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| | 1 1 I ~<=M014_WLNOZIYOH > yOLVeVdSasS; ; (6) Gathering and separation systems. In centralized gathering and separation systems it is necessary to transport gas-liquid mixtures for relatively long dis- tances. Correct sizing of the horizontal pipe used in these systems is important to prevent high pressure losses in the systems. (6) Sizing surface flow lines. The sizing of surface flow lines for oil production is extremely important in designing for maximum allowable production. The size of the surface flow line from the wellhead to the separa- tor combined with separator pressure establishes the flowing wellhead pressure. The flowing wellhead pres- sure controls the flowing bottomhole pressure which, in turn, controls the productive capacity of the well. (D Sizing of transmission lines. The prediction of pressure losses is important in the sizing of large transmission lines containing a liquid phase. (8) Sizing of gas lines. Pressure loss calculations must be made when gas lines where glycol or some other chemical is being injected to prevent freezing are designed, (9) Tubing design in deviated wells. The design of tubing strings for directionally-drilled wells is be- coming more and more important as additional off- shore wells are drilled. (10) Surface design for inclined flow. The calcula- tion of pressure losses for sizing of surface flow lines and transmission lines for inclined flow over hilly terrain, and for offshore-to-onshore facilities, is a necessity. (11) Heat exchanger design. In refineries and chemi- cal plants two-phase mixtures of petroleum fractions sometimes circulate through heat exchangers. The design of the heat exchangers involves two-phase pressure-drop correlations. (12) Condensate line design. Mixtures of partially- condensed vapors flowing through condensate lines in steam and refrigeration plants are in two-phase flow, ‘The design of these lines must take into account the additional pressure loss caused by the existence of the liquid phase. ‘There are other uses for multiphase flow caleula- tions. All of the mentioned applications point out the fact that an economic problem is involved in the ‘optimization of pipe sizes for vertical, horizontal, and inclined flow. 243. Objectives of this chapter With this chapter, we hope to attain the following objectives. The first is to introduce the basic concepts and discuss the variables affecting multiphase flow. It is a vital necessity for the reader to have a proper understanding of such liquid and gas properties as density, viscosity, surface tension, etc, For this reason, these basic factors will be reviewed and related to multiphase flow. ‘A knowledge of gas behavior is also needed. A com- plete review of gases and gas laws would require too much space; consequently, a brief resume of these basic laws will be given along with example problems that show how these laws apply to multiphase flow. ‘A usefull tool in multiphase flow calculations is dimensional analysis, often used to obtain dimension- less groups of numbers. A review of this subject, in- cluding example problems, is given. Multiphase Flow in Pipes 69 ‘The general energy equation is a basic requirement for background in multiphase flow and in calculations pertaining to this subject. This equation will be developed, and the terms will be individually dis- cussed. Other equations used in single and multiphase fiow will be described. ‘The second objective is to introduce the most signifi- cant correlations that are used for the calculation of pressure loss in multiphase vertical, horizontal, in- clined, and directional flow, and to define the ranges of multiphase flow where the correlations available today Predict pressure loss inaccurately. The final objective is to make the reader aware of those areas where additional research on multiphase flow is necessary. 22 MATHEMATICAL AND PHYSICAL BASES FOR PRESSURE LOSS CALCULATIONS IN MULTIPHASE. FLOW This section is a brief review off (1) units, con- versions and dimensional analysis; (2) liquid proper- ties; (8) gas properties; (4) variables such as solubility, viscosity, etc., that affect the pressure loss in multi- phase flow; and (5) thermodynamic equations perti nent to multiphase flow calculations. 221 Conversions and dimensional analysis 2.211 Introduction Common usage of both the English and metric sys- tems of units in publications on multiphase flow re- quires an understanding of units and the procedures for converting from one system to another. Most multiphase flow correlations utilize dimen- sional analysis to obtain dimensionless groups of variables for correlating parameters. Examples of such uuse are found in papers by Ros', and Hagedorn and Brown: In these papers the Buckingham z Theorem, was utilized to determine pertinent dimensionless groups of variables. Because many of the multiphase flow correlations are developed by using the The- orem, a procedure for its use is given in Section 2.216. 2212 Units The two systems of units in common use are the metric system (CGS) and the English system. Table 2.21 shows the applicable units in these two systems, TABLE 2.21 Metric (068) English Symbol Quantity absolute system _ absolute eystern L Length ‘centimeter ft m Mass {gram mass 1b mass (bm) F Force oyne poundal or Ib force (Ib) t Time second second T Temperature oy On E Energy (fg, joule, or ft'poundal, btu, or calorie ttelby v Velocity cemsec ftisee a Acceleration _emvsec: sect70 ~The Technology of Artificial Lift Methods— Volume | We use the standard symbol "p” for density. Schilson and Pollard? explain the relationship between density and specific weight. To clarify use of these quantities, we refer to Newton’s second law which states that force is directly proportiona? to the time rate of change of momentum. This is expressed mathematically as: =«/4 F=«[$en| (2.21) "The more common form for a constant mass is: F=Kma, 222) where K is a universal positive constant with a value dependent on the units employed in Eq. 2.22. For Fin Ib force, m in Jb mass, and a in ft per second, then K = +, where g, has the units of poundals/Ib & force. Poundals are equal to pounds mass times ac- celeration. Adopting these units, Eq. 2.22 becomes (2.23) In practice, we measure seale weight (W) which is the force of gravitational attraction that the earth exerts on a body. Thus, in Eq, 2.23, F=W and a= g; therefore, w=me ke Specific weight is expressed mathematically as Wooo W=p.V. The ratio is commonly assumed to equal unity, sulting in Ib force being numerically equal to 1b mass. This implies that specific weight is equal to density. ‘The average value of g is 32.2 ft/sec* and, according to Schilson and Pollard,’ varies less than one per cent at the various earth locations of interest to petroleum engineers. ) 2.213 Conversions An example of a unit conversion problem follows. ‘The real gas law is given as: pV = oR (2.24) In metric units: wressure, atmospheres V = volume, cubic centimeters yumber of gram moles absolute temperature, degrees Kelvin (°K) compressibility factor (dimensionless) R= universal gas constant Using these metric units, R has a value of 82.06 with ¢_(atm)(cu em) igm-moles)°K) ‘The problem is to convert to a value of R having com- ton field units using p= psia; V = cu ft; T=*R; and n= Ib-moles. This problem is solved by beginning with the known value of R= 82.06 and using its corresponding correct units. For example: R= 8206 |; units o igm-moles)K Co 1 atmosphere ~ 14.7 psia, (atm)(cu cm) 5 lev ft = (80.487 cu cm, LIbp 453.6 gin, 1K 1.8°R. ‘The units of R are then converted to the desired units in the following manner: 82,06 | atm | 14.7 psia|cucm| cu ft atm (80.48) cu em 453.6 gm-moles * gm-moles! IIb mole | °K | 18°R and: — 1079 | siavcu R= 10.72[ Gein). (2.26) ‘The real gas law is then written as: 10.72 nT, 2.214 Determining dimensions of variables Dimensional units are also used to find the dimen- sions of a particular variable, such a8 viscosity, and in verifying dimensionless numbers. It is important that correlations utilize dimensionless correlating groups, since non-dimensionless groups tend to lose their meaning. For example, we know that absolute vis- cosity is defined by: (2.29) where: For F in dynes, A in sq em, v in em/see, and x in em, has the units of poise. Suppose we wish to find the dimensions of viscosity using the mass-length-time system. F=mlt* ASL Lt x=LSubstituting these dimensions, we obtain, mLt-*/L¢ L/L. According to this, viscosity has the dimensions of mass per length time, The unit of gm-mass/em-sec in the metric system is called a poise. Kinematie viscosity is absolute viscosity divided by density. It has the dimensions of L?t-* in both the mass-length-time and force-length-time sys- tems, and is more difficult to use because g- is intro- duced into the problem. Be Lt 2215 Solving for conversion constants to make equi tions dimensionally correct ‘Many equations used in multiphase flow calculations are derived from one set of units and must be converted to another set of units before they can be applied. To do this, a constant that keeps the equation dimen- sionally correct must be determined. This presents a different problem than a straight conversion, as is illustrated by the following example. The general equation for pressure drop in single- phase liquid pipeline flow is: _efly’ r= pressure drop, Iby/sq ft density, Ib,/eu ft friction factor (dimensicnless) length, ft velocity, ft/sec diameter, ft & = conversion constant (32.174 Ib, ft/Iby- sec?) ‘The problem is to convert this equation to units so that: (2.29) where 4} (2.210) where Ap = pressure drop, Psi p= density, Ibp/ctt fiction factor (dimensionless), length, mites flow rate, cu ft/sec diameter, in. ‘There are two procedures to solve for the constant C to make this equation dimensionally correct. The first starts with an equation that is dimensionally correct, ‘converts it to the desired units, and solves algebraically for C. The second starts with an equation that is in the units desired, converts to the units that are dimension- ally correct, and the constant C will be in place, Both procedures are explained in detail by Brown.* It should be remembered that in following the first procedure any constant already in the equation re- mains in place and does not enter into the algebraic manipulations. Starting with the equation that is dimensionally correct, we have: Ape = c eliba/eu ft) £ Lift) viCfe/sec!™ Paq fi ~~ (ft) gc(baft/Ib; sec!) Multiphase Flow in Pipes 71 In the final equation, velocity is replaced by /A, where: v-$-% 211) Converting to the desired units: ap t_sa_ Pag ft 144 sq in ac Prleft|_mile_| 16g" ft ft 1 5280 Fela? d* 2)"in Td fe 12 in. 164.4 16 i ‘The constants =F and g7 remain in place Solving for C: (62800129012) [16_1 (14a) a? 64. Substituting this constant, the equation becomes: 2296g0 Pilb/cu ft) f Limiles) gP(cu ft/sec? & in? To solve for the constant in the second procedure, ‘we start with the desired units, convert to the units that are dimensionally correct, and obtain the con- stant in place, as follows: Ap Iby 144 sq in qin sqft Pr Limiles) 5280 ft 16 g? (12)"in.}*| 12 in. |_1 = mile din.) fe Id in, fe 64.4 p£L q (6280)(16)(12/(12) © om (144) (64.4) c ] = 220680. Ap (psi) p= 220680 F- (2.212) ‘The advantage of this second procedure is that the constant of conversion comes out in place, thereby eliminating the manipulation of the constants It is important to point out that when converting units, the unit equation can be treated algebraically the same way one treats the numbers. You can then check to make sure the units cancel. For example, in this problem we can write: CEP) (e) ~ Fas*)(G)(2) Pie) Le Ce) (ein) ] (Fe) er JA attr) ea ‘The unit equation is: anime) ~ (8) te) ene) in) Ci) in) (a)(ss) (2.214)72 The Technology of Artificial Lift Methods—Volume | When terms are cancelled: We thus have an automatic check to assure ourselves that the units conversion is correct. The numerical portion of the equation is: pfl.g? (5280)(16)(12)4112) 14 ap =O ren (2.215) . flag! (52800161129 _ ogg qq 0fla? or Ap axG4.8) 229680" Gs (2.212) 2.216 Determining dimensionless groups Dimensionless groups of numbers, determined by Buckingham’s 7 Theorem, are often used in correla- tions for multiphase flow. Publications by Ros', and Hagedorn and Brown’ contain specific examples which use the 7 Theorem. A rigorous proof of the theorem was made by Langhaar*. Other excellent discussions have been published (see Refs. 6, 7, 8, 9, 10, 11, 12 and 13). The procedure for using the 7 ‘Theorem’ and an example problem follows: 2.2161 Stepwise procedure for use of Buckingham's ‘Theorem (1) Determine the number of variables (n). These may be velocity, viscosity, density, diameter, length, and pressure loss. (2) Determine the number of dimensions (k) included in the n variables. These may be length, mass, time, etc. In fluid flow problems, we generally find k (3) Set up an n x k matrix consisting of the exponents of all variables: n for columns and dimension k for rows. Determine the rank, r, of this matrix, which in most cases will correspond to k dimension; that is, r=k for the majority of our problems. Therefore, for most cases step 3 may be eliminated. (4) Determine the number of m terms by subtracting (2) from (D); that is, n — r= number of 7 terms, which will correspond with n — k in most cases. (5) Retain as repeating variables the number of terms equivalent to the number of units involved, k. That is, if m, L, and t are involved, we have three repeating variables in each 7 term, plus one non- repeating variable in each term. The repeating variables must contain all dimensions as a group. This does not mean that each term must contain all dimensions. For example, if we have dimensions of m, L, and t and three repeating variables with dimensions of L, Lt, and mL-t~!, this will be satisfactory, since the three together contain m, L, and t (6) Write out the « terms. Keep the same repeating variables in each term and include one different non-repeating variable at the end of each 7 term, Each repeating variable must be raised to an un- Known exponential power, whereas the non. repeating variable is raised to the power of I. ‘Thus: m= AS m= Ag AM A Ay (2.216) Am AG A 217) (® Set up dimensional equations for each term; that is, substitute the dimensions of A,, A,, As, Av and As into (6) (8) Equate the exponents of like dimensions in each = term and solve for the value of the exponents. (9) Write out the final x terms. All of these are di- mensionless groups of numbers. 2.2162 Example problems making use of the Theorem EXAMPLE NO 1 Flow of a slightly compressible liquid through a pipe. () List the variables involved: = siscosity of liquid = mL“'t* AL = length of pipe = L Ap = pressure loss Since we are normally concerned with the pres- sure loss in terms of psi/ft, we can combine SL. and AP and have $P = mL-*t-+, thereby reducing the problem to 5 variables (n= 5). (2) The number of dimensions involved in the 5 vari- ables is 3: m, L, and t. (3) Set up an n x k matrix as follows: =a (oo (py we ($2)" zis) or 1 0b) (Le) (mbes) (mb) mL) 2.219) Collecting exponents of like terms, we have: (2.220) The exponents of m, L and t constitute three equa- tions and their sums are zero: Le micriditen) Liarsbrraerde-ten g-br-de-ae) m) gtd+e (2221) L) a+ bi— 3c (2.222) t) ~b,—d,— 2er (2223) From these three equations we set up the matrix as follows: Recalling that a determinant has equal columns and rows, we find that the following 3rd order determinant carved out of the matrix is not equal to zero: o 04 1 2 ~3/=0+0+(-1)-0-0-0=-140 0-1 0‘Therefore, this matrix has a rank of 8, or r= 3. If all third order determinants had been zero and any second order determinant not zero, then the rank would be 2, As noted, this value corresponds tok=3. (4) The number of = terms will be n— r= n— 5-3=2 (5) Since we have m, L, and t involved, we will retain three repeating variables. Let us select v, p, and #4, which in themselves contain m, L, and t. (6) Write out the = terms, as follows: my = (vw) (p)™ (a) (dt ; m= com (oom we (32) (2.224) (2.225) (7) Setting up dimensional equations for each = term, we have: For m,1= (Lt) (aL) (mL) (2.226) a For 72, (mL) (mL) mL“t (2.227) (8) Equating exponents of like dimensions in each a term, we have: For my: m) by toy (2.228) L) a,— 8b, +1=0 (2.229) 0 -a—q=0 (2.230) Solving, we find: For my: m) br +e+1=0 (2.231) L) a:~ 3b,—c—2=0 (2.232) t) ~a—c-2=0 (2.233) Solving, we find: a, =-3 = 1 (9) Writing out the final terms, we have: dvp We recognize this as the Reynolds number. ee 4B (yy-3 (p)-2 yt = SE Bp wa Ge (2.285) ‘This second term (7;) has not been found useful in pipe flow. Rather, it is better to combine 7 and 77, as follows: (rd (w= (a) @ v 2) _ 4 (dp/dl) vat) vip ‘This is now in the form of the commonly used friction factors, where the Moody factor has a multiplying coefficient of 2 and the Fanning fac- tor is divided by 2. If pressure is expressed as madv' pip (2.234) (2.236) Multiphase Flow in Pipes 73 Ib/sq ft rather than IbjJ/ft-sect, g. is added to render the friction factor dimensionless ‘These two groups represent two out of a possible 10 for the pipe flow problem. If repeating variables are changed, it is possible to arrive at eight more dimensionless groups; however, these are not independent terms, so have little meaning. EXAMPLE PROBLEM 2. Ros? gave the following variables encountered in multiphase vertical flow: (See Table 2.22) By applying the 7 Theorem to these thirteen vari- ables, Ros arrived at 10 dimensionless groups as follows: * 8. Vaal Vat, aa a # WF Group 5, which is 4, Pra jis calculated below. By inspection we see that g, p,, and o were kept as repeating variables, therefore we will write: (@) (pL? (oF wy, (2.237) Lt-#)* (mL.-*) (mt-*)° mL" t* (2.238) Equating exponents of like terms, we have: Dimensions ‘ Diameter L . Wall roughness t ° Inectination ® me Liquid density mL m Gas density mL he Liquid viscosity mite be Gas viscostty mite Vou ‘Superficial liquid velocity te Vee Supertcial gas velocity Le ° Surface tension liquid met a Wall contact angle a 8 Gravity acceleration tes dp/dx Proseure gradient muttOf special interest in vertical multiphase flow prob- iems is that part of the pressure gradient which is contributed by the liquid. This is due to the liquid 74 — The Technology of Artificial Lift Methods— Volume | Therefore: 2.221 Liquid density =)! (I (OF ty (2.239) ‘Table 2.29 is given to facilitate the selection of di- mensions: TABLE 229 DIMENSIONS OF ENTITIES Mass system Force system Length L u Time t t Mass m Fw Force mutt F Temperature a Q ‘Specific weight, mote Fle Mass density mes Fw Angle S 5 Prassure and stress FL Velocity ue Acceleration ure Angular velocity te ‘Angular acceleration w Energy, work FL Momentum Ft Power Fur Moment of a force FL Dynamic coetficient of viscosity FL Kinematic coefficient of viscosity ue Moment of inertia of an area u Moment of inertia of a mass Fur Surface tension FL Modulus of elasticity Flt Strain 5 = Poisson's ratio 5 Z 2.22 Liquid properties In every multiphase flow problem, we must deal with a liquid of some type. Generally this will be water, cil, condensate, or some combination thereof. The properties of liquids, particularly viscosity and den- sity, will greatly affect a multiphase flow pressure traverse. A brief review of liquid properties is offered in this section. Because all liquids are compared to pure water, the physical properties of pure water are given in Table 2: gravity at 20°C (68°F) Specific weight Hydrostatic pressure gradient Compressivilty 3% 10" psi Viscosity (68.4°F and 14,7 psia) ten Density (60°F and 147 psia) 10° APL ‘Surface tension (68°F and 147 psiay) —_72 dynes/em density and the hydrostatic head it exerts due to grav- ity. For example, a column of pure water exerts a pres- sure gradient of 0.433 psi/ft; whereas, a column of salt water with a specific gravity (y«) of 1.07 exerts a Pressure gradient of 0.464 psi/ft. For multiphase flow, this gradient is lightened be- cause the water is mixed with a gas having a much lower density. In addition, an oil of 42° API (y, = 0.815) has a lower density than pure water and exerts a pres- sure gradient of 0.352 psi/ft. Liquid density is the one property that normally has the greatest effect on pres- sure loss in vertical multiphase flow problems. The one exception is viscosity, especially where highly- viscous crudes are involved. 2.222 Compressibllity Changes in water volume caused by changing pres- sures and temperatures can be neglected in multiphase flow problems, because the water volume changes very little. For example, one bbl of water at 3,000 psi expands to 1.009 bbl at atmospheric pressure (14.7 psia). This is only a change of approximately 0.9%; therefore, it can be neglected in most practical calcu: lations, The change of oil volume is accounted for in the vol- ume factor for the oil. This factor also provides for volume changes which result from gas going into solu- tion in the oil. 2.223 Viscosity (a) Crude viscosity. Very viscous crudes present a serious lift problem in vertical multiphase flow. We now, for example, how the flow properties of thick molasses compare to those of gasoline. In general, if the liquid viscosity is greater than 10 cp (approxi- mately equivalent to a 30° API oil at 100°F), then the pressure loss per unit of pipe length for multiphase flow increases with increased viscosity of the liquid. ‘The viscosity ofa liquid varies depending upon tem- perature, pressure, density, gas in solution, and to some extent on other variables, including composi- tion. Temperature has a decided effect as shown in Figs, 22 and 2.3. Figs 24 and 2.6 show the effect of pressure on viscosity, while Fig. 2.6 shows the effect of solution gas on viscosity. Viscosity of oils can be correlated with density meas- ured in °API, and Fig. 2.7 shows such a correlation by Beal."* We will use the normal unit of centipoise for viscos- ity, recalling that pure water has a viscosity of one cp at 68.4°F and 14.7 psia. The units of viscosity are (GER): called poise, and it has dimensions of m/Lt The numerous charts, tables, ete. required to make viscosity conversions are found in the American So- ciety of Testing Materials Manual under ASTM Method D 446-53 (Standard Method for Conversion of Kine- matic Viscosity to Saybolt Universal Viscosity); ASTM.10,000 1000 loo VISCOSITY, cp Multiphase Flow in Pipes = 75 & viscosity, cP a s Ol 0 10 2 30 40 50 OIL GRAVITY, °API Fig. 22 Viscosity of gas—tree crude oils at atmospheric pressure (attor Bea, Method D 666-57 (Standard Method for Conversion of Kinematic Viscosity to Saybolt Furol Viscosity); and ASTM Special Technical Publication No. 43B (ASTM. Viscosity Tables for Kinematic Viscosity Conversions and Viscosity Index Calculations). See Appendix B. jot" and Connally" presented an equation as follows: He = A pas (2.241) where j, = live oil viscosity Hu = dead oil viscosity A and b = factors obtained from the Chew and Con- nally correlation (see Fig, 2.8). Chew and Connally gave viscosities at 100°F. The viscosity at any other temperature can be found from equations given by Beggs and Brill:"* Hot) = myo(t00°R) (Sr) 242) = tay 20°F) whore X= 1.346 in [fiat] (224) Beggs and Robinson'’ presented a more recent empirical correlation for visvosity: The correlation for dead oil viscosity was developed by plotting logio(T) vs. logio logy» (Hop + 1) on cartesian coordinates. The plots revealed a series of straight lines of constant slope. It was found that each line represented oils ={100°F 60 Fig. 2.3 Universal temperature-viscosity chart for crude oils (after Frick, courtesy MeGraw-Hil). 3.20 2.80 2.40 2.00 1.60 1.20 VISCOSITY, CENTIPOISE 0.80 SATURATION PRESSURE © 1000 2000 3000 4000 5000 6000 PRESSURE, PSIG Fig. 24 Viscosity of liquid hydrocarbons. 0.40LUTE VISCOSITY INCREASE FROM BUBBLE-POINT PRESSURE TO UNDERSATURATED PRESSURE (cp/1,000 pai) 76 RATE OF INCREASE OF ViScosiTy ABOVE BUBBLE POINT PRESSURE Fig. 2.5 Rate of increase of viscosity above bubble point pros- ‘Sure (after Beal, courtesy Aime) The Technology of Artificial Lift Methods—Volume | of a particular API gravity. The equation developed Hop = 10*— 1, (2.244) X=y T-", where T= °F 10% 38,0324 — 0.02023 °API ‘The correction of the dead oil viscosity for dissolved gas was developed by taking advantage of the fact that a linear relationship exists between logis so and log,(T) for a particular value of dissolved gas, R,. Live oil viscosity may be calculated from: =A poo", (2.241) where: A= 10.715 (R, + 100)-°5 B= 5.44 (R, + 150)" The following Table 2.25 presents a statistical comparison of the correlations of Beal, Chew, and Connally, and the findings of Beggs and Robinson: TABLE 225 STATISTICAL COMPARISON OF CORRELATIONS ‘Average error, Standard deviation jercent) of percent errors Dead ol! data used to develop Correlation of Beggs and Robinson Beal — 19.66 21.86 064 1353 literature (89 cases) Beal 378.46 1,368.08 Beggs & Robinson 1427 ‘520.00 Live oil data used to develop correlation ‘Chew & Connally 25.35 3570 Beggs & Robinson 183 27.25 a a 8 GAS-O1L, RATIO, ScF/ sol 10 10 10 VISCOSITY OF GAS-FREE OIL, ep (At Reservoir Temperoture ond Atmospheric Pressure) Fig. 28 Viscosity of gas—saturated crude oils at reservoir tom- perature and pressure (after Chow and Connally VISCOSITY OF GAS-SATURATED OIL, ¢p (At Reservoir Temperature ané Saturation Pressure ) 00 (b) Water Viscosity. Beal’ also showed how water viscosity varied with temperature and pressure. (Refer to Fig. 2.9) Pressure has very little effect but the viscosity ranges from 0.3 cp for temperatures above 200°F to 1.8 for low temperatures. In terms of temperature Beggs and Brill" gave an equation: Hey = exp (1.003 — 1.479 x 10-*T + 1,982 x 1077") (2.245) Fig. 2.10 shows the viscosity of various liquids 2.224 Surface tension Surface tension enters into many of the correlating groups for multiphase flow; therefore, a brief dis- cussion of this factor is included. Its relationship to the multiphase flow problem is presented in Sec. 2.243, ‘Surface tension measurements of liquids are usually made with the liquid surface in contact with air. ‘The interfacial tension of two immiscible liquids,‘9000 7000 5000 4000 3000 AT 100° F. 2000 Jo. GRAVITY APL. FROM | TO. 10.0 | 19.9 120.0 | 29.9 30.0 |39.9 lasove | 40.0 fOTAL Wooo 800 600 300 400 300 49 10 338 158 655 200 00 80 60 50 40 20 INIA_SAMPLES. -6, TROSTEL) 200 CALIFOR! (FROM E. 1 08 06 08 104 03 ABSOLUTE CRUDE OIL VISCOSITY AT 100° F, CENTIPOISES 02 01 10 15 Fig. 27. Correlation of viscosity with °AP! (after Bea. in contact with each other, is approximately equal to the difference between their individual surface tensions, as measured in contact with air. The surface tension for water is 72 dynes/em at 68°F and 14.7 psia, Most crudes have surface ten- sions at standard conditions which range from 25 to 35 dynesicm; however, at pressures of 3,000 psia or more, surface tensions for crudes are reduced to less than’2 dynes/em. The surface tension of hydrocarbon mixtures has been investigated by Knudsen and Katz" and Katz, et al," who give a method for cal- culating surface tension. NUMBER FORMULA: ABSOLUTE VISCOSITY AT 100°F (Cp)= — EXTRAPOLATED ico ueaezs| 30 35 CRUDE OIL GRAVITY, °A.P.1. AT 60°F. Multiphase Flow in Pipes 77 THE VISCOSITY OF GAS FREE CRUDE OIL @ ATMOSPHERIC PRESSURE "AVERAGE DEVIATION ARITHMETIC AVERAGE. ow SRavITY| viscosity | DEVIATION or NTIPOISES| FROM AVERAGE % [SAMPLES] FIELOS 39) 83 262 109 492 16.4 25.1 357 443 394 23.0 53 23 60.7 25.5 19.9 20.0 23.9 29,420, Cari-me7! ‘AVERAGE 40 45, 50 35 ‘AND ATMOSPHERIC PRESSURE 60s 2.23 Review of gases as related to multiphase flow 2.231 In every vertical multiphase flow condition a gas is present. This volume of free gas contributes more to the lightening of a pressure gradient than any other one factor. This is because gases have a low density compared to liquids. In vertical flow gas reduces pressure drop (at reasonably low G/L ratios); in hori- zontal flow, gas increases pressure drop. Since the properties of other gases are compared to Introduction78 — The Technology of Artificial Lift Methods— Volume | INTERCEPT & INTERCEPT OR SLOPE 0 200 400 600 600 1000 1200 1400 1600 SOLUTION GAS-OIL RATIO, SCF/ bi Fig. 28 A and b factors for use in Chew and Connally correlation (after Chew and Connally) those of air in this discussion, the physical properties of air are given in Table 2.26. In this book, one standard cubic foot (scf) of gas is defined as being one cu ft at 14.7 psia and 60°F. How- ever, it is possible to define one standard cu ft at other conditions of pressure and temperature. For example, the States of Texas and Oklahoma define one scf of gas as being one cu ft at 14.65 psia and 60°F; while Louisiana defines one sof of gas as one cu ft at 15.025 psia and 60° ‘The specific gravity of air is 1.00. The specific grav- ity of a gas, 7q, is defined as the ratio of the molecu- 4. ‘AasowTe viacoury, ceNTWONES £ ‘TewPeRaTuRe =F Fig. 29 Viscosity of water at oil feld temperatures and pressure (after Bes). courtesy AIME). Jar weight of the gas to the molecular weight of air. ‘One Ib-mole of a perfect gas at 14.7 psia and 60°F ‘occupies 379 cu ft of space, and one Tb-mole of any gas is one molecular weight of that gas, expressed in Ibs. For example, one Ib-mole of methane (CH) is 16.04 Ibs of methane since CH, has a molecular weight af 16.04, One Ib-mole of methane (CH,) and one Ib-mole of ethane (C,H,) will both occupy the same volume at 147 psia and 60°F, although there will be 16.04 Ibs of methane and 30.07 Ibs of ethane. 2232 Gas propert 22921 Density The density of a gas is the one property that greatly affects the pressure gradient in vertical multiphase flow. Its effect is to lower the pressure gradient. The density of air is 0.0764 Ib,/cu ft as compared to 62.4 Tog /cu ft for pure water. 2.2322 Viscosity The viscosities of gases will increase with pressure and temperature. The pressure effect is the same as in liquids, but the temperature effect is opposite to that in liquids. Numerous correlations showing these relationships are found in Katz, et al.” The two most widely used correlations for gas are those of Carr!” and Lee. Beggs and Brill'* recommend the one by Lee and gave the following equations: m=KX10-~exp(xpn » (2.246) Ko Sth T x= 35+ 9884 001M y=24-02X THR n=ep p= gion? M= molecular weight Reference can be made to Figs. 2.11, 2.12, 2.13 and 2.14 for various correlations for gas viscosity. 2.2323 Compressibility ‘Numerous correlations can be found for gas com- pressibility. Reference should be made to Fig. 2.15 for a simplified z factor chart based on specific gravity. Other commonly used correlations are shown in Figs. 2.16 and 2.17, Numerous other figures for determin- ing z can be found in Appendix A. 2.233. Gas problems related to multiphase flow 2.2331 Introduction Three types of problems related to gases are involved in most multiphase flow considerations. These are: (1) the calculation of gas density at a particular pres-4000. 3000. 2000. 1000. 400- 300- 200- in Centipoise 3 a i a 10 2° 30 40 @ 80 100 t - Temperature, in Degrees Fahrenheit 200 Multiphase Flow in Pipes = 79. 1. hone (CaM) 2. Propane (CMs) 3. Butone (CMa 4, Notwal Gorotioe 5. Gonofne 7. Karotone 8. initote ° 10, 40 Deg, API Crude 11, 35.6 Dag. API Grade 12, 326 Deg. API Crude 1, Salt Creek Crode 14, Fuel 3 (ox) 15, Fast $ Min) 16, SAE 10 Lube (100 VA) 17, SAE 20 Lube {100 Vi 18, Fuel 5 thon oF Feat 6 tain) 19, SAE 70 tebe (100 VU 20, Benker € Foal Mon ond MC. Renduum 21, Asphalt Data extracted in part from the 300 400 600 800 1000, Example: ‘The viscosity: of water at 125 F is 0.52 centipoise (Curve No. 6). Fig. 2.10 Viscosity of water and liquid petroleum products (courtesy Crane Co.) sure and temperature; (2) the determination of the ac- tual volume that a certain quantity (sef) of gas will ‘occupy under a set condition of pressure and tempera- ture; and (3) the velocity of gas in a pipe at a particu- lar condition of pressure and temperature. In order to understand these problems, a brief review of the real gas law is given, ‘The real gas law is pV= anRT, where z is the com- pressibility factor for gases and is defined as the ratio of the volume actually occupied by a gas at given con-