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ABSTRACT: The degradation of tetracycline by anode oxidation with Ti/RuO2 –IrO2 electrode was carried out in
an electrochemical cell. The effect of operating conditions such as electrical current density, initial pH, antibiotic
concentration, electrolyte concentration and hydroxyl radical scavenger on the oxidation of tetracycline was investigated.
The results showed that the degradation of tetracycline followed apparent pseudo-first-order kinetics. The rate constant
increased linearly with the current density, but the oxidation curves displayed the same dependence on the amount
of the specific charge passed. The degradation rate decreased with the initial antibiotic concentration. Either initial
pH or electrolyte concentration had little effect on the electrochemical oxidation of tetracycline. The presence of tert-
butanol did not hinder the degradation rate, indicating the radical contribution to the oxidation of tetracycline could be
neglected. 2009 Curtin University of Technology and John Wiley & Sons, Ltd.
Degradation of tetracycline
Effect of initial antibiotic concentration ratio. There is no significant difference for the cal-
culated rate constant (0.034 ± 0.001 min−1 ) values at
Figure 5(a) illustrates the degradation of tetracycline at different tert-butanol concentrations. Therefore, the rad-
different initial antibiotic concentrations when current ical contribution to the oxidation of tetracycline could
density is 47.6 mA cm−2 , electrolyte concentration is be neglected.
0.1 mol l−1 and initial pH value is 3.9. The degradation
rate of tetracycline was found to be decreased and
having no proportional variations with increase in the
initial concentration (Fig. 5(b)). The electrochemical CONCLUSION
oxidation of tetracycline would lead to the production
of intermediates, which may also simultaneously be The electrochemical method can effectively degrade
degraded on the anode by direct electron transfer tetracycline in aqueous solution. The oxidation of tetra-
and by hydroxyl radicals according to the reaction[2] . cycline followed apparent pseudo-first-order kinetics.
The decrease in rate of tetracycline degradation may The pseudo-first-order rate constant increased linearly
be due to the competitive reaction of the daughter with the current density, but the oxidation curves
compounds with the parent compound on the anode. showed the same dependence on the amount of the
Although the removal efficiency of tetracycline is specific charge passed. The degradation rate decreased
lower at the higher initial concentration, the total with the increasing initial antibiotic concentration. Ini-
amount of degraded tetracycline is increased. After tial pH and electrolyte concentration had little effect on
60 min reaction, a tetracycline removal efficiency of the electrochemical oxidation of tetracycline. The pres-
89.1% was achieved at the initial concentration of ence of tert-butanol did not slow down the degradation
50 mg l−1 compared with 82.2% at 200 mg l−1 initial rate, indicating anode oxidation of tetracycline mainly
concentration, corresponding to 44.6 and 164.5 mg l−1 proceeded through direct electron transfer from organics
of degraded tetracycline, respectively. to anode.
2009 Curtin University of Technology and John Wiley & Sons, Ltd. Asia-Pac. J. Chem. Eng. 2009; 4: 568–573
DOI: 10.1002/apj