Time Concentration Finite (dC/dt) ln(Conc.

) ln(-dC/dt)
10 2.45 -0.081 0.896088025 -2.51330612
20 1.74 -0.061 0.553885113 -2.79688141
30 1.23 -0.043 0.207014169 -3.14655516
40 0.88 -0.0305 -0.12783337 -3.4900286
50 0.62 -0.022 -0.4780358 -3.81671283
60 0.44 -0.014 -0.82098055 -4.26869795

Polynomial (dCdt) ln(Conc.) ln(-dC/dt)

-0.0828 0.896088025 -2.49132722
-0.0611 0.553885113 -2.79524341
-0.0436 0.207014169 -3.13269813
-0.0303 -0.12783337 -3.49660757
-0.0212 -0.4780358 -3.8537541
-0.0163 -0.82098055 -4.11659017

Alpha 1 avg. k (Finite) 0.0341731982

avg. k (Polynomial) 0.0350048061

Polynomial Fit(1)

2.5
f(x) = - 0.0000075x^3 + 0.0014392857x^2 - 0.1087142857x + 3.4
2

1.5

0.5

0
0 10 20 30 40 50 60 70
0.5

0
0 10 20 30 40 50 60 70
 k
0.033061224 Finite Difference
0.035057471
-1 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6 0.8 1
0.03495935
0.034659091 f(x) = 1.0136767027x - 3.3775778631
-2.7
0.035483871
0.031818182

k -3.2
0.033795918
0.035114943
0.035447154 -3.7
0.034431818
0.034193548
0.037045455
-4.2

-4.7

Polynomial Fit (2)

-1.5
-1 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6 0.8 1

-2

87142857x + 3.4
-2.5
f(x) = 0.9707917151x - 3.3516060421

-3

-3.5

70

-4
 -3.5

70

-4

-4.5
T 350 360 370 380 390
X 0.013 0.04 0.103 0.219 0.827
Ca 1.974 1.92 1.794 1.562 0.346
-r 0.0001386667 0.0004266667 0.001098667 0.002336 0.008821333
k 3.5585886E-05 0.0001157407 0.000341367 0.000957438 0.0736855
ln(k) -10.24356147 -9.064157862 -7.98255348 -6.95124932 -2.60794924
1/T 0.0028571429 0.0027777778 0.002702703 0.002631579 0.002564103

ln(k2/k1) - 1.1794036066 1.081604379 1.031304166 4.343300076

1/T1-1/T2 - 7.9365079E-05 7.50751E-05 7.11238E-05 6.74764E-05
E/R - 14860.485443 14406.97033 14500.13657 64367.70712
E 123550.07597 119779.5513 120554.1355 535153.117

Arrhenius Plot
0
0.0024 0.00245 0.0025 0.00255 0.0026 0.00265 0.0027 0.00275 0.0028 0.00285 0.0029

f(x) = - 24443.9936008929x + 58.8527117981

-2

-4

-6

-8

-10

-12

Fitting Distribution
0
0.0024 0.00245 0.0025 0.00255 0.0026 0.00265 0.0027 0.00275 0.0028 0.00285 0.0029

-2
f(x) = - 24441.9580970777x + 58.8469925002

-4

-6

-8
 -2

-4

-6

-8

-10

-12
 400 410
0.883 0.92 Fitting Distribution by Excel Solver
0.234 0.16 E 203210.4396 Sum error
0.009418667 0.009813333 A 3.60516E+25
0.172011591 0.383333333
-1.76019342 -0.95885035 lnk -10.9871735 -9.04733555 -7.21235371
0.0025 0.002439024 error^2 0.552958841 0.00028299 0.593207693

0.847755825 0.80134307
6.41026E-05 6.09756E-05
13224.99087 13142.02634 Avg E/R 22417.05278
109952.5741 109262.807 Avg E 186375.3768
 5.09364771

-5.47394986 -3.82469493 -2.25790274 -0.76753944

2.182413684 1.480470067 0.247714574 0.036599861