Adjuvants

Corrosion Inhibitors
For Oil & Gas

Your one-stop provider for high performance Solvay’s products for corrosion
inhibition applications are ideal
corrosion inhibitor actives for challenging environments
w High temperature
Solvay corrosion inhibitor range
w Corrosive fluids, e.g. brines
Solvay offers a wide range of corrosion inhibitor chemistries for the oil and gas industry.
Our products can be used in drilling, stimulation and production applications to protect w Sweet and sour conditions
metals and alloys against the corrosive effects of fluids and acidic gases.
Enhance productivity
Solvay’s portfolio of chemistries include: w Extend equipment lifetime
Miramine®, Marcor® and Fentamine® series: Imidazolines and fatty amines w Maintain storage tanks and
Fentacare®, Rhodaquat® and Marcor® series: Quarternary ammonium derivatives pipeline integrity

Mirataine®, Miranol® and Mackam® series: Amphoteric surfactants w Improve operational safety
of assets
Geropon® and Miranate® series: Alkyl ether carboxylates
Rhodafac® series: Phosphate esters Solvay’s corrosion
inhibitors offer
w Effective and persistent
corrosion inhibition
The actives form a protective film on the surface of the metal.
w Soluble or dispersible in aqueous
and non-aqueous systems

H+
w Ease of formulation
CO32- CO2 • Compatible with
HCO3- CO2 solvents and other
HCO3- ingredients,
H2S
HCO3- e.g. synergists

CO2 H2S H+ H2S

w Convenience
H+
• Easily formulated
into packages for
continuous or
batch dosing

METAL

Solvay’s corrosion inhibitor ranges may be used on their own or blended into cost
effective formulations.

A global presence….
Solvay has an extensive manufacturing network and our corrosion inhibitors are produced
at locations worldwide.
Our dedicated sales teams are supported by application laboratories that are located in
the major geographical zones – Europe, North America, Latin America & Asia Pacific.
Nitrogen Derivative Solutions for Corrosion Control
Miramine® Marcor® and Fentamine® series
Product Chemistry Active (%) Products designed for low and high water cut
Tall oil hydroxyethyl systems. The amines and imidazolines may be used
Miramine® TOI 100
imidazoline as intermediates in the manufacture of corrosion
inhibitors, e.g. quaternary ammonium derivatives.
Tall oil aminoethyl
Miramine® EA-TOI 100 Imidazolines exhibit enhanced performance in sour
imidazoline conditions.
Ethoxylated tall oil
Miramine® TAI/9 aminoethyl 100 Miramine® TAI/9 is recommended for water soluble
formulations and aids formulation stability at low
imidazoline temperatures. The ethoxylated imidazoline also aids
Fentamine® A-O Oleyl amine 100 compatibility of the formulation in the presence
Fentamine® A-T Tallow amine 100 of brines.

N-coco-1,3-
Fentamine® DA-CO 100
diaminopropane

Fentacare®, Marcor® and Rhodaquat® series

Product Chemistry Active (%) The Solvay range of quaternary ammonium
Didecyl dimethyl derivatives and amine ethoxylates are recommended
Fentacare® 1021-80 80
ammonium chloride as low cost, high performance additives for corrosion
inhibitor formulations.
C12-16 alkyl
Fentacare® 1227-80 dimethyl benzyl 80 The combination of the mono/diamine ratio and
ammonium chloride degree of ethoxylation provides additional flexibility
N-tallow-1,3- to alter the solubility of the corrosion inhibitor in
water or brine.
Fentacare® TD03 diaminopropane 100
ethoxylate (3E0) The quats are also recommended as corrosion
Tallow amine inhibitors for acidic conditions. Furthermore, the
Fentacare® TD10 100 performance attributes of the products are enhanced
ethoxylate (10 E0)
when they are formulated with non-ionic or
Marcor® 800 Quaternary derivative 60 amphoteric surfactants (wetting agents).
Marcor® 900 Quaternary derivative 80
Alkyl pyridine benzyl
Rhodaquat® CPB-75 75
ammonium chloride

Mackam®, Mirataine® and Miranol® series

Product Chemistry Active (%) The Solvay range of biodegradable amphoteric
Sodium octyl surfactants are recommended as corrosion
Mackam® OIP-40 40
iminodipropionate inhibitors for oil and gas applications. The products
also enhance the performance of anionic and
Miranol® C2M – SF Disodium
40 cationic inhibitors.
CONC Cocoamphodipropionate
Sodium Mackam® OIP-40, Miranol® C2M-SF CONC and
Mirataine® H2C-HA 30 Mirataine® H2C-HA are ‘salt free’ products and
Lauraminodipropionate
are recommended as actives in low corrosivity
Oleoamidopropyl formulations for capillary strings and umbilicals
Mirataine® BET-O-30 30
betaine Mackam OIP-40 is low foaming and is suitable
as a hydrotrope and wetting agent.
Phosphate Ester & Surfactant Solutions for Corrosion Control
Rhodafac®, Geropon® and Miranate® ranges are non-amine corrosion inhibitor actives. Solvay’s patented process for
manufacturing phosphate esters permits the control of the mono and diester ratio (MAM/DAP). A high monoester (MAP)
content produces a more even distribution of the inhibitor (packing of adsorbed molecules) on the surface of the metal
(surface film).

Hydrophobe selection and the degree of ethoxylation is also important. It determines the wetting, surface tension reduction
and emulsification attributes of the phosphate ester.

Solvay’s corrosion inhibitor ranges may be used on their own or blended into cost effective formulations.

Product Alcohol EO Active (%) Rhodafac® series

The Solvay range of phosphate esters are
Rhodafac® PA 15 2-Ethylhexyl 2 96 designed for low and high water cut
Rhodafac® RA 600 C8-10 4 98 systems. The acids are oil soluble and
dispersible in water. Solubility in water is
Rhodafac® PA 23 C10 -12 5 100 improved by neutralization with base.
Rhodafac® PL-6 PEG mono C8-10 - 99
The phosphate esters are recommended
C10-C16 EO/PO for controlling corrosion in sweet and sour
Rhodafac® PL-620 - 90
(mixed) conditions, and high shear applications.
The esters are recognized as forming highly
Rhodafac® RS 410 C13 (branched) 4 100 persistent films on metal surfaces. They are
Rhodafac® RS 510 C13 (branched) 5 100 also useful for mitigating the effects of
naphthenic acid corrosion in refineries.
Rhodafac® RS 610 C13 (branched) 6 100
Synergistic performance benefits are obtained
Rhodafac® PA 32 C18 3 100 when the phosphate esters are formulated with
Rhodafac® RE-610 Nonyl phenol 9 90+ cationic, amphoteric and non-ionic surfactants.

Product Chemistry Active (%) Geropon® and Miranate® series

The Solvay range of biodegradable anionic
C16-18 alkyl ether carboxylic surfactants are recommended as corrosion
Geropon® HW15 100
acid inhibitors for oil and gas applications. The
Sodium C12 alkyl ether surfactants may be used as co-actives to
Miranate® LEC-80 80 enhance the performance of amphoteric
carboxylate and cationic corrosion inhibitors.

Miranate® LEC-80 is water soluble and

compatible with high TDS brines. It is
recommended as a dispersant and
co-surfactant for corrosion inhibitors with
poor water solubility or brine tolerance.
 The way we do business
Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is depen-
dent upon the responsible way in which we conduct our current activities — a way that reflects our commitment to each of our
stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People
Sphere and the Economic Sphere.

Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self-assessments of their
practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable
value for all our stakeholders through innovation and partnership.

> Responsible Care is the chemical industry’s voluntary continuous improvement

initiative to promote safe handling of products. (1987)

> The UN’s Global Compact aims to ensure that heads of companies promote and
uphold 10 universal principles concerning human rights, working conditions,
respect for the environment and anti-corruption. (2003)

> The International Federation of Chemical, Energy, Mine a

 nd General Workers’
Unions. (2005)

> Solvay Novecare has achieved world-wide ISO-9001 Quality Management System
Multi-Site Certification. (2008)

SOLVAY NOVECARE - Dileo Graphic Design, mariadileo@comcast.net

North America
Solvay Novecare – 8 Cedar Brook Drive – Cranbury, NJ 08512 – USA
Phone: +1-800-973-7873 – Fax: +1-609-860-0463 – NovecareCC@solvay.com

Europe
Solvay Novecare – 40, rue de la Haie-Coq – F-93306 Aubervilliers Cedex – France
Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90

Asia Pacific
Solvay Novecare – 1, Biopolis Drive – #05-01/06 AMNIOS – Singapore 138 622
Phone: +65 - 6291 1921 – Fax: +65 - 6394 3376

Latin America
Solvay Novecare – Centro Empresarial – Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar
Cep: 05804-902 – São Paulo-SP Brazil
Phone: +55 11 3747-7637 – Fax: +55 11 3741-8378
2015

www.solvay.com
SEPT

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products described herein. Various patents owned by Solvay or others may be pertinent to their use and to compositions containing them. Nothing contained
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herein is intended as a recommendation to use our products so as to infringe any patent. We assume no liability for any intellectual property rights violation by
customers (direct or indirect). Customers (direct and indirect) should make their own patent investigation related to the freedom to operate for any specific intended
use. If a relevant patent is identified, customers (direct and indirect) should secure a license from the patent owner. Customers (direct and indirect) should evaluate
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the products to determine notably their strength, performance and safety. All applicable laws and regulations should be consulted. All the names mentioned are
registered trademarks of Solvay, its subsidiaries or affiliates.