Solución:

Datos:
500mL0,3284g Latón

 10mL Pb, Zn, Cu  37,56 mL de EDTA

 25 mL Pb, Zn 27,67mL de EDTA
 100mL Pb  10,80 mL de EDTA

- %Pb.

0,3284𝑔 𝐿𝑎𝑡𝑜𝑛
𝑔𝑙𝑎𝑡ó𝑛 = 100 𝑚𝐿 𝑠𝑜𝑙 ∗
500 𝑚𝐿 𝑠𝑎𝑙
𝑔𝑙𝑎𝑡ó𝑛 = 0,06568 𝑔 𝐿𝑎𝑡ó𝑛
𝑚𝑔 𝑉𝑝 𝑀𝑝 𝑃𝑚 ∗ 1000
Pb =
𝐾𝑔 𝑔𝑚
𝑚𝑔 mg
Pb = 85176,61 𝑑𝑒 𝑃𝑏
𝐾𝑔 Kg
𝑚𝑔
𝐾𝑔 𝑃𝑏 85176,61mg/Kg
%Pb = = = 8,51% 𝑑𝑒 𝑃𝑏
10000 10000
- %Zn y %Pb.
0,3284𝑔 𝐿𝑎𝑡𝑜𝑛
𝑔𝑙𝑎𝑡ó𝑛 = 25 𝑚𝐿 𝑠𝑎𝑙 ∗ = 0,01642𝑔 𝐿𝑎𝑡ó𝑛
500 𝑚𝐿 𝑠𝑎𝑙

100mL  10,8

10,8 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑔𝑎𝑠𝑡𝑎𝑑𝑜 𝑒𝑛 𝑃𝑏

𝑉𝑝 = 25 𝑚𝐿 𝑠𝑎𝑙 ∗
100 𝑚𝐿 𝑠𝑎𝑙
= 2,7 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑔𝑎𝑠𝑡𝑎𝑑𝑜 𝑒𝑛 𝑃𝑏
𝑉𝐸𝐷𝑇𝐴 gastado = 27,67 𝑚𝐿 − 2,7 𝑚𝐿
𝑉𝐸𝐷𝑇𝐴 gastado = 24,97𝑚𝐿
Entoncs:
𝑚𝑔 𝑉𝑝 𝑀𝑝 𝑃𝑚 ∗ 1000
Zn =
𝐾𝑔 𝑔𝑚
𝑚𝑔 mg
Zn = 248559,47 𝑑𝑒 𝑍𝑛
𝐾𝑔 Kg
 𝑚𝑔 mg
𝐾𝑔 𝑍𝑛 248559,47 Kg
%Zn = = = 24,85% 𝑑𝑒 𝑍𝑛
10000 10000

%Pb, %Zn y % Cu:

0,3284𝑔 𝐿𝑎𝑡𝑜𝑛
𝑔𝑙𝑎𝑡ó𝑛 = 10𝑚𝐿 𝑠𝑎𝑙 ∗ = 6,58𝑥10−3 𝑔 𝐿𝑎𝑡ó𝑛
500 𝑚𝐿 𝑠𝑎𝑙

10,8 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑔𝑎𝑠𝑡𝑎𝑑𝑜 𝑒𝑛 𝑃𝑏

𝑉𝑝 = 70 𝑚𝐿 𝑠𝑎𝑙 ∗
100 𝑚𝐿 𝑠𝑎𝑙
= 1,08 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑔𝑎𝑠𝑡𝑎𝑑𝑜 𝑒𝑛 𝑃𝑏
24,97 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑔𝑎𝑠𝑡𝑎𝑑𝑜 𝑒𝑛 𝑍𝑛
𝑉𝑝 = 10 𝑚𝐿 𝑠𝑎𝑙 ∗
100 𝑚𝐿 𝑠𝑎𝑙
= 9,98 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑔𝑎𝑠𝑡𝑎𝑑𝑜 𝑒𝑛 𝑍𝑛

𝑉𝐸𝐷𝑇𝐴 gastado = 9,98 𝑚𝐿 + 1,08 𝑚𝐿

𝑉𝐸𝐷𝑇𝐴 gastado = 11,06 𝑚𝐿

𝑚𝑔 𝑉𝑝 𝑀𝑝 𝑃𝑚 ∗ 1000
Cu =
𝐾𝑔 𝑔𝑚
𝑚𝑔 mg
Cu = 60914,28 𝑑𝑒 𝐶𝑢
𝐾𝑔 Kg
𝑚𝑔 mg
𝐾𝑔 𝐶𝑢 60914,28 Kg
%Cu = = = 64,09% 𝑑𝑒 𝐶𝑢
10000 10000

entoncs
%𝑆𝑛 + %Pb + %Cu + %Zn = 100%
%𝑆𝑛 = 100% − 64,09% − 8,51% − 24,85%
%𝑆𝑛 = 2,6% de Sn