ALCOHOL ISOPROPILICO

T (K) V(L)
341,45 0,001
349,75 0,002
353,05 0,003
355,55 0,01
La grafica sería:

V vs T
0.012

0.01

0.008
y = 4,98.10-4 x - 0.1703

0.006

0.004

0.002

0
340 342 344 346 348 350 352 354 356 358
-0.002

GAS IDEAL
𝑃𝑉 = 𝑛𝑅𝑇
𝑉 𝑛𝑅
= = 𝑝𝑒𝑛𝑑𝑖𝑒𝑛𝑡𝑒
𝑇 𝑃
𝑛𝑅
= 4,98. 10−4 𝐿/𝐾
𝑃
0,786𝑔 1𝑚𝑜𝑙
𝑛 = (0,2𝑚𝑙) ( )( ) = 2,62. 10−3 𝑚𝑜𝑙
1𝑚𝑙 60,1𝑔
𝐿 757𝑚𝑚𝐻𝑔
𝑅 = (4,98. 10−4 ) ( )
𝐾 2,62. 10−3 𝑚𝑜𝑙
𝑚𝑚𝐻𝑔 𝐿
𝑅 = 143,89
𝑚𝑜𝑙 𝐾
143,89 − 62,4
%𝐸𝑟𝑟𝑜𝑟 = ( ) 𝑥100% = 130,6%
62,4
VAN DER WAALS

Para el alcohol isopropílico: Tc = 508 K Pc =35720 mmHg

27 𝑅 2 𝑇𝑐2 𝑚𝑚𝐻𝑔𝐿2
𝑎= = 11867,765
64 𝑃𝑐 𝑚𝑜𝑙 2
𝑅𝑇𝑐 𝐿
𝑏= = 0,111
8𝑃𝑐 𝑚𝑜𝑙
Para T1 = 341,45 K
𝑉𝑚3 − 28,257𝑉𝑚2 + 15,677𝑉𝑚 − 1,74 = 0
3𝑉𝑚2 − 56,514𝑉𝑚 + 15,677 = 0
Resolviendo por Newton-Raphson:
𝑉𝑚 = 27,69316 𝐿/𝑚𝑜𝑙
Como n =3,553.10-5 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (3,553. 10−5 𝑚𝑜𝑙) (27,69316 ) = 9,84. 10−4 𝐿
𝑚𝑜𝑙
Para T2 = 349,75 K
𝑉𝑚3 − 28,941𝑉𝑚2 + 15,677𝑉𝑚 − 1,74 = 0
3𝑉𝑚2 − 57,882𝑉𝑚 + 15,677 = 0
Resolviendo por Newton-Raphson:
𝑉𝑚 = 28,39098 𝐿/𝑚𝑜𝑙
Como n =6,9372.10-5 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (6,9372. 10−5 𝑚𝑜𝑙) (28,39098 ) = 1,97. 10−3 𝐿
𝑚𝑜𝑙
Para T3 = 353,05 K
𝑉𝑚3 − 29,213𝑉𝑚2 + 15,677𝑉𝑚 − 1,74 = 0
3𝑉𝑚2 − 58,426𝑉𝑚 + 15,677 = 0
Resolviendo por Newton-Raphson:
𝑉𝑚 = 28,66828 𝐿/𝑚𝑜𝑙
Como n =1,03085.10-4 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (1,03085. 10−4 𝑚𝑜𝑙) (28,66828 ) = 2,955. 10−3 𝐿
𝑚𝑜𝑙

Para T4 = 355,55 K
𝑉𝑚3 − 29,419𝑉𝑚2 + 15,677𝑉𝑚 − 1,74 = 0
3𝑉𝑚2 − 58,838𝑉𝑚 + 15,677 = 0
Resolviendo por Newton-Raphson:
𝑉𝑚 = 28,8782232 𝐿/𝑚𝑜𝑙
Como n =3,412.10-4 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (3,412. 10−4 𝑚𝑜𝑙) (28,8782232 ) = 9,8533. 10−3 𝐿
𝑚𝑜𝑙
Se obtiene la siguiente tabla:
T (K) V(L)
341,45 9,84.10-4
349,75 1,97.10-3
353,05 2,955.10-3
355,55 9,8533.10-3

Graficando:

V vs T
0.012

0.01
y = 4,90738.10-4 x - 0.1678
0.008

0.006

0.004

0.002

0
340 342 344 346 348 350 352 354 356 358
-0.002
La nueva pendiente será:
𝑛𝑅
= 4,90738. 10−4 𝐿/𝐾
𝑃
𝑛 = 2,62. 10−3 𝑚𝑜𝑙
𝐿 757𝑚𝑚𝐻𝑔
𝑅 = (4,90738. 10−4 ) ( )
𝐾 2,62. 10−3 𝑚𝑜𝑙
𝑚𝑚𝐻𝑔 𝐿
𝑅 = 141,79
𝑚𝑜𝑙 𝐾
141,79 − 62,4
%𝐸𝑟𝑟𝑜𝑟 = ( ) 𝑥100% = 127,23%
62,4
REDLICH-KWONG
Para el alcohol isopropílico: Tc = 508 K Pc =35720 mmHg
VIRIAL
Para el alcohol isopropílico: C(T) = (0,111)2 = 0,012321
Reemplazando a y b para cada temperatura, resolvemos por Newton-Raphson la
ecuación (1) y corregimos el volumen.
Para T1 =341,45 K B(T) = -0,446
𝑉𝑚3 − 28,146𝑉𝑚2 + 12,553𝑉𝑚 − 0,3468 = 0
3𝑉𝑚2 − 56,292𝑉𝑚 + 12,553 = 0
𝑉𝑚 = 27,69318 𝐿/𝑚𝑜𝑙
Como n =3,553.10-5 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (3,553. 10−5 𝑚𝑜𝑙) (27,69318 ) = 9,8394. 10−4 𝐿
𝑚𝑜𝑙
Para T2 = 349,75 K B(T) = -0,43278
𝑉𝑚3 − 28,83𝑉𝑚2 + 12,4771𝑉𝑚 − 0,3552 = 0
3𝑉𝑚2 − 57,66𝑉𝑚 + 12,4771 = 0
𝑉𝑚 = 28,39097 𝐿/𝑚𝑜𝑙
Como n =6,9372.10-5 mol
𝑉 = 𝑛(𝑉𝑚 )
 𝐿
𝑉 = (6,9372. 10−5 𝑚𝑜𝑙) (28,39097 ) = 1,9695. 10−3 𝐿
𝑚𝑜𝑙
Para T3 = 353,05 K B(T) = -0,4277
𝑉𝑚3 − 29,102𝑉𝑚2 + 12,9795𝑉𝑚 − 0,35857 = 0
3𝑉𝑚2 − 58,204𝑉𝑚 + 12,9795 = 0
𝑉𝑚 = 28,6494 𝐿/𝑚𝑜𝑙
Como n =1,03085.10-4 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (1,03085. 10−4 𝑚𝑜𝑙) (28,6494 ) = 2,9533. 10−3 𝐿
𝑚𝑜𝑙

Para T4 = 355,55 K B(T) = -0,4239

𝑉𝑚3 − 29,308𝑉𝑚2 + 12,42375𝑉𝑚 − 0,3611 = 0
3𝑉𝑚2 − 58,616𝑉𝑚 + 12,42375 = 0
𝑉𝑚 = 28,87823 𝐿/𝑚𝑜𝑙
Como n =3,412.10-4 mol
𝑉 = 𝑛(𝑉𝑚 )
𝐿
𝑉 = (3,412. 10−4 𝑚𝑜𝑙) (28,87823 ) = 9,853. 10−3 𝐿
𝑚𝑜𝑙
Se obtiene la siguiente tabla:
T (K) V(L)
341,45 9,8394.10-4
349,75 1,9695.10-3
353,05 2,9533.10-3
355,55 9,853.10-3
Graficando:
 V vs T
0.012

0.01

y = 4,90682.10-4 x - 0.1678
0.008

0.006

0.004

0.002

0
340 342 344 346 348 350 352 354 356 358
-0.002

La nueva pendiente será:

𝑛𝑅
= 4,90682. 10−4 𝐿/𝐾
𝑃
𝑛 = 2,62. 10−3 𝑚𝑜𝑙
𝐿 757𝑚𝑚𝐻𝑔
𝑅 = (4,90682. 10−4 ) ( )
𝐾 2,62. 10−3 𝑚𝑜𝑙
𝑚𝑚𝐻𝑔 𝐿
𝑅 = 141,77
𝑚𝑜𝑙 𝐾
141,77 − 62,4
%𝐸𝑟𝑟𝑜𝑟 = ( ) 𝑥100% = 127,2%
62,4