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PETROLEUM SOCIETY PAPER 2002-256

CANADIAN INSTITUTE OF MINING, METALLURGY & PETROLEUM

Sand Production in Oil Sand


Under Heavy Oil Foamy Flow
R.C.K. Wong
The University of Calgary

This paper is to be presented at the Petroleum Society’s Canadian International Petroleum Conference 2002, Calgary, Alberta,
Canada, June 11 – 13, 2002. Discussion of this paper is invited and may be presented at the meeting if filed in writing with the
technical program chairman prior to the conclusion of the meeting. This paper and any discussion filed will be considered for
publication in Petroleum Society journals. Publication rights are reserved. This is a pre-print and subject to correction.

ABSTRACT INTRODUCTION
Sand production and foamy oil flow are the two key Sand production and foamy oil flow are interrelated
factors contributing the success in cold flow production mechanisms in primary production (cold production) of
in Alberta and Saskatchewan. However, two mechanisms heavy oil reservoirs in Alberta and Saskatchewan.
have been treated and studied separately as Massive sand production could cause excessive
geomechanics and multiphase flow problems, deformation in oil sand and overburden resulting in
respectively. Special experiments were designed to detrimental effects on the production facilities. However,
combine these two processes, and conducted to study sand control measures tend to reduce the oil production
their interaction. The experiments involved flow of dead rate. Numerical studies have been conducted to predict
and live heavy oil in undisturbed heavy oil sand cores. It sand production in heavy-oil reservoirs (Wong et al.
was found that gas nucleation in heavy-oil is the major 1994; Geilikam et al. 1994; Geilikam et al. 1995; Fang
factor in causing initiation of sand production in oil and Wong 1996). However, limited experimental work
sand. This finding is consistent with field observation. A has been performed to study the sand production in oil
model for sand production in heavy oil reservoir is sand. Trembaly et al. (1996; 1997) used computer
developed based on field and experiment observation. tomography imaging technique to examine the sand
This model includes the effects of geomechanics and gas production process in sand pack columns using dead oil
exsolution phenomena such as strength of oil sand, stress injected at a constant rate. They observed that a channel-
distribution in the reservoir, solution gas diffusion, foamy like cavity was developed and evolved under a critical
oil gas and fluid phase properties. flow pressure gradient. However, there is no
experimental reported study on sand production using

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natural oil sand cores and live heavy oil. The main and 150 mm in height to a porosity of 33% close to the in
objective of the paper is to investigate the effects of situ state using moisture tampering method, and (iv)
bitumen, oil sand interlocked structure, pressure gradient, freeze the specimen inside the steel mold under a small
and gas exsolution on sand production near a perforation axial load. The frozen specimen was allowed to thaw and
in heavy-oil reservoir. The first part of this paper consolidate under a 200-kPa confining pressure inside the
describes testing material, testing equipment, test details triaxial cell with a 0.3-inch hole disc (Fig. 1). After
and results. The second part focuses on interpretation and consolidation, the confining pressure was gradually
analysis of test results and observation, followed by increased. It was observed that sand was pushed out
conclusions. Details of mathematical models used in the through the hole and the neoprene sleeve burst when the
analysis of test results are presented in Appendix. confining pressure was increased to 1.3 MPa. This
finding is consistent with the results observed from the
TESTING MATERIAL AND EQUIPMENT borehole stability tests on reconstituted oil-free oil sand
hollow cylindrical specimens (Wong and Leung 2002). In
The oil sand cores for the experimental study
their tests, sand around the hole started to deform and
presented in this paper were recovered at a depth of 424
yield inward when the external confining pressure
m from an observation well (3-66-4-W4M) at a site near
applied to the hollow cylindrical specimen has reached to
Cold Lake, Alberta. Core sampling was carried out using
750 kPa. Massive yielding occurred at a pressure of 850
a conventional rotary core barrel of 89 mm inside
kPa.
diameter. Cores recovered were frozen at site and kept
inside PVC tubes in a freezer. Prior to any testing, the Oil-removed Oil Sand Specimens under
frozen cores were x-rayed for sample selection. Constant Flow Rate Injection and Choking
The objective of this test series is to study the effect of
A high-pressure (70-MPa capability) stainless steel
bitumen as a binding material on sand production in oil
triaxial cell was used to conduct the sand production
sand specimen under constant flow rate fluid injection
tests. The top and bottom platens used to provide
and choking. An intact oil sand specimen was secured
confining pressure to the test core were modified to allow
inside a Teflon shrinkable sleeve with two stainless
fluid injection and sand production (Fig. 1). Inlet and
sintered porous ends. Bitumen was removed from the oil
outlet drainage ports were provided at the top and bottom
sand specimen using Dean-Stark distillation method,
platens so that fluid could be injected through the core
followed by acetone distillation. Then, the oil-removed
using a displacement pump or pressurized reservoirs. The
specimen was mounted inside the triaxial cell with a 0.3-
bottom platen was made up of a removable disc and a
inch hole disc, and consolidated under a 10-MPa
hollow cylindrical section. The removable disc has a
confining pressure. Constant flow rate injection tests
circular hole of varying diameter (0.3, 0.5 and 0.8 inch)
were conducted with the outlet opened to atmosphere.
simulating the wellbore perforation. The hollow section
Water was injected at rates ranging from 0.33 to 1.2
with a recess was used to store any produced sand.
L/min for 7 hours. The oil-removed sand specimen had a
measured permeability value of 0.3 Darcy. The maximum
TEST DETAILS AND RESULTS pressure gradient measured across the specimen was
Reconstituted Oil-free Sand Specimen about 8.9 MPa/m. Traces of sand were produced. Then,
The objective of this test series is to study sand the sand production tests were repeated with 0.5- and 0.8-
production in reconstituted sand under constant flow rate inch hole discs. Again, small amount of sand was
fluid injection. The reconstituted oil sand specimen was produced.
prepared as follows: (i) remove the bitumen from the oil Then, a constant 3-MPa pressure was applied at the
sand cores using Dean Stark method, (ii) flush the sand upstream inlet using a pressurized water reservoir while
with acetone to make the sand water wet, (iii) compact the downstream outlet was closed. When the pore
the clean sand in a stainless mold of 89 mm in diameter pressure reached to the constant pressure, then the inlet

2
valve was opened instantaneously. This choking point pressure. When the outlet pressure dropped slightly
procedure was repeated for several times. X-ray image of below 2 MPa, sand was flushed out with foamy oil so fast
the specimen (Fig. 2) shows that some sand was produced that the test had to be terminated without rupturing the
forming a small conical cavity. Tensile fractures were neoprene sleeve. X-ray image of the specimen (Fig. 4)
also induced along the specimen length. shows that a bulb-like cavity was formed and tensile
parting was induced in the sand matrix around the cavity.
Oil Sand Specimen under Constant Pressure
Gradient and Choking ANALYSIS OF TEST RESULTS
The objective of this test series is to study sand Reconstituted Oil-free Sand Specimen
production in oil sand specimen under constant pressure
Sand started to yield and flow out of the 0.3-inch
gradient and choking. An intact oil sand specimen was
perforation hole when the confining pressure reached to a
consolidated under a 10-MPa confining pressure inside
value of 1.3 MPa. This is consistent with those
the triaxial cell with a 0.8 inch hole disc. Then, a constant
observations in the borehole stability tests (Wong and
3-MPa pressure was applied at the upstream inlet using a
Leung 2002). There was no support stress to the sand
pressurized water reservoir while the downstream outlet
face at the perforation. A sand arch was developed
was opened to atmosphere. The pressure gradient applied
around the perforation hole by mobilizing the friction of
to the specimen was 20 MPa/m that was much higher
sand particles since the strength derived from the
than those in the constant rate injection tests. However,
interlocked structure and bitumen was removed in the
no sand was produced after 2 hours of water injection.
reconstituted sand. When the confining stress exceeded
Then, the 3-MPa pressure choking procedure was the ultimate capacity of the sand arch, sand yielded and
applied to the specimen for several times. A channel-like flowed. Such stress induced sand yield and flow was not
cavity was developed at the perforation (Fig. 3). observed in experiments conducted by Trembaly et al.
(1996; 1997) because their sand specimen was packed
Oil Sand Specimen under Gas Exsolution
inside a rigid-walled long column and not subjected to a
The objective of this test series is to study sand
controlled confining stress. Thus, the sand production in
production in oil sand specimen under gas exsolution. An our series of tests is due to sand yielding caused by stress
intact oil sand specimen was consolidated under a 10- failure rather than fluid flow pressure gradient as detected
MPa confining pressure inside the triaxial cell with a 0.8
by Trembaly et al. (1996).
inch hole disc. Then, the specimen was saturated with
live heavy oil with a gas-oil ratio of 8 and viscosity of Oil-removed Oil Sand Specimens under
Constant Flow Rate and Choking
about 69000 cp at 21oC. The saturation process involved
displacement of dead heavy oil inside the specimen by In this series of tests, bitumen was removed from the
live oil while maintaining the pore pressure above the oil sand specimen to eliminate the effect of bitumen as a
bubble point pressure of 2 MPa. After two-pore volume binding material on the sand production and promote
displacement, then the pore pressure was maintained at a single fluid phase flow. Small amount of sand was
value of 3 MPa. The effective confining stress was 7 MPa produced under high rate water injection of 1 L/min. The
that was close to the in situ value. Then, the outlet measured pressure gradient across the specimen length
pressure was gradually decreased in step pressure was about 8.9 MPa/m. Wong et al. (1994) developed an
declines of 0.1 MPa while the upstream pressure was analytical solution relating the critical pressure gradient
maintained at a constant pressure of 3 MPa. In each step dp/dr destabilizing the sand arch around a cavity by shear
pressure decline, the pore pressure was allowed to failure:
equilibrate prior to the subsequent decline. Gas and oil
was produced and collected at the outlet. No sand was dp  φ 
= N c cot(45 o − )  ................................................. [1]
produced when the outlet pressure was above the bubble dr  2 

3
where N = shape factor (N = 2 and 4 for long circular and particles were washed out with the live oil
spherical cavities, respectively); c and φ = cohesion and instantaneously. It appears that the massive sand
friction angle of oil sand, respectively. Assuming φ = 45o production in this test was associated with gas exsolution
and N = 4, the back-calculated cohesion could be as high when the pressure dropped below the bubble point.
as 0.9 MPa that will be discussed in subsequent Consider the response of a sand element at the
paragraphs along with results from choking tests. perforation hole under the step pressure decline from 2 to
Oil Sand Specimen under Constant Pressure 1.9 MPa. In order to analyze the stability of the sand
Gradient and Choking element, it is necessary to study the interaction between
A constant differential pressure of 3 MPa applied to the matrix stress and foamy oil pressure. Solutions to
the specimen produces a pressure gradient of 20 MPa/m. such coupled problem are complex and difficult to obtain
Assuming φ = 45o and N = 4, the back-calculated (see Appendix). However, some assumptions can be
cohesion could be as high as 2.1 MPa. This cohesion made to produce tractable solutions. Since the sand was
value is much higher than those derived from the produced instantaneously in the step pressure decline, it
unconfined and triaxial compression tests of oil sand is reasonable to assume that free gas flow was not
reported in the literature. This peculiar behaviour raises significant. In addition, fluid flux in and out of the sand
the question as to why the oil sand is so strong around the element was small at the instant of sand production, i.e.,
perforation under flow flux. This behavior was also the sand element was subjected to an instantaneous
observed in the borehole stability tests in oil sand (Wong undrained unloading. The effective radial stress is always
and Leung 2002). They suggested that the effect of stress zero at the perforation since the confining pressure was
path, intermediate stress and size could enhance the shear provided by the fluid. With these simplifications, one
strength. Another important factor is the response of the only needs to determine the fluid pressure response of the
interlocked structure of oil sand under different imposed sand element under undrained unloading below the
boundary actions. The interlocked structure has low bubble point. The fluid pressure reacts to the step
resistance to tensile loading mode, but offers high pressure decline and drops from 2.0 to 1.9 MPa. Below
resistance to shearing mode, particularly in passive mode the bubble point, the live oil becomes supersaturated with
under confinement. High external compressive or shear dissolved gas solute resulting in gas exsolution. The fluid
load can be transmitted through the interlocked structure pressure starts to rebound as gas bubbles nucleate and
enhancing the overall stability. Thus, the resistance of the grow with no net flux. The final equilibrium pressure and
interlocked structure increases with confining pressure. It gas saturation can be determined by setting equation [A3]
was observed that interlocked oil sand was difficult to of Appendix to zero, i.e.
mine or erode under high pressure hydraulic jetting
(Sharpe et al. 1997). ∂ρ o ∂φ ∂( So )
φ (So ) + ρ o ( So ) + ρ oφ = 0 ..............[2]
Instant choking provides infinite pressure gradient at ∂t ∂t ∂t
the perforation, but this steep gradient only lasts for a
The first term of [2] relates to the change in volume
short duration. This explains why sand was produced in
due to fluid compressibility by pressure change. The
each choking procedure, but in a small amount.
second term defines the change in volume due to the sand
Oil Sand Specimen under Gas Exsolution matrix compressibility by pressure change. The third term
No sand was produced when the fluid pressure of live quantifies the evolution of oil or gas saturation due to gas
oil was reduced from 3 MPa to 2 MPa in pressure decline exsolution below the bubble point. For 0.1-MPa pressure
steps of 0.1 MPa. It took less than 15 minutes for the decline, the volume changes due to fluid and sand matrix
differential pressure between the upstream and compressibility are 0.0015% and 0.01% respectively,
downstream to equilibrate in each step. However, at the given that cf (fluid compressibility) = 4.8x10-4/MPa; ce
step pressure decline from 2 MPa to 1.9 MPa, sand (matrix compressibility) = 10-3/MPa; φ (porosity) = 0.32

4
(Wong et at. 1993; Wong et al. 1999). The gas saturation ratio (n) of the average spacing of bubbles (ζ) to the
at thermodynamic equilibrium is 0.0265% that is small to average diameter of the bubbles (d). The evolution of
affect the total compressibility. The gas bubbles evolved fluid pressure, gas saturation and effective radial stress
at this step pressure decline just below the bubble point are plotted against normalized time for n = 5 and 100, in
can be considered to be small, dispersed and rigid. This Figs. 6 to 8, respectively. The solution diffusion process
implies that the fluid pressure would rebound back to a depends on bubble density and spacing (n and ζ), and
pressure close to that before the decline. Based on the diffusion coefficient (D). It is important to note that the
mass balance of the gas phase existed in bubbles and effective radial stress becomes negative when the gas
solution, the equilibrium gas pressure in bubbles due to exsolution commences. It is postulated that the oil sand
changes in gas saturation and production is given by: would lose its interlocked grain contacts when the
negative effective stress exceeds the tensile strength of
 RT  the interlocked structure. Since the sand production
GOR ( 22.4 ) occurred almost instantaneously in the test, it infers either
 
pg = .................................. [3] the interlocked structure of oil sand has a low tensile
 (1 − α p ) RT 
 GOR ( ) + Sg  strength or the rate of gas exsolution is rapid. The tensile
 pb 22.4 
strength must be less than 0.1 MPa. Destabilization of
intact oil sand around a cavern was also observed in
where pg = gas pressure; GOR = solution gas-oil ratio; αp
hydraulic mining in deep heavy oil reservoir (Wong
= oil fraction produced from unit oil pore volume; pb =
1996). A 5-m wide cavern at a depth of 450 m was mined
bubble point; R = universal gas constant; T = absolute
out using high pressure water jetting. The cavern
temperature. For ideal gas law, one mole of gas occupies
remained stable when the fluid pressure inside the cavern
22.4 L. Undrained unloading condition satisfies the
was maintained at its hydrostatic pressure of 5 MPa.
condition of αp = 0, i.e., no net flux. In our case with GOR
However, when the fluid pressure was lowered to the
= 8, pb = 2 MPa, RT/22.4 = 0.101 MPa and Sg =
bubble point pressure of 2 MPa, massive sand was
0.0265%, the calculated pg is 1.998 MPa. For small
produced from mining. The cavern grew extensively to
capillary pressure effect, the gas pressure is equal to the
10 m wide. This field observation is in agreement with
fluid (oil) pressure. This justifies that the fluid pressure
those observed in this series of sand production tests.
rebounds back to a pressure close to that before the
decline. This is important to note this full pressure
rebound is only valid for unloading just below the bubble CONCLUSIONS
point or at small gas saturation. For high gas saturation, The following conclusions can be drawn from the sand
the total compressibility of the system is so large that a production experiments:
large amount of gas is required to pressurize the system.
• Sand production in remolded or reconstituted oil
The evolution time for thermodynamic equilibrium of sand pack is induced by stress induced yielding
gas exsolution depends on many factors such as bubble rather than fluid flow pressure gradient
nucleation site and population, imposed conditions
• The interlocked structure of natural oil sand
(pressure decline or withdrawal), gas-solution ratio and
provides a very high shear resistance against the
diffusion coefficient of dissolved gas (Szekely, J. and
seepage force generated by the fluid flow.
Martins, G.P. 1971; Kumar and Pooladi-Darvish 2001).
However, the oil sand is weak in resisting tensile
In this study, simplistic models are assumed for solution
failure mode.
diffusion of dissolved gas in live heavy oil (Craig 1997).
Gas solute diffuses towards the bubbles of constant • Solution gas evolved at the pressure state just
diameter, constant strength and fixed spacing (Fig. 5). below the bubble point could induce negative
Two bubble populations or densities were considered in effective stresses in oil sand at unsupported
the analysis. The bubble density (Fig. 5) is defined by the cavities or unscreened perforations. This unravels

5
the oil sand interlocked structure by tensile failure 9. Trembaly, B., Sedgwick, G. and Forshner, K. 1997.
or parting, resulting in massive sand production. Simulation of cold production in heavy oil
reservoirs: wormhole dynamics. SPE Reservoir
ACKNOWLEDGEMENT Engineering, pp. 110-117, May 1997.

This research investigation was funded through an 10. Wong, R.C.K., Barr, W.E. and Kry, P.R. 1993.
NSERC-Imperial Oil CRD Research Grant. Assistance Stress-strain response of Cold Lake oil sands.
provided by Bill Barr was appreciated. Canadian Geotechnical Journal, 30:220-235.
11. Wong, R.C.K., Samieh, A.M. and Kuhlemeyer, R.
REFERENCES 1994. Oil sand strength parameters at low effective
1. Craig, R.F. 1997 Soil mechanics; E & FN Spon, New stresses - its effects on sand production, Journal of
Canadian Petroleum Technology, 30(6), 44-50.
York, 481 pages.

2. Fung, L. and Wong, R.C.K. 1996. Modelling of 12. Wong, R.C.K. 1996. Behaviour of water pressurized
cavity stability and sand production in heavy-oil caverns in oil sand and shale. Canadian Geotechnical
reservoirs. Journal of Canadian Petroleum Journal, 33: 610-617.
Technology, 35 ( ): 46-52. 13. Wong, R.C.K., Guo, F., Weaver, J.S. and Barr, W.E.
3 . Geilikman, M.B., Dusseault, M.B. and Dullien, 1999. Heavy oil flow under solution-gas drive:
pressure depletion tests. Journal of Canadian
F.A.L. 1994. Sand production and yield propagation
Petroleum Technology, 38(4): 31-37.
around wellbores. Paper CIM 94-89 presented at the
1994 Annual Technical Conference, Calgary, 14. Wong, R.C.K. and Leung, K.C. 2002. Borehole
Alberta, June 12-15, 1994. stability oil sand in drilling. Journal of Canadian
4 . Geilikman, M.B., Dusseault, M.B. and Dullien, Petroleum Technology, 30 (1): 44-50.
F.A.L. 1995. Dynamic effects of foamy fluid flow n
sand production instability. Paper SPE 30251 APPENEDIX - COUPLED STRESS-FOAMY OIL
presented at the International Heavy Oil Symposium, FLOW PROBLEM
Calgary, Alberta, June 19-21, 1995. Sand production involves physical detachment of sand
particles from its matrix and transport through flow
5. Kumar, R. and Pooladi-Darvish, M. 2001. Effect of
medium. In order to analyze the mechanics triggering the
viscosity and diffusion coefficient on the kinetics of
initiation of detachment, it is necessary to study the
bubble growth in solution-gas drive in heavy oil.
equations governing the coupled mechanical-hydraulic
Journal of Canadian Petroleum Technology, 40(3):
process around a wellbore perforation.
30-37.
Equilibrium and Compatibility Equations
6. Sharpe, J.A., Shinde, S.B. and Wong, R.C.K. 1997.
Cold Lake borehole mining. Journal of Canadian Stresses around a spherical cavity under a hydrostatic
Petroleum Technology, 36(1): 58-63. overburden pressure are given by stress equilibrium and
strain compatibility equations, respectively:
7. Szekely, J. and Martins, G.P. 1971. Non-equilibrium
effects in the growth of spherical gas bubbles due to
solution diffusion. Chemical Engineering Science, dσ r σ −σ r
−2 θ = 0 ..............................................[A1]
26: 147-159. dr r
8. Trembaly, B., Sedgwick, G. and Forshner, K. 1996.
Imaging of sand production in horizontal pack by x- dε θ ε − εr
ray computed tomography. SPE Formation +2 θ = 0 .....................................................[A2]
dr r
Evaluation, pp. 94-98, June 1996.

6
where σr and σθ are total radial and tangential stresses,  kk kk rg  d [φ ( S g ρ g + ρ dg S o )]..... [A4]
∇ ⋅  ρ dg ro ∇po + ρ g ∇p g  =
respectively; εr and ε θ are radial and tangential strains,  µ µ  dt
 o g 
respectively; r is the radial distance. The strains can be
expressed in terms of total radial and tangential stresses, where ρg and ρd g are average free gas and dissolved gas
fluid (oil) pressure po and gas pressure pg using effective densities; krg is gas relative permeability values; pg is gas
stress-strain constitutive laws. pressure; Sg is gas saturation. In [A4], ρd gis highly
boundary condition dependent parameter that is governed
Mass Conservation Equations
by the gas exsolution process, i.e., mass diffusion of
Oil phase dissolved gas in oil phase to the bubbles of free gas
Oil is assumed to be the only mobile fluid phase, i.e., (Szekely and Martins 1971; Kumar and Pooladi-Darvish
water exists in a connate saturation. The continuity 2001)
condition yields the following equation:

Equations [A1] to [A4] provide a mathematical


 kk  dρ φS framework for the coupled stress-foamy oil flow process
∇ ⋅  ρ o ro ∇po  = o o .................................. [A3]
 µo  dt around a spherical cavity in oil sands. Total radial and
tangential stresses, oil pressure and oil saturation are the
where four dependent variables. Gas pressure can be related to
oil pressure using capillary pressure curve. Gas and oil
dρ oφS o ∂ρ ∂φ ∂ (S o )
= φ (S o ) o + ρ o ( S o ) + ρ oφ ; saturations are totaled to unity. The average dissolved gas
dt ∂t ∂t ∂t density is dependent on the gas pressure through Henry’s
ρο is oil density; k and kr ο are absolute and relative law. It can be seen that all four variables appear in each
of the four governing equations. Solutions to such fully
permeability values, respectively; φ is porosity; Sο is oil
coupled systems of equations are very complex and
saturation. In [A3], oil pressure, gas pressure and total
difficult. Since sand production is likely to occur at the
stresses are implicitly embedded.
periphery of the cavity, it is attempted to make some
Gas phase reasonable assumptions to make the solution tractable.
Gas phase exists as free gas in bubbles and dissolved
gas solute in oil. Thus, the mass conservation equation of
gas phase is given as:

7
triaxial cell

inlet

sleeve

core

disc
outlet

produced
sand
Fig. 1. Triaxial cell details for sand production tests Fig. 3. X-ray image of oil sand specimen under constant
pressure gradient and choking

Fig. 2. X-ray image of oil-removed oil sand specimen Fig. 4. X-ray image of oil sand specimen under gas
under constant flow rate injection and choking exsolution

8
bubble 0.03

0.025

Gas saturation (%)


η=5
0.02 η=100
0.015

2ζ 0.01

0.005

2ζ 0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
T=Dt/ζ2
perforation hole
Fig. 7. Evolution of gas saturation due to gas exsolution
zero effective in oil sand
radial stress

Fig. 5. Gas exsolution in a sand element near wellbore


perforation

2 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2


Fluid pressure (MPa)

0
1.98 η=5
Effective stress (kPa)

η=100 -20
1.96
-40
1.94
-60
1.92
-80 η=5 η=100
1.9
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 -100

T=Dt/ζ2 T=Dt/ζ2

Fig. 6. Evolution of fluid pressure due to gas exsolution Fig. 8. Evolution of effective stress due to gas exsolution
in oil sand in oil sand

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