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INTRODUCTION
A composite material can be defined as a combination of two or more materials that results in
better properties than those of the individual components used alone. In contrast to metallic
alloys, each material retains its separate chemical, physical, and mechanical properties.
The two constituents are a reinforcement and a matrix. The main advantages of composite
materials are their high strength and stiffness, combined with low density, when compared
with bulk materials, allowing for a weight reduction in the finished part.
The reinforcing phase provides the strength and stiffness. In most cases, the reinforcement is
harder, stronger, and stiffer than the matrix. The reinforcement is usually a fibre or a
particulate. Particulate composites have dimensions that are approximately equal in all
directions. They may be spherical, platelets, or any other regular or irregular geometry.
Particulate composites tend to be much weaker and less stiff than continuous fibre
composites, but they are usually much less expensive. Particulate reinforced composites
A fibre has a length that is much greater than its diameter. The length-to-diameter (l/d) ratio is
known as the aspect ratio and can vary greatly. Continuous fibres have long aspect ratios,
while discontinuous fibres have short aspect ratios. Continuous-fibre composites normally
have a preferred orientation, while discontinuous fibres generally have a random orientation.
winding, while examples of discontinuous reinforcements are chopped fibres and random
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mat. Continuous-fibre composites are often made into laminates by stacking single sheets of
continuous fibres in different orientations to obtain the desired strength and stiffness
Owing to their favourable performance characteristics composite materials have been gaining
wide use in commercial, military, and space applications. There is some concern, however,
that the mechanical properties of such materials may suffer when the material is exposed to
moisture for long periods of time. Therefore, in order to utilize the full potential of composite
moisture environments. It is well-known that the moisture has significant effects on their
physical and chemical properties of epoxy matrix as well as on their final performance of
composite structures especially in their long-term utilization. The absorbed water usually
depresses the glass-transition temperature Tg by plasticizing the polymer network and also
The incorporation of two or more types of fibre into a single matrix has led to the
determined by many factors, such as the matrix, length and shape of individual fibres, fibre–
matrix interface bonding, and volume fraction of the natural/ synthetic fibres. Previous
studies have studied the effect of varying the amount of fibre loading on the mechanical
properties of hybrid composites consisting of natural fibres and glass fibre. These include
al. reported that the water uptake of hybrid composites is lower than that of un-hybridized
composites.
2
Moisture absorption increases with increasing fibre loading. It was investigated the
relationship between the moisture absorption of pineapple-leaf fibre reinforced low density
Carbon-epoxy composites are widely accepted for use as primary aerospace components and
in other structural applications due to their high performance characteristics. In service these
humidity. Over the past few years, a great deal of experimental evidence has been collected to
demonstrate that both physical and mechanical properties of composite materials can be
strongly affected during hygrothermal ageing, affecting the composite performance. Carbon-
their behaviour under varied environmental conditions, of which the hygrothermal factor is of
vital importance.
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Because carbon fibre reinforced plastics (CFRP) are being considered as structural materials
it is necessary to determine the extent to which their favourable properties are retained in
adverse natural environments. The good chemical resistance of carbon fibres has been
dem0nstrated.l Being relatively inert when compared to glass and other fibres they offer the
order to give confidence to the designer and user. It is also necessary to develop life
izto the effect of water on carbon fibre reinforced plastics have indicated the strong
dependence of inter-laminar shear strength (ILSS) of the composite on the resin matrix and
the void content of the composite. During these studies water pick-up measurements were
made after immersion at elevated temperatures and in the present paper this data is analysed
diffusion coefficients and have been reported. The use of accelerated moisture conditioning
of graphite-epoxy composite and the comparison with regular conditioning was discussed.
Although many investigators have studied epoxy systems reinforced with various types of
fibres and fillers, there exists the capacity for further investigations. The adhesive bonding
between fibre and matrix is very important as it controls the interface profile in terms of voids
and pores, which can greatly affect the absorption according to the mechanisms previously
discussed. Moreover, a wide scatter of Tg values for given epoxy systems is reported in the
material preparation. However, from experimental data in the literature, the effects of
hygrothermal history (i.e., exposure to moisture and temperature) on Tg are also quite
significant.
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1.1.2 Glass-Epoxy Composite
specifically glass fibre. The glass fibre may be randomly arranged, flattened into a sheet, or
woven into a fabric. The plastic matrix may be a thermoset polymer matrix – most often
a thermoplastic. Fibre glass is unique in its strength and yet it is light weight.
The glass fibres are made of various types of glass depending upon the fibre glass use. These
glasses all contain silica or silicate, with varying amounts of oxides of calcium, magnesium,
and sometimes boron. To be used in fiberglass, glass fibres have to be made with very low
levels of defects.
Fibre glass is a strong lightweight material and is used for many products. Although it is not
as strong and stiff as composites based on carbon fibre, it is less brittle, and its raw materials
are much cheaper. Its bulk strength and weight are also better than many metals, and it can be
more readily moulded into complex shapes. Applications of fiberglass include aircraft, boats,
automobiles, bath tubs and enclosures, swimming pools, hot tubs, septic tanks, water tanks,
Other common names for fiberglass are glass-reinforced plastic (GRP), glass-fibre reinforced
plastic (GFRP) or GFK. Because glass fibre itself is sometimes referred to as "fibre glass",
the composite is also called "fiberglass reinforced plastic." This article will adopt the
convention that "fiberglass" refers to the complete glass fibre reinforced composite material,
.Unlike glass fibres used for insulation, for the final structure to be strong, the fibre's surfaces
must be almost entirely free of defects, as these permit the fibres to reach gigapascal tensile
strengths. If a bulk piece of glass were defect-free, it would be equally as strong as glass
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fibres; however, it is generally impractical to produce and maintain bulk material in a defect-
The process of manufacturing fiberglass is called pultrusion. The manufacturing process for
glass fibres suitable for reinforcement uses large furnaces to gradually melt
the silica sand, limestone, kaolin clay, fluorspar, colemanite, dolomite and other minerals to
liquid form. It is then extruded through bushings, which are bundles of very small orifices.
An individual structural glass fibre is both stiff and strong in tension and compression—that
is, along its axis. Although it might be assumed that the fibre is weak in compression, it is
actually only the long aspect ratio of the fibre which makes it seem so; i.e., because a typical
fibre is long and narrow, it buckles easily. On the other hand, the glass fibre is weak in shear
—that is, across its axis. Therefore, if a collection of fibres can be arranged permanently in a
preferred direction within a material, and if they can be prevented from buckling in
Unidirectional glass reinforced polymer (GRP) composites have become a popular alternative
to porcelain in the manufacture of high voltage insulators. Their mechanical and electrical
properties are of great importance, and both these factors will greatly depend on the presence
The use of two or more fibres in a polymeric matrix or the use of multiple matrix leads to
designs and provides better tuning compatibility to get desired properties in comparison with
additional fibre. The characteristics of hybrid composites, where more than one type of fibre
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is employed, are governed by a more complex behaviour of the interfacial properties. The
present study is on carbon–glass epoxy hybridisation. These materials have the potential for
extensive use in space launch vehicles like inter-tank truss members, thermal
In this study mainly two immersion liquids are used for moisture absorption of the composite.
Distilled water is water that has had many of its impurities removed through distillation.
Distillation involves boiling the water and then condensing the steam into a clean container.
deionized water are preferred to distilled water. But if these alternatives are not pure enough,
distilled water is used. If exceptionally high purity water is required, double distilled water is
used.
Distilled water is also commonly used to top off lead acid batteries used in cars and trucks.
The presence of other ions commonly found in tap water will drastically reduce an
Distilled water is preferable to tap water for use in automotive cooling systems. The minerals
and ions typically found in tap water can be corrosive to internal engine components, and can
cause a faster depletion of the anti-corrosion additives found in most antifreeze formulations..
This acidic solution is a liquid consisting of about 5–20% acetic acid (CH3COOH), water,
and other trace chemicals, which may include flavourings. The acetic acid is produced by the
fermentation of ethanol by acetic acid bacteria. It is now mainly used as a cooking ingredient,
or in pickling. As the most easily manufactured mild acid, it has historically had a great
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variety of industrial, medical, and domestic uses, some of which (such as its use as a general
slow methods are used in traditional solutions where fermentation proceeds slowly over the
course of a few months or up to a year. The longer fermentation period allows for the
accumulation of a non-toxic slime composed of acetic acid bacteria. Fast methods add
bacterial culture to the source liquid before adding air to oxygenate and promote the fastest
three days.
Carbon fibre is most notably used to reinforce composite materials, particularly the class of
materials known as carbon fibre or graphite reinforced polymers. Non-polymer materials can
also be used as the matrix for carbon fibres. Due to the formation of
metal carbides and corrosion considerations, carbon has seen limited success in metal matrix
graphite, and is used structurally in high-temperature applications. The fibre also finds use
because a dense, compact layer of carbon fibres efficiently reflects heat. Glass composite is
its RF permeability and low signal attenuation properties. It may also be used to conceal other
and steel support structures, due to the ease with which it can be moulded and painted to
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blend with existing structures and surfaces. Other uses include sheet-form electrical insulators
period.
To find the tensile and flexural strength in dry and wet conditions.
To compare the tensile and flexural strength in dry and wet conditions.
To find the tensile and flexural strength reduction.
CHAPTER 2
9
LITERATURE REVIEW
There has been some study about moisture absorption and mechanical degradation of
composites in general.
Ridzuan et.al. reported that the effect of moisture absorption on the mechanical degradation
immersion, the hybrid composite specimens were tested. The tensile and flexural properties
significantly degraded under wet conditions. Similar results were also observed for their
moduli. The tensile and flexural strength of the P. purpureum/glass–epoxy composites were
Londhe et.al. investigated that natural fibres are widely used in the area of composite material
applications because of their low density, low cost and acceptable specific mechanical
properties. However natural fibres have some disadvantages such as the poor water resistance
due to hydrophilic cellulose fibres resulting in poor mechanical properties. The effect of
Stark et.al. reported that wood-plastic composites are being examined for a greater number of
structural- type applications that may be exposed to different environments, some of them
adverse. Tensile properties and notched impact strengths decreased only for
composites placed in a water bath. Decrease of tensile and flexural properties in the
Pe´rez-Pacheco et.al. showed that carbon fibre/epoxy unidirectional laminated composite was
exposed to a humid environment and the effect of moisture absorption on the mechanical
properties and failure modes was investigated. The composites were exposed to three
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humidity conditions, at a constant temperature of 25 Degree Celsius. The carbon fibre–epoxy
laminated composites for two different carbon fibre surface treatments were used. The results
showed that the mechanical properties differ considerably for each fibre surface treatment. [7]
liquid and humid air. The amount of moisture absorbed by material immersed in distilled
water and in saturated salt water depends both on the immersion time and on temperature. [3]
Akbar et.al. investigated that Moisture diffusion studies were carried out on the carbon-epoxy
composite have been performed for three different cases with respect to different relative
absorption was correlated to the fracture mode of the laminate demonstrating the deleterious
effect of moisture on the interface which leads to de-bonding between fibre and matrix. The
maximum moisture content increased with the increase in relative humidity. The diffusivity
remains practically the same for all hydrothermal conditions considered. [1]
Kumosa et.al. reported the composites were exposed to a moist environment with a relative
humidity at a certain temperature, and their resistance to moisture absorption in terms of the
rate of moisture absorption, maximum moisture content and apparent diffusivities was
determined. The modified polyester based composites exhibited the worst moisture
however these materials did not reach equilibrium and kept slowly taking on more moisture
in a non-Fickian manner.[5]
Praveen et.al. investigated that hybridization avoids complex lay-up designs and provides
better tuning compatibility to get desired properties in comparison with their mono-fibre
counterpart. The characteristics of hybrid composites, where more than one type of fibre is
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Selzer et.al. examined that the effect of moisture on the mechanical properties and the failure
introduced into the specimens by immersion in distilled water the distinct fall of the matrix-
and interface-based values due to moisture can be ascribed to the weakening of bonding
between fibre and matrix and softening of the matrix material. The epoxy matrix becomes
softer with moisture absorption, and the fibre-matrix adhesion poorer. [9]
composites were examined. To the best of our knowledge, this is the first time a study has
been conducted on this specific composites and this study should provide new information to
CHAPTER 3
MATERIALS USED
There are many materials used in completing this study. They are listed & explained below.
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3.1 CARBON FIBRE
Carbon fibre is most notably used to reinforce composite materials, particularly the class of
materials known as carbon fiber or graphite reinforced polymers. These were bought from
Hindoostan Composite Solutions. They are cut into length that is required according to
ASTM standards.
a plastic reinforced by fine glass fibres. These were bought from Hindoostan Composite
Solutions. They are cut into length that is required according to ASTM standards.
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Fig.3.2. Glass fibre fabric.
Epoxies are used in producing fibre-reinforced or composite parts. The epoxy used are
3.4 BEAKERS
The composite after it is cut into required size they are immersed in the immersion liquids
inside beakers. There should be at least two beakers as there is two different immersion
liquids. They should be able to be tightly sealed to prevent leakage of the solution.
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3.5 HANDHELD CUTTER
The composite is needed to cut it into specific dimensions. This was achieved with the help of
hand held metal cutter. This helped cutting composite into the specific dimension and
In this the composite is immersed in two different solutions. They are distilled water and
acidic solution. They are poured into beakers and the composite is immersed in the solution
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CHAPTER 4
METHODOLOGY
Review of literature
Selection of fibres
Carbon Glass
Fabrication
Immersion of composite
16
A
Tensile Testing
Record results
Compare results
Conclusion
Literature review was conducted; various journals, review papers, and books were read. Then
fibres required to make the composite was selected. Carbon and glass were the selected
fibres. Then hand lapping was selected as fabrication method. Composites are fabricated.
Carbon, glass and hybrid composites. The composites are then cut according to ASTM
standards. Then the specimens are immersed in distilled water and acidic solution for 50
hours. They are taken out and tested for tensile strength in an UTM. Results are recorded and
17
CHAPTER 5
FABRICATION
It is a process that involves some form of moulding, to shape the resin and reinforcement.
The most basic fabrication method for composites is hand layup. This is the method that is
being used here. Firstly fibre is cut at 300x300x.50 mm. Mixture of epoxy resin and hardener
in the 10:1 ratio is taken. Then two tile pieces are taken, one is placed as a base. On top of it
paper is placed. On top of that one strip of fibre is taken and the adequate mixture is spread
upon it. Then next layer is taken and process is repeated until required thickness is achieved.
Then another paper is placed on top of it and another tile is placed on top of it. Then on top of
the tiles a load is placed on it for compression process for composite to be set.
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Fig.5.2. Load being applied.
19
The load is left on top of it for 24 hours. Composite fabricated is taken out from between the
tiles. Edges of the composite is trimmed to remove the dried up epoxy resin at edges. The
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CHAPTER 6
EXPERIMENTATION
Composites taken for testing is cut into specification required according to the ASTM
standards. It is cut into 250x25x3 mm. Several pieces of required specification are cut.
21
Specimens with 250x25x3 mm were immersed in liquids at room temperature for up to 50
hours. One specimen is immersed in distilled water and other is immersed in acidic solution.
The both dry and wet specimens are weighed after 50 hours using an using digital balance
Composite specimens are tested by attaching them in universal testing machine. This helps in
determining the strength of the composite material subjected to a simple stretching operation
before moisture absorption and after moisture absorption. Tensile strength of composite in
For bending test specimen is fixed at two points and a load is applied at the middle until
specimen breaks, the load applied is noted. This operation is done before and after moisture
22
Fig.6.3. Tensile tested specimen.
23
Fig.6.5. Flexural tested specimen.
The mass change of the samples was recorded after 50 hours. The moisture uptake, expressed
Where
24
Flexural strength reduction percentage is given as:
25
CHAPTER 7
RESULTS
Object 7
26
Table.7.2. Weight And Moisture Absorption Percentage Of Glass Composites.
Object 9
27
Dry 51 0
Wet(Distilled Water) 54 5.88
Wet(Acidic Solution) 55.1 8.03
Object 11
Tensile testing for carbon, glass and hybrid composite specimen are done and results for the
Tensile strength of carbon composite in dry, distilled water and acidic solution conditions are
found out. It is done so by dividing ultimate or peak load by cross sectional area.
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Object 13
The tensile strength of carbon composite is maximum when it is in dry condition it is because
mechanical properties of the composite has not been impaired by the moisture. In wet
Tensile strength of glass composite in dry, distilled water and acidic solution conditions are
found out. It is done so by dividing ultimate or peak load by cross sectional area.
29
Object 15
The tensile strength of glass composite is maximum when it is in dry condition it is because
mechanical properties of the composite has not been impaired by the moisture. In wet
Tensile strength of hybrid composite in dry, distilled water and acidic solution conditions are
found out. It is done so by dividing ultimate or peak load by cross sectional area.
30
Object 17
The tensile strength of hybrid composite is maximum when it is in dry condition it is because
mechanical properties of the composite has not been impaired by the moisture. In wet
Tensile strength of the composite is the highest when it is in the dry condition.
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Object 20
strength.
32
Object 23
Tensile strength reduces more in acidic solution when compared to distilled water because
33
Object 25
Tensile strength reduces more in acidic solution when compared to distilled water because
34
Object 27
Tensile strength reduces more in acidic solution when compared to distilled water because
Tensile strength reduction due to distilled water vary with each composite.
35
Object 30
Tensile strength reduction is not uniform across different composite. It is dependent upon the
Tensile strength reduction due to acidic solution vary with each composite.
36
Object 32
Tensile strength reduction is not uniform across different composite. It is dependent upon the
37
Flexural testing for carbon, glass and hybrid composite has been done. The results are
recorded.
Flexural strength of carbon composite has been found out. It is done so from the load applied
Object 34
because mechanical properties of the composite has not been impaired by the moisture. In
38
Flexural strength of glass composite has been found out. It is done so from the load applied
Object 36
The flexural strength of glass composite is maximum when it is in dry condition it is because
mechanical properties of the composite has not been impaired by the moisture. In wet
39
Flexural strength of hybrid composite has been found out. It is done so from the load applied
Object 38
because mechanical properties of the composite has not been impaired by the moisture. In
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Flexural strength of composites is highest when it is in dry condition.
Object 40
Flexural strength of carbon is higher than glass and hybrid due to its fibre having higher
flexural strength.
41
Flexural strength of carbon composite reduces with moisture absorption.
Object 42
Flexural strength reduces more in acidic solution when compared to distilled water because
42
Flexural strength of glass composite reduces with moisture absorption.
Object 44
Flexural strength reduces more in acidic solution when compared to distilled water because
43
Flexural strength of hybrid composite reduces with moisture absorption.
Object 46
Flexural strength reduces more in acidic solution when compared to distilled water because
44
Flexural strength reduction due to distilled water vary with each composite.
Object 48
Flexural strength reduction is not uniform across different composite. It is dependent upon
45
Flexural strength reduction due to acidic solution vary with each composite.
Object 50
Flexural strength reduction is not uniform across different composite. It is dependent upon
CHAPTER 8
46
CONCLUSIONS
Carbon, glass and hybrid composites all absorb moisture in wet condition and they all
water because more of acidic solution is absorbed by the composites. Tensile and
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