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Journal of Cleaner Production 164 (2017) 939e949

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Journal of Cleaner Production


journal homepage: www.elsevier.com/locate/jclepro

Mechanical characterization of high performance concrete prepared


with recycled aggregates and silica fume from precast industry
D. Pedro a, J. de Brito a, *, L. Evangelista b
a
CERIS-ICIST, Instituto Superior T
ecnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal
b
CERIS-ICIST, University of Stavanger, Postboks 8600, 4036, Stavanger, Norway

a r t i c l e i n f o a b s t r a c t

Article history: The growth of the precast industry has led to the emergence of waste with enormous potential for
Received 1 February 2017 recycling, given the strict quality control of these companies and the need of construction/demolition of
Received in revised form structures with increasing strength capacities. In this investigation, an analysis of the mechanical
29 June 2017
behaviour of high-performance concrete (HPC) incorporating fine and coarse recycled aggregates (FRA
Accepted 30 June 2017
Available online 3 July 2017
and CRA) was made. The recycled aggregates (RA) originated from rejected precast elements with
compressive strengths of 75 MPa and were used to replace natural aggregates (NA) in concrete mixes.
The experimental campaign also included three families of concrete with proportions of densified silica
Keywords:
Precast
fume (SF) of 0%, 5% and 10% (relative and in addition to cement). Each family comprised a reference
Recycled aggregates concrete (RC) and three recycled aggregate concretes (RAC) with replacement ratios (FRA/CRA%) of 50/50,
Silica fume 0/100 and 100/100. The results obtained in the compressive strength, splitting tensile strength, modulus
High performance concrete of elasticity, ultrasonic pulse velocity and bond strength tests showed that it is possible to produce high-
Mechanical performance performance concrete without NA. The silica fume led to a performance increase in the properties
analysed with the creation of a new concrete mixing method that considered the specificities of RA and
the difficulties of dispersing SF particles.
© 2017 Elsevier Ltd. All rights reserved.

1. Introduction in chemical mixing and increased availability of mineral additions


led to the development of high-performance concrete (HPC). HPC
Concrete is one of the most common and useful materials in the can be seen as conventional concretes modified/optimized to meet
construction industry. Its development has been associated with special requirements. Therefore, the incorporation of recycled ag-
attempts of optimizing its performance, which is typically achieved gregates (RA) is expected to cause a decrease in their performance.
by changing its characteristics. These changes, in a first stage, Limbachiya et al. (2000) sought to understand this phenomenon
resulted from the adjustment of the proportions of the materials by conducting an experimental campaign where coarse recycled
and, later, from the incorporation of new constituents (fly ash, silica aggregates (CRA) from precast waste (PC) were incorporated in
fume, superplasticizers, among others). In the history of the evo- high strength concrete. The mixes were produced without mineral
lution of concrete, the first concerns in terms of performance were additions, using only superplasticizers (SP). The CRA were incor-
related to strength increase. Subsequently, technological advances porated considering substitution ratios of 0%, 20%, 50% and 100%,
with the w/c ratio being slightly adjusted so that all the blends
reached target strengths of 50 MPa, 60 MPa and 70 MPa. The results
showed that it was possible for recycled aggregate concrete (RAC)
Acronyms: C, cement; CNA, coarse natural aggregates; CRA, coarse recycled
aggregates; FA, fly ash; FNA, fine natural aggregates; FRA, fine recycled aggregates; to achieve compressive strengths identical to those of the reference
HPC, high performance concrete; NA, natural aggregates; PC, precast concrete concrete. The authors noted similar trends in flexural strength and
(source concrete); RA, recycled aggregates; RAC, recycled aggregates concrete; RC, modulus of elasticity, registering maximum variations of 4% with
reference concrete; SC, source concrete; SEM, Scanning Electron Microscopy; SF, the introduction of 100% CRA. Regarding the abrasion resistance,
silica fume; SP, superplasticizer; UPV, ultrasonic pulse velocity; w/c ratio, water/
cement ratio; w/b ratio, water/binder ratio.
they also found that, for the different target strengths, RAC ach-
* Corresponding author. ieved a similar value to that of concrete with natural aggregates,
E-mail addresses: diogo.pedro@tecnico.ulisboa.pt (D. Pedro), jb@civil.ist.utl.pt regardless of the replacement ratio used in the mix. The
(J. de Brito), luis.m.evangelista@uis.no (L. Evangelista).

http://dx.doi.org/10.1016/j.jclepro.2017.06.249
0959-6526/© 2017 Elsevier Ltd. All rights reserved.
940 D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949

performance variations did not exceed 6%. recycled aggregates from the lowest resistance SC. At 28 days, the
Ajdukiewicz and Kliszczewicz (2002) studied the effects of the RAC with 100% CRA from the 40 MPa SC exhibited a performance
incorporation of fine and coarse recycled aggregates (FRA and CRA) loss of about 27% when compared to RC. However, the reduction
from demolished concrete with medium/high strength was only 8.5% when CRA from the 100 MPa SC was used.
(35e70 MPa) on the performance of HPC. The composition of the More recently, Gonzalez et al. (2016) evaluated the influence of
mixes with RA was very similar to that of those with natural ag- steam curing on the pore structure and on the mechanical prop-
gregates (NA), and only slight corrections in the amount of water to erties of HPC produced with the same coarse recycled aggregates
obtain an adequate workability were made. The results showed from the previous investigation (SC with 40 MPa, 60 MPa and
that the properties of the source concrete (SC) decisively condi- 100 MPa). However, they only considered a 100% CRA replacement
tioned the mechanical properties of RAC. At 28 days, RAC incor- percentage. The results showed that, when compared to the
porating 100% recycled aggregates of different origins showed reference concrete, the use of high quality CRA (100 MPa SC) leads
decreases in compressive strength and modulus of elasticity, rela- to similar results in terms of pore structure and mechanical prop-
tive to the corresponding RC, of 5e20% and 20e30%, respectively. erties (compressive strength, splitting tensile strength and
However, not replacing the 0e2 mm fraction improved the prop- modulus of elasticity). On the other hand, the physical and me-
erties of RAC, with four of these mixes presenting better chanical properties of the HPC decreased with the reduction and
compressive strengths than the corresponding RC mixes. The quality of the CRA, and it was found that the recycled concrete
splitting tensile strength followed an identical trend. At 28 days, the subjected to steam curing obtained (with respect to the reference
authors observed a decrease in this property of 12e20% due to the concrete) greater porosity reductions up until 90 days.
incorporation of 100% RA and that, when the fraction 0e2 mm was Following the same line of research, Gonzalez and Etxeberria
not replaced, the performance improved. (2016) tried to evaluate the effects of three types of CRA on the
Tu et al. (2006) also evaluated the consequences of the intro- shrinkage of HPC. For replacements of 20%, 50% and 100%, these
duction of FRA and CRA in the production of HPC. The authors authors observed that both the plastic and drying shrinkage
considered two groups of mixes: the DR group in which only increased with the decrease of CRA quality and increase of the
recycled aggregates were used and the DN group in which coarse replacement percentage. However, they found that it was possible
recycled aggregates and natural sand were used. However, no to reduce the autogenous shrinkage through the use of CRA, justi-
reference concrete was produced. For each group, three w/c ratios fying this fact with the performance of these aggregates as internal
(0.32, 0.36 and 0.40) were considered. The mixes were designed curing agents. This phenomenon also served to explain the similar
using a methodology developed by Hwang that has been used in results between RAC and RC concerning the compressive strength.
several projects in Taiwan, namely in the construction of the Taipei Concerning the introduction of silica fume (SF), its influence on
101 skyscraper (Hwang et al., 1996; Hwang, 1999). This methodol- concrete can vary significantly, depending on the manner in which
ogy is characterized by the use of algorithms and the use of fly ash it is used. It should be noted that, in many countries, silica fume is
as an extra material in the mix, not as cement replacement. At 28 only marketed in the form of agglomerates of small particles
days, and for 0.32, 0.36 and 0.40 w/b ratios, the DR group showed a (densified dry SF) because of the ease of transport, handling and
decrease in mechanical strength of approximately 15%, 11% and 5%, storage. However, despite these operational advantages, the char-
respectively, when compared to the DN group. The authors acteristics of silica fume in that form can be different from those
compared the results of these two groups with high-performance expected, namely, they can be a much less reactive pozzolanic
concrete mixes produced with natural aggregates using similar material.
compositions (Hwang et al., 1996; Hwang, 1999), and found a In the research carried out by St. John (1994) it was shown that,
strength reduction of 20e30%. In view of these results, they sug- even after the application of ultrasonic scattering techniques, sig-
gested that it was necessary to increase the design strength when nificant proportions of densified silica fume particles were between
RA were used in the production of HPC. 10 mm and 100 mm, and that larger agglomerates (between 100 mm
Gonzalez and Etxeberria (2014) incorporated CRA from three and 1000 mm) still existed. The high level of agglomeration of SF
distinct SC mixes (with 40 MPa, 60 MPa and 100 MPa) in high- particles is reported in some research works on cementitious ma-
performance concrete. The mixes were produced with replace- terials and may be the basis of the variations in efficacy of this
ment ratios of 20%, 50% and 100%. The authors observed that, at 28 product (Bonen and Diamond, 1992; Lei et al., 2016; Zhang et al.,
days, the RAC and RC exhibited similar compressive strengths 2016). The existence of densified grains that, in comparison to the
(approximately 100 MPa). The highest variations (about 10%) were individual particles, exhibit a larger diameter and a smaller specific
registered in the mixes produced with 50% and 100% CRA from the surface area, may thus lead to lower pozzolanic reactivity. Indeed,
40 MPa SC. This result was justified by the poor quality of mortar in the research conducted by Bonen and Diamond (1992), it was
adhered to these recycled aggregates. The authors concluded that observed that the pozzolanic reaction can take place only around
the low w/c ratios and the more adequate binding strength of RA the surface of the agglomerates. Nevertheless, in the literature most
allowed RAC to exhibit the same behaviour as RC. The values of works either continue to refer to unprocessed silica or do not
ultrasonic pulse velocity (UPV) decreased with the increase of the mention the type of SF used (Diamond and Sahu, 2006).
substitution ratio and with the decrease of the SC quality. At 28 More recently, the effects of the incorporation of SF in concrete
days, for the 20%, 50% and 100% substitution ratios, RAC with CRA with recycled aggregates have also been studied, and variations in
from the 100 MPa SC exhibited reductions of UPV, when compared its efficacy still exist. For example, in the work carried out by
to RC, of about 2.5%, 2% and 9%, respectively. In the case of RAC with Gonza lez-Fonteboa and Martínez-Abella (2008), where SF was
CRA from the 40 MPa SC, the reductions were of 4%, 8% and 14%. In considered as an additional material, its presence was found to
the splitting tensile strength test RAC presented a performance have led to residual compressive strength increases in both RC and
identical or even superior to that of RC. Again, the only exception RAC. In the same sense, small differences in the properties of tensile
was RAC with 100% CRA from the 40 MPa SC. This mix showed a strength and modulus of elasticity were observed. In contrast, in
tensile strength approximately 20% lower than that of the RC. the investigation developed by Corinaldesi and Moriconi (2009), in
Finally, and considering the modulus of elasticity, the authors which mixes were produced with RA only, the compressive
observed a greater sensitivity of the mixes to the incorporation of strength of the RAC mixes (in cubes, at 28 days), increased from
RAC. The worst performances were obtained for RAC that used 29 MPa to 42 MPa, with the use of silica.
D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949 941

On the other hand, in the work carried out by Çakır and Sofyanlı products complying with EN 12620 (2002). Siliceous sands and
(2014), SF was used as a cement substitute and the results showed crushed limestone aggregates were used respectively, as FNA and
that the compressive strength, at young ages, decreased with its CNA. In turn, the recycled aggregates came from precast concrete
presence. However, at 28 and 90 days, the situation changed, with (PC) waste, with a mean compressive strength of 74.5 MPa. The RA
the mixes with SF showing greater strengths than the reference were subjected to primary and secondary crushing, which occurred
mix (without SF). In turn, Fallah and Nematzadeh (2017) concluded as a continuous process in a jaw crusher (primary crushing) and
that the use of nano-silica and silica fume was responsible for then passed through a hammer mill (secondary crushing). The
increasing the compressive strength by 14.0% and 41.1%, for crushing process occurred in a quarry, simulating the production
replacement percentages of 2% and 12%, respectively. Concerning conditions of NA.
the splitting tensile strength, the use of 3% nano-silica and 10% The aggregates (natural and recycled) were subjected to density
silica fume resulted in a performance increase of 16.1% and 28.4%, and water absorption tests (EN 1097-6, 2003). The shape index (EN
respectively. 933-4, 2002) and the resistance of coarse aggregates to fragmen-
In this context, this work intends to promote the use of recycled tation through the Los Angeles test (EN 1097-2, 2011) were also
concrete aggregates as an alternative to natural aggregates and also determined. In the case of FRA, and since EN 1097-6 does not
evaluate the use of a densified silica fume, in the production of HPC. consider the particularities of these aggregates, namely their
Hence, one of its main objectives is the creation of a more sus- cohesive and binding capacity (Rodrigues et al., 2013a; Evangelista
tainable high-performance concrete, minimizing the consumption and de Brito, 2014), it was necessary to determine their water ab-
of natural resources and thus significantly decreasing the envi- sorption by the method defined in Rodrigues et al. (2013b).
ronmental impacts. Estimates of the world’s consumption of nat- The results presented in Table 1 show that the recycled aggre-
ural aggregates for concrete production, point to values of gates exhibited worse performances than the natural aggregates
37.4  103 million tons in 2010 and 48  103 million tons in 2015, due to the presence of adhered mortar, which is responsible for
showing a growing consumption of this material and, conse- decreasing the bulk density and increasing the absorption of the RA
quently, the need for a solution with a lower environmental impact (Evangelista and de Brito, 2014).
(Freedonia, 2012). On the other hand, in 2012, concerning the total This result seems to be heightened by the use of the recycled
production of waste in the European Union, the construction and fine fraction. For example, FRA reached absorption values of 6.1%,
demolition sector contributed with 33% of this value (with 821 well above the 0.2e0.3% evidenced by FNA. However, recycled ag-
million tons, almost two tons per capita), followed by the extraction gregates (fine and coarse) met the requirements of the LNEC
industry sector (29% or 734 million tons), manufacturing industry standard E-471 (2009), for density and water absorption proper-
(11% or 270 million tons), households (8% or 213 million tons) and ties. The referred LNEC standard stipulates that the CRA (single
energy sector (4% or 96 million tons); the remaining 15% were fraction considered) must have a density higher than 2200 kg/m3
wastes generated by other economic activities (Eurostat, 2016). and a water absorption lower than 7%. In the Los Angeles test, the
Therefore, an experimental campaign was developed to evaluate RA were also able to meet the requirements of the LNEC standard E-
the feasibility of introducing recycled aggregates from pre-existent 373 (1993) for natural aggregates.
concrete into HPC. RA are usually associated with low-grade ap- The cement, fly ash, densified silica fume and superplasticizer
plications, but the investigations abovementioned show that this used were all commercial products, complying with standards EN
type of aggregates may exhibit a greater potential. Therefore, this 197-1 (2011), EN 450-1 (2012), EN 13263-1 (2005) and EN 934
research intends to contribute to increase the existing knowledge, (2009), respectively. Table 2 shows that the amount of SF
by evaluating the mechanical behaviour of HPC with simultaneous retained in the 45 mm sieve (96.4%) obtained by laser diffraction
incorporation of fine and coarse recycled aggregates (thus reducing (not requested by EN 13263) is much higher than was expected
the complexity of its industrial application). It should be high- (Neville, 1981). This situation demonstrates the actual dispersion
lighted that most investigations only analyse the recycled coarse difficulties associated with densified silica fume. On the other hand,
fraction (Limbachiya et al., 2000; Gonzalez and Etxeberria, 2014, the specific surface values measured by the nitrogen adsorption
2016; Gonzalez et al., 2016; Gonzalez and Etxeberria, 2016). How- method (BET) remain within those usually considered, about
ever, important conclusions obtained on those works, related to the 20 m2/g (Neville, 1981). Similar conclusions were obtained by Yajun
importance of the original concrete, will be taken into account for and Cahyadi (2003).
the maximization of the HPC potential produced with both FRA and The authors justified the results by stating that laser diffraction
CRA, fully replacing their natural counterparts. Its effective imple- measures the size of the agglomeration while nitrogen is able to
mentation may, in addition to the environmental advantages measure the original size of the particles.
(Blengini and Garbarino, 2010), contribute to open new market
opportunities (Coelho and de Brito, 2013a, b). At the same time, the 2.2. Composition of the concrete mixes
paper tries to evaluate the effects of the introduction of a densified
silica fume on the behaviour of HPC. Considering the dispersion The composition of the mixes was initially defined for the
difficulties of densified SF particles and the specificities of the use of reference concretes and only afterwards adapted for the mixes with
RA, a mixing process was developed by the authors, on which a recycled aggregates (Table 3). The determination of the aggregates’
patent application was made (Pedro et al., 2016), will also be used. content was made based on Faury (1958) particle size reference
curve, which was the same, in each family, for the various concrete
2. Experimental programme

Table 1
2.1. Materials
Properties of the aggregates.

In the experimental campaign carried out the following mate- Physical tests FNA CNA FRA CRA
rials were used: fine and coarse natural aggregates (FNA and CNA), Oven-dried density (g/cm3) 2.7 2.6 2.3 2.4
fine and coarse recycled aggregates (FRA and CRA), cement (C), fly Water absorption (%) 0.2 1.3 6.1 3.9
ash (FA), densified silica fume (SF), superplasticizer (SP) and water. Shape index (%) e 14.5 e 13.9
Los Angeles wear (%) e 28.4 e 33.0
The natural aggregates came from certified commercial
942 D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949

Table 2
Properties of the fly ash and densified silica fume.

Parameter FA SF

Density (g/cm3) 2.3 2.0


Specific surface area (m2/g) e 20
Sieve residue, 45 mm (%) <15 96.4
SiO2 (%) 54.7 94.3
Al2O3 (%) 24.7 e
Fe2O3 (%) 5.4 0.03 Fig. 1. Diagram of the mixing process.

mixes. The natural and recycled aggregates were separated using 2.3. Mixing process
mechanical sieving, allowing the replacement of NA with RA to be
made in volume, sieve by sieve. The adoption of this methodology The mixing process used for standard concrete appears to be
allowed, on the one hand, the particle size distribution of the ag- inefficient in the elimination of densified silica fume agglomerates.
gregates (natural and recycled) to remain unknown and also, on the This situation has been justified by the existence of high interpar-
other hand, the production of concrete mixes with optimized and ticle forces (Baweja et al., 2003; Diamond and Sahu, 2006). In fact,
similar compositions. Given the fact that RA possess lower density we also found that their production process of recycled aggregate
than NA, unsurprisingly, adjustments in the mass contents of RAC concrete was not suitable for this type of supplementary cemen-
(Table 3) were needed. The Dmax value considered was 16 mm. titious materials (Pedro et al., 2017). In summary, the procedure
In the case of the RAC mixes, the water compensation method that had been used by the research team consisted in initially
was also considered (Ferreira et al., 2011). In this sense, it is placing the natural and recycled aggregates with a mixing water
important to distinguish two w/b ratios: effective w/b ratio (w/bef) amount corresponding to 2/3 of the total water amount predicted
and total w/b ratio. The w/bef ratio only considers the amount of plus the extra water to be absorbed by the RA (determined prior to
water available for the hydration of the cement at the time of mixing). After 6 min, the cement (with fly ash and silica fume) and
mixing the materials. In other words, when calculating the w/bef the remaining 1/3 of the water with the superplasticizer would be
ratio, contrary to what happens in the assessment of the total w/b added to the mix.
ratio, the water that will be absorbed by the aggregates during the For the mixes studied in this work, and due to the problems
concrete production process is not taken into consideration. The encountered regarding silica fume dispersion, a new production
ratio w/bef was also determined, to achieve slumps within the process was adopted, considering new mixing times and different
190 ± 20 mm range. The two adaptations made were due to the orders of addition of the constituents into the mixer (Fig. 1).
significant water absorption of RA and the increase of internal Through Scanning Electron Microscopy (SEM) analyses, the new
friction of the RAC. procedure proved to be more effective than the previous one. The
As for the binder, cement (CEM I 52.5R) was used at a constant images collected of the concrete (Fig. 2) show that the modifica-
content of 550 kg/m3. Silica fume and fly ash were then introduced tions made improved the quality of the cement matrix, making it
as supplementary materials (relative to the mass of cement). Three much more homogeneous.
SF contents (0%, 5% and 10% SF) and a fixed amount of 10% FA were
used.
The superplasticizer, which is based on a combination of 2.4. Tests
modified polycarboxylates, was added at 2% of the mass of cement
and fly ash. After production, the specimens were cured in a climatic
In total, the performance of 12 types of concrete mixes was chamber under humid conditions, following the procedures of EN
evaluated. In the recycled aggregate mixes, the following replace- 12390-2 (2009). Tests on the fresh state, namely the slump
ment contents (FRA/CRA%) were considered: 50/50, 0/100 and 100/ measured with the Abrams cone and density, were performed ac-
100%. The reference concrete mixes with 0%, 5% and 10% SF and cording to EN 12350-2 (2009) and EN 12350-6 (2009), respectively.
using NA were designated: RC-SF0; RC-SF5 and RC-SF10. The RAC In the hardened state, compressive strength, splitting tensile
mixes without SF and made with RA from PC were nominated: strength, modulus of elasticity, ultrasonic pulse velocity and bond
C50F50C-SF0; C100C-SF0; C100F100C-SF0. For families with 5 and strength were determined according to the standards EN 12390-3
10% SF, the same terminology was used. (2011), EN 12390-6 (2011), LNEC E-397 (1993), EN 12504-4
(2004) and RILEM 7.11.128 (1970), respectively.

Table 3
Composition of the concrete mixes tested (/m3).

Concrete mix FNA (kg) CNA (kg) FRA (kg) CRA (kg) Cement (kg) FA(kg) SF (kg) w/bef ratio SP (kg)

SF0 RC-SF0 690 889 0 0 550 55 0 0.28 12.1


C50F50C-SF0 342 440 348 453 550 55 0 0.29 12.1
C100F100C-SF0 0 0 659 829 550 55 0 0.31 12.1
C100C-SF0 683 0 0 847 550 55 0 0.29 12.1
SF5 RC-SF5 666 857 0 0 550 55 27.5 0.28 12.1
C50F50C-SF5 329 424 324 408 550 55 27.5 0.29 12.1
C100F100C-SF5 0 0 626 788 550 55 27.5 0.32 12.1
C100C-SF5 658 0 0 816 550 55 27.5 0.29 12.1
SF10 RC-SF10 633 815 0 0 550 55 55 0.29 12.1
C50F50C-SF10 313 402 308 387 550 55 55 0.30 12.1
C100F100C-SF10 0 0 601 756 550 55 55 0.32 12.1
C100C-SF10 633 0 0 784 550 55 55 0.29 12.1
D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949 943

(a) (b)
Fig. 2. Comparison of the microstructure of the concrete mixes with SF: (a) old concrete mixing process; (b) new concrete mixing process.

Table 4 explained by the lower density of the RA when compared to NA.


Slump and effective w/b ratio of the concrete mixes. Similar conclusions were obtained by Pedro et al. (2014), for recy-
Concrete 0% SF 5% SF 10% SF cled aggregates with origin in concrete and in Bravo et al. (2015), for
mix aggregates with origin in several recycling plants. The increase in
Slump w/bef Slump w/bef Slump w/bef
(mm) ratio (mm) ratio (mm) ratio entrained air content and amount of voids, as a consequence of the
presence of RA, are other possible causes (Bravo et al., 2016).
RC 207 0.28 209 0.28 208 0.29
C50F50C 208 0.29 200 0.29 185 0.30 It should be noted that the observed reduction presents a linear
C100F100C 196 0.31 185 0.32 180 0.32 trend with the simultaneous introduction of FRA and CRA, with a
C100C 207 0.29 205 0.29 200 0.30 maximum variation that does not exceed 4% (Fig. 3).
In concrete mixes in which only coarse recycled aggregates (and
natural sand) are used, the maximum decreases are even lower,
3. Results and discussion presenting values between 1% and 1.1% (Table 5).
Analysing Fig. 3, it is also possible to observe a small decrease in
3.1. Fresh-state concrete properties the density with the increase in SF content. The reduction obtained
is related to the fact that the incorporation of SF (as an additional
3.1.1. Workability material in the mix) implies a reduction of the quantity of aggre-
From the results presented in Table 4, it can be perceived that gates (which have a higher density than SF). However, the varia-
the concrete mixes produced comply with the specified slump class tions observed are lower or equal to 1.5%.
(190 ± 20 mm). In Fig. 4 the theoretical and experimental density values are
However, it was necessary to increase the effective w/b ratio of compared, and it is possible to observe that the latter is higher than
RAC to reach similar values to those of the RC. This becomes more the former, with the difference reaching a maximum of about 5%.
evident for higher replacement ratios and when fine recycled ag- As the theoretical air content is not estimated, based on the
gregates are incorporated in the concrete mixes. maximum aggregate dimension, it is natural that slight deviations
The existence of ultrafine particles in the FRA may be respon- as these can be observed.
sible for the workability decrease. In fact, Quiroga and Fowler
(2004) observed this phenomenon and also had to increase the
w/b ratio to maintain a constant slump. This stems from the higher 3.2. Concrete mechanical properties
specific surface area presented by these particles, which implies the
need for a higher amount of kneading water. In the case of mixes 3.2.1. Compressive strength in cubic specimens
with 100% CRA, the small variation registered may be due to the The compressive strength tests were performed in 150 mm side
rougher surface of the coarse recycled aggregates that causes a cubic specimens, at 7, 28 and 91 days. In Table 6, the mean values
higher friction in the cementitious paste (Bravo et al., 2015). (fcm) and the variations due to the incorporation of RA (DRA) and of
Regarding the influence of the incorporation of silica fume, it is silica fume (DSF) are presented.
found that the concrete mixes with 10% SF already required an The results show that the compressive strength tends to
increment of the wef/b ratio (in relation to its 0% and 5% SF coun- decrease with the increase of recycled aggregates content.
terparts) in order to obtain the same workability. The higher water Considering the different ages, performance decreases of 1e6% and
demand may be also associated with the higher specific surface 2e8% are found, for replacement ratios (FRA/CRA%) of 50/50 and
area of silica fume particles (Holland, 2005). 100/100, respectively. It is also observed that, in the case of high-
performance concrete, the replacement of sand with FRA leads to
marginal performance decreases. The variations between the
3.1.2. Density reference mixes and the C100C mix reached a maximum of about
Table 5 presents the results of density on the fresh state and the 6%, which is not too far from those observed for C100F100C mixes.
variations due to the incorporation of RA (DRA) and those associated The worst performance of RAC concerns the fraction of mortar
with the introduction of silica fume (DSF). that exists in the RA. The presence of this mortar leads to a more
They show a reduction of the density with the increase of porous material and leads to mixes with higher effective w/c ratios
incorporation of recycled aggregates, a phenomenon that can be (Poon et al., 2004; Zong et al., 2014). The latter effect may be
944 D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949

Table 5
Fresh-state density of the concrete mixes.

Concrete mix 0% SF 5% SF 10% SF

Density (kg/m3) DRA (%) DSF (%) Density (kg/m3) DRA (%) DSF (%) Density (kg/m3) DRA (%) DSF (%)
RC 2384.6 0.0 0.0 2373.3 0.0 0.5 2350.9 0.0 1.4
C50F50C 2340.2 1.9 0.0 2326.8 2.0 0.6 2311.6 1.7 1.2
C100F100C 2297.7 3.6 0.0 2287.0 3.6 0.5 2274.9 3.2 1.0
C100C 2359.8 1.0 0.0 2348.0 1.1 0.5 2324.1 1.1 1.5

coarse recycled aggregates (of medium/high quality) led to strength


decreases between 5% and 20%. In turn, Tu et al. (2006), who
compared the performance between concrete mixes produced with
recycled aggregates only and mixes using RCA and natural sand,
obtained strength variations in the order of 5e15%.
Concerning the influence of densified silica fume, it is found that
its incorporation (as additional material in the concrete mix) is
responsible for increasing the performance of concrete. This seems
to take place from early age (Fig. 5).
At 7 days, both the RC and the RAC with silica fume show
strength increases of 9e13% in relation to non-SF concrete. For
subsequent ages (28 and 91 days), the beneficial effect of SF par-
ticles remains, although variations due to their presence appear to
decrease (3e7%). The efficiency of SF particles at early ages is
related to the fact that it coincides with the period of higher
development of their pozzolanic reactions (Mazloom et al., 2004;
Holland, 2005). Also during this period, the physical refinement
effect of the mix plays an important role (Holland, 2005).
Fig. 3. Fresh-state density for RA concretes versus aggregates’ replacement ratio. In this way, the advantages obtained by the addition of SF can be
explained by two distinct reasons (Aïtcin, 2003): filler effect and
pozzolanic effect. The pozzolanic effect is related to the high
mitigated by the use of high-performance recycled aggregates, reactivity of silica fume which is capable of reacting with calcium
thereby limiting strength decreases. According to Poon et al. hydroxide (Ca(OH)2) to form calcium silicate hydrate (C-S-H). On
(2004), increasing the quality of RA leads to a stronger bond in the other hand, the filler effect is related to the fineness of SF par-
the interfacial transition zones. Gonzalez and Etxeberria (2014) also ticles that can occupy the voids that occur between particles,
observed that the strength of the source concrete (SC) mix is an resulting in an increase in the compactness and cohesion of the
important factor. For instance, the use of 100% CRA from a 40 MPa mix.
SC originates a decrease of about 10% in strength, whereas the The mixing process used seems to have attenuated the disper-
decreases associated with aggregates from the 60 MPa SC were sion problems associated with densified SF particles, contributing
irrelevant. to their effectiveness at early ages, a result that was not found in
The trends found in this investigation are also in agreement other research works (Elahi et al., 2010; Çakır and Sofyanlı, 2014).
with the studies made by Ajdukiewicz and Kliszczewicz (2002) and Thus, the entry order of the constituents and the mixing times
Tu et al. (2006). In the first case, the incorporation of 100% fine and promoted the disaggregation of the silica fume agglomerates. The
objective of the definition of these parameters was to maximize the
impact actions to which SF particles would be subjected and to take
into account the differences between recycled aggregates and
natural aggregates.

3.2.2. Splitting tensile strength


The splitting tensile strength test was performed at 28 days in
cylindrical specimens with 150 mm diameter and 300 mm height.
In Table 7 the values obtained for this property as well as the var-
iations due to the incorporation of RA (DRA) and of silica fume (DSF)
are shown.
Concerning the use of RA, the performance of these mixes is
found to decrease with increasing replacement of natural with
recycled aggregates. The losses obtained are between 18% and 29%,
and it is clear that, the higher the RA content, the greater the
decrease in strength. In absolute terms, RC reached values between
5.0 and 5.3 MPa, while RAC values were 3.6e4.4 MPa (Table 7). This
can be explained by the more porous structure of the recycled
aggregates. The results of Fig. 6 show that the model corresponding
to a linear variation is the one that best fits the relation between the
Fig. 4. Comparison between real and theoretical fresh-state density. splitting tensile strength and the simultaneous incorporation of
D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949 945

Table 6
Compressive strength in cubes at 7, 28 and 91 days.

Concrete mix 7 days 28 days 91 days

fcm (MPa) DRA (%) DSF (%) fcm (MPa) DRA (%) DSF (%) fcm (MPa) DRA (%) DSF (%)
RC-SF0 79.9 ± 0.9 0.0 0.0 93.4 ± 2.9 0.0 0.0 96.4 ± 1.4 0.0 0.0
C50F50C-SF0 74.9 ± 1.0 6.3 0.0 91.3 ± 3.0 2.2 0.0 94.7 ± 2.3 1.8 0.0
C100F100C-SF0 73.4 ± 1.6 8.1 0.0 90.1 ± 2.0 3.5 0.0 94.0 ± 2.1 2.5 0.0
C100C-SF0 76.6 ± 1.4 4.1 0.0 91.5 ± 1.8 2.0 0.0 95.2 ± 2.5 1.2 0.0

RC-SF5 87.1 ± 0.5 0.0 9.0 97.9 ± 2.0 0.0 4.8 101.1 ± 2.6 0.0 4.9
C50F50C-SF5 82.6 ± 0.4 5.2 10.3 95.5 ± 3.0 2.5 4.6 97.8 ± 1.3 3.3 3.3
C100F100C-SF5 80.3 ± 2.3 7.8 9.4 93.7 ± 1.9 4.3 4.0 96.4 ± 2.4 4.6 2.6
C100C-SF5 83.9 ± 0.5 3.7 9.5 96.0 ± 1.6 1.9 4.9 98.4 ± 2.2 2.7 3.4

RC-SF10 88.0 ± 1.3 0.0 10.1 102.2 ± 1.7 0.0 9.4 103.3 ± 3.5 0.0 7.2
C50F50C-SF10 83.5 ± 2.1 5.1 11.5 99.3 ± 1.0 2.8 8.8 101.4 ± 1.3 1.8 7.1
C100F100C-SF10 81.2 ± 2.8 7.7 10.6 97.3 ± 1.4 4.8 8.0 99.1 ± 2.9 4.1 5.4
C100C-SF10 86.5 ± 1.3 1.7 12.9 100.4 ± 0.4 1.8 9.7 101.5 ± 2.4 1.7 6.6

strength up to about 9% when compared to that of concrete without


SF. The strengthening of the interfacial transition zone may also
contribute to this performance improvement (Isaia et al., 2003). In
parallel, the increase of compactness generated in the mixes and the
reduction of the volume of macropores are responsible for the me-
chanical performance benefits (Elhakam et al., 2012; ACI 234R-06).

3.2.3. Modulus of elasticity


The test to determine the modulus of elasticity of the concrete
mixes was performed at 28 days in cylindrical specimens with
150 mm diameter and 300 mm height. Table 8 presents the mean
values (Ecm) and the variations due to the incorporation of recycled
aggregates (DRA) and silica fume (DSF).
Overall, the reference concretes exhibited, for the families of 0%,
5% and 10% SF, values of 48.7, 51.1 and 56.7 GPa, respectively. For the
same families, the recycled concretes show results of 39.5e45.2 GPa,
40.7e49.0 GPa and 41.9e53.8 GPa. Further analysing the results, it is
Fig. 5. Compressive strength in cubes versus time.
possible to perceive that there is an approximately linear decrease of
this property with the increase of recycled aggregates content
FRA and CRA (R2 ¼ 0.80e0.88). (Fig. 7).
Table 7 also allows observing that, in concrete mixes with 100% Regarding the replacement ratio of 100% (fine and coarse),
CRA, the gain associated with not replacing sand with FRA as well maximum decreases are observed, compared to RC, of 18.9e26.1%.
is, in most cases, less than about 0.5 MPa. Therefore, for the high- Ajdukiewicz and Kliszczewicz (2002) obtained similar reductions
performance mixes produced, the recycled fines fraction does not in their research on HPC (20e30%).
seem to play a decisive role. The worst performance of RAC may be associated with the fact
The results also show that the decrease in splitting tensile that the modulus of elasticity depends on both the stiffness of the
strength is more pronounced than that of the compressive strength. paste and that of the aggregates. Hence, the higher propensity for
This situation is in agreement with Khoshkenari et al. (2014), where deformation of RA relative to NA, since they have a lower modulus
a decrease of 26e32% was observed when natural aggregates (fine of elasticity, contributes decisively to the degradation of the per-
and coarse) were replaced with recycled aggregates in standard formance of recycled concrete mixes (Silva et al., 2016).
concrete. Ajdukiewicz and Kliszczewicz (2002) obtained more From the observation of Table 8, it is still possible to perceive
satisfactory results for HPC. The maximum splitting tensile strength that the lowest performance decreases occur in the concrete mixes
losses resulting from the incorporation of 100% RA were around where only coarse recycled concrete aggregates were incorporated
20%. (4e13%). The variations found are in agreement with those of
Concerning the incorporation of densified silica fume, it is found Gonzalez and Etxeberria (2014), where reductions of about 9% were
that the concrete mixes exhibited an increase in splitting tensile measured (using 100% high quality CRA). The substitution of sand
with FRA seems to be more conditioning, a situation that may be

Table 7
Splitting tensile strength at 28 days.

Concrete mix 0% SF 5% SF 10% SF

fct,sp (MPa) DRA (%) DSF (%) fct,sp (MPa) DRA (%) DSF (%) fct,sp (MPa) DRA (%) DSF (%)
RC 5.08 ± 0.06 0.0 0.0 5.22 ± 0.13 0.0 2.8 5.33 ± 0.17 0.0 4.9
C50F50C 3.91 ± 0.12 23.0 0.0 3.97 ± 0.12 23.9 1.5 4.18 ± 0.22 21.6 6.9
C100F100C 3.60 ± 0.17 29.1 0.0 3.83 ± 0.07 26.6 6.4 3.87 ± 0.10 27.4 7.5
C100C 4.02 ± 0.07 20.9 0.0 4.26 ± 0.12 18.4 6.0 4.36 ± 0.23 18.2 8.5
946 D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949

Fig. 6. Splitting tensile strength versus aggregates’ replacement ratio. Fig. 7. Modulus of elasticity versus aggregates’ replacement ratio.

related to the greater porosity of this type of concrete mixes. The 3.2.5. Bond strength
irregularity of FRA and the weakening of the interfacial transition This test was performed at 91 days in a selected set of concrete
zones are factors that may also contribute to this reality (Solyman, mixes. Cubic specimens with 120 mm side were used incorporating
2005). steel reinforcement bars of class A500 NR SD with 12 mm diameter.
Concerning the incorporation of silica fume, it is found that its The anchorage length considered was 100 mm, with the casting of
addition caused an increase of the values of modulus of elasticity. the specimens being done in the direction perpendicular to the
The highest increases were obtained in the family with 10% SF, with steel bar, in order to simulate as close as possible the most common
variations up to 20%. The results show that SF can cause variations situation observed in construction environment. However, this
in the stiffness of RC and RAC, either by densification of the matrix, type of procedure tends to cause worse adhesions between steel
increasing its stiffness, or by improving the aggregate-paste tran- and concrete since the steel bars are more prone to exudation
sition zone, which will reduce micro-cracking formation at lower phenomena (El-Hacha et al., 2006). In Table 10, the values obtained
stress levels. for the maximum load (Fmax), the mean bonding stress of the
reinforcement steel bar for maximum load (tbPmax), the relative
displacement at the unloaded end for the maximum load DLFmax
3.2.4. Ultrasonic pulse velocity and the type of collapse mode. The value of tbPmax was calculated
The ultrasonic pulse velocity (UPV) was determined in cubic according to the following equation:
specimens with 150 mm edge at 28 days. Table 9 shows the values
obtained for this property and the variations due to the incorpo- Fmax
PbPmax ¼ (1)
ration of RA (DRA) and silica (DSF). p  F  lb
In general, the UPV was 5049e5092 m/s for reference concretes
and 4778e5012 m/s for mixes with recycled aggregates. where Fmax is the applied load (N), F is the diameter of the steel
Performance losses, although not exceeding 9%, exhibit an reinforcement bar (m) and lb is the anchorage length (mm).
approximately linear trend (R2 ¼ 0.98e0.99) with the simultaneous From Table 10, it is found that the failure mode of several
incorporation of FRA and CRA (Fig. 8). This can be attributed to the specimens occurred by splitting. This failure mode is most often
higher porosity of the recycled aggregates mixes. associated with reduced cover concrete depths or large reinforce-
Regarding the incorporation of SF, there is a very slight increase ment bar diameters. However, in addition to the cover concrete
in performance, not exceeding 2%. In the study performed by Çakır depths, the volume of concrete between the loaded end and the
and Sofyanlı (2014), slight variations associated with the presence anchorage zone may play a key role in the splitting failure mode.
of SF (of about 6%) are also reported. It should be mentioned that this type of failure mode does not
According to the classification suggested by Malhotra (1976) all allow quantifying the maximum bond strength of concrete, making
concrete mixes can be classified as “good” since even the lowest it difficult to compare. However, the results obtained allow the
values of UPV fall in the range of 3660e4580 m/s. This indicates evaluation of the concrete behaviour in situations in which
that any voids or cracks that could affect structural integrity of the confinement is reduced.
concrete mixes are absent. Analysing Fig. 9, it is further noted that, during splitting, the ribs

Table 8
Modulus of elasticity at 28 days.

Concrete mix 0% SF 5% SF 10% SF

Ecm (GPa) DRA (%) DSF (%) Ecm (GPa) DRA (%) DSF (%) Ecm (GPa) DRA (%) DSF (%)
RC 48.7 ± 0.1 0.0 0.0 51.1 ± 0.9 0.0 4.9 56.7 ± 0.9 0.0 16.4
C50F50C 43.9 ± 0.1 9.9 0.0 47.0 ± 0.1 8.0 7.1 48.6 ± 2.4 14.3 10.7
C100F100C 39.5 ± 1.4 18.9 0.0 40.7 ± 0.1 20.4 3.0 41.9 ± 2.6 26.1 6.1
C100C 45.2 ± 1.1 7.2 0.0 49.0 ± 0.1 4.1 11.6 53.8 ± 2.2 5.1 22.6
D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949 947

Table 9
Ultrasonic pulse velocity at 28 days.

Concrete mix 0% SF 5% SF 10% SF

UPV (m/s) DRA (%) DSF (%) UPV (m/s) DRA (%) DSF (%) UPV (m/s) DRA (%) DSF (%)
RC 5049 ± 25 0.0 0.0 5064 ± 43 0.0 0.3 5092 ± 40 0.0 0.9
C50F50C 4882 ± 20 3.3 0.0 4927 ± 60 2.7 0.9 4931 ± 31 3.2 1.0
C100F100C 4778 ± 29 5.4 0.0 4815 ± 29 4.9 0.8 4828 ± 26 5.2 1.0
C100C 4919 ± 29 2.6 0.0 4974 ± 65 1.8 1.1 5012 ± 19 1.6 1.9

Fig. 9. Splitting failure mode.

Fig. 8. Ultrasonic pulse velocity versus aggregates’ replacement ratio.

Table 10
Bond strength at 91 days (* indicates lower limit value of the bonding stress).

Concrete mix Fmax (kN) tbFmax (MPa) DLFmax (mm) Failure mode

RC-SF0 70.0 18.6* 0.26 Splitting


C100F100C-SF0 58.0 15.4* 0.17 Splitting
RC-SF10 71.7 19.0* 0.2 Splitting
C100F100C-SF10 60.4 16.0* 0.14 Splitting

are fully mobilized. The presence of crushed concrete is also


observed in their surrounding area. This situation, which is com-
mon to both reference concretes and mixes with recycled aggre-
gates, seems to indicate that there is an approximately uniform Fig. 10. Bond strength versus splitting tensile strength.
distribution of bond stresses after slipping starts to occur (vali-
dating the hypothesis considered in the calculation of tb).
Hence, given this type of failure mode, the maximum bond mixes, respectively.
strength was conditioned by the tensile strength of concrete. In Thus, normalized stresses appear to be affected by the incor-
fact, in Fig. 10, there is an excellent correlation between these two poration of RA, presenting variations of 15e21%. This can be
properties (R2 ¼ 0.99). Similar conclusions were obtained in the attributed to the higher compactness of the RC cement paste for a
work done by Gjørv et al. (1990) for standard concrete. given strength and to the improved quality of its interface.
It is thus concluded that RAC have, in relation to RC, worse
performances, justified by their lower splitting tensile strength. 4. Conclusions
Bond strength decreases of 15e17% are observed. In addition, the
quality of concrete in the vicinity of the steel bars is another factor Due to population growth in the main metropolitan regions of
to be taken into account. The higher porosity of RAC in this zone the world, structures have become larger and more complex,
may negatively influence this property (Kim and Yun, 2013). It requiring a constant improvement of the properties of concrete, in
should be noted, however, that the real effect of the aggregates on particular its mechanical properties. Construction in height (given
bond strength should only be analysed when the failure mode is by the lack of horizontal space in big cities) and the use of structural
pull-out. elements with increasingly smaller cross-sections (allowing
Concerning the influence of silica fume, its introduction does smaller self-weight loads to be applied to foundations and the
not seem to influence the performance of the concrete mixes occupation of smaller areas) are examples of this reality. Despite
(maximum variations under 4% are observed). the technical developments, the construction industry has become
In Table 11, values of steel-concrete bond strength are normal- the economic activity that consumes more raw materials world-
ized to f1/2
cm are shown. The results exhibit values of 1.9 and 1.5e1.6 wide (almost 50% in mass), also generating a high amount of
MPa1/2 for the reference concrete and for the recycled aggregates associated waste (Pacheco-Torgal and Labrincha, 2013).
948 D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949

Table 11 considered of good quality, meaning that they are free of voids
Bond strength normalized to f1/2
cm . or cracks that could affect their structural integrity, displaying
Concrete mix tbFmax/f1/2
cm (MPa
0,5
) DRA (%) DSF (%) values between 4500 and 5100 m/s. Tu et al. (2006) also ob-
RC-SF0 1.9 0.0 0.0
tained satisfactory, though lower, values, between 4000 and
C100F100C-SF0 1.6 15.8 0.0 4200 m/s;
RC-SF10 1.9 0.0 0.0  Finally, for bond strength, only a few concrete mixes were
C100F100C-SF10 1.6 15.8 0.0 evaluated. In all the selected mixes, it is found that the failure
mode of the specimens occurs by splitting of the concrete, thus
not allowing determining the maximum bond strength capacity,
In this context, the work developed sought to analyse, from a which makes the comparison between concrete mixes difficult.
mechanical characterization point of view, a high-performance Despite this observation, there is a worse performance of RAC
concrete (HPC) that could combine technical issues with environ- (compared to the corresponding RC), although this does not
mental concerns. Thus, one of its objectives was to recycle existing compromise their use.
concrete waste and apply it again in concrete as replacement of
natural aggregates. A further objective was to assess possible con- The results show that the conclusions found in the literature,
sequences that may arise from the use of some certified commercial which are mainly focused on CRA may also be valid for FRA, that is,
silica fumes (SF) in which there is no mention of the difficulties it may be feasible to produce HPC, replacing the totality of natural
associated to their dispersion. aggregates with recycled aggregates and to obtain a similar
The results obtained during the experimental campaign, in behaviour. This new concrete meets the societal challenges estab-
which concrete mixes containing recycled aggregates (RA) and SF lished for the coming years, in which a “greener” culture is
were compared with reference concrete (RC) mixes, allowed required, in order to meet current needs without preventing future
concluding the following: generations from satisfying their own needs. At European level,
there are already a number of measures and programs aimed at
 In the fresh state, it was possible for recycled HPC to obtain sustainability, and the construction industry will certainly have to
similar workability as that of the reference HPC (produced with look at environmental issues in the development of its products in
natural aggregates only). For this purpose, it was necessary to the future. Furthermore, this investigation shows that the process
use a water compensation method (minimizing transfers of of densification of silica fume appears to be “irreversible” using
kneading water into the RA) and to slightly increase the effective standard mixing procedures. It was necessary to adopt a new
w/b ratio of the recycled aggregate concrete (RAC) mixes (given procedure (developed by the authors) that guaranteed an adequate
the greater roughness and the presence of ultrafine particles in dispersion of SF particles. This factor may be responsible for the
RA). Concrete mixes with 10% SF also required a higher effective variations in efficacy registered in the literature and should be an
w/b ratio, which may be associated with the higher specific alert for users of this product, which has a much cost higher than
surface area of these particles. Concerning the density of the that of cement.
mixes, variations due to the introduction of RA and SF did not Since the mechanical properties may not be the main require-
exceed 6%; ment for the use of a HPC, the present research team is also
 In the hardened state, despite the decrease in performance of developing a study in which it evaluates its durability. In addition to
the RAC relative to the RC, extremely satisfactory values were this study, it may also be interesting to carry out a life cycle cost
found, which were further increased with the presence of SF. For analysis of high-performance concrete. Although they may possess
instance, at 28 days, the concrete compressive strength a higher initial cost compared to that of standard concrete, the costs
measured in cubic specimens yielded values of about 97 MPa of future maintenance and repair actions may be lower.
and 102 MPa, for concrete mixes C100F100C-SF10 and RC-SF10,
respectively. In the investigation of Ajdukiewicz and Acknowledgements
Kliszczewicz (2002), for the same age and in cylindrical speci-
mens, values of 65e85 MPa and 55e80 MPa were obtained, in The authors gratefully acknowledge the support of the CERIS-
reference concrete mixes and concrete mixes with recycled cnico from Univer-
ICIST Research Institute, Instituto Superior Te
aggregates only. The results show that by using suitable com- sity of Lisbon, and FCT (Portuguese Foundation for Science and
positions and good quality recycled aggregates it is possible to Technology) through project PTDC/ECM/118372/2010 “Perfor-
obtain identical strengths in mixes with RA and natural aggre- mance evaluation of high-performance concrete mixes made with
gates (NA). On the other hand, in the investigation by Tu et al. recycled aggregates from prefabrication industry” (EXCELlentSUS-
(2006) the maximum strengths (in cylinders) did not exceed tainable-CONCcrete) and through the doctoral fellowship SFRH/BD/
40 MPa approximately; 97178/2013.
 For the modulus of elasticity, it was found that the highest value
recorded by a mix incorporating 100% RA was around 41 GPa
References
(C100F100C-SF10). According to Eurocode 2 (EN 1992-1-1,
2008), this value can be classified as being of (strength) class ACI, 2006. Guide for the Use of Silica Fume in Concrete (ACI 234R-06). American
C70/85. In the study by Ajdukiewicz and Kliszczewicz (2002), Concrete Institute. Farmington Hills, USA.
Aïtcin, P., 2003. The durability characteristics of high performance concrete: a re-
mixes with 100% RA exhibited values between 25 and 35 GPa;
view. Cem. Concr. Compos 25 (4e5), 409e420.
 On the other hand, the splitting tensile strength appears to be Ajdukiewicz, A., Kliszczewicz, A., 2002. Influence of recycled aggregates on me-
the most affected, in which the highest value obtained by a mix chanical properties of HS/HPC. Cem. Concr. Compos 24 (2), 269e279.
with only RA (fine and coarse) was about 3.9 MPa, while the Baweja, D., Cao, T., Bucea, L., 2003. Investigation of dispersion levels of silica fume in
pastes, mortars and concrete. In: Proceedings of CANMET/ACI Conference on
maximum value of RC was of 5.3 MPa. As in previous properties, Concrete Durability. Athens, Greece, pp. 1019e1034.
the best performances were achieved by the 10% SF concrete Blengini, G., Garbarino, E., 2010. Resources and waste management in Turin (Italy):
family. the role of recycled aggregates in the sustainable supply mix. J. Clean. Prod. 18
(10e11), 1021e1030.
 In terms of ultrasonic pulse velocity, according to the classifi- Bonen, D., Diamond, S., 1992. Occurrence of large silica fume-derived particles in
cation suggested by Malhotra (1976), all concrete mixes may be hydrated cement paste. Cem. Concr. Res. 22 (6), 1059e1066.
D. Pedro et al. / Journal of Cleaner Production 164 (2017) 939e949 949

Bravo, M., de Brito, J., Pontes, J., Evangelista, L., 2015. Mechanical performance of the shrinkage of high performance concrete. Constr. Build. Mater 115, 32e41.
concrete made with aggregates from construction and demolition waste recy- Gonza lez-Fonteboa, B., Martínez-Abella, F., 2008. Concretes with aggregates from
cling plants. J. Clean. Prod. 99, 59e74. demolition waste and silica fume. Materials and mechanical properties. Build.
Bravo, M., Silva, A., de Brito, J., Evangelista, L., 2016. Microstructure of concrete with Environ. 43, 429e437.
aggregates from construction and demolition waste recycling plants. Microsc. Gonzalez, A., Etxeberria, M., Poon, C., 2016. Influence of steam curing on the pore
Microanal. 22 (1), 149e167. structures and mechanical properties of fly-ash high performance concrete
Çakır, Ӧ., Sofyanlı, Ӧ., 2014. Influence of silica fume on mechanical and physical prepared with recycled aggregates. Cem. Concr. Compos 71, 77e84.
properties of recycled aggregate concrete. HBRC J. 11 (2), 157e166. Holland, T., 2005. Silica Fume User’s Manual. Technical Report Nº FHWA-IF-05-016.
Coelho, A., de Brito, J., 2013a. Economic viability analysis of a construction and Silica Fume Association, p. 193.
demolition waste recycling plant in Portugal e part I: location, materials, Hwang, C., 1999. Properties and Behaviors of Concrete. Chan’s Arch Books, Taipei.
technology and economic analysis. J. Clean. Prod. 39, 338e352. Hwang, C., Lin, J., Lee, L., Lin, F., 1996. Densified mixture design algorithm and early
Coelho, A., de Brito, J., 2013b. Economic viability analysis of a construction and properties of high-performance concrete. J. Chin. Inst. Civ. Hydraulic Eng. 8 (2),
demolition waste recycling plant in Portugal e part II: economic sensitivity 217e219.
analysis. J. Clean. Prod. 39, 329e337. Isaia, G., Gastaldini, A., Moraes, R., 2003. Physical and pozzolanic action of mineral
Corinaldesi, V., Moriconi, G., 2009. Influence of mineral additions on the perfor- additions on the mechanical strength of high-performance concrete. Cem.
mance of 100% recycled aggregate concrete. Constr. Build. Mater 23 (8), Concr. Compos 25 (1), 69e76.
2869e2876. Khoshkenari, A., Shafigh, P., Moghimi, M., Mahmud, H., 2014. The role of 0e2 mm
Diamond, S., Sahu, S., 2006. Densified silica fume: particle sizes and dispersion in fine recycled concrete aggregate on the compressive and splitting tensile
concrete. Mater. Struct. 39 (9), 849e859. strengths of recycled concrete aggregate concrete. Mater. Des 64, 345e354.
Elahi, A., Basheer, P., Nanukuttan, S., Khan, Q., 2010. Mechanical and durability Kim, S., Yun, H., 2013. Influence of recycled coarse aggregates on the bond behavior
properties of high performance concretes containing supplementary cementi- of deformed bars in concrete. Eng. Struct. 48, 133e143.
tious materials. Constr. Build. Mater 24 (3), 292e299. Lei, D., Guo, L., Sun, W., Liu, J., Shu, X., Guo, X., 2016. A new dispersing method on
El-Hacha, R., Elagroudy, H., Rizkalla, S., 2006. Bond characteristics of high strength silica fume and its influence on the performance of cement-based materials.
steel reinforcement. ACI Struct. J. 103 (6), 771e782. Constr. Build. Mater 115, 716e726.
Elhakam, A., Mohamed, A., Awad, E., 2012. Influence of self-healing, mixing method Limbachiya, M., Leelawat, T., Dhir, R., 2000. Use of recycled concrete aggregate in
and adding silica fume on mechanical properties of recycled aggregates con- high-strength concrete. Mater. Struct. 33, 574e580.
crete. Constr. Build. Mater 35, 421e427. LNEC E-373, 1993. Aggregates for Mortars and Concrete: Characteristics and Con-
EN 1097-2, 2011. Tests for Mechanical and Physical Properties of Aggregates - Part formity Checking (In Portuguese). National Laboratory of Civil Engineering
2: Methods for the Determination of Resistance to Fragmentation. Comite  (LNEC), Lisbon, Portugal.
Europe en de Normalisation (CEN), Brussels, Belgium. LNEC E-397, 1993. Hardened Concrete: Determination of the Modulus of Elasticity
EN 1097-6, 2003. Tests for Mechanical and Physical Properties of Aggregates - Part in Compression (In Portuguese). National Laboratory of Civil Engineering
6: Determination of Particle Density and Water Absorption. Comite  Europeen (LNEC), Lisbon, Portugal.
de Normalisation (CEN), Brussels, Belgium. LNEC E-471, 2009. Guide for the Use of Coarse Recycled Aggregates in Concrete (In
EN 12350-2, 2009. Testing Fresh Concrete. Part 2: Slump-test. Comite  Europeen de Portuguese). National Laboratory of Civil Engineering (LNEC), Lisbon, Portugal.
Normalisation (CEN), Brussels, Belgium. Malhotra, V., 1976. Testing Hardened Concrete: Nondestructive Methods. American
EN 12350-6, 2009. Testing Fresh Concrete. Part 6: Density. Comite  Europeen de Concrete Institute, USA.
Normalisation (CEN), Brussels, Belgium. Mazloom, M., Ramezanianpour, A., Brooks, J., 2004. Effect of silica fume on me-
EN 12390-2, 2009. Testing Hardened Concrete. Part 2: Making and Curing Speci- chanical properties of high-strength concrete. Cem. Concr. Compos 26 (4),
mens for Strength Tests. Comite  Europe en de Normalisation (CEN), Brussels, 347e357.
Belgium. Neville, A., 1981. Properties of Concrete. Pitman, London, UK.
EN 12390-3, 2011. Testing Hardened Concrete. Part 3: Compressive Strength of Test Pacheco-Torgal, F., Labrincha, J., 2013. The future of construction materials research
Specimens. Comite  Europe en de Normalisation (CEN), Brussels, Belgium. and the seventh UN millennium development goal: a few insights. Constr.
EN 12390-6, 2011. Testing Hardened Concrete. Part 6: Tensile Splitting Strength of Build. Mater 40, 729e737.
Test Specimens. Comite  Europeen de Normalisation (CEN), Brussels, Belgium. Pedro, D., de Brito, J., Evangelista, L., 2014. Influence of the use of recycled concrete
EN 12504-4, 2004. Testing Concrete - Part 4: Determination of Ultrasonic Pulse aggregates from different source on structural concrete. Constr. Build. Mater 71,
Velocity. Comite  Europe en de Normalisation (CEN), Brussels, Belgium. 141e151.
EN 12620, 2002. Aggregates for Concrete. Comite  Europe
en de Normalisation (CEN), Pedro, D., Evangelista, L., de Brito, J., 2016. High Performance Concrete Made with
Brussels, Belgium. No Natural Aggregates and its Preparation. International Bureau Application No
EN 13263-1, 2005. Silica Fume Concrete - Part 1: Definitions, Requirements and PCT/PT2016/000014, Submitted.
Conformity Criteria. Comite  Europe en de Normalisation (CEN), Brussels, Pedro, D., Evangelista, L., de Brito, J., 2017. Evaluation of high-performance concrete
Belgium. with recycled aggregates: use of densified silica fume as cement replacement.
EN 197-1, 2011. Cement - Part 1: Composition, Specifications and Conformity Constr. Build. Mater 147, 803e814.
Criteria for Common Cements. Comite  Europe en de Normalisation (CEN), Poon, C., Shui, Z., Lam, L., 2004. Effect of microstructure of ITZ on compressive
Brussels, Belgium. strength of concrete prepared with recycled aggregates. Constr. Build. Mater 18
EN 1992-1-1, 2008. Eurocode 2-Design of Concrete Structures, Part 1-1: General (6), 461e468.
Rules and Rules for Buildings. Comite  Europe en de Normalisation (CEN), Quiroga, P., Fowler, D., 2004. The Effects of Aggregates Characteristics on the Per-
Brussels, Belgium, p. 259. formance of Portland Cement Concrete. Research Report ICAR - 104-1F. Inter-
EN 450-1, 2012. Fly Ash for Concrete - Part 1: Definition, Specifications and Con- national Center for Aggregates Research, Austin, USA, p. 358.
formity Criteria. Comite  Europe en de Normalisation (CEN), Brussels, Belgium. RILEM, 1970. Essais Portant sur l’adhe rence des Armatures du Be ton. 2- Essais Par
EN 933-4, 2002. Tests for Geometrical Properties of Aggregates - Part 4: Determi- Traction. Bond Test for Reinforcing Steel. Mate riaux et Constructions. RILEM
nation of Particle Shape e Shape Index. Comite  Europeen de Normalisation Doc. 3 (15), 175e178, 7.11.128.
(CEN), Brussels, Belgium. Rodrigues, F., Carvalho, M., Evangelista, L., de Brito, J., 2013a. Physical, chemical and
EN 934-2, 2009. Admixtures for Concrete, Mortar and Grout - Part 2: Concrete mineralogical characterization of fine aggregates from construction and de-
Admixtures - Definitions, Requirements, Conformity, Marking and Labelling. molition waste recycling plants. J. Clean. Prod. 52, 438e445.
Comite  Europeen de Normalisation (CEN), Brussels, Belgium. Rodrigues, F., Evangelista, L., de Brito, J., 2013b. A new method to determine the
Evangelista, L., de Brito, J., 2014. Concrete with fine recycled aggregates: a review. density and water absorption of fine recycled aggregates. Mater. Res. J. 16 (5),
Eur. J. Environ. Civ. Eng. 18 (2), 129e172. 1045e1051.
Eurostat, 2016. Eurostat, Environment and Energy. Generation and Treatment of Silva, R., de Brito, J., Dhir, R., 2016. Establishing a relationship between the modulus
Waste. Available at. http://ec.europa.eu/eurostat/statisticsexplained/index.php/ of elasticity and compressive strength of recycled aggregate concrete. J. Clean.
Waste_statistics/pt (Accessed December 2016). Prod. 112, 2171e2186.
Fallah, S., Nematzadeh, M., 2017. Mechanical properties and durability of high- Solyman, M., 2005. Classification of Recycled Sands and Their Applications as Fine
strength concrete containing macro-polymeric and polypropylene fibers with Aggregates for Concrete and Bituminous Mixtures. Universita €t Kassel, p. 194.
nano-silica and silica fume. Constr. Build. Mater 132, 170e187. St. John, D., 1994. The Dispersion of Silica Fume. Industrial Research Limited Report
Faury, J., 1958. Le Beton, third ed. Dunod Editions, Paris, France. nº 244, Lower Hutt, New Zealand.
Ferreira, L., de Brito, J., Barra, M., 2011. Influence of the pre-saturation of recycled Tu, T., Chen, Y., Hwang, C., 2006. Properties of HPC with recycled aggregates. Cem.
coarse concrete aggregates on concrete properties. Mag. Concr. Res. 63 (8), Concr. Res. 36 (5), 943e950.
617e627. Yajun, J., Cahyadi, J., 2003. Effects of densified silica fume on microstructure and
Freedonia, 2012. World Construction Aggregates to 2015-Industry Study # 2838. compressive strength of blended cement pastes. Cem. Concr. Res. 33 (10),
The Freedonia Group, Cleveland, USA, p. 334. 1543e1548.
Gjørv, O., Monteiro, P., Mehta, P., 1990. Effect of condensed silica fume on the steel- Zhang, Z., Zhang, B., Yan, P., 2016. Comparative study of effect of raw and densified
concrete bond. ACI Mater. J. 87 (6), 573e580. silica fume in the paste, mortar and concrete. Constr. Build. Mater 105, 82e93.
Gonzalez, A., Etxeberria, M., 2014. Experimental analysis of properties of high Zong, L., Fei, Z., Zhang, S., 2014. Permeability of recycled aggregate concrete con-
performance recycled aggregate concrete. Constr. Build. Mater 52, 227e235. taining fly ash and clay brick waste. J. Clean. Prod. 70, 175e182.
Gonzalez, A., Etxeberria, M., 2016. Effects of using recycled concrete aggregates on

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