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Editors
Zohaib Khurshid
B.D.S, MRes (Biomaterials),
MFGDP (UK), FICD (USA),
FPFA (USA), MADM (USA), MIADR
Prosthodontics and Implantology, College of Dentistry,
King Faisal University, KSA
Zeeshan Sheikh
Dip.Dh, BDS, M.Sc, Ph.D
University of Toronto,
Lunenfeld-Tanenbaum Research Institute
Mt. Sinai Hospital, Toronto, Canada
Co-Editor
Muhammad Sohail Zafar
B.D.S, M.Sc (Dental Material), Ph.D (Dental Materials),
FICD (USA), FADI (USA)
Associate Professor of Dental Biomaterials
College of Dentistry, Taibah University, Saudi Arabia
Visiting Professor, RIPHAH International University, Islamabad.
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted
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This book is sold subject to the condition that it shall not, by way of trade or otherwise, be lent, resold, hired out or
otherwise circulated without the publisher’s prior consent in any form of binding or cover other than that in which it
is published and without a similar condition including this condition being imposed on the subsequent purchaser.
Medical knowledge is constantly changing. As new information becomes available, changes in treatment,
procedures, equipment and the use of drugs become necessary. The editors, contributors and the publishers
have, as far as it is possible, taken care to ensure that the information given in this text is accurate and up-to-date.
However, readers are strongly advised to confirm that the information, especially with regard to drug usage,
complies with the latest legislation and standards of practice. Neither the publisher nor the authors assume any
responsibility for any loss or injury and/or damage to person or property arising out of or related to any use of the
material contained in this handbook.
Copyright © 2018
All Rights Reserved
Second Edition...........................2014
Third Edition...............................2018
ISBN: 978-969-637-440-4
Printed in Pakistan
DEDICATION
My Late Grandfather Dr. Munawar Alvi
My Parents and Family
PREFACE TO SECOND EDITION
Dentists will be authorized and legalized end-users of dental materials, both as students and after
graduation. During undergraduate studies, it is essential that dental materials should be taught so as to
enhance understanding of their properties and clinical uses. There are still a few challenges in this respect;
not all the dental schools have dental biomaterial science as an independent status in the curriculum. In
too many cases, the facilitation is provided by colleagues lacking commitment. Clinical procedures of
operative dentistry may be thoroughly taught but little attention is paid to the actual material properties.
It may remain unexplained what is then so special regarding certain materials that they are more often
used clinically. What does actually happen during setting of say restorative filling materials and luting
cements? We never should overlook the significance of adhesion, its applications and understanding in
contemporary dentistry.
In the retail market we have a plethora of dental textbooks with varying contents and perspectives. All of
them certainly serve well today. For a dental educator one of the problems is selecting the most appropriate
book to serve in dental facilitation. Should it cover all basic sciences behind? Hardly. Would it need delve
into the physio-chemical theories? I doubt-as we may leave such aspects for post-graduate levels. Would
we then need some fresh faces to contribute for a totally new textbook in dental biomaterials? I believe a
justified answer is: yes, this is needed.
I was both surprised and pleased when Lecturer Dr Zohaib Khurshid (of Fatima Jinnah Dental College,
Karachi, Pakistan) contacted me. For those who don’t know, he has already earned a feather to his cap by
having published a dental textbook “Dental Materials–Principles and Applications”, 1st edition, in 2010.
He invited me to contribute a chapter on dental silver amalgam to his textbook “Dental Biomaterials–
Principles and Applications”- 2nd edition. This kind invitation I accepted with great content. In addition,
the two editors of this book, Dr. Zohaib and Dr. Zeeshan Sheikh, have invited a team of contributors
representing a dynamic, expanding generation of tomorrow’s dentists from Pakistan, Canada, Saudi-
Arabia, Serbia, USA, Europe and UK. This said, we could see and conclude from the table of contents of
this book that it provides the undergraduate readers with sufficient basics of dental biomaterials.
After being introduced to dental materials and dental biomaterials, readers of “Dental Materials–Principles
and Applications” may gain a fresh insight of biomaterials in implant dentistry, endodontics, nanomaterials
in dentistry, dental silver amalgam, resin composites, dental cements and bone replacement materials.
Procedures at dental laboratories and clinics are sufficiently covered as well as dental polymeric, metallic
and ceramic materials.
I feel privileged to write this preface to the book Dr. Zohaib Khurshid and Dr. Zeeshan Sheikh have
successfully edited. The outcome of a laborious team of dental professionals and experts has now
materialized. Let me conclude by saying that Dr. Zohaib and Dr. Zeeshan are to be congratulated with
their contributing team for this cornerstone outcome in dental education and modern learning. I am
convinced that you, the reader, will agree with me, and I am confident that this book will find wide use
not only in Asia but globally.
October 17, 2013, Hong Kong, PR China
1
Dental Material
Zohaib, Sohail and Zeeshan
GOAL OF DENTISTRY
Maintain or improve the quality of life of dental
patients by preventing disease, relieving pain,
improving mastication efficiency, enhancing
speech and improving the general appearance of
patients.
Fig. 1.1: Lab analysis.
BRANCHES OF DENTISTRY
TYPES OF MATERIALS
ASSOCIATED WITH THE SUBJECT
Preventive Materials Restorative Dentistry
Sealants, liners, bases • Branch of dentistry that deals with the pre-
vention and treatment.
Restorative Materials
Silicate, GIC, composites, metallic inlays • Deals with the restoration of original func-
tion and color of natural teeth.
Auxillary Materials
Prosthodontics
Impression materials, casts, waxes
• Branch of dentistry that deals with the
OBJECTIVES OF THE DENTAL replacement of function and aesthetics.
BIOMATERIAL SCIENCES ARE TO • Three types of appliances are:
• Know the proper usage of dental materials ˚ Fixed Partial Denture
• Know the physical and chemical properties Replacement of a single tooth or a seg-
of dental materials ment of teeth.
1
Characterization of Biomaterials Chapter
2
in Relation to Dentistry
Faaz and Zohaib
Materials Characterization
During Storage
(before use)
Shelf life
3
Chapter
3
Gypsum Products in Dentistry
Maria, Zohaib and Sohail
Fig. 3.1: Showing crystal form of gypsum. Fig. 3.2: Dental cast.
11
Chapter
4
Dental Waxes
Fahad
27
Chapter
5
Investment and Refractory Dies
Zohaib and Maria
Fig. 5.1: Showing packing of acrylic. Fig. 5.2 (a): Showing investment procedure.
35
Application of Metals and Chapter
6
Alloys in Dentistry
Faaz, Adeel and Zohaib
Classification of Metals:
Metals
Alkaline - Rare -
Actinide Alkali Noble Rare Transition
earth earth
41
Casting Procedure for Dental Chapter
7
Alloys
Maria, Zohaib and Adeel
CASTING
Casting is the process by which a wax pattern of
a restoration is converted to a replicate in a dental Molten
alloy (Fig. 7.1). The casting process is used to make alloy
dental restorations such as inlays, onlays, crowns,
bridges and removable partial dentures (Fig. 7.2).
In dentistry, all casting is done using same form
or adaptation of the lost wax technique. The lost
wax technique has been used for centuries but Mould
its use in dentistry was not common until 1907 Asbestos
when W.H. Taggart introduced his technique subst. liner
with the casting machine. Investment
Metallic ring
The process consists of surrounding the wax pat-
tern with a mold made of heat resistant invest-
ment material, eliminating the wax by heating
Fig. 7.1: Illustration showing the procedure of casting.
and then introducing molten metal into the mold
through a channel called sprue. In dentistry the
resulting casting must be an accurate reproduc-
tion of the wax pattern in both surface details and
overall dimension. Small variation in investing or
casting can significantly affect the quality of the
final restoration. Successful castings depend on
attention to detail and consistency of technique.
An understanding of the exact influence of each
variable in the technique is important so rational
decisions can be made to modify the technique as
needed for a given procedure.
Fig. 7.2: Porcelain fused to metal crown.
STEPS IN MAKING A CAST • Attachment of sprue former
RESTORATION • Ring liner placement
Following are the Steps of Making Metal • Investing
Crown • Burn out or wax elimination
• Tooth/teeth preparation • Casting
• Impression • Recovery
• Model pouring • Pickling
• Wax pattern fabrication • Polishing
69
Dental Implants and Their Chapter
8
Surface Modifications
Shariq and Prof. Jukka PM
INTRODUCTION
A dental implant is a metallic prosthesis that Dental implant
functions as a root for supporting artificial teeth
to replace missing or lost dentition (Fig. 8.1). Replacement
Over one million dental implants are placed Natural crown
every year. An implant is in direct contact with tooth
Abutment
the alveolar bone. The idea of placing ‘prosthe- Gums
ses’ such as shells into the jaw bone dates back to
the ancient Mayan civilization; archeological ex-
cavation sites have led to the discovery of human
jaw bone with tooth-shaped shells embedded in Root
it. The concept of modern implantology was dis- Implant
covered rather accidentally by P. I. Brånemark.
While conducting research on bone regenera- Bone
tion around titanium chambers inserted in rabit
femurs, he noticed that after several months he
was unable to remove them. He later developed
an implant system which could be used to sup-
port dental prostheses. The requirements of Fig. 8.1: Comparison between a dental implant (right)
dental implants are: biocompatibility, stability, and a natural tooth (left).
acceptable function and ease of manufacture.
Prior to the introduction of the Brånemark cell adhesion proteins. Surface characteristics
implant system, sub-periosteal implants were such as wettability and charges affect the quali-
used. Sub-periosteal consisted of a cobalt-chro- ty of absorption of these proteins onto the im-
mium framework resting over the bone under plant. Cells then interact with these proteins to
the oral mucosa. This design is now outdated adhere to the implant surface. Similarly in bone
and has been replaced by osseointegrated dental tissue, osteoblasts, the bone forming cells, are
implants. Another older type of implant is the laid down onto the implant surface and conse-
blade-vent implant. In these implants, one end quently, there is a direct bone-implant interface
of the implant (the blade) is inserted into the formed. This interface is known as osseointegra-
bone whilst the other end projects through the tion. If there is a loose connective tissue formed
mucosa into the oral cavity. These implants carry instead of a bone-implant interface, the implant
a very high risk of infection and ultimately, im- fails. osseointegration is the main factor that dic-
plant failure. tates the success of dental implants. According
to Brånemark, osseointegration depends on the
OSSEOINTEGRATION quality of the bone, surface morphology of the
When any biomaterial is inserted into the liv- implant, the implant material, surgical technique
ing tissue, almost immediately, it is covered by employed to place the implant and the design of
79
Application of Polymer Chapter
9
Technology in Dentistry
Maria, Zohaib and Sohail
INTRODUCTION
Polymer science or macromolecular science is Nowadays, synthetic polymers have been wide-
a subfield of materials science concerned with ly used in both restorative and prosthetic den-
polymers, primarily synthetic polymers. The tistry for over five decades, and used in medical
field of polymer science comprises three main disposable supplies, dental materials, implants,
sub-disciplines. dressings, bleaching tray, extracorporeal devices,
Polymer chemistry or macromolecular chem- encapsulants, polymeric drug delivery systems,
istry which deals with the chemical synthe- tissue engineering scaffold, and brackets in or-
sis and chemical properties of polymers or thodontic treatment.
macromolecules. Applications for acrylic polymers based on func-
1. Polymer physics is concerned with the bulk tional methacrylate, include dentures, (Fig. 9.2
properties of polymer materials and engi- and 9.3) restorative materials, relining and repair
neering applications. material, soft liners, bonding agents, temporary
2. Polymer characterization is concerned with crown and bridges. Elastomeric materials such
the analysis of chemical structure and mor- as silicones, polysulphides and alginates are used
phology and the determination of physical for recording impressions of the hard and soft
properties in relation to compositional and oral tissues, which are then utilized for con-
structural parameters. structing appliances outside the mouth. Water-
soluble polymers are used in adhesive dental
3. Polymers (poly = many, mer = unit) are cements. Polymer composites an important part
made by linking small molecules (mers) of restorative dentistry, at present is the material
through primary covalent bonding in the main with the widest range of indications and is vital
molecular chain backbone with C, N, O, Si, to modern dentistry.
etc (Fig. 9.1). Polymers have a major role in
most areas of dentistry.
85
Chapter
10
Dental Impression Materials
Zohaib and Sohail
INTRODUCTION
Those materials that are used to take impression
of teeth and surrounding structures of oral cavity
for making accurate prosthesis of the patient.
How do we use impression material?
D. Pour Model
The model is poured with dental stone plaster.
For examination of oral tissues or for making
prosthesis e.g. Partial denture, crown and bridge.
105
Chapter
11
Ceramic Products in Dentistry
Zohaib and Sohail
INTRODUCTION
CLASSIFICATION OF DENTAL
PORCELAIN
Dental porcelain can be classified as follow:
1. ACCORDING TO FIRING
TEMPERATURE
• High fusing-1300 °C
• Medium fusing-1100-1300 °C
(a) • Low fusing–850 °C
• Ultra low fusing–less than 850 °C
2. ACCORDING TO TYPES
• Feldsphatic porcelain
• Aluminous porcelain
• Cast glass ceramic
• Lucite reinforced
• Glass infiltrate
(b)
129
Chapter
12
Dental Amalgam
Prof. Jukka PM
INTRODUCTION Examples
Some dental materials are used to restore Restorative dental materials can be classified as
diseased (caries, secondary caries), traumatized (a) direct and (b) indirect materials.
(incl. wear) or lost teeth, or neighboring tooth Direct restorative materials, such as resin-based
structures (and tissues), and rehabilitate biting composites (resin composites, filled resins), den-
functions. tal silver amalgam and glass ionomer cements
Dental materials can be classified as restorative (GIC), are used directly inside the oral cavity in
materials, preventive materials and auxiliary ma- a plastic form which will then set to restore the
terials. On the other hand, any material that is function of teeth.
used for the above described purpose may be re- Provisional (temporary) dental materials are used
garded as a biomaterial. for a limited planned period of time, usually
a few days or a few weeks. It may be necessary
IDEALLY RESTORATIVE DENTAL for the dentist to decide the definitive treatment,
MATERIALS SHOULD BE such as in the case of very deep cavities. In such a
• Inert case the application of zinc oxide (ZnO) eugenol
cement (ZOE) as a temporary filling material
• Biocompatible
may be used. Also, a prepared tooth may need
• Non-irritant to be covered with an acrylic temporary crown
• Non-cytotoxic before the definitive crown is prepared by the
• Not carcinogenic or mutagenic dental laboratory.
• Not appreciably soluble in oral fluids
DENTAL SILVER AMALGAM
• Dimensionally stable
An amalgam is an alloy that contains mercury
• Possessing adequate biomechanical (Hg) as one of its constituents. Mercury is a
properties liquid metal at room temperature.
• Acceptable to patients Dental silver amalgam has been the most com-
• Cleansable monly used direct restorative filling material hav-
• Indistinguishable from natural tissue ing served for more than 160 years. It is a perma-
• Long lasting when a permanent restoration nent restorative material mainly used to restore
done cavities of decayed permanent posterior teeth. It
is has been a very effective and economical re-
• Induce fast healing process (if relevant)
storative material over a long time. Its challenges
• Possessing adhesion to tooth tissues (if may be related to its appearance and while some
relevant) have expressed doubts about its safety, there
• Osteoconductive and capable of osseointe- are no substantiated problems. One of the cur-
gration (if relevant) rent aspects in the discussion is whether resin
139
Dental Resin-Based Composite Chapter
13
Chemistry and Its Uses
Zohaib and Samina
145
Glass Ionomer Cements and Chapter
14
Their Modifications
Zohaib and Sohail
INTRODUCTION CLASSIFICATION
Glass ionomer restorative materials are hybrids Types and their uses:
of silicate and polycarboxylate cements. It Type I: For luting cast restorations and ortho-
consists of interpenetrating network of inorganic dontic bands
and organic components forming a matrix in Type II(A): Aesthetics restorative cements, used
which particles of unreacted glass are embedded for class III and class V cavities
(Fig. 14.1).
Type II(B): Reinforced restorative material,
Polycarboxylate were developed several years mainly used for core build up
earlier and were the first dental cements for
1. Miracle mix–GIC powder + Ag amalgam
which an inherent adhesion to tooth substance
alloy powder
could be demonstrated. In late 1960s Glass-
ionomer became available as a result of the pi- 2. Class cermet–GIC powder + pure Au/Ag
oneering studies of Alan Wilson and Brian Kent (mostly Ag), also known as ketac silver
at the Laboratory of the Government Chemist, Type III: Lining cement, base
London. Commercial dental cements of this Type IV: Visible light activated liners/bases
type were launched in 1975, though these had
Type V: Glass1 ionomer for stabilization and
very inferior properties compared with the ma-
protection
terials available today.
Type VI: Atraumatic Restorative Technique(ART)
When zinc oxide of the polycarboxylate material
in anterior teeth
was replaced by a reactive ion leachable glass
similar to that used previously in silicate cements Type VII: High viscous/condensable glass iono-
a storage, less soluble and more translucent mers, ART for posterior teeth
cement could be produced.
SUPPLIED AS
• Powder and liquid
• Powder mixed with water
• Encapsulated form
159
Chapter
15
Dental Adhesive Systems
Vesna Miletic
INTRODUCTION COMPOSITION
Dental adhesive systems form an intermediate Dental adhesives consist of resin monomers,
layer between the tooth and restoration, effec- solvents, initiators, stabilizers and may contain
tively bonding a resin-based restorative material fillers. There are three categories of resin mon-
or cement and hard dental tissues, enamel and omers: functional, cross-linking and intermedi-
dentine. Dental adhesives are based on a blend of ary monomers. Functional monomers contain
resin monomers, mostly methacrylates and di- at least one acidic group, -COOH or –H2PO3.
methacrylates. Adhesion to enamel and dentine Their primary role is interaction with Ca ions
is primarily based on “micro-mechanical inter- from hydroxyapatite that leads to demineralisa-
locking” through superficial demineralisation of tion. Functional monomers are also responsible
enamel and dentine followed by adhesive infil- for enhanced wetting and promoting adhesion
into the substrate. Polymerizable methacrylate
tration into the demineralised tissue [1] though
groups (C=C) allow functional monomers to
certain monomers are able to chemically bond
become part of polymer chains. The so-called
to hydroxyapatite [2]. This inter-phase formed
spacer groups between the methacrylate and
by adhesive resin and tooth tissue is called the
acidic groups affect properties such as acidi-
“hybrid layer” [3]. On the other side, the adhe- ty, hydrophilicity, hydrolytical stability. Among
sive forms covalent bonds with monomers in the most common functional monomers are
resin-based composite or cement. Similarly to HEMA, 4-META, 10-MDP, Phenyl-P1.
resin-based composites, adhesives too harden
Cross-linking monomers are mostly dimeth-
through the process of polymerization which
acrylates, such as BisGMA, UDMA, TEGDMA
may be light-or chemically-initiated. Most con-
and BisEMA2, which contain two polymerizable
temporary adhesives belong to the light-cured methacrylate groups (C=C). During polym-
rather than chemically-cured materials. Some erization, these monomers form cross-linked
adhesives contain both photo-initiators and polymers which are responsible for mechanical
chemically curing initiators and are referred to as properties of the adhesive [4]. Cross-linking
dual-cured adhesives. monomers are well solvated in organic solvents,
Dental adhesives are often referred to as “dentine ethanol and acetone, and only limitedly in water
bonding agents” or “dentine adhesives”. This due to their hydrophobic nature. Cross-linking
terminology most likely originates from the monomers are often used in conjunction to
scientific focus being on dentine bonding which • HEMA-2-hydroxyethyl methacrylate; 4-ME-
remains to be a challenge as oppose to enamel TA-4-methacryloyloxyethyl trimellitate an-
bonding which proves to be reliable and durable hydride; 10-MDP-10-methacryloyloxydecyl
following phosphoric acid etching and adhesive dihydrogenphosphate; Phenyl-P-2-(methacry-
loyloxyethyl)phenyl hydrogenphosphate
application. Since the adhesives are applied to
• BisGMA-bisphenol A diglycidyl methacrylate;
enamel as well as to dentine, the term “dental UDMA-urethane dimethacrylate; TEGDMA-
adhesive system” or “dental adhesive” is more triethyleneglycol dimethacrylate; BisEMA-
appropriate. ethoxylated bisphenol A glycol dimethacrylate
169
Dental Cements Chapter
LINING MATERIALS
Certain filling materials are not suitable for
placing directly into a freshly prepared cavity.
Fig. 16.1: Diagram illustrating the way in which a
In such circumstances, a layer of cavity lining
cavity lining protects the dental pulp.
material is placed in the occlusal floor of the
cavity, and on the pulpal axial dentine wall for
A. Thermal Barrier
class II cavities, prior to placement of the filling.
The cavity lining or base is often expected to form
REQUIREMENTS a thermally insulating barrier in order to protect
the pulp from sudden intolerable changes in
Depends on the temperature. A thermally insulating cavity lining
a. Depth of the cavity is particularly required when a metallic filling,
b. Thickness of residual dentine such as amalgam is used because the thermal
c. Type of filling material diffusivity value for amalgam is about 40 times
greater than that for dentine.
PURPOSE OF LINING OR BASE
a. To acts as a barrier between the filling mate- 1. In deep cavities
rial and the dentine which, by virtue of the • Having only a thin residual layer of dentine,
dentinal tubules, has direct access to the sen- and there is a danger of “thermal shock” to
sitive pulp the pulp when the patient takes hot or cold.
183
Hybridization VS.
Chapter
Biomineralization: An Evolution
for Dental Restorations
John C. Comisi 17
ABSTRACT the creation of a long term beneficial method to
In the early 1980’s the dentin hybridization model bring the dentition back to function and health.
was proposed. It was described as a bioengineered In this chapter we will focus on the benefits and
tissue integration of resin into the living dentin challenges presented to us each day with the
of the tooth. Over the following years there utilization of resin bonding adhesive restorations
have been generations of dentin hybridization and look at the evolution currently going on that
adhesives created to attempt to overcome the is looking at a way to with the use of bioactive
shortcomings of the previous generations or to materials create biomineralization and enable
attempt to make the process easier for clinical our materials to work with nature not have the
application. However, it has been determined natural protective mechanisms of the tooth
that the average life span of typical resin bonded essentially “reject” our attempts to help the tooth.
composite restorations is 5.7 years at a cost of
approximately five billion dollars annually in 2. THE HISTORY OF ADHESION
the United States alone. Various agents have While at Eastman Dental Dispensary in
been proposed and subsequently used in an Rochester, NY (now the Eastman Institute
attempt to create more long lasting hybrid for Oral Health), Dr. Michael Buonocore [1]
bonds. However, it has been stated that the use had a paper published in the Journal of Dental
of these agents applied either separately or mixed Research entitled “A simple method of increas-
with the primer/adhesive agents appear to only ing the adhesion of acrylic filling materials to
retard rather then prevent bond degradation. It enamel surfaces”. At that time there was a need
is obvious that a different pathway needs to be get the acrylic fillings of that time to adhere to
traveled and it is proposed the use of bioactive/ the tooth surface. He proposed the use of an acid
biomineralization integrating materials could be etch technique to enable this to occur. He stated:
the direction to success. “A filling material capable of forming strong
bonds to tooth structures would offer many
1. INTRODUCTION advantages over present ones. With such a
The restoration of dental tooth structure material, there would be no need for retention
after it has been damaged by dental caries or and resistance form in cavity preparation, and
trauma has been the goal of the profession of effective sealing of pits, fissures, and beginning
well over one hundred years. Over this time various lesions could be realized.”
the procedures performed have evolved from This was the first step in attempting to create a
extraction of the tooth, to the placement of cast better adherence to the tooth structure: a way
gold restorations, direct gold foil restorations, of working so that a non-mechanical intimate
amalgam restorations, porcelain jacket crowns, interface could be created. Dr. Ray Bowen [2],
porcelain fused to metal crowns and finally to in 1963, noted that there was a need to improve
the use of glass ionomer restorations, bonded the materials being used (silicate cements and
adhesive restorations and pressed and milled self cure methyl methacrylates), so that those
ceramics and zirconia. The ultimate goal being materials would have less solubility, sensitivity to
199
Regenerative Dentistry Chapter
213
Degradation and Durability of Chapter
19
Resin-Dentine Hybrid Layers
Jonathan Dixon and Salvatore Sauro
219
Chapter
20
Introduction to Partial Denture
Shujah
231