DEDUCCION DE FORMULAS

1.-
𝑃 𝑃𝑖 𝑃𝑖 ∗ 𝐺𝑝
= −
𝑍 𝑍𝑖 𝑍𝑖 ∗ 𝐺𝑂𝐸𝑆
Como 𝑛𝑝 = 𝑛𝑖 − 𝑛 ……1 np=moles producido
ni= moles iniciales
n= moles remanentes
ecuación de estado de gases:
𝑃𝑉 = 𝑍𝑛𝑅𝑇

𝑃𝑠𝑐 ∗𝐺𝑝
𝑛𝑝 = …….2 V=Gp= volumen de gas producido Z=1
𝑍𝑠𝑐 ∗𝑅∗𝑇𝑠𝑐

𝑃𝑖 ∗𝑉𝑖
Para 𝑛𝑖 = …….3 Vi= volumen inicial de gas
𝑍𝑖 ∗𝑅∗𝑇

𝑃∗𝑉
𝑛= ………4
𝑍∗𝑅∗𝑇

Reemplazamos 2, 3, 4, en 1

𝑃𝑉 𝑃𝑖 𝑉𝑖 𝑃𝑠𝑐 𝐺𝑝
= −
𝑍𝑅𝑇 𝑍𝑖 𝑅𝑇 𝑅𝑇𝑠𝑐

𝑃 𝑅𝑇 𝑃𝑖 𝑉𝑖 𝑃𝑠𝑐 𝐺𝑝
= ( − )
𝑍 𝑉𝑅 𝑍𝑖 𝑇 𝑇𝑠𝑐

𝑃 𝑇 𝑃𝑖 𝑉𝑖 𝑃𝑠𝑐 𝐺𝑝
= ( − )
𝑍 𝑉 𝑍𝑖 𝑇 𝑇𝑠𝑐

𝑃 1 𝑇𝑃𝑖 𝑉𝑖 𝑇𝑃𝑠𝑐 𝐺𝑝
= ( − )
𝑍 𝑉 𝑍𝑖 𝑇 𝑇𝑠𝑐

𝑃 1 𝑃𝑖 𝑉𝑖 𝑇𝑃𝑠𝑐 𝐺𝑝
= ( − ) …….5
𝑍 𝑉 𝑍𝑖 𝑇𝑠𝑐

Como los cambios de volúmenes son despreciables tenemos:

V=Vi

𝑃 𝑃𝑖 𝑉𝑖 𝑇𝑃𝑠𝑐 𝐺𝑝
= −
𝑍 𝑉𝑖 𝑍𝑖 𝑉𝑖 𝑇𝑠𝑐

𝑃 𝑃𝑖 𝑇𝑃𝑠𝑐 𝐺𝑝
= − …….6
𝑍 𝑍𝑖 𝑉𝑖 𝑇𝑠𝑐
Donde 𝑉𝑖 = 𝐺 ∗ 𝐵𝑔𝑖
 𝑍𝑖 𝑇𝑃𝑠𝑐
𝑉𝑖 = 𝐺 ………………7
𝑇𝑠𝑐 𝑃𝑖

Reemplazamos 7 en 6

𝑃 𝑃𝑖 𝑇𝑃𝑠𝑐 𝐺𝑝
= −
𝑍 𝑍𝑖 𝑇 (𝐺 𝑍𝑖 𝑇𝑃𝑠𝑐 )
𝑠𝑐 𝑇𝑠𝑐 𝑃𝑖
Tenemos:

𝑃 𝑃𝑖 𝑃𝑖 𝐺𝑝
= −
𝑍 𝑍𝑖 𝑍𝑖 𝐺𝑂𝐸𝑆

2.- Ecuación general de balance de materia

𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑓𝑙𝑢𝑖𝑑𝑜𝑠 𝑝𝑟𝑜𝑑𝑢𝑐𝑖𝑑𝑜𝑠 = 𝐺𝑝 𝐵𝑔 + 𝑁𝑝 𝐵𝑛

𝑌𝑎𝑐𝑖𝑚𝑖𝑒𝑛𝑡𝑜 = 𝐺(𝐵𝑦 − 𝐵𝑔𝑖 ) + ∆𝑉𝑛 + ∆𝑉𝑝 + 𝑊𝑒

𝐹 = 𝐺𝑝 𝐵𝑔 + 𝑁𝑝 𝐵𝑛

𝐸𝑔 = 𝐵𝑔 − 𝐵𝑔𝑖

∆𝑉𝑤 = 𝐶𝑤 𝑉𝑛 (𝑃𝑖 − 𝑃) 𝑉𝑤 = 𝑉𝑝 𝑆𝑤𝑖 ∆𝑉𝑝 = 𝐶𝑓 𝑉𝑝 (𝑃𝑖 − 𝑃)

𝐺𝐵𝑔𝑖
𝑉𝑝 =
1 − 𝑆𝑤𝑖

𝐺𝐵𝑔𝑖
∆𝑉𝑤 + ∆𝑉𝑝 = (𝐶 + 𝐶𝑤 𝑆𝑤𝑖 )(𝑃𝑖 − 𝑃)
1 − 𝑆𝑤𝑖 𝑓

𝐸𝑡 = 𝐸𝑔 + 𝐸𝑓𝑤

Reemplazando
𝐺𝐵𝑔𝑖
𝐺𝑝 𝐵𝑔 + 𝑁𝑝 𝐵𝑛 = 𝐺(𝐵𝑔 − 𝐵𝑔𝑖 ) + (𝐶 + 𝐶𝑤 𝑆𝑤𝑖 )(𝑃𝑖 − 𝑃) + 𝑊𝑒
1 − 𝑆𝑤𝑖 𝑓

𝐹 = 𝐺𝑝 𝐵𝑔 + 𝐺 ∗ 𝐸𝑓𝑤 +𝑊𝑒

𝐹 = 𝐺(𝐵𝑔 + 𝐸𝑓𝑤 ) + 𝑊𝑒

𝐹 𝑊𝑒
=𝐺+
𝐸𝑡 𝐸𝑡
3.- Ecuación de balance de materia para yacimientos volumétricos

𝐺 ∗ 𝐵𝑔𝑖 = (𝐺 − 𝐺𝑝 )𝐵𝑔

𝐺 ∗ 𝐵𝑔𝑖 = (𝐺 − 𝐺𝑝 )𝐵𝑔 + ∆𝑉𝑤 + ∆𝑉𝑓

1 𝜕𝑉𝑤 1 ∆𝑉𝑤
𝐶𝑤 = − ( ) =−
𝑉𝑛 𝜕𝑃 𝑇 𝑉𝑤 ∆𝑃

∆𝑉𝑤 = −𝐶𝑤 𝑉𝑤𝑖 ∆𝑃

𝑆𝑤𝑖 𝐺𝐵𝑔𝑖
𝑉𝑤𝑖 = 𝐶𝑤
1 − 𝑆𝑤𝑖

𝑆𝑤𝑖 𝐺𝐵𝑔𝑖
∆𝑉𝑤 = 𝐶𝑤 (𝑃 − 𝑃)
1 − 𝑆𝑤𝑖 𝑖

1 𝜕𝑉𝑝 1 ∆𝑉𝑝
𝐶𝑓 = ( ) ; ̅̅̅
𝐶𝑓 =
𝑉𝑓 𝜕𝑃 𝑇 𝑉𝑝𝑖 ∆𝑃

∆𝑉𝑝 = ̅̅̅
𝐶𝑓 𝑉𝑝𝑖 ∆𝑃

𝐺𝐵𝑔𝑖
𝑉𝑝𝑖 =
1 − 𝑆𝑤𝑖

𝑉𝑝 = −𝑉𝑝

𝐺𝐵𝑔𝑖
−∆𝑉𝑝 = 𝐶𝑓 (𝑃 − 𝑃) = 𝑉𝑓
1 − 𝑆𝑤𝑖 𝑖

𝑆𝑤𝑖 𝐺𝐵𝑔𝑖 𝐺𝐵𝑔𝑖

𝐺𝐵𝑔𝑖 = (𝐺 − 𝐺𝑝 )𝐵𝑔 + 𝐶𝑤 (𝑃𝑖 − 𝑃) + 𝐶𝑓
1 − 𝑆𝑤𝑖 1 − 𝑆𝑤𝑖

𝐺𝐵𝑔𝑖 (𝑃𝑖 − 𝑃) (𝐶𝑤 𝑆𝑤𝑖 + ̅̅̅

𝐶𝑓 )
𝐺𝐵𝑔𝑖 = (𝐺 − 𝐺𝑝 )𝐵𝑔 +
1 − 𝑆𝑤𝑖

(𝐶𝑤 𝑆𝑤𝑖 + ̅̅̅

𝐶𝑓 )(𝑃𝑖 − 𝑃) 𝐵𝑔𝑖
𝐺 − 𝐺𝑝 = 𝐺 [1 − ]
1 − 𝑆𝑤𝑖 𝐵𝑔
𝐵𝑔𝑖 𝑃𝑍𝑖
=
𝐵𝑔 𝑃𝑖 𝑍

𝑃 (𝐶𝑤 𝑆𝑤𝑖 + ̅̅̅

𝐶𝑓 )(𝑃𝑖 − 𝑃) 𝐺𝑃𝑖
[1 − ]=
𝑍 1 − 𝑆𝑤𝑖 𝐺𝑝 𝑍𝑖
𝑃 𝑃𝑖 𝐺𝑝
[1 − 𝐶𝑒 (𝑃𝑖 − 𝑃)] = [1 − ]
𝑍 𝑍𝑖 𝐺

1 𝐺𝑝
𝐶𝑒 (𝑃𝑖 − 𝑃) = 1 − [1 − ]
(𝑃⁄𝑍) 𝐺
(𝑃⁄𝑍)
𝑖

(𝑃⁄𝑍) 𝐺𝑝
𝑖
𝐶𝑒 (𝑃𝑖 − 𝑃) = 1 − [1 − ]
(𝑃⁄𝑍) 𝐺

(𝑃⁄𝑍) (𝑃⁄𝑍) 𝐺𝑝
𝑖 𝑖
𝐶𝑒 (𝑃𝑖 − 𝑃) = 1 − +
(𝑃⁄𝑍) (𝑃⁄𝑍)𝐺

(𝑃⁄𝑍)
𝑖
−1
𝑃
( ⁄𝑍) 1 (𝑃⁄𝑍) 𝐺𝑝
𝑖
= [ ] − 𝐶𝑒
(𝑃𝑖 − 𝑃) 𝑃
𝐺 ( ⁄ )(𝑃𝑖 − 𝑃)
𝑍

(𝑃⁄𝑍)
𝑖
−1
𝑃
( ⁄𝑍) (𝑃⁄𝑍) 𝐺𝑝
𝑖
𝑉𝑠 [ ]
(𝑃𝑖 − 𝑃) (𝑃⁄𝑍)(𝑃𝑖 − 𝑃)