PHY./INO.

CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 55

This DPP is to be discussed in the week (30.11.2015 to 05.12.2015)

DPP No. # 55 (JEE-ADVANCED)_REVISION DPP

Total Marks : 71 Max. Time : 47 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Multiple choice objective ('–1' negative marking) Q.6 to Q.10 (4 marks, 2 min.) [20, 10]
Integer type Questions ('–1' negative marking) Q.11 to Q.15 (4 marks 3 min.) [20, 15]
Match the Following (no negative marking) Q.16 to Q.17 (8 marks, 6 min.) [16, 12]

ANSWER KEY
DPP No. # 55 (JEE-ADVANCED)_REVISION DPP
1. (D) 2. (C) 3. (A) 4. (A) 5. (C) 6.* (AD) 7.* (BCD)
8.* (ABC) 9.* (AC) 10.* (ABCD) 11. 5 12. 34 13. 9 14. 7
15. 4 16. (A – r), (B – p ), (C – q,s), (D – q)
17. (A)  (P, Q) ; (B)  (P, S) ; (C)  (R, P) ; (D)  (P)

1. Which of the following is a mismatch :

(A) Lyophilic colloids – reversible sols
(B) Associated collides – micelles
(C) Tyndall effect – scattering of light by colloidal particle
(D*) Electrophoresis – movement of dispersion medium under the influence of
electric field
buesa ls dkSu lqesfyr ugha gSA
(A) nz o Lus gh dksykbM & mRØe.kh; lksy
(B) la ;qDr dksykbM & felSy
(C) fVa Msy izHkko & dksykbM d.kksa ds }kjk izdk'k dk izdh.kZu
(D*) oS| qr d.k la pyu & fo|qr {kS=k ds izHkko esa ifj{ksi.k (dispersion) ek/;e dh xfr ¼ movement½

2. A sample of oleum is labelled as 104.5%. What amount of pure NaOH is required to neutralize the 100 g of
the sample of oleum.
,d vksfy;e ds] izkn'kZ ij 104.5% vafdr gSA rc vksfy;e izkn'kZ ds 100 g ds iw.kZ mnklhuhdj.k ds fy, 'kq) NaOH dh
fdruh ek=kk vko';d gSA
(A) 172.2 g (B) 80 g (C*) 84.8 g (D) 62 g (E) 40 g
4.5
Sol. Wt. of free SO 3 = × 80 = 20 g
18
Equivalent of NaOH = Equivalent of H2SO4 + Equivalent of SO3
W 80 20
= ×2+ ×2
40 98 80
W = 84.8 g

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 4.5
Sol. eqDr SO3 dk Hkkj = × 80 = 20 g
18
NaOH ds rqY;kad = H2SO4 ds rqY;kad + SO3 ds rqY;kad
W 80 20
= ×2+ ×2
40 98 80
W = 84.8 g

3. Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (C). Gas (C) on
reaction with magnesium give compound (D) which on hydrolysis gives again gas B. Identify (B), (C) and (D).
dSfYl;e ,bekbM ty vi?kVu ij xSl (B) nsrk gS tks fojatd pw.kZ ls vkWDlhdj.k ij xSl (C) nsrk gSA xSl (C) eSXuhf'k;e
ds lkFk vfHkfØ;k ij ;kSfxd (D) cukrk gSA tks ty vi?kVu ij iqu% xSl (B) nsrk gS I (B), (C) o (D) dks igpkfu;s &
(A*) NH3, N2 and ¼rFkk½ Mg3N2 (B) N2, NH3, MgNH
(C) N2, N2O5, Mg(NO3)2 (D) NH3, NO2,Mg(NO2)2
Sol. Ca(NH) + 2H2O Ca(OH)2 + NH3(g)
(B)
2NH3 + 3CaOCl2 N2(g) + 3CaCl2 + 3H2O
(B) (C)
N2(g) + 3Mg  Mg3N2
(C) (D)
Mg3N2 + 6H2O 3Mg(OH)2 + 2NH3
(D) (B)

4. The following electrochemical cell is taken.

Cu | Cu2+(aq) || Ag+ (aq) | Ag, and has emf E1 > 0. By which of the following actions, E1 increases?
(A*) Adding Ag+ to the cathodic chamber. (B) Adding Ag(s) to the cathodic chamber.
2+
(C) Adding Cu to the anodic chamber. (D) Adding Cu(s) to the anodic chamber.

fuEu fo|qrjklk;fud lsy Cu | Cu2+(aq) || Ag+ (aq) | Ag fy;k x;k gS rFkk bldk emf E1 > 0 gSA fuEu esa ls fdl
izØe }kjk E1 c<+rk gS \
(A*) dSFkksM Hkkx esa Ag+ feykus ij (B) dSFkksM Hkkx esa Ag(s) feykus ij
2+
(C) ,uksM Hkkx esa Cu feykus ij (D) ,uksM Hkkx esa Cu(s) feykus ij

Sol. Adding Ag+ anodic chamber will shift the reaction forward and increase the voltage.
Sol. ,uksM Hkkx esa Ag+ feykus ij vfHkfØ;k vxz fn'kk esa foLFkkfir gksxh vkSj foHko c<+sxkA

5. Find out the concentration of Ni2+ in solution at equilibrium :

(A) 5 × 10–18 M (B) 1017 M (C*) 10–17 M (D) data insufficient
lkE; ij foy;u esa Ni2+ dh lkUnzrk Kkr dhft, %
(A) 5 × 10–18 M (B) 1017 M (C*) 10–17 M (D) vk¡dMs vi;kZIr gSaA
2+ 2+
Sol. The cell reaction for the cell Zn, Zn || Ni , Ni is :
Zn + Ni2+ Zn2+ + Ni for which,

0 0.06 [ Zn 2 ]
Ecell = Ecell – log
2 [ Ni 2  ]
At equilibrium Ecell = 0

0 0.06 [ Zn 2 ]
 Ecell = log
2 [ Ni 2  ]

0 0 0.06 [Zn2  ]
E Ni 2  EZn 2
, Zn = log
, Ni
2 [ Ni 2  ]

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 2
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 0.06 [ Zn 2 ]
–0.24 – (–0.75) = log
2 [ Ni 2  ]

[Zn2  ]
log = 17
[ Ni 2  ]

[ Zn 2 ]
Taking antilog, = 1017
[ Ni 2  ]
This concentration ratio shows that almost whole of the Ni2+ ions is reduced to Ni and therefore, the concen-
tration of Zn2+ produced from Zn would be nearly 1 M [ Ni(NO 3)2 = 1 M]. Thus,
1
= 1017
[ Ni 2 ]
or [Ni2+] = 10–17 M.
Sol. lSy ds fy, lSy vfHkfØ;k] Zn, Zn2+ || Ni2+, Ni gSA
Zn + Ni2+ Zn2+ + Ni ftlds fy,

0 0.06 [ Zn 2 ]
Ecell = Ecell – log
2 [ Ni 2  ]
lkE; ij Ecell = 0

0
0.06 [ Zn 2 ]
 Ecell = log
2 [ Ni 2  ]

0 0 0.06 [ Zn 2  ]
E Ni 2  EZn 2
, Zn = log
, Ni
2 [ Ni 2  ]

0.06 [ Zn 2 ]
–0.24 – (–0.75) = log
2 [ Ni 2  ]

[ Zn 2  ]
log = 17
[ Ni 2  ]

[Zn2  ]
,UVh yksx ysus ij, = 1017
[ Ni 2  ]
;g lkUnzrk vuqikr n’kkZrk gS fd yxHkx lEiw.kZ Ni2+ vk;uksa dk vip;u Ni esa gks tkrk gS o blfy, Zn ls Zn2+ dh lkUnzrk
izkIr gksrh gS tks fd yxHkx 1 M [ Ni(NO3)2 = 1 M]. gksrh gSA bl izdkj,
1
= 1017
[ Ni 2 ]
or ;k [Ni2+] = 10–17 M.

6.* Out of Cu2S, HgS, Ag2S, PbS and ZnS, roasting will convert the minerals into metal in case of :
Cu2S, HgS, Ag2S, PbS rFkk ZnS, esa ls fdlesa HktZu ds }kjk [kfut dks /kkrq esa ifjofrZr djrs gSA
(A*) Cu2S, PbS (B) HgS,ZnS (C) Cu2S, Ag2S (D*) HgS,Cu2S.
Sol. If the sulphide ore of some of the less electropositive metals like Hg, Cu, Pb etc. are heated in air, a part of
these is changed into oxide or sulphate that then reacts with the remaining part of the sulphide ore to give its
metal and SO2. 2HgS + 3 O2  2HgO + 2SO2 ; 2HgO + HgS  2Hg + SO2
Cu2S + 3O2  3Cu2O + 2 SO2 ; 2Cu2O + Cu2S  6Cu + SO2
2PbS + 3O 2  2PbO + 2 SO 2 ; 2PbO + PbS  3Pb + SO2

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 3
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
gy % de oS|qr/kukRed /kkrq,as tSls Hg, Cu, Pb vkfn ds lYQkbM v;Ld dks ;fn ok;q esa xeZ djrs gSa rc budk dqN Hkkx vkWDlkbM
;k lYQsV esa :ikUrfjr gks tkrk gS tks fd lYQkbM v;Ld ds 'ks"k Hkkx ds lkFk vfHkfØ;k dj /kkrq rFkk SO2 nsrk gSA
2HgS + 3 O2  2HgO + 2SO2 ; 2HgO + HgS  2Hg + SO2
Cu2S + 3O2  3Cu2O + 2 SO2 ; 2Cu2O + Cu2S  6Cu + SO2
2PbS + 3O 2  2PbO + 2 SO 2 ; 2PbO + PbS  3Pb + SO2

7.* Ammonia gas is prepared by :

(A) heating ammonium dichromate. (B*) hydrolysis of calcium cyanamide.
(C*) heating ammonium chloride with slaked lime. (D*) alkaline hydrolysis of aluminium nitride.
veksfu;k xSl dk fuekZ.k fd;k tkrk gS :
(A) veksfu;e MkbZØksesV dks xeZ djus ij
(B*) dSfY'k;e lk;ukekbM ds ty vi?kVu }kjk
(C*) cq>s gq,s pwus (slaked lime) ds lkFk] veksfu;e DyksjkbM dks xeZ djus ij
(D*) ,yqfefu;e ukbVªkbM ds {kkjh; ty vi?kVu }kjk

Sol. (A) (NH4)2Cr2O7  N2 + Cr2O3 + 4H2O

(B) CaCN2 + 3H2O  CaCO3 + 2NH3

(C) NH4Cl + Ca(OH)2  2NH3 + CaCl2 + 2H2O

(D) AlN + NaOH + H2O  NaAlO2 + NH3

8.* Which of the following statement(s) is/are correct ?

(A*) Sulphide gives black precipitate with AgNO 3 solution and is soluble in hot concentrated nitric acid.
(B*) Sulphide gives no precipitate with barium chloride solution.
(C*) Sulphide ions react with sodium nitroprusside giving a purple colouration.
(D) Free H2S gas form white precipitate with tetrahydroxo plumbate (II) solution.
fuEufyf[kr esa ls dkSulk@dkSuls dFku lgh gS@gSa \&
(A*) lYQkbM] AgNO3 foy;u ds lkFk dkyk vo{ksi nsrs gSa tksfd xeZ rFkk lkanz ukbfVªd vEy esa foys; gSA
(B*) lYQkbM] csfj;e DyksjkbM foy;u ds lkFk dksbZ vo{ksi ugha nsrk gSA
(C*) lYQkbM vk;u] lksfM;e ukbVªksçqlkbM ds lkFk tkequh jax dk foy;u nsrk gSA
(D) eqDr H2S xSl] VªsVkgkbMªkWDlksIyEcsV (II) foy;u ds lkFk lQsn vo{ksi cukrh gSA

Sol. [Pb(OH)4]2– + H2S  PbS  (black) dkyk + 2OH– + 2H2O.

9.* Which of the following orbitals can form  bond, if internuclear axis is y-axis?
fuEu esa ls dkSuls d{kd  cU/k cuk ldrs gS] ;fn vUrjkukfHkdh; v{k y-v{k gS\
(A*) px + dxy (B) pz + dxz (C*) dyz + dyz (D) dxz + dxz

Sol. (A) (B)

(C) (D)

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 4
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
Sol. (A) (B)

(C) (D)

10.* Which one of the following statements is/are correct ?

(A*) In the aluminothermite process, aluminium acts as reducing agent.
(B*) Lead is extracted from its chief ore by both carbon reduction and self reduction.
(C*) Zinc is extracted from its chief ore by carbon reduction.
(D*) Extraction of gold involves the leaching of ore with cyanide solution followed by reduction with zinc.
fuEu dFkukas esa ls dkSulk@dkSuls dFku lgh gS\
(A*) ,Y;qfeuks rkih; izØe esa ,yqehfu;e vipk;d ds leku dk;Z djrk gSA
(B*) ysM dk fu"d"kZ.k blds eq[; v;Ld ls dkcZu vip;u rFkk Lor% vip;u nksuks izØeksa ls fd;k tkrk gSA
(C*) ftad dk fu"d"kZ.k] blds eq[; v;Ld ls dkcZu vip;u }kjk fd;k tkrk gSA
(D*) xksYM ds fu"d"kZ.k esa] lk;ukbM foy;u }kjk v;Ld dk fu{kkyu rFkk blds i’’'pkr~ ftad ds lkFk vip;u lfEefyr
gSA
3
Sol. (A) Cr2 O3 + 2Al  A I O + 2Cr
2 3

(B) 2PbS + 3O2  2PbO + 2SO2

PbS + 2PbO  3Pb + SO2 (self reduction)
PbO + C  Pb + CO (carbon reduction)
(C) ZnO + C  Zn + CO (carbon reduction)
(D) 4Au(s) + 8CN–(aq) + 2H2O(aq) + O2(g)  4[Au(CN)2]–(aq) + 4OH–(aq) - leaching
2[Au(CN)2]– (aq) + Zn(s)  2Au(s) + [Zn(CN)4]2– (aq) - reduction
(E) It is molten mixture of alumina and cryolite
3
g y- (A) Cr2 O3 + 2Al  A I O + 2Cr
2 3

(B) 2PbS + 3O2  2PbO + 2SO2

PbS + 2PbO  3Pb + SO2 (Lor% vip;u)
PbO + C  Pb + CO (dkcZu&vip;u)
(C) ZnO + C  Zn + CO (dkcZu&vip;u)
(D) 4Au(s) + 8CN–(aq) + 2H2O(aq) + O2(g)  4[Au(CN)2]–(aq) + 4OH–(aq) - fu{kkyu
2[Au(CN)2]– (aq) + Zn(s)  2Au(s) + [Zn(CN)4]2– (aq) - vip;u
(E) ;g ,Y;qfeuk rFkk Øk;ksykbV dk xfyr feJ.k gSA

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 5
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
11. How many of the following metals will displace Hydrogen (H2) from HCl ?
fuEu esa ls fdruh /kkrq;s HCl esa ls gkbMªkstu (H2) eqDr djsxh \
Zn, Hg, Fe, Ag, Mg, Au, Cu, Li, Cs.
Ans. 5
Sol. Zn, Fe, Mg, Li, Cs

12. Argon crystallizes in fcc arrangement, and the density of solid and liquids Ar is 1.59 g cm– 3 and 1.42 g cm– 3
respectively find the approximate percentage of empty space in liquid Ar.
vkWxZu fcc O;oLFkk esa fØLVyhd`r gksrk gS rFkk Bksl rFkk nzo vkxZu dk ?kuRo Øe'k% 1.59 g cm– 3 rFkk 1.42 g cm– 3 gS
rks nzo Ar esa fjDr LFkku dk izfr'kr ¼yxHkx½ Kkr dhft,A
Ans. 34
Sol. Let the volume of solid Ar = 100 ml
Mass of solid Ar = v × p = 100 × 1.59 = 159 g

159
Volume of liquid Ar = = 112 ml
1.42
Since Ar crystalizes in fcc = type lattice the packing fraction = 0.74
Actual volume occupied by Ar = pf × volume of solid Ar
= 0.74 × 100 = 74 mL

(112 – 74 )  100
% Empty space in liquid Ar =  34%
112

ekuk Bksl Ar dk vk;ru = 100 ml

Bksl Ar dk nzO;eku = v × p = 100 × 1.59 = 159 g

Bksl Ar dk vk;ru = 159 = 112 ml

1.42

pwafd Ar, fcc izdkj ds tkyd esa fØLVyhd`r gksrk gS o ladqy izHkkt = 0.74 gSA
Ar }kjk ?ksjk x;k okLrfod vk;ru = ladqy izHkkt × Bksl Ar dk vk;ru
= 0.74 × 100 = 74 mL

(112 – 74 )  100
% Empty space in liquid Ar =  34%
112

13. Number of chelate rings in [Cr(ox)3]3– = a

Number of chelate rings in [Co(en) (NH3)2(Py)2]3+ = b
Number of chelate rings in [Fe(EDTA)]– = c
Number of chelate rings in brown ring complex [Fe(H2O)5(NO)]SO4 = d
Calculate the value of (a + b + c + d) is..........
[Cr(ox)3]3– esa fdysV oy;ksa dh la[;k = a
[Co(en) (NH3)2(Py)2]3+ esa fdysV oy;ksa dh la[;k = b
[Fe(EDTA)]– esa fdysV oy;ksa dh la[;k = c
Hkwjs oy; ladqy [Fe(H2O)5(NO)]SO4 esa fdysV oy;ksa dh la[;k = d
(a + b + c + d) ds eku dh x.kuk djksA
Ans. 9
Sol. a = 3, b = 1, c = 5, d = 0  (a + b + c + d) = 9

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 6
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
14. How many oxides are soluble in moderately concentrated aqueous solution of NaOH.
NaOH ds {kkjh; e/;e lkUnz tyh; foy;u esa fdrus vkWDlkbM foys; gSaA
SO3 , Cl2O7 , N2O5 , CO
(1) (2) (3) (4)
K2O , Cr2O3 , BaO , GeO2
(5) (6) (7) (8)
Ans. 7
Sol. SO3 , Cl2O7 , N2O5 , GeO2 Acidic (vEyh;)
Cr2O3 Amphoteric (mHk;/kehZ)
K2O , BaO Basic ({kkjh;)
CO , Neutral (mnklhu)
Reactions : (vfHkfØ;k,¡ %)
SO3 + 2NaOH  Na2SO4 + H2O
Cl2O7 + 2NaOH  2NaClO4 + H2O
N2O5 + 2NaOH  2NaClO4 + H2O
CO + NaOH  No reaction (dksbZ vfHkfØ;k ugha)
K2O + NaOH  No reaction (dksbZ vfHkfØ;k ugha) but K2O + H2O  2KOH

BaO + NaOH  No reaction (dksbZ vfHkfØ;k ugha) but BaO + H 2O  Ba(OH)2

Cr2O3 + 2NaOH + 3H2O  2Na[Cr(OH)4]

GeO2 + 2NaOH  Na2GeO3 + H2O

15. The plot of log (V – V) versus t (where V is the volume of nitrogen collected under constant temperature
and pressure conditions) for the decomposition of C 6H5N2Cl is given at 50°C with an amount of C 6H5N2Cl
equivalent to 58.3 cc N2. Calculate the rate constant for the reaction in hr –1 expressing your answer in a
single significant digit.

log (V – V) dk t ds
lkis{k vkjs[k (tgk¡ fu;r rki o nkc ifjfLFkfr esa ukbVªkstu dk vk;ru V fy;k x;k gS½ C6H5N2Cl
ds fo;kstu ds fy, 50°C rki fn;k x;k gSA ftl ij C6H5N2Cl dh ek=kk 58.3 cc N2 ds leku gSA
nj fu;rkad dh x.kuk ?k.Vs–1 esa djks o mÙkj dsoy ,d vad esa nksA

Ans. 4

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 7
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 (1  1.75 )
Sol. Slope ¼<ky½ = = – 0.03
25  0

k = – 2.303 (slope) min–1

= – 2.303 (– 0.03) min–1 = 0.06909 min–1 = 4.14 hr–1  4 hr–1

16. Match the following

Column A Column B
(Reagent) (Acid radical)
(A) Neutral ferric chloride (p) NO 3 –
(B) Ferrous sulphate (freshly prepared) (q) S 2–
(C) Lead acetate (r) CH3COO–
(D) Sodium nitroprusside (s) SO 42–

fuEu dks lqesfyr fdft;s

dkWye A dkWye B
¼vfHkdeZd½ ¼vEyh; ewyd½
(A) mnklhu Qsfjd DyksjkbM (p) NO 3 –
(B) Qsjl lYQsV ¼rktk cuk gqvk½ (q) S2–
(C) ysM ,lhVsV (r) CH3COO–
(D) lksfM;e ukbVªksçqlkbM (s) SO42–
Sol. (A – r), (B – p ), (C – q,s), (D – q)

17. Column A Column B

(A) B2H62NH3 200ºC (P) H2
 
(B) B2H6 Re d heat (Q) B3N3H6
   
(C) B2H6 + H2O  (R) H3BO3
(D) B2H6 + HCl  (S) B
Ans. (A)  (P, Q) ; (B)  (P, S) ; (C)  (R, P) ; (D)  (P)
200ºC
Sol. (A) 3B2H62NH3   2B3N3H6 + 6H2
(B) B2H6  Re d heat
   2B + 3H2
(C) B2H6 + 6H2O  2H3BO3 + 6H2
(D) B2H6 + HCl  B2H5Cl + H2

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 8
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029