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Isomerism
1. Define polymer.
2. Explain the Natural
coagulation process of
rubber
CARBON
latex when it is added COMPOUND
with formic acid.
2. Explain why 1. Define the
vulcanized rubber is homologous series of
stronger than natural alcohol
rubber. 2. Write the chemical
equation of combustion
Alcohol of propanol.
Fat 3. Describe a laboratory
experiment to produce
alcohol
Ester
Carboxylic acid
1. Define saturated fat
and unsaturated fat.
2. Stated the difference
between saturated fat
and unsaturated fat. 1. Define an ester. 1. Define carboxylic
3. What is the type of 2. Write the general acid.
reaction that changes formula of ester. 2. Write the equation
unsaturated fat to 3. Describe an involved in the
saturated fat? experiment to production of carboxylic
produce etil acid from propanol.
methanoic. 3. Explain why
methanoic acid cannot
conduct an electric
ORGANIC COMPOUND
Definition of carbon
compound
Examples
ORGANIC CARBON
Combustion of
COMPOUND
organic compounds
sebatian organik
Saturated Unsaturated
hydrocarbon hydrocarbon
s s
Compounds contain
Examples; carbon and come from
. organism (living thing). Examples:
Animal or plants Carbonate of metal,
Bicarbonate of metal,
Chemistry Module 2009 carbon dioxide, carbon
@ Hak Milik JPN Pahang monoxide, etc
3|Page
Examples:
Glucose,
Protein,
Fat, etc
ALKANE
4 C4H10 butane
10
1. Non soluble in
water
2. Non conductor of
electricity
Physical
Explanation to
properties and
General formula and the physical
the changes properties
group members
change.
ALKENE
n Molecular Name Structural
Formula Formula
10
1. Non soluble in
water
2. Non conductor of
General Physical electricity
formula General formula and properties and
group members the changes
Explanation to
CnH2n the changes
n = 2.3,4, … Homologous
Series ALKENE
1. Addition reaction
2. Combustion
Combustion in the air (oxygen) C2H4 + 3O2 2CO2 + 2H2O
Chemistry Module 2009
@ Hak Milik JPN Pahang
C4H8 + …… ……. + ……
5|Page
ISOMERISM
IUPAC
Example of isomer naming
Definition of isomerism
Instruction:
ISOMERISM 1. Specify the number of carbon
atom in the longest continuous
carbon chain.
2. Numbering carbon atoms with
1,2,3,… starting near functional
Isomer of an alkene (pentene)
IUPAC name of group /and branch..
isomer Isomer of alkane (hexane)
3. Branch names -CH3 , methyl
-CH2CH3, ethyl
ALKOHOL
Carbon compound CH3OH methanol
Misuse of the contained hydroxyl C2H5OH ethanol
alcohol and the functional group, OH C3H7OH propanol Physical
effect C4H9OH butanol properties and the
changes
downward series.
Fuel, solvent, Formula Am:
Medical aspect, CnH2n+ 1OH
Cosmetic aspect.. n = 1,2,3,… Naming
Definition
of alcohol
Usage of Homologous
alcohol series of alcohol
Chemical properties of
the ethanol
1. Combustion Ethanol
C2H5OH + O2 CO2 + H2O
2. Oxidation
2[O]
C2H5OH CH3COOH +
H2O Preparation In industry:
The physical properties of ethanol Steam + ethene
3. Dehydration of the ethanol
Alumina
C2H5OH C2H4 + H2O
Heat
7|Page
Ethene
Diagram
Water
Dehydration of ethanol
Carboxylic Acid
CnH2n+1COOH
n = 0,1,2,…
Preparation of
ethanoic acid
Ketertiban dalam CARBOXYLIC
siri homolog ACID
Physical properties of
the carboxylic acid
karboksilik
The usage of
carboxylic acid
Chemical properties
of ethanoic acid
0 2
CnH2n+1COOCmH2m+1
n = 0,1,2,…
m = 1,2,3,… 1 1
2 3
General formula
of ester
Diagram?
Molecular formula and
the name of ester
Homologous
series of ester Preparation
A group of
homologous series Definition
ESTER
with functional
group of carboxyl, Ethyl ethanoate
-COO- etanoat
Physical properties
Natural source
The ester daily life of the ester
usage To predict the
formation of the ester
FAT AND
OIL The fat molecule that built of
only singular covalent bond
…is an ester formed from between carbon atom in the The fat molecules that built of
glycerol (alcohol) and molecules. multiple bond between
carboxylic acid. carbon atom in molecules.
Definition
Definition
Examples: definition
Chicken’s fat,
? fat and oil. Cow’s fat,
Saturated Unsaturated
Etc. Contoh:
fat fat
Comparison
Type of fat
Fat Oil
Higher melting Lower melting Conversion of the
point (more than point (less than unsaturated fat to the
20oC) 20oC) saturated fat.
Solid at room Liquid at room FAT AND OIL
temperature temperature
Found in animals Found in plants
& human & fish
Production of margerine:
The effect of Hydrogenation process of unsaturated fat
fat on health (palm oil)
Palm oil
Ni
- C = C - + H2 -C – C –
The needed to H H
use palm oil Extraction process of Double bond single bond
palm oil in industry
R O R O R O R O
n H2N - CH - C - OH + H - N - CH – C - OH N - CH – C - N - CH – C - + nH2O
H H H n
Amino acid amino acid protein
(monomer) (monomer) (polymer)
NATURAL
Several polymer
RUBBER
Definition of and it’s monomer
natural polymer
Usage of
natural rubber Natural nC5H8 (C5H8)n
rubber Isoprene natural rubber
(monomer) (polymer)
Comparing the properties
of the natural and
vulcanized rubber
-- Explain Preventing Coagulating of
coagulation of the latex Experiment
latex
Vulcanization
of rubber. Definition
Latex is a colloid. It is a mixture of rubber particles
and water. A rubber particle is made up of negatively
charged protein membrane surrounds many rubber
Experiment: molecules. The negative charges are preventing the
1. Vulcanization of natural collision between molecules. When an acid is added to
rubber.
the latex, H+ from an acid is neutralized the negative
2. Comparison of properties
Chemistry
between Module 2009
natural and charge at protein membrane to allow the collision
@ Hakrubber
vulcanized Milik JPN Pahang between the rubber particles. The protein membrane
breaks, and then the rubber molecules are free to
clump together. Latex has coagulated
11 | P a g e
Diagram
ACTIVITIES 1
A. Analysing Alkanes
2.. Complete the table by writing the name , molecular formula and structural formula of alkanes.
________________________________________________________________________
________________________________________________________________________
a) C2H6 + O2
b) C5H12 + O2
6. Alkanes undergo substitution reaction with halogrns in the presence of ultra violet light.
CH4 + Cl2
ACTIVITIES 2
B. Analysing Alkenes
2 Complete the table below by writing the names, molecular formula and structural formula .
Number of
Molecular
Carbon atom per Name Structural formula
formula
molecule
3. Alkenes undergo addition reaction due to the presence of the double bonds.
a) Hydrogenation : C3H6 + H2
c) Hydration :
d) Oxidation :
4 . Polimerization : The process whereby small molecules are joined together to form large
molecules.
Alkanes Alkenes
General Formula
Bonding
Combustion
Physical properties
Chemical properties
Ethane-1,2-diol Poliethene
C2H4(OH)2
IV VI Ethanoic acid
CH3COOH
II I
Ethanea IX Ethyl ethanoate
C2H5Cl
Ethene VIII
C2H6 C2H4 VII CH3COOC2H5
III
X
V Ethanol
C2H5OH
1,2 dibromoethane
C2H4Br2
Carbon dioxide and
water
Write the balanced equation for the processes labeled above.
I VI
II VII
III VIII
IV IX
V X
Butane-1,2-diol Polibutene
C4H8(OH)2
IV VI
Butanoic Acid
C3H7COOH
II I
Butane Butene IX Butyl butanoate
C4H9Cl VIII
C4H10 C4H8 VII C3H7COOC4H9
III
X Butanol
V C4H9OH
1,2 dibromobutane
C4H8Br2
Carbon dioxide and
water
Write the balanced equation for the processes labeled above.
I VI
II VII
III VIII
IV IX
V X
propane-1,2-diol Polipropene
C3H6(OH)2
IV VI
Propanoic acid
C2H5COOH
II I
Propane Propena IX Propyl propanoate
C3H7Cl VIII
C3H8 C3H6 VII C2H5COOC3H7
III
X Propanol
V C3H7OH
1,2 dibromopropane
C3H6Br2 Carbon dioxide and
water
I VI
II VII
III VIII
IV IX
V X
1 What are the expected major products of the fermentation of glucose solution in the
presence of yeast?
5 Which of the following correctly describes the properties of both hexane and hex-1-ene?
A They are unsaturated hydrocarbons
B They readily decolourise bromine solution in tetrachloromethane
C They react with steam to give ethanol
D They burn completely to produce carbon dioxide and water
B Ethene D Isoprene
17 The chemical equation below represents the reaction between Butene and bromine.
Butene + Br2 → Y
H–C–C –C–C–H
Br H H Br
B H H H H
H–C–C –C–C–H
H Br H Br
C H H H H
H–C–C –C–C–H
Br Br H H
D H H H H
B
H – C – C – C – C – Br
H H H Br
20.
Propene Propanol Propanoic Acid
X Y
Two reaction schemes in the transformation of propene to propanoic acid are shown
above.Which of the following represents reactions x and y?
X Y
A Oxidation Addition
B Dehydration Oxidation
C Hydration Oxidation
D Dehydration Reduction
I Br
II
III
IV
A I dan II only
B I, II and III only
C II, III and IV only
D I, II, III and IV
22. Which of the following substance can be used to differentiate ethane from ethene?
23. What are the products formed when ethanol burns completely in excess air?
A Water and carbon dioxide gas
B Water, carbon and carbon dioxide gas
C Water, carbon monoxide gas and carbon dioxide gas
D Water, carbon, carbon monoxide gas and carbon dioxide gas
24. The following chemical equation shows the conversion of ethanol to ethane.
Piece of porcelain
A Dehydration B Oxidation
C Reduction D Fermentation
Which of the following are structural formulae and correct names for isomers of pent-1-ene?
I II
Pent-2-ene 3-methylbut-1-ene
IV
III
Pent-3-ene 2-methylbut-2-ene
A . I and IV only
B. II and III only
C. I, II and IV only
D. I, II, III and IV
n
Substance R Substance S
Br
’29. A liquid produced effervescence (pembuakan) when reacted with sodium carbonate solution.
What is the molecular formula of the liquid?
A. HCOOH B .CH3CH2OH
C . CH3COOCH3 D. CH3COONa
CH3COOH
Reaction I
C2 H5OH
Reaction II
C2H4
Reaction I Reaction II
A Esterification Dehydration
B Oxidation Dehydration
C Oxidation Esterification
D Dehydration Esterification
31. One hydrocarbon is found to contain 75.0% of carbon and 25.0% of hydrogen based on its
mass. The empirical formula of the hydrocarbon is
[Relative atomic mass: C, 12; H, 1]
A. C3H
B. CH3
C. CH4
D. C4H
32. Complete combustion of one mole of an alkane in excess oxygen produces 8 moles of
water. The alkane is
A. Pentane
B. Hexane
C. Heptane
D. Octane
Based on the IUPAC system, what is the name of the compound having this structural
formula?
A. 3-methylpent-1-ene
B. 3-ethyl-3-methylbut-1-ene
C. 3,3-dimethylpent-4-ene
D. 3,3-dimethylpent-1-ene
A Protein
Protein
B Cellulose
Selulosa
C Polyethene
Polietena
DIAGRAM 8
RAJAH 8
What is the name of the hydrocarbon?
Apakah nama hidrokarbon itu?
A pent-2-ene
pent-2-ena
B 2-methylbut-2-ene
2-metilbut-2-ena
C 3-methylbut-2-ene
3-metilbut-2-ena
D 1,1-dimethylprop-1-ene
1,1-dimetilprop-1-ena
36 Polymerization occurs when many small molecules combined to form a long chained molecule
(polymer).
Diagram 16
Which of the following represents the structure of a polymer formed when these small molecules
are linked together?
A C2H5COOC2H5
B C3H7COOC2H5
C C3H7COOCH3
D CH3COOC3H7
A CH3CH=CHCH3
B CH3CH=C(CH3)2
C (CH3)2CHCH=CH2
D CH3CH2CH=CH2
STRUCTURE QUESTIONS
1. Diagram 2 shows the formation of compound X from glucose and its conversion to several
other carbon compounds.
Gambar rajah 2 menunjukkan penghasilan sebatian X dan perubahannya kepada
sebatian karbon lain.
Process I Process II
[Proses I] Compound X [Proses II]
Glucose [Sebatian X] Compound Y
[Glukosa] C2H6O [Sebatian Y]
...........................................................................................................................................
........
[1 mark]
(b) Compound Y is formed when the vapour of compound X is passed over heated porcelain
chips in Process II.
Sebatian Y terbentuk apabila wap sebatian X dialirkan melalui serpihan proselin yang
panas dalam Proses II.
(i) Write the general formula for the homologous series of compound Y.
Tuliskan formula am bagi siri homolog untuk sebatian Y.
................................................................................................................................
[1 mark]
(ii) Suggest a chemical test to identify compound Y.
Beri satu ujian kimia untuk mengenalpasti sebatian Y
…...............................................................................................................................
.......................................................................................................................................
[2 marks]
(d) Compound Z liberates carbon dioxide gas when calcium carbonate is added to it.
Bahan Z membebaskan gas karbon dioksida apabila kalsium karbonat dicampur
kepadanya.
..........................................................................................................................................
...... [1 mark]
(ii) Write a chemical equation for the conversion reaction in Process III.
Tuliskan persamaan seimbang untuk tindak balas yang berlaku dalam Proses III
..........................................................................................................................................
[1 mark]
................................................................................................................................................
[1 mark]
(e) Describe briefly the method of preparing ethyl propanoate from compound X in the
laboratory.
Secara ringkas terangkan kaedah penyediaan etil propanoat dari sebatian X dalam
makmal.
...............................................................................................................................................
...............................................................................................................................................
.
[2 marks]
ANSWER FOR Q 1
fermentation 1 .......1
1 .......1
(c) (i) [able to write the general formula for the homologous series of
compound Y]
CnH2n
1 .......1
(e) [able to identified the reagent and describe briefly the method of
peparing ethyl propanoate from compound X]
Total 10
2 Diagram 6.1 shows the changes of a carbon compound involving a series of reaction.
Rajah 6.1 menunjukkan perubahan suatu sebatian karbon yang melibatkan beberapa siri tindak
balas.
Porcelain
Chips
Serpihan
Butanol porselin Butene H2 Butane
Butanol Heat Butena Heat Butana
Panas Panas
Diagram 6.1
Rajah 6.1
..........................................................................................................................................
[1 mark]
[2 marks]
Procedure Observation
Prosedur Pemerhatian
Table 6
Jadual 6
..........................................................................................................................................
..........................................................................................................................................
[2 marks]
(d) Butene reacts with hydrogen to produce butane. Write the chemical equation of the
reaction.
Butena bertindak balas dengan hidrogen untuk menghasilkan butane.
Tuliskan persamaan kimia bagi tindak balas ini.
..........................................................................................................................................
[2 marks]
(e) Butene can be obtained from the reaction of butanol through dehydration process.
Draw a labeled diagram of the set-up of the apparatus for the experiment.
Butena boleh didapati daripada tindak balas butanol melalui proses penghidratan.
Lukis gambar rajah berlabel susunan radas untuk eksperimen ini.
2 marks]
Soot
Jelaga
Filter paper
Kertas turas
Porcelain dish
Mangkuk pijar
Hexane Hexene
Heksana Heksena
Diagram 6.2
Rajah 6.2
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
[2 marks]
NO ANSWER MARK
6 (a) C4H10 1
(b)
1
(c) - Butene is an unsaturated hydrocarbon/ has double
1
bond
- Butane is a saturated hydrocarbon/ has single bond
1
(d) C4H8 + H2 C4H10
1
- correct reactants and products
- balanced equation
(e)
Glass wool soaked with
Porcelain chips
butanol
Butene
Heat Heat
1
Water 1
1
- Functional diagram 1
- Labelled diagram
Total
(f) Hexene produced more soot
% of carbon in one molecule of hexene higher than in hexane
9 (a ) (i) Explain by naming an example each, the meaning of saturated hydrocarbons and
unsaturated hydrocarbons.
Dengan menamakan setiap contoh, terangkan maksud hidrokarbon tepu dan
hidrokarbon tak tepu
[4marks]
Unsaturated hydrocarbon can be converted into saturated hydrocarbon.
(ii) State the process and the condition needed
Write the chemical equation involved.
Hidrokarbon tak tepu boleh ditukarkan kepada hidrokarbon tepu.
Nyatakan proses dan keadaan yang diperlukan
Tuliskan persamaan kimia yang terlibat.
[4marks]
By using an example describe the properties of carboxylic acid. Include your answer with
chemical equation.
Dengan menggunakan contoh, terangkan sifat-sifat asid karboksilik.
Sertakan persamaan kimia dalam jawaban anda.
[8 marks]
No Answer Marks
9 (a) SaturateUnsaturated hydrocarbons – hydr d hydrocarbons – hydrocarbons that
(i) contain only carbon-carbon single bonds or single covalent bond. 2
Example : hexane
c) carboxylic acid reacts with carbonate to produce salt, carbon dioxide and 2
water
2CH3CH2OOH + ZnCO3 Zn(CH3CH2O)2 + H2O + CO2
( any example) ( any carbonate)