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10 Institute of Post Graduate Studies, University of Malaya, 50603 Kuala Lumpur, Malaysia
65
A safe drinking water programme known as The National Drinking Water Quality
Surveillance Programme (NDWQSP) was launched by the Ministry of Health,
15 Government of Malaysia in 1983 to ensure safe practices in water treatment and
distribution. The aim of this work was to assess the effectiveness of this programme in the 70
improvement of tap water quality in and around Kuala Lumpur. The results indicate that
there was no microbial contamination in 100 random samples collected from 20 selected
areas. Other quality parameters such as colour, pH, turbidity, hardness, magnesium,
20 sulphate and chloride were within acceptable limits. Heavy metals such as Cuþ2, Pbþ2,
Cr (total), Niþ2, Cdþ2, Fe (total) and Mn (total) were also under control. The only 75
exception was Baþ2, which did not comply with the standard and was up to ten times
higher than the guideline value. Moreover, there was significant variation in water quality
as indicated by the test results.
25
Keywords: Tap water quality; Survey; Kuala Lumpur; Malaysia 80
150
205
155
210
160
215
Figure 1. Colour of tap water (TCU) in selected areas.
Survey of tap water quality in Kuala Lumpur 3
and Puchong were yellowish with value of 20 TCU and 15 As shown in figure 3, the hardness of tap water in these
TCU respectively. 20 selected areas ranged from 48 mg CaCO3/L to 92 mg
CaCO3/L with an average of 65 mg CaCO3/L. The tap
220 water in all these areas is considered soft as the hardness
3.2 Turbidity
level is below 100 mg CaCO3/L. Although there is no 275
Turbidity is a measure of water’s ability to absorb or health-based guideline value, soft water and low pH may
scattered light. Turbidity is caused by the presence of cause corrosion of pipes resulting in the presence of certain
particulate matter in water such as clay, silt, colloidal heavy metals such as cadmium, copper, lead and zinc. A
225 3 particles, plankton and other microscopic organisms (Katz hardness of 100 mg/L would ensure CaCO3 encrustation of
1986). As shown in figure 2, the turbidity of tap water the mains and very little corrosion. 280
ranged from 0.13 NTU to 4.86 NTU with an average of
0.86 NTU. The turbidity of tap water was generally low
3.4 pH
(51 NTU) except for areas such as Tropicana, Bandar
230 Utama, USJ and Puchong. These four areas did not comply The principal system regulating pH in natural waters is the
with the recommended value of 1 NTU for safe drinking carbon dioxide – bicarbonate – carbonate equilibrium phe- 285
water using chlorine as disinfectants. nomenon. Although minor variations in pH have little or
no direct impact on water consumers, it is one of the most
important operational parameters. The pH should be less
3.3 Hardness
235 than 7 for more effective disinfection with chlorine.
The principal source of hardness in water is dissolved As shown in figure 4, the pH of tap water in 20 selected 290
polyvalent metallic ions from sedimentary rocks, seepage areas varied from 6.70 to 7.99 with an average of 7.72. In
and run-off from soils. Water with the hardness above Malaysia, chlorine is used to disinfect water for public
200 mg/L (approximately) may cause scale deposition in supply. However, the lower the pH the higher is the
240 the distribution system, as well as increased soap consump- corrosion of copper, lead, zinc and cadmium. If the tap
tion. In contrast, soft water, with hardness less than about water is above pH 6, then corrosion of lead and cadmium is 295
100 mg/L, has a greater tendency to cause corrosion of insignificant.
pipes, resulting in the presence of certain heavy metals, such The corrosion of copper and zinc might occur due to
as cadmium, copper, lead and zinc in drinking water. The slightly acidic tap water in areas such as section 12,
245 degree to which such corrosion and dissolution of metals Tropicana and Bandar Utama. The pH values of tap water
occur also depends on the pH, alkalinity and dissolved in other areas were above 7. While corrosion may not be 300
oxygen concentration. There is no conclusive evidence that significant, the disinfection would be less effective at pH
water hardness causes adverse health effects in humans 47. Therefore, consumers in these areas should boil their
other than an increased risk of kidney stone (Bellizzi et al. drinking water for safety reasons. Generally, the pH values
250 1999). of tap water in these areas were acceptable as they fell
305
255
310
260
315
265
320
325
380
330
385
335
390
340
Figure 3. Hardness mg CaCO3/L in selected areas. 395
345
400
350
405
355
410
360
415
within the recommended interim standards of pH 6.5 to 8.5 microbial contamination in the supply system. A low level
for drinking water. of residual chlorine generally shows the effectiveness of
chlorine as disinfectant. However, if the level is too high
365 then there might be complaints regarding taste and odour
3.5 Chlorine
from consumers. In a recent study, Codony et al. (2005) 4420
In Malaysia, chlorine is widely used to disinfect drinking demonstrated the count of microbial cells in drinking water
water. It is important to control the concentration of free system can increase by 10 fold in the absence of residual
chlorine in the water, as any free chlorine adversely affects chlorine. Areas such as SS 1, Taman Tun, Sunway and
370 the taste and odour of water. Concentrations higher than section 17 had high residual chlorine. The residual chlorine
the taste and odour threshold of 5 mg/L and 2 mg/L, in SS1 and Taman Tun exceeded the odour threshold of 425
respectively, may give rise to complaints from consumers. 2 mg/L (as Cl2/L). As the taste threshold is at 5 mg/L, all
Chlorine is usually present in disinfected drinking water at the water samples complied with the guideline value.
concentrations of 0.2 to 1.0 mg/L.
375 As shown in figure 5, the residual free chlorine in tap
3.6 Sulphate
water of these selected areas varied from 0.3 mg/L to 430
2.10 mg/L with an average of 0.75 mg/L as Cl2/L. This was Sulphates occur naturally in drinking water. As shown in
considered adequate to ensure protection against any figure 6, the concentration of sulphate in tap water of the
Survey of tap water quality in Kuala Lumpur 5
435
490
440
495
445
500
Figure 5. Residual free chlorine concentration, mg/L.
450
505
455
510
460
515
465
Figure 6. Sulphate concentration in tap water, mg/L.
520
selected areas ranged from 3.0 mg/L to 13.3 mg/L with an these areas were much lower than the guideline value of
470 average value of 7.0 mg/L. The lowest taste threshold of 5 mg/L.
sulphate is its sodium salt at a concentration of 250 mg/L. 525
As the concentration of sulphate in tap water of these areas
3.8 Barium
is much lower than the lowest threshold value, the presence
of sulphate should not affect the taste of water. Barium in water comes primarily from natural sources, such
475 as igneous and sedimentary rocks. The solubility of barium
compounds increases as the pH level decreases (US EPA 530
3.7 Zinc
1985b). Barium is not considered an essential element for
Zinc is an essential element in human nutrition. The daily human nutrition (Schroeder et al. 1972).
requirement is 4 to 10 mg depending on age and sex (Cohen As shown in figure 8, the concentration of barium in tap
480 et al. 1960). water varied from 3.15 mg/L to 20.5 mg/L with an average
It can be observed from figure 7 that the concentration of 12.1 mg/L. The lowest concentration was found at 535
of zinc in tap water of the selected areas varied from section 10 and the highest was at Puchong. Barium in tap
2.2 micrograms/L (mg/L) to 453.0 micrograms/L (mg/L) water is regulated at 0.3 mg/L. None of the tap water
with an average of 130.2 mg/L. The presence of a trace sample from these 20 selected areas can meet the regulatory
485 element such as zinc is good as it is essential for human guideline and they are more than 10 times higher in
nutrition. The concentrations of zinc in tap water of concentration. 540
6 C. Ong et al.
595
545
600
550
605
560
615
565
620
650
705
655
710
660
715
665
720
Figure 9. Cadmium concentration in tap water in selected areas, micrograms/L.
670
725
675
730
680
735
760
815
765
820
770
825
780
835
785
840
790
845
795
3.13 Iron 3.14 Manganese
850
The presence of iron in our drinking water may contribute Manganese is abundant in the earth’s crust. It is widely
a certain taste and colour that might not be acceptable. used in the manufacture of steel and other alloys.
However, the taste is usually not noticeable at iron Manganese dioxide and other manganese compounds are
800 concentration below 0.3 mg/L. used in other products such as batteries, glass and
As shown in figure 13, the total concentration of iron in fireworks. Laboratory studies on animals tested with water 855
tap water in these selected areas ranged from 11.6 micro- of different manganese concentration showed neurotoxic
grams/L (mg/L) to 98.7 micrograms/L (mg/L) with an effects. Based on various reports, a provisional health-
average concentration of 34.7 mg/L. Since iron concentra- based guideline value of 0.5 mg/L is considered adequate
805 tion was below 100 mg/L in the samples, the water did not to protect public health. If the concentration of manganese
develop any turbidity and colour, typical of iron. At the is below 0.1 mg/L, then both guidelines for organoleptic 860
same time, any noticeable change in taste or stains on properties and health guidelines can be met (Ong 2001).
laundry was not found. All the tap water samples complied It may be observed from figure 14 that the concentration
with the regulatory value of 300 mg/L of iron for domestic of manganese in tap water of the selected areas varied from
810 water supply. ‘below detection limit’ to 5.33 micrograms/L (mg/L) with
Survey of tap water quality in Kuala Lumpur 9
865
920
870
925
875
930
885
940
890
945
895
950
Figure 14. Manganese concentration in tap water, micrograms/L.
900
an average concentration of 1.43 mg/L. Manganese affects highest Mg/Ca ratio in tap water with the best anticorrosive 955
the organoleptic properties of tap water and human health power.
at different concentrations. As all the tap water samples As shown in figure 15, the concentration of magnesium
have manganese concentration below 20 mg/L, no staining in the tap water ranged from 66 mg/L to 733 mg/L with an
905 of plumbing fixtures, and laundry might occur. The taste of average concentration of 469 mg/L. The concentrations of
tap water also should not be influenced at these concentra- magnesium in all water samples were much higher than 960
tions. All samples also comply with the provisional health 30 mg/L. There is no provisional guideline for magnesium.
based guideline of 500 mg/L. However it is advisable to have a concentration of 30 mg/L
of magnesium in tap water. This is because magnesium
910 deficiency increases toxicity of cadmium and lead and it is
3.15 Magnesium
shown that magnesium has an inverse relationship to 965
The importance of magnesium intake in drinking water is cardiovascular disease (Ong 2001).
both quantitative and qualitative. Magnesium in water is Magnesium is usually linked to water hardness as
more readily assimilated by the intestinal tract than the calcium and magnesium contribute to the bulk of total
915 same quantity in food, therefore resulting in higher bio- hardness. If the water hardness in the samples is low and
availability (Dawson et al. 1978). If the water is corrosive, it the concentration of magnesium is quite high, it can be 970
will be filtered in processing stations through an antic- assumed that the concentration of calcium in these samples
orrosive filter with optimum Mg/Ca ratio to ensure the is quite low.
10 C. Ong et al.
975
1030
980
1035
985
1040
995
1050
1000
1055
1005
1060
1010
Figure 16. Nickel concentration in tap water, micrograms/L. 1065
concentration of barium in all water samples. However, Grandjean, P., Nielsen, G.D. and Andersen, O., Human nickel exposure 1135
and chemobiokinetics. In Nickel and the Skin: Immunology and
there is no evidence that barium is carcinogenic and causes
Toxicology, edited by T. Menne and H.I. Maibach, pp. 9 – 34, 1989
adverse health effects at low concentrations. (CRC Press: Boca Raton, Florida).
The survey showed that consumers’ feedback on the Kaltz, E.L., The stability of turbidity in raw water and its relationship to
1085 smell, colour, turbidity and taste of the tap water were chlorine demand. J. Am. Water Works Assoc., 1986, 78, 72 – 75.
acceptable except on certain days. The consumer survey Kruawal, K., Sacher, F., Werner, A., Müller, J. and Knepper, T., Chemical 1140
water quality in Thailand and its impacts on the drinking water
showed that 74% of the households used to boil tap
production in Thailand. Sci. Total Environ., 2005, 340, 57 – 70.
water before drinking. Moreover, 50% of the consumers LeChevalier, M.W., Evans, T.M. and Seidler, R.J., Effect of turbidity 5
had water filter fitted to their kitchen supply. It shows on chlorination efficiency and bacterial persistence in drinking water.
1090 that there is a lack of confidence among the consumers Appl. Environ. Microbiol., 1981, 42, 159 – 167.
about the quality of tap water. The result of the survey, Ong, C., Quality of tap water in 20 selected areas in Selangor. M Tech 1145
Dissertation, University of Malaya, Kuala Lumpur, 2001.
however, is not the true representative of the whole of
Ros, J. P. M. and Sloof, W., Integrated criteria document cadmium.
Malaysia. At the same time, the survey covered a Report No. 758476004, National Institute of Public Health and
significant area in and around Kuala Lumpur, in the Environmental Protection, Bilthoven, The Netherlands, 1987.
1095 Klang Valley, covering urban population. In general, the Schock, M.R., Understanding lead corrosion control strategies. J. Am.
awareness about drinking water quality has increased in Water Works Assoc., 1989, 81, 88 – 93. 1150
Schroeder, H.A., Tipton, I.H. and Nason, P., Trace metals in man:
the region, which has been reflected in this work as well
strontium and barium. J. Chronic Diseases, 1972, 25, 491 – 517.
as in a recent report published from south-east Asia Shapiro, J., Effect of yellow organic acids on iron and other metals in 5
(Chung et al. 1997, Kruawal 2005). water. J. Am. Water Works Assoc., 1964, 56, 1062 – 1068.
1100 Siru, D., Quality assurance of water supply in Malaysia. 20th WEDC 5
Conference on Affordable Water Supply and Sanitation, Colombo, Sri 1155
References Lanka, 1994, pp. 259 – 260.
Bellizzi, V., Nicola, L., Minutolo, R., Russo, D., Cianciaruso, B.,
Sloof, W., Integrated criteria document chromium. Report No. 758701002, 5
1989.
Andreucci, M., Conte, G. and Andreucci, V.E., Effects of hardness on
urinary risk factors for kidney stones in patients with idiopathic
US Environmental Protection Agency, National primary drinking water 5
1105 nephrolithiasis, Nephron, 1999, 81, 66 – 70.
regulations: synthetic organic chemicals, inorganic chemicals and
microorganisms. Fed. Register, 1985a, 50, 46936. 1160
Chung, Y., Shin, D., Park, S., Lim, Y., Choi, Y., Cho, S., Yang, J., Hwang,
US Environmental Protection Agency, Office of the drinking water,
M., Park, Y. and Lee, H., Risk assessment and management of drinking
Health advisory-barium, 1985b (US Environmental Protection Agency:
water pollutants in Korea. Water Sci. Technol., 1997, 36, 309 – 323.
Washington D.C.).
Cohen, J.M., Taste threshold concentration of metals in drinking water.
J. Am. Water Works Assoc., 1960, 52, 660 – 670.
US Environmental Protection Agency, National primary drinking water 5
1110 Clement, M., Seux, R. and Rabarot, S., A practical model for estimating
regulations for lead and copper, Fed. Register, 1988, 52, 31515 – 31578.
total lead intake from drinking water. Water Res., 2000, 34, 1533 – 1542.
World Health Organisation, Nickel: Environmental Health Criteria, 5 1165
No. 108, 1991 (World Health Organisation: Geneva).
Dawson, E.B., Frey, M.J., Moore T.D. and McGanity, W.J. Relationship
of metal metabolism to vascular disease mortality rates in Texas. Am. J.
Clinical Nutrition, 1978, 31, 1188 – 1197.
1115
1170
1120
1175
1125
1180
1130
1185
12 C. Ong et al.
Appendix A
1190
The 20 different areas in and around Kuala Lumpur (known as the Klang Valley) are shown in figure A1 using numbers 1 to 1245
20. The number code for each area is shown in table A1.
1195
1250
1200
1255
1205
1260
1210
1265
1215
1270
1220
1275
1225
1280
1230
1285
1235
1290
Table A1. Number codes for the selected areas in the Klang
Valley.
1320
1375
1325
1380
1330
1385
1335
1390
1340
1395
1345
1400
1350