(PHYSICAL CHEMISTRY) /)\ Resonence D P Pp Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 DAILY PRACTICE PROBLEMS: Course : VIKAAS (JA & JA-Plus) Date : 01-06-2015 TEST INFORMATION DATE : 14.06.2015 CUMULATIVE TEST (CT) - 1 (ADVANCED) Syllabus : Introduction To Chemistry and Atomic Structure (upto Electronic Configuration) {All Cheminfos and Handouts till date) This DPP is to be discussed in the week (01-06-2015 to 06-06-2015) DPP_ No. # 10 (JEE-ADVANCED) Total Marks : 64 Max. Time : 43 min. Single choice Objective (1° negative marking) Q.1 to Q.2 (3 marks, 2 min.) (06, 04) Multiple choice objective (1" negative marking) Q.3 to 2.6 (4 marks, 2 min.) [16,08] Comprehension ('~1" negative marking) Q.7 to 0.8 (3 marks, 2 min.) (06, 04) Single Integer type Questions ('=1" negative marking) @.9toQ.14 (4 marks'3 min) ——_([24, 18] Double Integer type Questions (' negative marking) Q.15 (4 marks 3 min.) [04, 03] Match the column (no negative marking) Q.16 (8 marks 6 min.) {08, 06} Ques.No [1] 21314] 5]6|7] 8] 9] | | 12] 18[ 14] 16] 16] Toa Mark obtained 4. Inagaseous mixture, if an alkane (C,H>,,.) and an alkene (C,H,,) are taken in 2 : 1 mole ratio, the average ‘molecular weight of mixture is observed to be 20. Ifthe same alkane and alkene are taken in 1: 2moleralio, the average molecular weight of mixture is observed to be 24. Then, the value of x andy’ are respectively se Art Fee A, Ae TH CBT (Hye 2) TO WH IEA (CHa) BT 2: 1 te rT A fer GT a, ipso ar tir ope 20-Bfr Sten & | AAS IATA Ue a MATA wy: 2aterargare 4 Sea sae a, ct FeO aor ster siopare 24 Ber ete 8] axa yD TH sow Pes at 81,2 ©2,3 (3,2 Sol My, Bilder D+ 14) «99 28x + 14y = 56 (a) Myc= OBB = 94 14x + 28y = 70 @ = xstye2 2. _ Inlexperiment, electromagnetic radiations of a certain frequency are irradiated on a metal surface ejecting photoelectrons having a certain value of maximum kinetic energy. However, inl experiment,on doubling the frequency of incident electromagnetic radiations, the maximum kinetic energy of ejected photoelectrons becomes three times. What percentage of incident energy is converted into maximum kinetic energy of photoelectrons in Il experiment ? User, ar eg, are oR Cee Paar argh aH Reger PAP Te ae oer Rt wat PR i ard Plekatagin Seats aA 2, aR Wate A gat org aA gags fle Stary we Seu Breese Bofors aftr wal, A PN a ae 8 se A ofa at a Pera aera, waeresaRTA a) ifterer fs al aR ete ? Ans. (A)75% (©) 50% (©) 125% (0)25% [Corporate Otfice + OG Tower, AAG & 62, PIA, Neat Giy Wall, Jhalawar Road, Kota (Raj) W24005 J Resonsence| ducating for better tomorrowSol For lexperiment, “ For'l experiment, ® here, = 3KE,,,, ‘© (v2) _, (KEmae2 ) From (A) and (©) Cieee Gai al lemme :. % of incident energy converted into max KE in Il experiment _ KE max a = fe x 100= Fx 100 = 75%, sri 3 fare, W+KE.,..., “ igen & fe, hv, =W+KE,_., ® ei, ¥)= 2v, and KE,..,= 3 KE, 5 2hv,=W+3 KE... From (A) and (C) hy,=2KE,., oF °. % of incident energy converted into max KE in II experiment Ws ¥ orfterery KE A afkafefa airaferer ait a1 % KE max 2 3 = Tyg * 100= Gx 100 = 75%, Which of the following can exist on an oil drop. we de A dew fs 4S ais fer Bt we 8? (A321 C (B83 1079 (48x10 C — (96K 101°C 4s Which of the following statement is(are) true in the context of photoelectric effect (&°) The kinetic energy of ejected electronsis independent ofthe intensity of radiation (B) The threshold frequency is same for all metals. (C) The number of photoelectrons ejected depends on the frequency of the incident radiation (D*) The kinetic energy of the emitted electrons depends on the frequency of the incident radiation weprer Pega mara ade A fer A a ahve ga wale (AY) scatter geet at aero cant fafarer at sft oy fie set echt 2 | (©) wh angel & faq Sect aglaw ath (C) scufela Grelgcagin at een fafa a angie oe Prix aed &1 (04 seaitia eaagia a afte Gal oTaRte Ree Hy MGA Pele wed 2 | 5+ Asingle electron orbits around a stationary nucleus of charge +Ze where Zis atomic number and isthe magnitude of the electric charge. The hydrogen like species required 47.2 eV to excite the electron from the ‘second Bohr orbit to the third Bohr orbit. Which of the following is/are correct. (A*) Atomic number of species is 5 (B*) The kinetic energy in first excited state is 85 eV (C*) the potential energy in second state is -170 eV (D*) First excitation potential of species is 255 V yegoagita ett 4 gcagia +Ze sitar aa ya earth afte & aR she ara cee &, tel Z TRANNY ATA wen 'e' seragis } ater wr ars B | eregiord S wars Shelter A goats S Reta sree wen B gels atee Ger 4 softs wer & fore 47.2 ev a sree 2 ot fer A a wee (as) sitio ar aay wai 6 eT (8°) 3am Tass sere TH afr Gat 85 ev ett 2) (C*) fra safore rarer a feerfere Gat -170 ev erat 21 (D*) whatisr ar very waar fara 255 V2 Sol. 255 eoipeate OWICe © GS Tovar KAGE EPR Wot ly Wal, Talat Road, Kola Ry SEE Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETOSol. Sol. Which ofthe following electronic transitions will definitely produce at least one line in visible region (1.55-3.1 eV) of electromagnetic spectrum (A*) From n= 6 upto n= 2 in He* ion (8*) From n= 4 upto n= 4 in H-atom (C*) Fromn = 7 upto n = 4 in Li2* ion (0) From n = 9 upto n= 6 in He* ion Fr a a ere) ear, Pg gears wag S Gea Ga (1.55-3.1 eV) HoT a wa Os ta TT @) &@) (A) Het sia n= 6a n=20@ (6) Here 3 n (C) LP one A n= 7H n= 4am (Het aire in an 118 eae For He* ion, Eg = So, fora line terminating at n= 6 in He" ion, Ejyac= > 6= 1.51 eV (less than visible region). 'No line in 9 to 6 transition in He* ion lies in visible region. 2 196% 5 #- 1.51 0¥. Het ors @ fe Ey gafey, Het oma Hn =6 ax ware a ar yw ta} fe Epac= 2 ->6= 1.51 eV (G24 8 & 3H) Het aert 98 6 ore viarrer Hang Yet quite da soon agi eh 8 Comprehension # Niles Bohr a Danish physicist received his Ph.D from the University of Copenhagen in 1911. He then spent a yearwith J.J. Thomson and Emest Rutherford in England. In 1913, he returned to Copenhagen whrere he remained for the rest of his lif. In 1920 he was named Director of the Institute of theoritical Physics, After first World War, Bohr worked energetiocally for peaceful uses of atomic energy. He recieved the first Atoms for Peace award in 1957. Bohr was awarded the Nobel Prize in Physics in 1922, n= 1,2, 3... Thus an electron can move only in those orbits for which its angular momentum is intergal ‘multiple of h/2x that is why only certain fixed orbits are alowed () The radi ofthe stationary states are expressed as r= n'a, where a, = 52.9 pm. Thus the radius of the fist stationary state, called the Bohr radius, is 52.9 pm. Normally the electron in the hydrogen atom is found in this orbit that is n = 1).As n inoreases the value of r will increase. (©) The mostimportant property associated with the electron, isthe energy ofits stationary stat. itis given (a) The Angular momentum of an electron in a given stationery state can be expressed as m, vi 22) by the expression. €,=-2.18x10"| Tz |s n= 1.23. (a?) (@ Itisalso possible to calculate the velocities of electrons moving in these orbits by using v, = 2.18 x 10 Zz x 7 misec . Qualitatively the magnitude of velocity of electron increases with increase of positive charge on the nucleus and decreases with increase the value of n (@) Bohr's theory can also be applied to the ions containing only one electron, similar to that present in hydrogen atom. For example, He* Lit, Be and so on, ays Pre ohftenfag row atew % 1911 F aPraRe ott age a PROD of | gad ART SA CH ad GA elf ae ones Taras & eres Gems H eT | 19134 , ga eReeyE oll fran sredaer Bh gue 2) ra | er a yee Boe ae} HT wl a erg raw FS ser de aT P| SF 1957 8 aif Gee Bret fre | dre a1 1922 4 aft A ates GeeoR fea aT (ey 8 ead eH ergs aN aa aon mrs ng a Rr a, EL = 1, 2,3... arpa Oc TCS Tot SH BER ar CW Tay Ro Rae ly EOS Resonance} ducating for better tomorrowAns. ‘bere GH weal A ersare cree & FS MT woe a de ar GOH UT ele Baie: bet eBE FARRER wea aera (©) ear stave roar, = na, TRI ara PH oT 8 | se a, = $2.9 pm B | or: sere eer sraeH a fT frat dre Pacer ar Gre 8, 52.9 pm ee By ATAPI: TEATS eM A SARIS ge ET (n= 1) A Tar oT Bina saw rage (ae owes mea gd ert wer A wot 8) ae Ae aiew aa a one (22 e218 «10"(2) n=1,23 (01 wee eens oY TS Gaels $A A THT v,= 2.18 x 10x = miése0d sR A aT 1 echt & or crn a ae oe aa ASA TR AST BN NT AT ASA cB | ate PENT TH aegis TS SP, ot ereghors weary + aa ye oA Py ete 2] Sere | Fey He" Li, Be? eee | ‘Choose the correct statement (A) The order of velocity is v, E, > E,> E,(E,': where nis orbit number for a given atom) (©) The order of velocity of electron in H, He", Lit, Be* species in second Bohr orbits Be** E,>E,>E, (E4eF A A eT a ar ee & ) (©) hehor H, Het, Lit, BoP HB ate ar A gals Aer rw Boe < Li"? < Ho" Radius of n' orbit with atomic number "2" U,, —> Potential energy of electron in n'* orbit with atomic number K,,, —> Kinetic energy of electron in n' orbit with atomic number "2 Vag Velocity of electron in n"* orbit with atomic number "2" T,, > Time period of revolution of electron in n* orbit with atomic number" Calculate zin all in cases. @ Ujp:K,2-8:9 @ tyaityyetit2 @ vyaivye= 18:4 0 Tearth,=9:32 Report your answer as (2r-p-q-s) where p, q, rand s represents the value of "z" in parts (i), (ii) ,(iii) & (iv). ane Hise 4, wa gears wie & fey fs aba aya PA OTe B| yg AMY oH "2" aS the FT U,, > Fry ware "2" TS ot we eSaIA a Reh oat kK, Fry aie 2" a nt eT SRA A ate ot Vq2 > SRAM oH "2" aS nth en ESRI A] Tyg——> SRT wesw "2" are nl ean A gael wT arate | anh Raft A 2a meen at 0 Uy 2:Ky,=-8:9 G) yatta = 1:23 Gi) Vy Mg p= 1524 @M = Th: T,,= 9:32 Sry GER (Ze-pia-shd HH H fA TET p,q, eA ATH (i, Gi) Gi) eM Gv) HZ" A aH gad & A arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow13, Calculate number of possible spectral lines which may be emitted in bracket series in H atom, if electrons present in 9" excited level returns to ground level Horry Habe Soh A oonitier cera eta Tansll aA ere ae we, wis” safe oeEN H GoRem gah rer rae on GET ans. 6 Sol. For Bracket Series , electrons jump from high energy level to 4” energy level if high energy level is 10” then number of spectral line belong to bracket series is 6 (5 to 4), (6 to 4) , (7 to 4),(8 to 4) , (9 to 4) and (10 to 4) abe 3h § seats sea Gal ER a 4° Gal eR a ar Sear, ae Gea Gal we 10" Ba ade Awh 4 tags tea aH dem (84), 6 84), (79 4),(8 84), (984) 3 (104 4) 44, What minimum numberof atomssions should be present ina sample of Hike species, so that a maximum of 6 spectral ines can be produced of electronic transition from ith excited state upton = 2? We Haar oonfe & areal a ceampsii/areri a wen epraa een Garters ert any, anes dred sefort sree Bone 2aw, sagt ia f sro 6 etagH Vane art a ah ? ans. 2 Sol. To produce a maximum of 6 spectral lines, minimum two atoms/ions must be present in the sample, as show inthe diagram: area 6 ta Tart aa & fey, TTA a Tees wrest FH Sohera es unfey, Oren fe wanes Heater THz) 8 e! Ls ah 45. Ina mixture of sample of H-atoms and He ions, electrons in all the H-atoms and He* ions are present inn = 4" state. Then, find maximum number of different spectral lines obtained when all the electrons make transition from n = 4 upto ground state. Hecearysit cen Het oer && apt a ca far a ee Howat ae Het ore @ eagia n= 4h oan eaters & | a wit serach Sore omen we wrraTaea ate &, at ora fafter Saget tars at afar WON SIT FR | ans. 11 Sol. Total spectral ines obtained from H-atom = 6 Total spectral lines obtained from He*-ior ne tine is common between them so total numberof ines are 11 Sol. Hawa a ore Ga Bagh tant = 6 Het oa & ort a era tet FA & ww tar orate 2, at Ga Wa at 118 16. Match the following : [Atomic structure] frst ah gate are Column (I) ‘Column (I) (A) Binding energy of 5" excited state of Li?* sample (p) 10.2V (B) I" excitation potential of H-atom (q)3.4ev (C) 2” excitation potential of He* ion (9 13.6eV (D) LE. of H-atom (9) 48.4V eoipeate OWICe © GS Tovar KAGE EPR Wot ly Wal, Talat Road, Kola Ry SEE Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETOeters (1) ‘arerm (I) A) Lit srg a 88 aia ore A aE Sot @102v (©) Hee a7 1s OT PI @34ev (©) Het a1 2 sitar faa ()136ev (O) Herery At ores oat (9) 48.4V Ans. (Aq (8) p (C)s Or Sol. (A)Transitionn-+6 to n> aoForLi®* sampl (B)Transitionn-+1 to n-»2 For H-atom sample (C)Transitionn>1 to n-»3 ForHe* sample (O)Transitionn>1 to n> a ForH-atom sample Fa: (AAT NS to n> oLiPt & fay (sw nt to n 2 Honey fey (cy not to n>3 Het & fae (yee nt to n> co HAIN fay DPP No. #11 (JEE-MAIN) Total Marks : 73 Max. Time : 46 min. Single choice Objective ('-1" negative marking) Q.1 to @.20 (3 marks, 2 min.) (57, 38] aus. no 171213] 4]5]*]7]#| 2] | 1] 2] 13] | 18] 16] 17] 1] 19] 20] To Mark obtained) 1. Fluoxymesterone, C,,H..FO,, is an anabolic steroid. A solution is prepared by dissolving 10.0 mg of the steroid in 500 mL of water. How many moles of Fluoxymesterone are present in 1 mL.of solutions. qastfters e225 C,,H,,FO,, Uw a Prar Tags 8 500 mL wa H 10.0 mg wares Hae Ww Re Bl aaren Gren 8 | ge Port B 1.0 mL A goalie eee } Pert Ate ath (A) 1.16 = 10°" (B) 1.19 « 10°" (C*) 5.95 = 10% (D) 2.38 « 10°" 10107 |. Number of = 1oxto® Sol. Number of molesin s00mt = 19210 500 mL sta at se = 10210 336 10x10 . Number of motes int mt. = 20°10 «5.95 x 10 tL stat ah to = 19219? 5 95 x 108 396500 2. Volume at STP of 0.22 g of CO, is same as that of (A) 0.01 gof hydrogen (8) 0.0859 of NH, (©) 320mg of gaseous SO, (©>Altne above CO, # 0.229 % fae STP oy ares fen TR (4)0.01 geese > (@)0.085qNH,# (©) 320 mg *ita SO, (0) aa wht sol. 022960, 92 mot ol. 0.22g60,= “mo 001 gH, = 92" mot arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETOSol. Sol. Ans. Sol. 0.085 9 NH, = — [=~ mol 0.32 320mg SO, = ~g,-mol All are same. (anf airs @ |) Which of the following is incorrect about a sample of 11.2L CH, gas at STP (A) Number of molecules in the sample are 3.01 x 107° (B) Weight of 11.2L of CH,(g) at STP is 8g. (C*) Number of atoms in the sample are 15.05 x 1022 (O)None ofthese STP WR 11.2L.C,Hy ta & Ry we a fs a a ahaa we ee (A) 559 4 ga aall A ee 3.01 « 10% F ©) STP 1.2LCHAg) 1 Ka Bg? (Co FH 7 Ga TIS BH eT 15.05 « 102 #1 Ora a ag =e 11.2 Noy 224 05 Number of molecules = 0.5 Ny = 0.5 * 6.02 x 10% = 3.01 x 10% no, of atoms of CH, = 0.5 x Ny x 5 wi. of CH, = 0.5 « 16 = 8g ney, «U2 - cn oo orast # Se = 0.5 Ny = 0.5 « 6.02 « 102 = 3.01 « 102 CH, # wears BH ee = 0.5 x NyxS CH, 3 HR =0.5 x 16= 8g 05 Boron has two isotopes, B-10 and B-11. The average atomic mass of boron is found to be 10.80 u. Predict the percentage of abundance of these elements respectively. ares et erent B10 gem Bt cere & ates ar sere TATE] He 10.80 u ore aT 2, er ah HY after SoeTerT T: B (A) B-10 = 80% ; B11 = 20% (B) B-10 = 40% ; B-11 = 60% (C*) B-10 = 20% ; B-11 = 80% (D) B~10 = 70% ; B-11 = 30% B10 = 20% ; B11 = 80% 0.2 moles of an unknown compound weigh 5.6 g. The unknown compound is uw rane iw a 0.2 sitet wT AI 5.6 g &| orate ahr fee e (AYN, (8)CO,, (cco. (O)N,O. 5.69 0.2 moles = —>9 — = Molarmass = 28 g ‘molar mass Both N, and CO have molar mass 28 g but N, is element and CO is a compound 569 o2tta= Gree = dex ger = 28g N,4CO etei a Flow eri 28g een 8 af N, aa 8 a CO us afte & Which of the following statements about the electromagnetic radiation is incorrect (A) IR radiations have larger wavelength than X-rays (B) The frequency of visible region is less than that of UV region. (©) Gamma rayshave larger wave number than micro wave (01) The velocity of cosmic rays is more than that of IR radiations arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrowfra a ate wer tye grace fared + fey aa 8? G)IR Rafrent aH gengel X- Rent safe ere (©) Gea dra A sigh UV ASB oF eB (0) fare aH Tee & sift ce sie we 8 (0%) aie Prem ar eR PaO ar eta 8 | 7 Li* and a proton are accelerated by the same potential, their de-Broglie wavelengths have the ratio (assume mass of proton = mass of neutron) Liem ga sie a ear Pra aren car Rear ar 8] eA Bach areal wr org & Grn sites a gos = gh a aT) : (A) 1:2 (B) 1:4 (4 v2t () 1:3V3 Sol. Tamav Mop : agree 21:24 YM Qe 8. _fnumerical value of mass and velocity are equal fora particle, then its de-Broglie wavelength in terms of K.E. is ary @) ©) both tO ct O) KE © ake (©)both are correct (D) none is corre aft ya oo & fea ger cen aa an ener aM away @, aT KE. } ae 4 Gea 2 aheh ge eel aa eri ®) saKE (©) ert wae (O) aig wa TAS Sol. , hm (gfe) therefore 7, = 3 9. Thewave motion of an electron in a Bohs orbit of Hydrogen atom is as shown in diagram. The orbit number is: erties # argghory wemrey ww ate wer A ew Tage A cee aH abe A 81 wa wee FFT 2 (B)3 C4 (Oe 10. _Ifthede-Broglie wavelength of an electron revolving in 2%4 orbit of H-atom is x, then radius ofthat orbit is given by 2x x @) On Ox (0) Cannot be determined a Hee a 26a A RPI MA aa eH Kas A atch eae, at ge aN aA Pro et ay * @* Ox (©) ara at ah or oh arpa Oi CS Tost A BER, Wat Gy Wa tay Roe Ra RESONSNCE rene rmaresmmeonT Educating for better tomorrow carrraeTaGO ZOD ZIGT TOD 255 SESS] CH USSISERIEOOTPT COTOSol. 1, Sol. 12. Sol. 13. 2ar= mi Here (uel), n= 2. 2nr = 2x ‘The most probable radius (in pm) for finding the electron in He* is Her gaggia a fog sat arf Poa (pm ay Pres 8 (A)0.0 (B) 52.9 (C*) 26.5 (0) 105.8 52.9% n* ma eer pr 2 ForHe’,r, = 529% = 96.5 pm, Zz 52.9% 7 He'd fy, 1, = 26.5 pm What isthe ratio of minimum to maximum wavelength of radiation emitted by electron when itjumps from a higher state to ground state in Li ion a Li arene gehen Fey soa raver rer raven omen 8, at aR aren seers PART aH TT 4 aitterery anneal at sigur eer a 1 8 3 1 Wy ®5 5 ©, (1 14 (2) era] fl 34 GG rors] An electron jumps from n' level o the first level. The correct statement is emia J nin=1) (A) Number of spectral ines = “> ni (8) Number of spectral ines = “> (©) Ifn=4,, number of spectral lines = 6 (0) Both (A) and (B) vo gdagia nan & vert ee A ae wa oo 8 (0) Bagh Rent deon= WED (vag east a vier = MOD ©) 2% n=4, aah tool H eM =6 (0%) (A) aeH (B) ait arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow14. Sol. 45. Sol. 16. Sol. 47. Sol. Statement-t : It is possible to measure simultaneously both the position and momentum of a moving microscopic particle with absolute accuracy. Statement-2 : In case of moving microscopic particle, if uncertainty in position is reduced, then uncertainty in velocity is very high and vice versa. (A) Statement-t is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2is False _(D*) Statement-1 is False, Statement-2is True wert se aeneher & arr gw afer geet wor a fey Reka a eae, Sat wor gw eer AKT ea were-2: nfcreflel yeneell aor & fore ate Rafe 4 ofseaca A ah onl &, al an 4 ofan aga sift et cart & cen gerant fatter at aia 2 (A) eR Ger 8, w-2 ae a | TIF, TO a we eT B | (B) war—1 wea B, Bert—-2 Gere | wIA—-2, Hr—1 wr we erctanr ae zt) (©) 1 wea B, eZ sR (D*) wert RCT 8, eT? aes According to Heisenberg's uncertainty principle, itis impossible to measure simultaneously both the position ‘& momentum of a microscopic particle with absolute accuracy. According to Heisenberg's uncertainty principle, on increasing the wavelength of light used to locate a microscopic particle, uncertainty in measurement of position of particle (A*) increases (8) Decreases (C) Remains unchanged (D) Cannot be predicted agua! PRET REPT, WH Eee wor wr Prater wea S fore sa ore AH eae A oe aT we, ao ah Reefs A offen & ars H (A) afar Bre (Bh ahs (CsmRatia wea 8 (D) wer ae oH ETT Refer notes. The uncertainty in momentum of an electron is 1 x 10-° kg.m/s. The uncertainty in its position will be (h= 6.62 « 10° kg m*/s) fore gSagin idm a offen 1 x 10-5 kg Aa 8 | geal Reif a sefARaeT er (h= 6.62 « 10 kg mis): (A) 1.05 «10m (B) 1.05% 10%m_— (C+)5.27 «10m (0) $.25 x 10m ‘According to Heisenberg's uncertainty principle aa Ap x AX> Ge 6.62x10°4 1x10 axe 4. 22 7 662x104 x= eee 461075422 = 5.265 x 10m 27 «10m Given : The mass of electron is 9.11 x 10- kg, planck constant is 6.626 x 10 J s, the Uncertainity involved in the measurement of velocity within a distance of 0.1 A is fear ma Be aT OMT 9.11 x 10-51 kg 2, Siw Prati 6.626 « 10% Js8) 0.1 A ah d wa any attra Fr & (A) 5.79 x 108 mst (8) 5.79 x 10° ms (C)5.79x 108m s* (0) 5.79x 10'mst axmAv= hide - (0.1 «10-m) (9.11 x 10*"kg) (Av) _ 6.626 «10-4 kgm?s—1 = 43.14 or Av= 5.79 10° ms arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow18. Sol. The uncertainties in measurement of position and momentum (in SI units) of an electron are equal. Choose fe the correct statement : (Given y4- = 7.2x 10-8) (A) The uncertainty in measurement of speed = 8 « 101° mis, (B) The uncertainty in measurement of kinetic energy = h/8xm, (C) Increasing the wavelength of light used in the experiment will decrease the uncertainty in position and increase the uncertainty in momentum. (0*) None of these ford oo gcagin a fate cd eae ob ara 4 aftPaerd (SI gore Hy eae B | PTA a aha ger we (Ren gat 8 ge = 72% 10") (A) 37 a afar = 8 x 1019 mis. (@) vit ot ara A ofa = Wea. (©) ser Ha a ae ware aA eT Be aTY oe Rea A IPR Heh 8 ae am A iPaRRaaTT AeA a (09 57 Bats ax= Ap h 2 So, (Ap? = 4 ‘or (may)? = hax 1 [irs 72x10" mVax 9x07 = 8x10! mis So, A 1 Now, AKE= >-mx2vx (Av) We will require base value of v for calculation, which is not given. So, the uncertainty in measurement of kinetic energy cannot be determined. AX= Ap h ora: (Ap)P= = vera (mav)?= hid 1 fh | 72x10 SAVE ae 9x10" 8x 10'2 mis 1 srl AKE Zn zyx (av) aor & fy wiv & are ar BH sree @, Gi A set fee ee) are, afer Hot | are A afAPete A aor wei GT Tat | arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow19. __Ifuncertainty in momentum is twice the uncertainty in position of an electron, then uncertainty in velocity of h electronis: [A= 5] aft we daria & fey, dae 8 aftercare, Refs A ofan at ey 8 aa ga taxa & fey an A h aftftac an 8: [A= 5] i h 1 — @ an vi Op © an ©) vi h Sol. Ap. x2 ge 2ax= Ap (given) (Rea 72 wer fh 2. > 4x fe ap= aves ie oo ave 20, Which ofthe following statements is correct, (A) Two charged particles having the same mass and accelerated through same potential difference from rest will have same value of de-Broglie wavelength, (&*) Heisenberg's uncertainty principle is more significant for microscopic paticles than for macroscopic articles. © When electron jump lower energy level two higher energy level it emit energy. (©) According to de-Broglie wavelength associate with electron and proton are same. (If both have same velocity) fre 4 8 ahrar/atae port we 2/e (a) 2 orate au ore cor we 8, FT Ree sere Baars Plea are ake eA gr FHA Sa anal ara wart ee | (>) eed ar aififteran a Rear, a8 wo a gar A oftges weil o RA sare nec ee BI (0) a gagia fr Gal eR D ved Gol eR A ara 2 ad Gal weultiar weet 8 (CO) Sar & agae gaagie a sels Saag cael ears abel 8 (aA gor Br aerax a) Sol. 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