Академический Документы
Профессиональный Документы
Культура Документы
Sridhar Gudipati
Scientist
National Metallurgical Laboratory
Jamshedpur - 831 007
. _ _. ..• -4
••, • -- 0 •,,,F «V , .. a„k
•-.3,
'...."...: . li, • •
•
.• -A.', 1. :;.:.;"4'' .. ::. ' . 1h ' .4 • 0 4 t'll$,-
it ••••'.... ,.. •7.- • . ilb....., : * i:r.0
•••••:"..':'?... ..":137 •
- _ '...' Ar'..Z''.;. •'*;
.;i'±.....:
- ', . •%.' • .4 •
s7r
?-''',
-7.̀ :"..r.e?" ;1(- ' 45>%...
::,2;:.:i
" . :. - ., „ • • W. tcp-.? . .'4, *:4'ir
-.3.=,1*-"4r: 7 '''''.......r:-: :
',---
-_, t • • ...,...a, .....` . '.."\A*4
4.!,••••••0/*
*AZ,'......7•44;?..e.0*--2-PA. .• 0....• .i,-...) 'J..... - ..
. ••::',-"t'N le, It •••' •• V
•731'-"
,.*. ...:o
... l„ ...c 1-r..,....
et.r.-•?. ','.?:- 1-7-1".i4 . :-,?.,.e.s724!%
1:' sr:'::
• •r-'+.','
..: ;:41':1#1S-
-•::•:!
--..'r-'117,
,,..: •-k, :-.
',-• ..-';'k .....:-.. .?. ,1.- -- 1:
. ••... .;!'-:. .1. :,et -
.
:,-' 4-;•. ; c)-;:it,-.:: ;FfvIT, 1-/
4 2 .
::.)....
4 ..1-:r ,-..4.,.........,_,,..,,,; :: .....,.:.:z1:„ ...; ,,,,
,.:
. 4:„. . -, - , I ... ....
▪..: . 31 : ',;.1i.. -:
-4. , a) t7
- ; ; .-1--7-46, : 4 .. -.. ..f
.:4 -- 7, .
...
.: - , ,i,* - •-:;e ..• -
, ...-..-• •
,,:"•'..
.. i . . .•
;••- -7 . r .1" .!
a- .3,1...:-..,
-. ,.,t-_ - ,,'",.. 5.4- i
l, ..-4-s- :-... ..• ,,,,:,-, - - A:: ..- - -.:. - ...:- -. . : . •
'---.' -5-'77--
4----,..r.. sv • - -:, .-,7t , ...--.-..-....,!-:• .„ r,,....,-„ .,.; ,„....t 7
,.:::::;$?......:1e;I....i.-•-,.-.::-.%..
. I..- 7t6:,-11',...!--1,.1:•:!:':- . :;'.-:!,..:,.... "-;• #r.-. .::i.-:; '
-7-,.
,. i-. v4-..t7-4- ' -,-,3•1',..'''`",t,; -:' --7 ".."4."..- -k:4-''.e.. -4 . '," •--. . .----. I •-• _.--' • • • .
"Ce.-
-..--. ..fr.
.,..7:t 4 er
- - '-c-r-
.".. w'1741
- :0 3.1; 71....
-_, -'-.7...2;%"4:.%.-
. -; %•- ..:•-'. .s.:Z4..'-:. ' • • "47.
'4- A.- ;1.-- . ' ..
4
, .0fp_ ,
.--,..,, 1;: .1. . '
,-
9 4. •.‘,..,^ ',.:7.. !..; .'.."-: ±,.."..
..„4-
", ..4 -,..-',. " .-T .:"/ tk .,...-
'14-7f2-.
• -' - • -,.....,---
1 . S . ,-..-r'*ft,
1,- ,...):%-b." •-•••••-ve-- - •
'7- I -r :.(= . -.4:5,-7-74'-i,-.....- :-.....1:. ,..:44-;?
.....•-,.---
. .i;t1442
-.. i- 'T
• :.- *,
: .,;:g. ,, *--
'A ' (-'. -.1. - .,•&-..,'", ..1.:1- -.-
g•.g. ." ••••‘ • • ••,wo - • •••• „,,...'• • •••• ......• ,g; •g: ...., ..1 .4 . ..... ..:-
A-,,,,-.4., .-- 4 ' -;,' :. .7.%,..) ; - , -r•-‘ , -...;,.--... . ..:..--r • - - .t. e:." - ,•• .,..i , .7.
-.-.. ‘1,-----.&z..- , 4.. 4 ;
.::..:
.7
.,..t-,41
-1-!:-..‘,
.::1,-..
-7 .::7 4..,......,
' .--r:,:.),..
.1:::11-..'::1:_
;T.IL::...17.1::"..‘"„-.....'.r
. ," :".si:.-1
-v
$.•
--.1 . t• • 4` . . - • .: .. - - tr • , . -r -•-1 -• -..V.:•:'
-"-:;.*:-;.....:-:
:7
. • ,. C. .,••-• " . t
'' .
' . , ' i * ''..... t (1‘..l..;.*: -• - : h....i., 4., '.... • ":"- ...
4 '
!•: r.. vs*.;--'..• • 4 -ti' . k .. '''./,'4 - • . . • '...••• ''' ‘ - .•-•-• -
, 217:*:1--.*-2v1- * ,•,,,•,..• - • , • •- • -4- .... • '•• ' ' .." •
• •••
•
• ' • -• .-
4 . - .. . •.
'7'4'
-
•
•••••••• • •• ...t--:'4 :
;"--- :-: ..:.Z.-.:::-. .-.."' '. ",---. - -;1..... , -:'.. -. .... - ^ '
7. - ! `,"' -- . - - - - • ' "*"' - ,,. - - ,
- - A.,••• • ,-- ..• A .- Z:
io
. ..". • #_._
-• " l''
.4,":
',:t
-:f. . .,*
- -C.
'. "'"1
-
--... N -
) ; -1
,..
4-'
t..-_-_,
-;„ rt s,
...•5 ,...... • ' • • •
; ::. t.t,-.. -: - - - ... ,. .-.:. . , , - , . . .
. .... . -„,
r - - .- •
Z1,7: . t.-,,Li.:1- - '',.....t-5_: 37
- ,"7•3'-'..-14•,-..4
,--.:. .-,--;:::-.4. ,• :
:4: 1- :::::.. •-•::
::1!
4.. "...1"'-':1za-
--;7.
--.f.....:--' "--i-4--ts..1.
; ..,...,.... ....3, •••••
i?1,%
,..-fb::t.... -.11'"!•-
''...:-.‘-' ‘..,i.:4",. .
4 ° `,
.,-; ... .Z-, n'-
- .1.c... ...r....,-;7.', ..:;
1-; ,..." -. :-. ....
✓ 7-7
-' i
e - - .. - v$.4%
• '. 7%.',7" - ?".. • ,„,.. 4, •, d
- #
' , $, 4
...v.- 44" ;).=• :.:-.A.`-'..4.-:-13-:44....,'"`'t ." ..; .r . . --in+
. - . . '1..*-
•;.' .' ..r
1 .•
•1 .7.-.',4 :„:•-n ,. -... ....%.4. ...4-tr-,....., tf, ,--, '..:"..-^,'F. ";*1.-t.,:•,"
,y. k7--i., .t1., "7.1.....si.tys",....
+ •:-1-. • ..-0--. f,- ..,-• .., 4 - f...:„ 1„.,-.-...i . 7..„
---4
,--t......,-;--- ...-:.-1,:-
,.-•-• z.,•... "7.....„:12-.,.-.-, t„.. • -,.., I -r./.1.1.;'-t; L....:- -7. -.(z
1,. - -
.......„.-..:.?-••-..,
• . ......„, - 2., -• - _ ....'
-. .,•a.,,..45-7 s:4, • „ _. 2•. .: .. - . . • ,'. `,17--:5_,7:',.--,C. g-, - .2*
Types of Copper
Arsenical copper Free-cutting copper Silver-bearing copper
about 0.3% arsenic 0.6% tellurium 7 to 30 oz per ton
Wrought alloys
Cast alloys
600
.."-,-
,-‘-r,
...-yssTa ,<..
+ ''''
3 , y
.
-
-,
0 •.,„., s 76.5
-
8.4—
1200
g-
--,,, • IA --7 1.-z.-1 78.5 98.3
•,:. 0.5 1coo
`456% % ,. . , e+ L
500
4.§r_ t, . > I
.? -1 45
rk...,
58 : -
_ _-_'•%.
1 424° f,
4,6 (.2 800
5: 1,i - 87.5
_.‘ 420°
-r.-.,„,. . •., t/3 13' 97:3
9•1_,..,
, 1- c+` 5• ÷ •,. ,,i
%/ 3 6. 600
300 _•:. -'•-•
,4. • ' t
- .4C ---- 71.
'NA: %.,
il""t rte '11k- L.
0 10 20 30 40 50 - 60 70 80 90 Zn
Cu 90 80 70 60 50 40 30 20 10 0
Composition, w/o
Fig.3 : Copper-zinc phase diagram
- Commercial Brasses
a Brasses a + 0 Brasses
* for cold working * for hot working
Yellow a Brasses
• Contain 20 to 36% zinc
• Good strength & high ductility
Common practice : Stress relief anneal after cold working to
prevent season cracking/stress corrosion cracking.
This is because of high residual stresses left in the brass as a
result --")1,/ ti/
-P 47
.
11
''.t 1':''
, : ,• ,
.. ( -' i"t
1-6
Most widely used yellow a brasses : Cartridge brass, 70 Cu - 30 Zn
Used for the manufacture of cartridge and shell cases because of
its high ductility (ReferFig. 5).
Red Brasses
a + f3 Brasses
Uses : in the sheet form —> for ship sheathing, condenser heads,
perforated metal, architectural work, valve stems, brazing rods,
condenser tubes.
Note : The structures of high-tensile brasses are generally (a + p), but may
sometimes be wholly 13. Used in the form of castings and hot worked
products.
Typical Applications
BRONZES
Bronzes
1. Uri bronzes :
I-8
Phosphorus between 0.01 and 0.5%
Refer Fig.7 —>
1. The 13 phase, within the limits shown, forms as the result of a
peritectic reaction between a and melt of 25% tin at 798°C
2. is bcc and transfoiins eutectoidally at 586°C to a + y, y is also bcc
3. Now, 7undergoes a eutectoid transformation at 520°C
to a and 8(Cu31Sn8) ---> new two-phase constituent (a+6)
4. Again, 8 phase by eutectoid reaction at 350°C to (a +e)
5. The solvus line on the diagram below 520°C indicates a decrease
in the solubility of tin as the a phase cools. These changes are so
sluggish, so they may be disregarded. So, for all practical
purposes, the reaction 5—> a ÷ c, may be considered non-
existent. Atomic percent tin
11
to 20 30 40 50 60 7
I 2000
1084°
1
1800
a± L 72 Liquid
-s- I f I
5.5 /9+ L 1600
...,....
A 798° , I 756°
800 ,13.5
.- ti;:rif ''z' 30.6
t _ _ 1400
70(
- tl.,:e.... ,1 I i
tzfrrk,
,?.4....o: 38.2 59 415'
400 9 .4— 00
-' -,...i....ir +
— -•
300
,.... 7)-1 -,t10
a+f f 227°
200 8.2 189° ,i -- 6 I 186'
T-0 991 - 00
E+ 7j` i
I
0 ---
1001)
10 20 30 40 50 70 80 90 Sn
Cu 90 80 70 60 50 40 30 20 10 0
Composition. wio
2. Silicon Bronzes
1-9
Properties :
3. Aluminum Bronzes
Two-phase Al-bronzes :
Uses : Heat treated ones; gears. propeller hubs, blades. pump parts.
bearings. bushings. nonsparking tools. drawing and forming dies.
11 0
c 000
Beryllium Bronzes t i
100
L 1 .1
; 1. 1800
1,i i 0 1- t 1
900
q
t
F t. , , 1t _.
1----1--------
........
I —
'600
800 I _/-----"
— •1—
ai
1,
1 i _ •1400 4
-
i a + a I
700 I— ■ r —4
:
I 0 + Y . — 1200
.7?
500
I I _ 1000
500 i
1
!
1+ Y i BOO
400
300 — BOO
2 4 5 6 10
■
.ye.qht cement terythum
I-10
1. The solubility of beryllium in the a solid solution decreases from
2.1% at 1590°F to less than 0.25% at room temperature.
2. This indicates the possibilities of age-hardening
For a given alloy —> two principal methods to increase strength &
hardness : (1) cold working, (2) heat-treatment
Conditions : (1) Most metals show some solubility for each other in the
solid state and therefore they form solid solutions. So, the equilibrium
diagram must show partial solid solubility. (2) The slope of the solvus
line must be such that there is greater solubility at a higher
temperature than at a lower temperature i.e. the solid solubility limit
should decrease with decreasing temperature.
Atop Alloy Alloy Alloy
1 4 3 2
IT
Lliqutd
Tj
4 0 !0 <0 50 60 70 =
Coo, osi'l ■
on, weight percent
/3 particles (ccteally
submicroscopic)
a groins
(b) (c)
800
600
2 400
0
E
V
200
wt % Cu
1-12
5. Cupronickels :
1500
1400 2600
U-
e- 1300 2400
TT;
1200 2200 t
a
1100
2000
IWO
Ni 10 20 30 40 50 60 70 80 90 Cu
Weight percent. copper
6. Nickel Silvers
Properties
Liquid
300 —
2 C0i- a + Liquid
100
1
100% Sn 20 40 60 50 0 % Sn
C% Pb 100% Pb
Composition (% Pb)
'1/44•
Fig. 16 : Lead-base babbitt (Pb-10 Sb-5 Sn-0.5 Cu)
Etchant : 15 ml acetic acid, 20 ml nitric acid, 80 ml water at 42°C
Features: (1) Dendritic grains of lead rich solid solution (black),
(2) Primary cuboids of antimony-tin intermetallic phase (white),
(3) matrix: ternary eutectic; (a) antimony-rich solid solution
(white) (b) lead-such solid solution (black) (c) antimony-tin phase
(also white).
Properties
Melting point 232°C
Crystal structure Body centered tetragonal
Density 7.29 x 103 kg/m3
E, Young's modulus 40.8 GPa
Electrical resistivity 1.15 x 10-7 S2 m at 20°C
Corrosion resistance Very good
Uses
1. Tin is an ideal metal for coating mild steel to make tin-plate for
the manufacture of cans because tin is attractive in appearance,
low melting point, good corrosion resistance and lack of toxicity.
In the beginning, tin-plate was made by dipping sheets of mild
steel into baths of molten tin. Now-a-days it is done by
electrolysis.
2. Used in the manufacture of white metal bearings.
3. As an alloying element.
4. Earlier, tin foils were used for packaging, because of its high
price, aluminium is being used now-a-days.
General Etchants
1. 2 ml Hcl. 5 ml HNO3, 93 ml methnol : Immersion
2. 5 ml Hcl, 2g Fecl3, 30 ml 1-120, 60 ml methanol or ethanol :
Immersion
3. Picral (4g picric acid, 100 ml methanol or ethanol) : Immersion
Tin-base Babbitts
Fig.17 : Tin-base babbitt (80% Sn, 11% Sb, 6% Pb, 3% Cu). Showing
cuboids of SbSn and network of Cu6Sn5 needles
1-16
1. Tin and antimony conbine to form a very hard intermetallic
compound, with the formula SbSn.
2. SbSn appear as cuboids
3. They appear in a soft matrix of ternary tin-lead-antimony eutectic
4. During the solidification of bearing metals, the hard SbSn cuboids
solidify from the liquid first.
5. Since they are having low density, they come to the surface of the
liquid metal.
6. To prevent the presence of SbSn cuboids (to some extent),
copper (- 3%) is added to the alloy.
7. Now, Cu6Sn5 (intermetallic compound) —> which is hard,
solidifies first
8. Cu6Sn5 looks like needle-shaped crystals
9. They form a continuous network throughout the melt.
10. This network largely prevents the SbSn cuboids from segregating
to the surface of the melt when they begin to solidify.
Properties
Titanium Alloys
1-17
• Neutral element Zirconium, tin and silicon
- they do not have effect on either a or (3 phases
Alpha Alloys
The compositions of these alloys are balanced by high aluminium
content so that the alloys are essentially one-phase alpha.
• Because of the one-phase microstructure, weldability is very good.
• Because of the aluminium, retention of strength at high
temperature is obtained. They cannot be strengthened by heat
treatment (Ti-5 Al- 2.5 Sn).
Applications :
Aircraft tail pipe assemblies, formed sheet components operating
up to 900°F, missile fuel tanks and structural parts operating for
short times up to 1100°F.
1-18
•
Beta Alloys
BIBLIOGRAPHY