JP XII Organic Chemistry

ORGANIC CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 36
This DPP is to be discussed in the week (23-11-2015 to 28-11-2015)
DPP No. # 36 (JEE-ADVANCED)

Total Marks : 47 Max. Time : 32 min.
One or more than one choice Objective Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Comprehension Type (One Option Correct) ('–1' negative marking) Q.6 to Q.7 (3 marks, 2 min.) [06, 04]
Match the Following (no negative marking) Q.8 (8 marks, 6 min.) [08, 06]
Single Integer Type Questions Q.9 to Q.10 (3 marks 2 min.) [06, 04]
ChemINFO : 4 Questions ('–1' negative marking) Q.11 to Q.14 (3 marks, 2 min.) [12, 08]
ANSWER KEY
DPP No. # 36 (JEE-ADVANCED)
1. (A) 2. (BD) 3. (BD) 4. (B) 5. (AC) 6. (B) 7. (A)
8. (A – p, r) ; (B – q, r) ; (C – s, q) ; (D – q) 9. 9 10. 4 11. (C) 12. (D)
13. (B) 14. (D)
1. Which of the following monosaccharides are present as five membered cyclic structure (furanose structure)?
(A*) Ribose (B) Glucose (C*) Fructose (D) Galactose
fuEu esa ls dkSulk eksukslsdSjkbM ik¡p lnL;h pfØ; lajpuk ¼¶;wjsukst lajpuk½ ds :i esa ik;k tkrk gS \
(A*) jkbcksl (B) XYkwdksl (C*) ÝDVksl (D) xSysDVksl
2. Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-
reducing sugar. Sucrose is a __________.
(A) monosaccharide (B*) disaccharide
(C) reducing sugar (D*) non-reducing sugar
dkcksZgkbMªsVks dks tyvi?kVu djus ds buds O;ogkj rFkk vipk;d ;k vu~&vipk;d 'kdZjk ds vk/kkj ij oxhZÑ r fd;k
tkrk gSA vr% lqØksl ,d ------------ gSA
(A) eksukslSdsjkbM (B*) MkbZlSdsjkbM
(C) vipk;d 'kdZjk (D*) vu~&vipk;d 'kdZjk
3. Which of the following carbohydrates are branched polymer of glucose?

(A) Amylose (B*) Amylopectin (C) Cellulose (D*) Glycogen
fuEUk esa ls dkSulk dkcksZgkbMªsV Xywdksl dk 'kkf[kr cgqyd gS \
(A) ,ekbyksl (B*) ,ekbyksisfDVu (C) lsyy
w ksl (D*) Xyk;dkstu
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Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
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4. In disaccharides, if the reducing groups of monosaccharides i.e. aldehydic or ketonic groups are bonded,
these are non-reducing sugars. Which of the following disaccharide is/are non-reducing sugar?
MkblSdsjkbMksa esa ;fn eksukslSdsjkbM ds vipk;d lewg vFkkZr ,fYMgkbfMd vFkok dhVksfud lewg cfU/kr gks tkrs gS ] rks
bUgs vu~&vipk;d 'kdZjk dgrs gSA fuEu esa ls dkSulk MkblSdsjkbM ,d vu~&vipk;d 'kdZjk gS@gSa \
(A) (B*)
(C) (D)
5. The correct statement(s) about biopolymer X is(are) :

ck;ksikWfyej X ds lanHkZ esa dkSuls dFku lR; gS :
X=
(A*) It is a non-reducing sugar. (B) It exhibits mutarotation.

(C*) It has (C1 – C4) glycosidic linkage. (D) Its hydrolysis product is D-Galactose.
(A*) ;g ,d vuvipk;d 'kdZjk gSA (B) ;g E;wVkjksVs'ku (mutarotation) iznf'kZr djrk gSA
(C*) blesa (C1 – C4) XykbdkslkbfMd ca/ku gSA (D) blds tyvi?kVu dk mRikn D-xsysDVksl (Galactose) gSA
Hint. It is non-reducing sugar because it lacks hemiactal linkage. Its hydrolysis product is -D-Glucose.
Hint. ;g ,d vuvipk;d 'kdZjk gS D;ksafd blesa gseh,slhVy ca/ku mifLFkr ugha gSA blds tyvi?kVu dk mRikn -D-Xywdksl gSA
Comprehension #
Observe the following sequence of reaction
KCN / H H O  4LiAlH

 3 
    
This is the method to prepare the higher homolog of monosaccharide sugar.
PAGE NO.- 2
vuqP Nsn #
fuEufyf[kr vfHkfØ;k vuqØe ij fopkj dhft,s %
KCN / H H O  4LiAlH

 3 
    
;g fof/k eksukslsdsjkbM 'kdZjk dks mlds mPp ltkr esa cnyus ds fy, gSA
6. Lactone (L) when treated with acetic anhydride requires how many moles of Ac 2O
ysDVksu (L) dks tc ,lhfVd ,ugkbMªkbM Ac2O ls fØ;k djkrs gSa rks blds fdrus eksy dh vko';drk gksxsaA
(A) 3 (B*) 4 (C) 5 (D) 6
Sol. Four –CHOH require 4 moles of Ac2O
pkj –CHOH lewg ds fy, 4 eksy Ac2O dh vko';drk gksrh gSA
7. What is the end product of following sequence of reaction

bl vfHkfØ;k vuqØe dk vafre mRikn gSA
 
KCN / H HO  4 LiAlH
  3 
    
(A*) (B) (C) (D)
Sol. KCN / H H O  4 LiAlH


 3 
    
8. Match the following : fuEu dk feyku dhft,s&

Column-I (dkWye-I) Column-II (dkWye-II)
(A) (p) Anomers ,uksej
(B) (q) Epimers ,ihej
PAGE NO.- 3
(C) (r) Hemi Acetal gseh,lhVsy
(D) (s) Acetals ,lhVsy
Ans. (A – p, r) ; (B – q, r) ; (C – s, q) ; (D – q)
9. The number of chiral centres present is the following compound is :

fuEu ;kSfxd esa mifLFkr fdjSy dkcZu ijek.kq dh la[;k gS %
CH2OH
H O H
H
OH H
OH
H HO D (+) - Sucrose (D (+) - lqØkssl)
O
HOH2C O
H OH
H
CH2OH
OH H
Ans. 9
CH2OH
* O H
Sol. H
H
* *
OH H
* *
OH
H HO
O
HOH2C O
* *
H OH
* *
H CH2OH
OH H
The star shown indicates chiral centre. (;kSfxd esa rkjkafdr Hkkx fdjSy dsUnz dh mifLFkfr dks n'kkZrs gSA )
PAGE NO.- 4
10. Observe the following reaction and find out that how many number of reactant stereoisomers can be
reduced to optically inactive meso products.
fuEu vfHkfØ;k dk izs{k.k djds crkb;s fd vfHkdkjd ds fdrus f=kfoe leko;oh izdk'kh; vlfØ; ehlks ;kSfxdksa esa
vipf;r gksrs gSA
NaBH
4
 
Ans. 4
4NaBH
Sol. NaBH
4 ;  
 
so in total 4 stereoisomers are reduced to meso products.
4NaBH
NaBH
4 ;  
 
dqy 4 f=kfoe leko;oh ehlks mRiknksa esa vipf;r gksrs gSA
PAGE NO.- 5
ChemINFO-2.9 ARTIFICIAL SWEETNERS
Daily Self-Study Dosage for mastering Chemistry Artificial sweetening
Artificial sweetening agents :
Natural sweetners e.g. sucrose added to calorie intake and therefore many people prefer to use artificial sweetners.
Artificial Structural Sweetness value in
sweetners formula comprehension to cane
sugar
1. Saccharine
(O-sulphobenzimide) 550
100
On metabolic decomposition
2. Aspartame give phenylpyruvic acid which
is harmful to the people
600
Stable at cooking
temperatur e and
3. Sucralose does not provide
calories
4. Alitame 2000
Food preservatives : The chemical which are used to stop undesirable change in food caused by micro organisms
and save them from spoling are called preservatives
Eg. Table salt, sugar vegetable oils and sodium benzoate salts of sorbic acid and propanoic acid.
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
PAGE NO.- 6
11. Which of the following is the correct order sweetness value in comparison to cane sugar :
(A) Saccharide > Aspartame > Sucralose > Alitame
(B) Aspartame > Saccharine > Sucrolose > Alitame
(C*) Alitame > Sucralose > Saccharine > Aspartame
(D) Alitame > Saccharine > Sucralose > Aspartame
12. Which of the following is/are used as food preservatives :

(A) Sodium benzoate (B) Propanoic acid (C) Table salt (D*) All the above
13. Which of the following artificial sweetner on decomposition gives Phenyl pyruvic acid :
(A) Saccharide (B*) Aspartame (C) Alitame (D) Sucralose
14. Which of the following do not contain – bond

(A) Saccharine (B) Aspartame (C) Alitame (D*) Sucralose
PAGE NO.- 7
ChemINFO-2.9 ARTIFICIAL SWEETNERS
Daily Self-Study Dosage for mastering Chemistry d`f=ke
d`f=ke eèkqjd %
izkd`frd eèkqjd tSls&lqØksl xzg.k dh xbZ dSyksjh dks c<+krs gS] blfy, cgqr ls yksx d`f=ke eèkqjd dk iz;ksx djuk vfèkd ialn
djrs gSA
d`f =ke eèkqj d laj pukRed lw= k b{kq 'kdZjk dh rqyuk eèkqjd eku
1. lSdsjhu
(O-lYQkscfs UtekbM) 550
2. ,sLikVsZe
3. lqØkyksl
4. ,sfyVse 2000
[kk| inkFkZ ifjj{kd % ,sls jlk;u ftudk mi;ksx [kk|&inkFkksZ esa lw{ethokas }kjk mRiUu gksus okys vokNauh; ifjorZu dks jks dus
ds fy, fd;k tkrk gS rFkk bUgsa lM+us vFkok xyus ls cpk;k tkrk gS] mUgsa ifjj{kd jlk;u dgrs gSA
mnk. lkèkkj.k ued ¼Vscy lkYV½] 'kqxj osftVscy vkW;y rFkk lkfcZd vEy ,oa izksisuksbd vEy ds lksfM;e csUtks ,V yo.kA
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
PAGE NO.- 8
11. fuEu esa ls dkSulk Øe b{kq 'kdZjk dh rqyuk esa eèkqjd eku ds lanHkZ esa lgh Øe gS \
(A) lSdsjkbM > ,sLikVsZe > lqØkyksl > ,fyVse
(B) ,sLikVsZe > lSdsjhu > lqØkyksl > ,fyVse
(C*) ,fyVse > lqØkyksl > lSdsjhu > ,sLikVsZe
(D) ,fyVse > lSdsjhu > lqØkyksl > ,sLikVsZe
12. fuEu esa ls fdl ;kSfxd dk mi;ksx [kk| inkFkZ ifjj{kd dh rjg fd;k tkrk gS\
(A) lksfM;e csUtks,V (B) izksisuksbd vEy (C) lkèkkj.k yo.k (D*) mijksDr lHkh
13. fuEu esa ls dkSulk d`f=ke eèkqjd vi?kVu ij Qsfuy ikb:fod vEy nsrk gSA
(A) lSdsjkbM (B*) ,sLikVsZe (C) ,sfyVse (D) lqØkyksl
14. fuEu esa ls fdl ;kSfxd esa – caèk ugha ik;k tkrk gSA
(A) lSdsjhu (B) ,sLikVsZe (C) ,sfyVse (D*) lqØkyksl
PAGE NO.- 9

JP XII Organic Chemistry

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JP XII Organic Chemistry

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ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 36

This DPP is to be discussed in the week (23-11-2015 to 28-11-2015)

DPP No. # 36 (JEE-ADVANCED)

3. Which of the following carbohydrates are branched polymer of glucose?

5. The correct statement(s) about biopolymer X is(are) :

(A*) It is a non-reducing sugar. (B) It exhibits mutarotation.

This is the method to prepare the higher homolog of monosaccharide sugar.

7. What is the end product of following sequence of reaction

(A*) (B) (C) (D)

Sol. KCN / H H O  4 LiAlH

8. Match the following : fuEu dk feyku dhft,s&

(A) (p) Anomers ,uksej

(B) (q) Epimers ,ihej

(D) (s) Acetals ,lhVsy

9. The number of chiral centres present is the following compound is :

so in total 4 stereoisomers are reduced to meso products.

dqy 4 f=kfoe leko;oh ehlks mRiknksa esa vipf;r gksrs gSA

12. Which of the following is/are used as food preservatives :

14. Which of the following do not contain – bond

(O-lYQkscfs UtekbM) 550

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