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What is the velocity of the - particle. [Given 1 amu = 1.66 1027 kg, atomic mass of
1
He = 4 and gold = 79 and = 9 109 Nm2C2]
4pe0
1. v = 3.311 105 m/s
Problem 2. Prove that density of the nucleus is constant..
Problem 3. The wave number of a radiation is 400 cm1. Find out its
(a) Wavelength (b) Frequency
(c) J per photon (d) kcal per mol of photons
(e) kJ per mol of photons
4. 496 nm
Problem 5. Calculate the velocity of an electron in Bohr’s first orbit of hydrogen atom
(Given r = 0.53 10–10 m)
5. 2.18 106 m/s
Problem 6.. A series of lines in the spectrum of atomic hydrogen lies at wavelengths 656.46,
482.7, 434.17, 410. 29 nm. What is the wavelength of next line in this series?
6. 397.2 nm
Problem 7. Find the energy released in (ergs) when 2.0 gm atom of hydrogen undergo transition
giving spectral line of lowest energy in visible region of its atomic spectrum.
7. 3.63 1012 ergs
Problem8. Which hydrogen like ionic species has wavelength difference between the first line of
Balmer and first line of Lyman series equal to 59.3 10–9 m? Neglect the reduced mass
effect.
8. Z=3
ionic species is Li2+
Problem9. If the principal quantum number n has a value of 3, what are permitted values of the
quantum numbers ‘’ and ‘m’?
9. n=3 = 0 m = 0 (s)
=1 m = – 1 (p)
m=0
m=+1
=2 m = – 2 (d)
m=–1
m=0
m = +1
m = +2
Problem 10. Through what potential difference an electron must be accelerated to have a
o
de-Broglie wavelength of 1 A .
10. 1.5 106 volt