Class : XII (Sepals) NEET Paper Subject : Chemistry

Topic : Carbonyl compounds + Carboxylic acids + Nitrogen compounds

Single Answer type question: (+4, -1)
46. Product (A) of given reaction is:

47.

A and B are respectively:

(a) P and Q (b) Q and S (c) T and U (d) P and R
48. Major product (X) is:

49. Which of the following will give carbylamine reaction?

(a) CH3CONH2 (b) H2NCONH2 (c) CH3NH2 (d) all of these
50. Major product (P) in the given reaction is :

1
51. In the given reaction the final product ‘M’ is :

52. In which of following reaction CO2 gas will not be evolved?

53. An optically active compound ‘A’ has molecular formula C5H10O3. It gives CO2 with aqueous
NaHCO3 and reacts with LiAlH4 to give an achiral compound then the structure ‘A’ will be :
(a) CH 3CH 2CH 2  CH  COOH (b) CH 3CHCH 2CH 2COOH
| |
OH OH
(c) CH 3CH 2  CH  COOH (d) CH 3CH 2CH CH 2COOH
| |
CH 2OH OH

54. In which of the following reaction product acetaldehyde is formed?

2
 (a) a, b, c (b) a,b, d (c) b, c, d (d) a, b, c, d
55. Which of the following is correct regarding products:

(a) One of the product will give positive iodoform test

(b) One of the product will give CO2 on direct heating
(c) One of the product will give only one oxime with NH2OH
(d) One of the product will give chiral alcohol with C2H5MgBr followed by hydrolysis
56. Which of the following is the correct order of decarboxylation of following carboxylic acids using
soda lime?

(a) R > S > P > Q (b) R > S > Q > P (c) P > Q > R > S (d) P > Q > S > R
57.

58. What will be the correct product represented for the reaction?

(c) Mixture of both (a) and (b) (d) Cannot comment on stereochemistry of product
59. Order of basic strength for the given compound:

3
 (a) I > II > III (b) I > III > II (c) II > III > I (d) III > II > I
60. Which of the following is the correct sequence of reagents of the given conversion?

(a) KMnO4, NH3, KOBr (b) AgCN, HOH, NaOBr

(c) KCN, Partial hydrolysis, KOBr (d) Aq. KOH, NH3, NaOBr
61. Identify the correct product in the given reaction
CH3
(1) PhCOCl/Pyridine

(2) OH, Heat

OH
CH3
CH3 CH3 CH3 (d)
(a) (b) (c) OPh

OH OH OH O
62. Which of the following will not give carbylamine reaction?
(a) t-butylamine (b) Aniline (c) Benzylamine (d) Ethylmethylamine
63.

Assertion: is optically inactive, it is taken in a glass container and plane polarized

light (PPL) is passed through it after heating it for several minutes. The PPL shows significant
optical rotation.
Reason: Like -keto acid, gem dicarboxylic acid eliminates CO2 on heating.
(a) Both Assertion & Reason is True; Reason is a correct explanation for Assertion.
(b) Both Assertion & Reason is True; Reason is not a correct explanation for Assertion.
(c) Assertion is True, Reason is False.
(d) Assertion is False, Reason is True
64. Which of the following is a correct set of reagents for the given conversion:

(I) Reduction by LiAlH4 (II) Reaction with SOCl2 followed by H2/Pd-BaSO4

(III) Catalytic reduction by H2/Ni (IV) Reaction with PCl5 followed by DiBAL-H
(a) I, III (b) II, IV (c) I, IV (d) I, II, IV

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65. O
|| 18


H OH
CH 3  C  O  CH 2CH 3  
 Ethanoic acid + Ethanol.
H

Isotopic oxygen of water will be present with :

(a) Ethanol
(b) Ethanoic acid
(c) After some time it will also be present in some molecules of ester
(d) Both (b) and (c)
66. The correct order of basicities of the following compounds is:

(a) II > I > III > IV (b) I > III > II > IV (c) III >I >II > IV (d) I > II > III > IV
67. The reagent which does not react with both acetone and benzaldehyde is
(a) NaHSO3 (b) phenyl hydrazine.
(c) Fehling solution. (d) Grignard reagent.
68. The formation of cyanohydrine from a ketone is an example of
(a) electrophilic addition. (b) nucieophilic addition.
(c) nucleophilic substitution. (d) electrophilic substitution.
69. Product (Q) is

14
70. Which of the following compounds give CHI3 as a product when treated with I2 in presence of
NaOH?

(a) (b) (c) (d) None of these

71. Which of the following reaction do not yield cyclohexanone as major product?

72. Compare basic strength of following:

5
 (a) A > B > C (b) B > A > C (c) B > C > A (d) C > B > A
73. Product (E) is

(a) (b) (c) (d)

74. The reactivity of carboxylic acid derivatives from highest reactivity to lowest reactivity is
(a) acid anhydride> acid chloride > ester> amide
(b) acid chloride > acid anhydride > ester> amide
(c) acid chloride > acid anhydride > amide > ester
(d) amide > ester> acid anhydride > acid chloride
75. O
||
NaHCO3 / 
Ph  C  OH    A . (A) is :
14

(a) CO2 (b) 14CO2 (c) H2 (d) NH3

76. In the following reaction sequence, the correct structures of E, F and G are respectively

77. The final product C, obtained in this reaction would be:

6
78. Which of the following is the correct decreasing order of basicity :

(a) I > II > III > IV (b) II > I> III > IV (c) II > III > I > IV (d) II>III>IV>I
79. Amongst the compounds given, the one that would form a brilliant coloured dye on treatment with
NaNO2 in dil. HCl followed by addition to an alkaline solution of -naphthol is

(a) (b) (c) (d)

80. How many number of times of Hofmann exhaustive methylation takes place to remove nitrogen
from the given compound.

(a) 3 (b) 2 (c) 1 (d) None of these

81. Arrange the following in increasing order of acid strength:

(a) c < f < d < a < b < e (b) f < d <c < b <e <a
(c) f < c < d < b <e <a (d) c < d < f < a < b < e
82. Which order of acidic strength is wrong?

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83. Which of the following is weakest acid?

84. Assertion : When CH3COCl react with chiral alcohol, stereochemistry of the alcohol is inverted.
Reason: Carbon  oxygen bond in the alchol is never broken so the configuration of stereocentre is
retained.
(a) Both Assertion & Reason is True; Reason is a correct explanation for Assertion.
(b) Both Assertion & Reason is True; Reason is not a correct explanation for Assertion.
(c) Assertion is True, Reason is False.
(d) Assertion is False, Reason is True
85. How many of the functional groups in the given compound are reduced by LiAlH4 and NaBH4.
O
CHO
H2NC

COOCH3

COCl
(a) 4, 2 (b) 2, 4 (c) 2,2 (d) None of these
86. How many moles of Grignard reagent react with following compound :
CHO

HS
CN
(a) 5 (b) 4 (c) 2 (d) 3

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87. NH2
Br2
X 
KOH

COO
Then the compound ‘X’ will be:
O O

NH2
(a) (b) O
NH2

O O

O O

(c) N  CH 3 (d) NH

O O
88. Product C is :
COOH

SOCl2 1. NH3 Br2

  A 
2. 
 B 
KOD / D2O
C

(a) C6 H 5  OH (b) C6 H 5  NH 2 (c) C6 H 5  OD (d) C6 H 5  ND2

89. An organic compound A upon reacting with NH3 gives B. On heating, B gives C. C in presence of
KOH reacts with Br2 to give Ethylamine then A will be

90. Which of the following reaction is used to decrease number of carbon atoms?
(A) Hundsdicker reaction (B) Wurtz reaction
(C) Decarboxylation reaction (D) Riemer Tiemann reaction
(a) A & C (b) A & B (c) B & D (d) A, B and C

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Answer Key
CHEMISTRY (XII-NEET) - 22-07-2018
46. C 47. B 48. A 49. C 50. D
51. D 52. D 53. C 54. B 55. A
56. B 57. D 58. A 59. B 60. C
61. B 62. D 63. A 64. B 65. D
66. B 67. C 68. B 69. D 70. C
71. D 72. C 73. C 74. B 75. A
76. C 77. A 78. C 79. C 80. A
81. D 82. C 83. B 84. D 85. A
86. B 87. D 88. D 89. A 90. A