Condiciones de entrada y salida del gas y operación de la Torre

Composición gas de entrada

CO2 15,0%
SO2 0,56%
N2 83,0%
O2 1,4%
Caudal del gas de entrada: 0.5 m^3/s
Temperatura de entrada del gas: 25°C
Presión:700 Kpa
Composición de SO2 en gas de salida: 0.01%

Para entra del líquido determinamos 2 veces el flujo mínimo

Flujo de entrada del gas

𝑦𝑛𝑝+1 = 0.0056

𝑦1 = 0.0001

𝑚3 700 𝐾𝑝𝑎
𝐺𝑁𝑝+1 = 0.5 ( )
𝑠 𝐿 𝐾𝑝𝑎 1 𝑚3
8.31 (1000𝐿) (298 𝐾)
𝑚𝑜𝑙 𝐾

𝑚𝑜𝑙
𝐺𝑁𝑝+1 = 141,3353
𝑠

𝐺𝑆 = 𝐺𝑛𝑝+1 (1 − 𝑦𝑛𝑝+1 )
𝑚𝑜𝑙
𝐺𝑆 = 140,5439 𝑠
𝑃𝑣𝑎𝑝𝑜𝑟
𝑦𝑛𝑝+1 = 𝑃𝑡
∗ 𝑥𝑛𝑝
𝑦𝑛𝑝+1∗𝑃𝑡
= 0,0071 = 𝑥𝑛𝑝
𝑃𝑣𝑎𝑝𝑜𝑟
𝑌 𝑛𝑝+1
𝑦𝑆1 = = 0,0056
(1 − 𝑌𝑛𝑝+1 )
𝑋 𝑛𝑝
𝑋𝑠 = = 0,0071
(1 − 𝑋𝑛𝑝 )

Gs*Ys1+Lo*Xo=Gs*Y1+LsX
𝐺𝑠 (𝑌𝑠1 − 𝑌1)
𝐿= = 77.7657 Flujo mínimo
(𝑋𝑠 − 𝑋𝑜)
Ecuaciones de Entalpias

𝐻𝐺 = (1 − 𝑦)(37.51 + 29.51 + 29.12)(𝑡𝐺 − 25) + 𝑥 (39.5)(𝑡𝐺 − 25) + 25755.52𝑦

 𝐻𝐺 = (𝑡𝐺 − 25)(96.14 − 56.64𝑦) + 25755.52𝑦

𝐻𝐿 = (1 − 𝑥)(28.03)(𝑡𝐿 − 25) + 𝑥 (40.4)(𝑡𝐿 − 25)

𝐻𝐿 = (𝑡𝐿 − 25)(28.03 + 12.37𝑥)
Entrada de gas

𝑦𝑁𝑝+1 = 0.0056

𝑚𝑜𝑙
𝐺𝑁𝑝+1 = 100,9538
𝑠
Entalpías de entrada y salida de la torre de absorción

(𝑡𝐺𝑁𝑝+1 − 25) = 0 ; (𝑡𝐿0 − 25) = 0

𝐻𝐺𝑛𝑝+1 = (𝑡𝐺𝑛𝑝+1 − 25)(96.14 − 56.64𝑦𝑛𝑝+1 ) + 25755.52𝑦𝑛𝑝+1

𝐻𝐺𝑁𝑝+1 = 144.2309

𝐻𝐿0 = (𝑡𝐿0 − 25)(28.03 + 12.37𝑥0)

𝐻𝐿0 = 0

Entrada liquido

𝑥0 = 0
𝑚𝑜𝑙
𝐿0 = 77.7657
𝑠
Salida gas

𝑦1 = 0.0001
Flujo de gas que ingresa es igual al flujo del gas que sale

𝐺𝑁𝑝+1 (1 − 𝑦𝑁𝑝+1 ) = 𝐺1 (1 − 𝑦1 )

𝐺𝑁𝑝+1 (1 − 𝑦𝑁𝑝+1 )
𝐺1 =
(1 − 𝑦1 )
(100,9538)(1 − 0,0056)
𝐺1 =
(1 − 0.0001)
𝑚𝑜𝑙
𝐺1 = 100,39850
𝑠
Salida del líquido

Balance General

𝐿0 + 𝐺𝑁𝑝+1 = 𝐺1 + 𝐿𝑁𝑝

77,7657 + 100,9538 = 100,3985 + 𝐿𝑁𝑝

𝐿𝑁𝑝 = 78,3210

𝐿0 𝑥𝑜 + 𝐺𝑁𝑝+1 𝑦𝑁𝑝+1 = 𝐺1 𝑦1 + 𝐿𝑁𝑝 𝑥𝑛𝑝

(77,7657)(0) + (100,9538)(0.0056) = (100,3985)(0.0001) + (78,3210)𝑥𝑛𝑝

𝑥𝑛𝑝 = 0,0071

Suponiendo 1 Grado más para encontrar entalpias de salida de los Gases (luego se verificará)

𝐻𝐺1 = (𝑡𝐺1 − 25)(96.14 − 56.64𝑦1 ) + 25755.52𝑦1

𝐻𝐺1 = (26 − 25)[86.14 − 56.64(0.0001)] + 25755(0.0001)

𝐻𝐺1 = 98,7099
Balance de entalpias, proceso adiabático

𝐿𝑜𝐻𝐿 + 𝐺𝑁𝑝+1 𝐻𝐺𝑁𝑝+1 = 𝐿𝑁𝑝 𝐻𝐿𝑁𝑝 + 𝐺1 𝐻𝐺1 + 𝑄 ∗ 𝑇

(100,9538)(48,4081) = (78,3210)𝐻𝐿𝑁𝑝 + 100,3985(98,7099)

𝐻𝐿𝑁𝑝 = 59,3753

𝐻𝐿𝑛𝑝 = (𝑡𝐿𝑛𝑝 − 25)(28.03 + 12.37𝑥𝑛𝑝) = 59,3753

(𝑡𝐿𝑁𝑝 − 25)[28.03 + 12.37(0,0071)] = 59,3753

𝑡𝐿𝑁𝑝 = 24,8219°𝐶 → 𝑝𝑣𝑎𝑝𝑜𝑟𝐶𝑆2 = 368,4808 𝐾𝑝𝑎

𝑝𝑣𝑎𝑝𝑜𝑟𝐶𝑆2 ∗𝑋𝑁𝑝
𝑦𝑁𝑝 =
𝑃𝑡
368,4808
𝑦𝑁𝑝 = ∗ 0,0071
500
𝑦𝑁𝑝 = 0,0052

Balance del flujo gas que entra y sale del primer plato

𝐺𝑁𝑝 (1 − 𝑦𝑁𝑝 ) = 𝐺𝑁𝑝+1 (1 − 𝑦𝑁𝑝+1 )

𝐺𝑁𝑝+1 (1 − 𝑦𝑁𝑝+1 )
𝐺𝑁𝑝 =
(1 − 𝑦𝑁𝑝 )
 100,9538(1 − 0.0056)
𝐺𝑁𝑝 =
(1 − 0,0052)
𝐺𝑁𝑝 = 100,7348

Entalpia del gas

𝐻𝐺𝑛𝑝 = (𝑡𝐺𝑛𝑝 − 25)(96.14 − 56.64𝑦𝑛𝑝 ) + 25755.52𝑦𝑛𝑝

𝐻𝐺𝑁𝑝 = (24,8219 − 25)(86.14 − 56.64 (0,0052)) + 25755.52(0,0052)

𝐻𝐺𝑁𝑝 = 117,5080

Plato Np-1

𝐿𝑁𝑝−1 + 𝐺𝑁𝑝+1 = 𝐿𝑁𝑝 + 𝐺𝑁𝑝

𝐿𝑁𝑝−1 = 𝐿𝑁𝑝 + 𝐺𝑁𝑝 − 𝐺𝑁𝑝+1

𝐿𝑁𝑝−1 = 78,3210 + 100,7348 − 100,9538

𝐿𝑁𝑝−1 = 78,1019

(𝐿𝑁𝑝−1 )(𝑥𝑁𝑝−1 ) = (𝐿𝑁𝑝 )(𝑥𝑁𝑝 ) + (𝐺𝑁𝑝 )(𝑦𝑁𝑝 ) − (𝐺𝑁𝑝+1 )(𝑦𝑁𝑝+1 )

(78,3210)(0,0071) + (100,7348)(0,0034) − (100,9538)(0,0056)

(𝑋𝑁𝑝−1 ) =
78,1019
(𝑋𝑁𝑝−1 ) = 0,0043

Entalpia del líquido Np-1

𝐿𝑁𝑝 𝐻𝐿𝑁𝑝 + 𝐺𝑁𝑝 𝐻𝐺𝑁𝑝 − 𝐺𝑁𝑝+1 𝐻𝐺𝑁𝑝+1
𝐻𝐿𝑁𝑃−1 =
𝐿𝑁𝑝−1

(78,3210)(−64,1379) + (100,7348)(117,5080) − (100,9538)(48,4081)

𝐻𝐿𝑁𝑃−1 =
(78,1019)
𝐻𝐿𝑁𝑃−1 = 24,8851

𝐻𝐿𝑛𝑝−1 = (𝑡𝐿𝑛𝑝−1 − 25)(28.03 + 12.37𝑥𝑛𝑝 − 1) = 24,8851

24,8851
𝑡𝐿𝑁𝑝−1 = + 25
(28.03 + 12.37𝑋𝑁𝑝−1 )

𝑡𝐿𝑁𝑝−1 = 24,0691°𝐶 → 𝑝𝑣𝑎𝑝𝑜𝑟𝐶𝑆2 = 354,8837𝐾𝑝𝑎

𝑝𝑣𝑎𝑝𝑜𝑟𝐶𝑆2 ∗𝑋𝑁𝑝−1
𝑦𝑁𝑝−1 =
𝑃𝑡
354,8837
𝑦𝑁𝑝−1 = ∗ 0,0043
500
 𝑦𝑁𝑝−1 = 0,0047

𝐺𝑁𝑝 (1 − 𝑦𝑁𝑝 ) (117,5080)(1 − 0,0052)

𝐺𝑁𝑝−1 = = = 100,8615
(1 − 𝑦𝑁𝑝−1 ) (1 − 0,0047)

𝐻𝐺𝑛𝑝−1 = (𝑡𝐺𝑛𝑝−1 − 25)(96.14 − 56.64𝑦𝑛𝑝−1 ) + 25755.52𝑦𝑛𝑝−1

𝐻𝐺𝑁𝑝−1 = (24,8219 − 25)(86.14 − 56.64 (0,0047)) + 25755.52(0,0047)

𝐻𝐺𝑁𝑝−1 = 31,5356

Como está por encima de la composición de salida deseada del gas seguimos con el siguiente
plato

Plato Np-2

Balance del plato Np-1

𝐿𝑁𝑝−2 + 𝐺𝑁𝑝 = 𝐿𝑁𝑝−1 + 𝐺𝑁𝑝−1

𝐿𝑁𝑝−2 = 𝐿𝑁𝑝−1 + 𝐺𝑁𝑝−1 − 𝐺𝑁𝑝

𝐿𝑁𝑝−2 = (78,2830) + (100,8615) − (100,9158)

𝐿𝑁𝑝−2 = 78,2287

𝐿𝑁𝑝−2 𝑥𝑁𝑝−2 + 𝐺𝑁𝑝 𝑦𝑁𝑝 = 𝐿𝑁𝑝−1 𝑥𝑁𝑝−1 + 𝐺𝑁𝑝−1 𝑦𝑁𝑝−1

(78,2830)(0,0066) + (100,8615)(0,0047) − (100,9158)(0,0052)

𝑥𝑁𝑝−2 =
(78,2287)
𝑥𝑁𝑝−2 = 0,0059

Entalpia del Liquido

𝐿𝑁𝑝−1 𝐻𝐿𝑁𝑝−1 + 𝐺𝑁𝑝−1 𝐻𝐺𝑁𝑝−1 − 𝐺𝑁𝑝 𝐻𝐺𝑁𝑝
𝐻𝐿𝑁𝑃−2 =
𝐿𝑁𝑝−2

(78,2830)(24,8851) + (100,8615)(31,5356) − (100,9158)(117,5080)

𝐻𝐿𝑁𝑝−2 =
12,9618
𝐻𝐿𝑁𝑝−2 = −86,0247

𝐻𝐿𝑛𝑝−2 = (𝑡𝐿𝑛𝑝−2 − 25)(28.03 + 12.37𝑥𝑛𝑝 − 2) = −86,0247

24,8851
𝑡𝐿𝑁𝑝−2 = + 25
(28.03 + 12.37𝑋𝑁𝑝−2 )

𝑡𝐿𝑁𝑝−2 = 23,7614°𝐶 → 𝑝𝑣𝑎𝑝𝑜𝑟𝐶𝑆2 = 380,2741𝐾𝑝𝑎

𝑝𝑣𝑎𝑝𝑜𝑟𝐶𝑆2 ∗𝑋𝑁𝑝−2
𝑦𝑁𝑝−2 =
𝑃𝑡
380,2741
𝑦𝑁𝑝−2 = ∗ 0,0059
500
 𝑦𝑁𝑝−2 = 0,0046

𝐺𝑁𝑝−1 (1 − 𝑦𝑁𝑝−1 ) (100,8615)(1 − 0,0047)

𝐺𝑁𝑝−2 = = = 100,8521
(1 − 𝑦𝑁𝑝−2 ) (1 − 0,0046)

𝐻𝐺𝑛𝑝−2 = (𝑡𝐺𝑛𝑝−2 − 25)(96.14 − 56.64𝑦𝑛𝑝−2 ) + 25755.52𝑦𝑛𝑝−2

𝐻𝐺𝑁𝑝−2 = (24,8219 − 25)(86.14 − 56.64 (0,0047)) + 25755.52(0,0047)

𝐻𝐺𝑁𝑝−2 = 31,5356