DETERMINACIÓN DE NITRÓGENO EN: NH3 (AC); NH4+.

Métodos de: Valoraciones por retroceso, sustitución o desplazamiento, y HMTA para NH4+.

Valoración por retroceso.

0.095708 ± 0.00029 𝑚𝑚𝑜𝑙 𝐻𝐶𝑙

𝑚𝑚𝑜𝑙 𝐻𝐶𝑙 = 50 ± 0.0500 𝑚𝐿 𝐻𝐶𝑙 × = 4.7854 𝑚𝑚𝑜𝑙 𝐻𝐶𝑙
1 𝑚𝐿 𝐻𝐶𝑙

𝑆𝑦 0.05172 0.000292
= √ + = ±0.003
4.7854 502 0.0957082

𝑆𝑦 = ±0.003 × 4.7854 = ±0.0144

𝑚𝑚𝑜𝑙 𝐻𝐶𝑙 = 4.7854 ± 0.0144 𝑚𝑚𝑜𝑙 𝐻𝐶𝑙

0.1017 ± 0.000148 𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻

𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 = 20.2 ± 0.0517 𝑚𝐿 𝑁𝑎𝑂𝐻 × = 2.05434
1 𝑚𝐿 𝑁𝑎𝑂𝐻

𝑆𝑦 0.05172 0.0001482
= √ + = ±0.003
2.05434 20.2 0.10172

𝑆𝑦 = ±0.003 × 2.05434 = ±0.0062

𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 = 2.05434 ± 0.0062 𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻

𝑚𝑚𝑜𝑙 𝑁𝐻3 = 𝑚𝑚𝑜𝑙 𝐻𝐶𝑙 − 𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻

𝑚𝑚𝑜𝑙 𝑁𝐻3 = 4.7854 ± 0.0144 𝑚𝑚𝑜𝑙 − 2.05434 ± 0.0062 𝑚𝑚𝑜𝑙 = 2.73106 𝑚𝑚𝑜𝑙 𝑁𝐻3

𝑆𝑦 = √0.01442 + 0,00622 = ±0.0157

𝑚𝑚𝑜𝑙 𝑁𝐻3 = 2.73106 ± 0.0157 𝑚𝑚𝑜𝑙 𝑁𝐻3

 𝑚 1𝑚𝑚𝑜𝑙 𝑁 14 𝑔 𝑁
% 𝑁 = 2.73106 ± 0.0157 𝑚𝑚𝑜𝑙 𝑁𝐻3 × ×
𝑣 1𝑚𝑚𝑜𝑙 𝑁𝐻3 1000 𝑚𝑚𝑜𝑙 𝑁
1
× × 100% = 0,1530% 𝑁
25 ± 0,04243 𝑚𝐿 𝑚𝑢𝑒𝑠𝑡𝑟𝑎

𝑆𝑦 0,01572 0,042432
= √ + = ±0,006
0.1530 2.731062 252

𝑆𝑦 = ±0,006 × 0.1530 = ±0,00092

𝑚
% 𝑁 = 0,1530 ± 0,00092% 𝑁
𝑣

Sustitución o desplazamiento.

𝑚 0.095708 ± 0.00029 𝑚𝑚𝑜𝑙 𝐻𝐶𝑙 1 𝑚𝑚𝑜𝑙 𝑁𝐻3

% 𝑁 = 20.6 ± 0.0517 𝑚𝐿 𝐻𝐶𝑙 × ×
𝑣 1 𝑚𝐿 𝐻𝐶𝑙 1 𝑚𝑚𝑜𝑙 𝐻𝐶𝑙
1 𝑚𝑚𝑜𝑙 𝑁 14𝑔 𝑁 1
× × × × 100%
1 𝑚𝑚𝑜𝑙 𝑁𝐻3 1000 𝑚𝑚𝑜𝑙 𝑁 25 ± 0,04243 𝑚𝐿 𝑚𝑢𝑒𝑠𝑡𝑟𝑎
= 0,1104% 𝑁

𝑆𝑦 0,05172 0,000292 0,042432

= √ + + = ±0,0043
0,1104 20.82 0,0957082 252

𝑆𝑦 = ±0,0043 × 0.1104 = ±0,00047

 𝑚
% 𝑁 = 0,1104 ± 0,00047% 𝑁
𝑣

HMTA NH4+.

O N

6 + -
+ 2 (NH 4 )2SO4 N N + 6 H 2O + 2 H 2SO4

H H
N
Esquema 6.

𝑉𝑁𝑎𝑂𝐻 𝑟𝑥𝑛 ≅ 𝑉𝑁𝑎𝑂𝐻 𝐷𝑃 − 𝑉𝐵𝑙𝑎𝑛𝑐𝑜 ≅ 20 ± 0,0517 𝑚𝐿 𝑁𝑎𝑂𝐻 − 0,5 ± 0,0517 𝑚𝐿 𝑁𝑎𝑂𝐻

= 19.5 ± 𝑚𝐿 𝑁𝑎𝑂𝐻

𝑆𝑦 = √0.05172 + 0,05172 = ±0.073

𝑉𝑁𝑎𝑂𝐻 𝑟𝑥𝑛 = 19.5 ± 0.073 𝑚𝐿 𝑁𝑎𝑂𝐻

 𝑚 0.1017 ± 0.000148 𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1 𝑚𝑚𝑜𝑙 𝑁𝐻3
% 𝑁 = 19.5 ± 0.073 𝑚𝐿 𝑁𝑎𝑂𝐻 × ×
𝑚 1 𝑚𝐿 𝑁𝑎𝑂𝐻 1 𝑚𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
1 𝑚𝑚𝑜𝑙 𝑁 14 𝑔 𝑁 1
× × ×
1 𝑚𝑚𝑜𝑙 𝑁𝐻3 1000 𝑚𝑚𝑜𝑙 𝑁 25 ± 0,04243 𝑚𝐿 𝑚𝑢𝑒𝑠𝑡𝑟𝑎
250 𝑚𝐿 (𝑁𝐻4 )2 𝑆𝑂4
× × 100% = 18.4565% 𝑁
1,5043 𝑔 (𝑁𝐻4 )2 𝑆𝑂4

𝑆𝑦 0,0732 0,0001482 0,042432

= √ + + = ±0,0044
18.4565 19.52 0,10172 252

𝑆𝑦 = 18.4565 × ±0,0044 = ±0,0812

𝑚
% 𝑁 = 18.4565 ± 0,0812% 𝑁
𝑚