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OXYGEN DEMAND
env20:
introduction to environmental
engineering
oxygen
equivalent of
organics
BODt L0 1 e kt
7
BOD Kinetics
A midnight dumper discharged a tank truck full of industrial
waste in a gravel pit. The truck was spotted there 3 days
SP2
ago, and a pool of pure waste remains. A laboratory
technician determined that the waste has a 5-day BOD of 80
mg/L with a rate constant of 0.1 per day. Three factories in
the vicinity generate organic wastes: a winery (ultimate
BOD=275 mg/L), a vinegar manufacturer (ultimate BOD=80
mg/L) and a pharmaceutical company (ultimate BOD=200
mg/L). Determine the source of the waste.
8
Laboratory Determination of BOD
▫ special BOD bottle (300 mL) made of special
nonreactive glass with a glass stopper with lip
to create a water seal
▫ dark
▫ 20C
▫ 5 days
BOD I F Dil
bottle volume
Dil
sample volume
9
Dilution Estimation
▫ at least 2 mg/L DO remaining
▫ at least 2 mg/L DO used
DOsat K H PO2
D DOsat DOact
D deficit
DOsat saturation concentration
DOact actual concentration
13
Oxygen Deficit
14
Oxygen Deficit
Plug of stream as a black box and a mixed batch
reactor
reoxygenation 0 0 deoxygenation
dO2
dt
15
Oxygen Deficit
rate of reoxygenation k2 D
1 k2 D0 k2 k1
tc ln 1
k2 k1 k1 k1 L0
D oxygen deficit at any time t
D0 oxygen deficit immediately below the pollutant
discharge location
L0 ultimate oxygen demand immediately below the
pollutant discharge location
tc time downstream when the dissolved oxygen is at the
lowest concentration
17
Oxygen Deficit
A river traveling at a velocity of 10 km/day has a
SP5 dissolved oxygen content of 5 mg/L and an ultimate
CBOD of 25 mg/L immediately downstream of a
waste discharge. The waste has a reaeration rate
coefficient of 0.4/day and a saturation dissolved
oxygen concentration of 9 mg/L. What is the initial
dissolved oxygen deficit? What is the location of the
critical point, in time and distance? What is the
dissolved oxygen deficit at the critical point? What is
the dissolved oxygen concentration at the critical
point? Will there be fish at the critical point?
18
Oxygen Deficit
A large stream has a reoxygenation constant of 0.4
SP6 /g and a velocity of 0.85 m/s. At the point at which
an organic pollutant is discharged, it is saturated
with oxygen at 10 mg/L (D0= 0). Below the outfall
the ultimate demand for oxygen is found to be 20
mg/L and the deoxygenation constant is 0.2 /d.
What is the dissolved oxygen 48.3 km downstream?
04
OXYGEN DEMAND
env20:
introduction to environmental
engineering