ID) fan of the ESP. Based on extensive investigations, it has been
demonstrated that how FGC influences the overall characteristics of the fly ash in the ESP.
2261
This power station is operated with dual flue gas conditioning system (ammonia and sulfur trioxide as the flue gas
conditioning agents). Ash samples from hopper were collected and mix together so as to create a representative
sample. Later, samples from different locations of the ESP, as depicted in Fig.1, were also collected during the
shutdown of the power station for maintenance work.
3
From
boiler
2 Stack
4
1
1. Hopper 2. Bottom portion 3. Collection plates 4. Induced Draft Fan
Details of these samples are presented in Table 1 and various analyses carried out to characterize these samples
are presented in the following.
Table 2 Physical and chemical characteristics of the samples used in the study
S pH EC (μS/cm)
Sample G 2
(m /g) L/S=10 20 10 20
HR 2.05 0.215 5.8 5.7 158 86
ESP Plate 2.27 0.389 4.9 5.0 579 333
ESP 2.36 0.432 4.5 4.8 1982 1004
ID 2.70 0.558 4.5 4.7 1910 1056
2262
HR ESP Plate ESP ID
110
100
90
80
70
60
% Finer 50
40
30
20
10
0
1E-3 0.01 0.1 1
Particle Size (mm)
Fig. 2 Particle size distribution of fly ash samples
Chemical composition of the fly ash, in the form of major oxides, was determined using an X-Ray Fluorescence
(XRF) setup, (Phillips 1410, Holland). Details of the sample preparation are presented in the following.
4 g ash sample, 1 g of microcrystalline cellulose and isopropyl alcohol were mixed thoroughly, and the mixture
was kept below an infrared lamp for slow drying. A small aluminum dish (with inner diameter of 33 mm and height
of 12 mm) was taken and one third of this dish was filled with methyl-cellulose, followed by filling up the container
by the dried sample. The sample was compressed with the help of a hydraulic jack and the chemical composition
of the sample was determined by mounting the compressed dish (pellet) in the sample holder of the XRF setup.
The results are presented in Table 3.
2263
Q - Quartz M - Mullite H - Hematite
2000 ID
Q
1500
H
1000 M MM HM
QQ Q
M
500
0
Q
ESP
2000
1500
Relative Intensity
H
1000 M Q MM H
Q M
500 Q QM Q Q
Q
2000 ESP plate
1500
1000 H
Q H
M MM M M M
500 QQ Q Q Q
0
Q
HR
2000
1500 Q
M H
1000 HM
MMQ Q Q Q M Q
500
0
0 10 20 30 40 50 60 70 80
Cu-Kα (2θ)
Fig. 3 X-Ray diffractograms of fly ash samples
2264
(a) (b)
(c) (d)
(e) (f)
2265
3.00 1.0
0.9
2.75
0.8
0.7
2.50
0.6
S (m /g)
2.25 0.5
2
G
0.4
2.00
0.3
0.2
1.75
0.1
1.50 0.0
HR ESP Plate ESP ID HR ESP Plate ESP ID
Fig. 5 Specific gravity of fly ash samples Fig. 6 Specific surface area of fly ash samples
pH of the solution prepared from the ash samples, decreases slightly as moving towards the farthest portion of
the ESP whereas, the electrical conductivity, EC, increases, as depicted in Fig. 7. Further, it can also be noted
from Table 3, that the chemical composition of ash samples (in oxide form) by X-Ray fluorescence studies
reveals that all the ash samples are having the major oxides (SiO2, Al2O3, Fe2O3) more than 70% and hence they
belong to Class F ash (ASTM C 618). The morphology of ash samples obtained by scanning electron
microscopy, as depicted in Fig. 4, reveals that the surface of most of the spherical particles has attached
microspheres. It can be observed from the figure that the fly ash samples contain mostly hollow spheres i.e.,
cenospheres (Fig. 4a). Some particles (from hopper) are irregular in shape which indicates the presence of
unburned carbon (Fig.4b). It also consists of broken spheres filled with smaller spheres i.e., pleurospheres (Fig.
4c). Also, Figs. 4(d) and 4(e) depict the effect of FGC on fly ash samples collected inside the ESP. It can be
observed that the particles get agglomerated due to the increase in cohesion. This results in collection of more
particles (mostly small in size) in the ESP and hence, the increase in collection efficiency, which in turns results in
less emission from the stack/chimney of the power stations. It can also be observed from Fig 4(f) that the
particles from ID fan of the ESP are the finest particles and hence exhibit much more agglomeration.
10000
10
L/S=10
L/S=10
L/S=20
9 L/S=20
7 1000
EC (μS/cm)
6
pH
4 100
1 10
HR ESP Plate ESP ID HR ESP Plate ESP ID
2266
4 Concluding Remarks
This paper presents details of the investigations conducted on fly ash samples, collected at various locations of
the ESP unit from a coal based power station in India, where dual flue gas conditioning is being practiced. The
study reveals that the ash characteristics vary from one location to another of the ESP unit. In addition, from the
SEM micrographs of the fly ash samples, agglomeration of the ash particles can be noted very clearly, which is
responsible for an increased collection efficiency of the ESP and hence reduction in SPM level. However,
extensive investigations should be conducted to establish relationships between various operational parameters
of the ESP units with physico-chemico-mineralogical and morphological characteristics of the conditioned ash.
5 Acknowledgements
The first author expresses his sincere gratitude to Mr. S. N. Trivedi, Managing Director, CHEMITHON Engineers
Pvt. Ltd., Mumbai, for his encouragement and support during the course of this study. The financial support
received from M/s. CHEMITHON Engineers Pvt. Ltd., Mumbai, for conducting this research, under CEPL
fellowship, is gratefully acknowledged.
6 References
ACRL. 1998. Electrostatic Precipitation of fly ash from Australian bituminous coal. ACARP Report. Australian Coal Research
Limited, Issue No.4, January 1998.
Alvarez E., Blanco J., Knapp C., Olivares J., Salvador L. 2000. Pilot plant performance of a SO2 to SO3 oxidation catalyst for
flue-gas conditioning. Catalysis Today, 59, 417-422.
ASTM C 204. 2005. Standard test method for fineness of Portland cement by air permeability apparatus. Annual Book of ASTM
standards. ASTM, West Conshohocken, PA (USA), Pages-10.
ASTM C 618. 2005. Standard Specofication for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete.
Annual Book of ASTM standards. ASTM, West Conshohocken, PA (USA), Pages-3.
ASTM D 422. 1963. Standard test method for particle size analysis of soils. Annual Book of ASTM standards, ASTM, West
Conshohocken, PA (USA), Pages-10.
ASTM D 5550. 2000. Standard test method for specific gravity of soil solids by gas Pycnometer. Annual Book of ASTM
standards. ASTM, West Conshohocken, PA (USA), Pages-4.
Bayat O. 1998. Characterisation of Turkish fly ashes. Fuel, 77, 1059-1066.
Bottner C. U. 2003. The role of the space charge density in particulate processes in the example of the electrostatic precipitator.
Powder Technology, 135-136, 285-294
Brown T. D., Lee G. K., Reeve J., Sekhar N. 1978. Improved electrostatic precipitator performance by use of fly ash
conditioning agents. Journal of the Institute of Fuel, December 1978, 195-198.
Cheremisinoff P. N. 1977. Advanced fly ash conditioning technology. Power Engineering, November 1977, 110-112.
Das S. K., Yudhbir. 2006. A simplified model for prediction of pozzolanic characteristics of fly ash, based on chemical
composition. Cement and Concrete Research, 36, 1827-1832.
Foner H. A., Robl T. L., Hower J. C., Graham U. M. 1999. Characterization of fly ash from Israel with reference to its possible
utilization. Fuel, 78, 215-223.
Hanne O., Timo N., Hannu K. 2006. Increase the utilisation of fly ash with electrostatic precipitation. Minerals Engineering, 19,
1596-1602.
Harker J. R., Pimparkar P. M. 1988. The effect of additives on the electrostatic precipitation of fly ash. Journal of the Institute of
Fuel, September 1988, 134-142.
JCPDS. 1994. Powder Diffraction File, 44, 7354-CD ROM (PDF 1- 44. International Centre for Diffraction Data, Pensylvania
(USA).
Joshi R. C., Lohtia R. P. 1997. Fly ash in concrete: production, properties and uses. Gordon and Breach Science Publishers,
Amsterdam, (The Netherlands).
Kiattikomol K., Jaturapitakkul C., Songpiriyakij S., Chutubtim S. 2001. A study of ground coarse fly ashes with different
finenesses from various sources as pozzolanic materials. Cement and Concrete Composites, 23, 335-343.
Kim S. H., Lee K. W. 1999. Experimental study of electrostatic precipitator performance and comparison with existing
theoretical prediction models. Journal of Electrostatics, 48, 3-25.
Morena N., Querol X., Andres J. M., Stanton K., Towler M., Nugteren H., Jurkovicova M. J., Jones, R. 2005. Physico-chemical
characteristics of European pulverized coal combustion fly ashes. Fuel, 84, 1351-1363.
Navarrete B., Canadas L., Cortes V., Salvador L., Galindo J. 1997. Influence of plate spacing and ash resistivity on the
efficiency of electrostatic precipitators. Journal of Electrostatics, 39, 65-81.
2267
Pandian N. S. 2004. Fly ash characterisation with reference to geotechnical applications. Journal of Indian Institute of Science,
84, 189-216.
Parker K. R. 1997. Applied electrostatic precipitation. Blackie Academic & Professional, London, (UK).
Ray T. K. 2004a. Air pollution control in industries – Volume 1: Theory, selection & design of air pollution control equipment.
Tech Books International, New Delhi, (India).
Ray T. K. 2004b. Air pollution control in industries – Volume 2: Application of air pollution control equipment. Tech Books
International, New Delhi, (India).
Sear L. K. A. 2001. The properties and use of coal fly ash. Thomas Telford Publishing, (London).
Singh D. N., Kolay P.K. 2002. Simulation of ash-water interaction and its influence on ash characteristics. Progress in Energy
and Combustion Science, 28, 267-299.
Vassilev S. V., Vassileva C. G. 2007. A new approach for the classification of coal fly ashes based on their origin, composition,
properties and behavior. Fuel, 86, 1490-1512.
2268