Advanced Paper 1 CTY 1719 AB Lot PT 4

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
CPT - 1 CODE:110662 PAPER - 1

SET - A
Time Allotted: 3 Hours Maximum Marks: 210
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
BATCHES – 1719
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part-A (01 – 10) contains 10 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks and – 2 mark for wrong answer.
(ii) Part-C (01 – 10) contains 10 Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and – 1 mark for
wrong answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________

PT-1-(1719) (Paper-1) Set-A – PCM-2
Useful Data Chemistry:

Gas Constant R = 8.314 J K−1 mol−1
= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79. V = 23, Cr = 24, Co = 27, Xe = 54
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Ar=40, Cr=52, Br=80, Cu=63.5,
Fe=56, Mn=55,
Pb=207,
Au=197, Ag=108, F=19, H=1, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
FIITJEE Ltd., Bhopal Centre, 48-A, Gurukripa Plaza, Zone – 2, M.P. Nagar, Ph. 0755-42553355, 4253455
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(JEE ADV PAPER – 1 SET - A) 3
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
(Multi Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. A particle of mass m and charge q is projected in a region where an electric field is existing and given
by E = E0 ˆi , with a velocity v 0 ˆj from the origin at time t = 0, then choose the correct statements
(assuming m2 v 02 = 2qE0mx0 ).
(a) radius of curvature of the particle when its x-coordinate becomes x0 is 2x0.
(b) radius of curvature of the particle when its x-coordinate becomes x0 is 4 2 x0.
(c) speed of the particle when its x-coordinate becomes x0 is 2v 0 .
(d) speed of the particle when its x-coordinate becomes x0 is 2v 0 .
2. Two cells of unequal emfs E1 and E2 and internal resistances r1 and r2 are joined as shown in figure.
Vp and VQ are the potential at P and Q respectively. E1,r1
(a) The potential difference across both the cells will be equal.
(b) One of the cell, will supply energy to the other cell
P Q
(c) The potential difference across one of the cells will be greater than its emf.
E r + E2r1
(d) VP − v Q = 1 2
r1 + r2 E2 ,r2
3. Three wires are carrying same constant current i in different directions. Four loops enclosing the wires
in different manners are shown. The direction of d is shown in the figure.
(a) Along closed Loop-1  B.d = −0i
Loop-1
(b) Along closed Loop-2  B.d = 0i i i
(c) Along closed Loop-3  B.d =0 Loop-2
(d) The net work done by the magnetic force to

move a unit charge along the loop is zero. Loop-3
4. In the circuit shown in the figure C1 = C2 = C and capacitor C1 is having initial charge Q. The switch is
closed at t = 0 . Which of the following options are correct.
 Q  −2t /RC
(a) The current at time t through the circuit will be  e R
 RC 
(b) The charge on capacitor C1 at time t will be

Q
2
(
1 + e−2t /RC ) C1
+
−
C2
(c) The charge on the capacitor C2 at time t will be

Q
2
(
1 − e−2t /RC )
Q2
(d) Total heat loss in the process of charge transfer will be
8C
5. Velocity and acceleration vector of a charged particle moving in a magnetic field at some instant are
v = 3iˆ + 4ˆj and a = 2iˆ + xjˆ . Select the correct alternative (s)
(a) x = -1.5
(b) x = 3
(c) magnetic field is along z-direction
(d) kinetic energy of the particle is constant
6. In the given circuit ammeters are ideal then, which of the following 6R A3
statements are true?
(a) Reading of A 3 will be half as shown by A 2
2R A2 R
(b) Reading of A1 will be thrice as shown by A 2
(c) Reading of A 3 will be lowest
E R A1
(d) Reading of A1 will be thrice as shown by A 3
7. A metallic conductor of irregular cross-section is as shown

in the figure. A constant potential difference is applied (1) P Q (1)
across the ends (1) and (2). Then:
(a) the current at the cross-section P equals the current at the cross-section Q
(b) the electric field intensity of P is less than that at Q
(c) the rate of heat generated per unit time at Q is greater than that at P
(d) the number of electrons crossing per unit area of cross-section at P is less then that at Q.
8. Figure shows three concentric thin spherical shells A, B and C of radii R,

2R, and 3R. Shells A and C are given charges q and 2q and shell B is
earthed. Then
4
(a) charge on inner surface of shell C is q
3
4
(b) charge on outer surface of shell B is − q A
3
2
(c) charge on outer surface of shell C is q B
3
4 C
(d) charge on outer surface of shell C is q
3
9. Four identical plates (equally spaced) and a battery are connected as shown. If the capacitance
between two consecutive plates are C then choose the correct statement. 1 2 3 4
(a) Energy supplied by the battery is CV 2 .
1
(b) Energy linked in the space between plates 1 and 2 is CV 2 .
6
(c) Potential difference between plates 2 and 4 is V.
(d) The surface charge density on plate 3 on it’s right side is
more than that of on left side.
V(ideal)
10. A positive charge is passing through an electromagnetic field in which E & B are directed towards y-axis
& z-axis respectively. If a charge particle passes through the region undeviated, then its velocity is/are
represented by (here a, b & c are constant)
Eˆ ˆ Eˆ Eˆ Eˆ
(a) v= i + aj (b) v= i + bkˆ (c) v= i + ciˆ (d) v = i
B B B B
PART – C
(Integer Type)
This section contains 10 questions. The answer to each question is a single-digit integer, ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled.
1. Consider a hollow spherical shell of radius R carrying a charge Q distributed uniformly over its surface.
If the spherical shell rotates with an angular velocity  about an axis passing through its centre, then
QR2
the magnetic moment of hollow sphere is given by M = . Find the value of K.
k
2. Consider a non conducting sphere of radius a carrying uniformly distributed charge q surrounded by a
spherical shell of radius 2a. The region between a  r  2a is filled with charge density  = C / r, where r
is the distance from the centre. If the magnitude of electric field in the region a  r  2a is constant, then
the magnitude of charge in the volume a  r  2a can be written as nq. Find the value of n?
2a a
3. Consider a metallic ring of radius 1 m, mass 1 kg and carrying a current of 1A in a gravity free space in
the x-y plane with its centre O at the origin as shown in the figure. If a uniform magnetic field (3iˆ + 4ˆj) T
is applied, then the instantaneous acceleration of the point P (which is on the y-axis at the moment) will
be C   m / s2 . Find the value of C. y
P
O
x
4. Solid sphere A of mass M and radius R has charge Q at centre.

X
A
Q
q
Insulated rod
of height R
Very Rough Insulated Surface
A point charge q is at the same level with centre. The force of friction acting on sphere, immediately
Qq
after the sphere is released is then find the value of k.
2K0 X2
5. A miliammeter of range 10mA and resistance 9  is joined in a 9 ,10mA

circuit as shown. The meter gives full scale deflection for current I
when A and B are used as its terminals, i.e. current enters at A and
leaves at B (C is left isolated). The value of current I in ampere 0.1 0.9
A B C
6. A uniform, 500 g metal bar 100 cm long carries a current I in a uniform, horizontal, 0.5 T magnetic field as
shown in figure. The bar is hinged at b but rests unattached at a. What is the largest current, in ampere,
that can flow from a to b without breaking the electrical contact at a ? Assume that the wire be inclined to
the horizontal at an angle of 60º as shown. (Take g = 10 ms -2).
7. A small current carrying loop having current I0 is placed in the plane of paper as shown. Another
semicircular loop having current I0 is placed concentrically in the same plane as that of small loop, the
radius of semicircular loop is R(R >> a). Find the force applied by the smaller ring on bigger ring in
40
newton. (Given R = 1 m, I = I0 = A, a = 0.1 m)
0
8. The figure shows a network of five resistances and two batteries
Ratio of current (in ampere) through the 30V battery and 15V battery is X. Find X
9. A current I flows in a circuit shaped like on isosceles trapezium ABCD. A

Given AB = 2CD where CD=  . Magnetic field at point P located in the D
plane of the trapezium ABCD at a distance a from the mid-point of CD is
 oI P
found to be , where value of n is a
na  2 + na2 C
B
10. Figure shows one quarter of a simple circular loop of wire that carries Y
a current of 10A. Its radius is a = 5cm. A uniform magnetic field, B = →
4 B
T, is directed in the +X−direction, Then the torque on the entire
 I
−4
loop is found to be 5 n
n 10 N-m where value of n is X
60o
S
SEEC
CTTIIO
ONN--2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART– A
1. In which of the following product is formed according to Hofmann’s rule ?
(a) (b) − +
Me CO− K +
⎯⎯⎯⎯
3
⎯
→ ⎯⎯⎯⎯
EtO K
→
Br Br
(c) −
(d) ⎯⎯⎯⎯
−
EtO K
→
+
+ OH / 
N ⎯⎯⎯ ⎯→
F
2. Which reagent(s) can be used in the conversion of 2-butanone to propanoic acid.

(a) NaOH, NaI/H+ (b) Fehling solution (c) NaOH, I2/H+ (d) Tollen’s reagent
3.
CH − C  C−Na+
⎯⎯⎯⎯⎯⎯
→(A) ⎯⎯⎯ →(B) ⎯⎯⎯⎯ ⎯
→(C)
3 3 H2 CH I
Pd −BaSO4
(a) (b)
CH2 C C CH3 CH2 C C CH3
+ -
(A) is Na O (B) is CH3O
(c) OCH3 (d) H CH3
CH3 C C
H3C CH
CH3O CH H
C C
H (C) is CH3
(C) is H
4. Which of the following will give Cannizzaro reaction ?
(a) (b)
CHO
CHO
(c) Cl (d) HCHO
Cl CHO
Cl
5. Pyrimidine bases present in DNA are

(a) Cytosine (b) guanine (c) thymine (d) adenine
6. Acetaldehyde can be obtained from which of the following reactions ?
Cu /  O
(a) CH3 − CH2 − OH ⎯⎯⎯ → (b)
Pd −BaSO4
H3C C Cl ⎯⎯⎯⎯H2 , 
⎯
→

(c) (CH3COO)2 Ca + (HCOO)2 Ca ⎯⎯ → (d) H3C CH C Ph ⎯⎯⎯⎯
O3
Zn−H2 O
→
CH3
7. Which of the following compounds will give iodoform test ?
(a) O (b) O
H3C C H H3C C CH3
(c) O (d) O
H3C C Cl H3C C NH2
8.
O CH2 CH *
CH2

⎯⎯ →?
(a) OH (b) OH
*
CH2 CH CH2
H2C CH *
CH2
(c) OH (d) OH
CH2 CH *
CH2
H2C CH CH2
*
9. The phenomenon of mutarotation is shown by
(a) Glucose (b) Fructose (c) Cellulose (d) Starch
10. Which of the following compounds give positive Tollen’s test ?
(a) O (b) O
H C OH OH
(c) H3C CH OC2H5 (d) O

OH H3C C H
PART – C
(Integer Type)
1. How many of the following are reducing sugars ?
Glyceraldehyde, Glucose, Fructose, Sucrose, Starch, Maltose
2. The presence/absence of hydroxyl group on which carbon atom of sugar differentiates RNA and DNA ?
3.
OCH3
⎯⎯⎯⎯
conc. HI
→ (a) mole of HI is consumed
OCH3
⎯⎯⎯⎯
conc. HI
→ (b) mole of HI is consumed
a+b=?
4. How many of the following are addition polymers ?
Polythene, PVC, natural rubber, Bakelite, nylon-6,6, Teflon.
5. How many of the given compounds would give aldol condensation ?

O
C CH3 CHO CHO

O CHO
H3C C CH3 , , , ,
CH3
CHO
H3C CHO
, , CHO
CH3 O
6.
O
HOOC COOH

HOOC COOH ⎯⎯→
HOOC
HOOC COOH
‘n’ moles of CO2 are evolved in this reaction.
Value of ‘n’ is _____
7.
O
O
⎯⎯⎯⎯⎯⎯ → HO
' x mole ' CH MgBr
3
H+ / H O
OH
2
Find out the value of ‘x’.
8. Of the following reactions, how many reactions are used for the preparation of amines
(a) R − C  N ⎯⎯⎯
LiAlH4
→ (b) O
R − C − NH2 ⎯⎯⎯
LiAlH4
→
(c) O (d) O
−
Br2 + OH
R − C − NH2 ⎯⎯⎯⎯ → R − C − CH3 ⎯⎯⎯
NaOH
→
(e) O (f) O
−
CH3 ⎯⎯⎯⎯→
N2H4 ,OH
- + R− X
N K ⎯⎯⎯⎯
H+ / H2 O
→ R
O
(g) O (h) R − CH2 − NO2 ⎯⎯⎯
H2 ,Ni
→
P O /
R − C − NH2 ⎯⎯⎯⎯
2 5
→
9. How many moles of HI reacts with glycerol to give 2-iodopropane ?
10. Lassaigne’s test is used for the detection of

N, O, S, Cl, P, As, K, Ca
PT-1-(1719) (Paper-1) Set-A – PCM-10
S
SEEC
CTTIIO
ONN--3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1
1. Let f, g : R → R be defined by f(x) = 3x − 1+ | 2x + 1| and g(x) = ((3x + 5)− | 2x + 5 |) , then
5
(a) fog = gof
(b) (fog)-1 = gog
(c) y = min (fog(x), (fog(x))2, (fog(x))3, … (fog(x))101) is not differentiable at exactly three distinct values
of x.
(d) fogofogofog...fog (5) = 3
100 times
1 + x2 − 1
2. If f(x) = sin−1 , then which of the following is(are) correct ?
2 1 + x2
−1  
(a) f '( −1) = (b) Range of f(x) is 0, 
4  2
f(x) 1
(c) f '(x) is an odd function (d) lim =
x →0 x 2
3. Identify which of the following function(s) is (are) bijective ?

 
(a) f : ( −,0] →  0,  ,f(x) = sin−1(e x )
 2
(b) f : [−1,1] → {−1,01}, f(x) = sgn(sin−1 | x | − cos−1 | x |)
(c) f : [−3,0] → [cos3,1],f(x) = cos x
(d) f : R − I → R,f(x) = ln{x}
Note : sgn(y) and {y} denote signum function of y and fractional part function of y respectively

 n(1 + x) − x + px 2
 ; 0 x 1
 x3
4. Let g(x) = q ; x=0 then
  x
 tan  3 
 ; −1  x  0
 x
1 1
(a) g(x) is continuous at x = 0, if p = ,q=
2 3
1
(b) g(x) is discontinuous at x = 0, if q 
3
1
(c) g(x) has irremovable discontinuity at x = 0 if p 
2
1 1
(d) g(x) has removable discontinuity at x = 0 if p = ,q 
2 3
  1 + ax 
 n 
5. Let f(x) =   1 − bx  , x  0 . If f '(0) = 1, then
 x
1, x=0
1 −1 3
(a) a + b = 1 (b) a = b = (c) a = ,b = (d) a – b = 1
2 2 2
6. Let f(x) be a non constant twice derivable function defined on R such that f(2 + x) = f(2 - x) and
 1
f '   = 0 = f '(1) . Then which of the following is/are correct ?
 2
(a) f(-4) = f(8)
(b) Minimum number of roots of the equation f ''(x) = 0 in (0, 4) are 4.

4
(c)  f(2 + x)sin x dx = 0

−
4
2 4
 f(t)5 dt =  f(4 − t)5 dt x

cos t cos t
(d)
0 2
x2
dt
7. If f(x) =  (log t)
x
2
, x  0 , then f(x) is
(A) Monotonically increasing in (2, ) (B) monotonically increasing in (1, 2)

(C) Monotonically decreasing in (2, ) (D) monotonically decreasing in (0, 1)
8. If the tangent at the point (p, q) to the curve x3 + y3 = k meets the curve again at the point (a, b), then
q−b p2 q−b p2 + ap + a2
(A) =− 2 (B) =− 2
p−a q p−a q + bq + b2
a b a b
(C) + = −1 (D) + =1
p q p q
sin x − cos x
9. If I =  ( sin x + cos x ) sin x cos x + sin2 x cos2 x
dx = cosec–1(g(x)) + c  x  R, then
(A) g(x) = 1 + sin2x (B) g(x) = 1 – sin2x

(C) g(x)  0 (D) – 1  g(x)  1
1
dx
10. If I = then
0 4 − x 2 − x3
 
(A) I (B) I
6 6
 
(C) I (D) I
4 2 4
PART – C
(Integer Type)
y
If f(y) = lim  
(
tx 2 + x (t + 1)2t + 2 − 1  )
1.
t →0 
 dx
0 e− x .t 
Then find the number of solution(s) of the equation 2f(− | x |) − 1 = 0
(x + 2)3 , −3  x  −1

x
2. Let f(x) =  2
 −1  x  2
and g(x) =  f(t)dt, − 3  x  2 . Find the number of extremum points of
x ,
3
−3
g’(x).
PT-1-(1719) (Paper-1) Set-A – PCM-12
3. A polynomial y = f(x) of degree 4 increases in the interval (−,1)  (2,3) and decreases in the interval
(1, 2)  (3, ) and satisfy f(0) = 1 and f '(0) = 6 . Find the value of f(2).
x
If f(x) =  (t − bt 3 + (b + 1)t 2 − bt + b) dt increases  x R then find the number of integers in the range
4
4.
−2
of b.
4
  sin x   cos x 
5. The value of   sin x − 
0
2  −  2  dx is _______ [where [x] represents greatest integer

function]
6. If f(x) + f(– x) = 2  x  R, where f(x) is continuous, differentiable and invertible function, then the value
1+ x
f
−1 (
of t ) dt is equal to _________
1− x
  1 
n−1
7. lim 1 − ln  1 +   is equal to _______
n→ 
  n  
8. The number of points in the interval [0, ] at which the function f(x) = max{|sinx|, |cosx|} is non–
differentiable are ______
 x + 59 
9. The function ‘f’ satisfies the functional equation 3f (x) + 2f   = 10x + 30 for all real x  1. The
 x −1 
value of f (7) is ______
k k
10. Let f be a positive function. Also let I1 =  xf ( x (1 − x ) ) dx, I2 =  f ( x (1 − x ) ) dx , when
1−k 1−k
I2
2k − 1 > 0. Then is equal to ________
I1
ANSWERS
(ADV) PAPER – 1 (SET – A)
SR. NO PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. BC P120305 ACD C124606 AC M120311
2. ABCD P120204 C C121403 AC M121502
3. ABD P120303 ABC C121807 AC M120310
4. ABC P120217 ABD C121405 ABCD M120405
5. ACD P120305 AC C121705 AC M120411
6. ACD P120212 ABCD C121401 ABCD M120813
7. ABCD P120201,202 AB C121402 AD M120604
8. ABC P120111 B C121806 ABC M120601
9. ACD P120118 AB C122901 AC M120712
10. BD P120308 ABCD C121403 BC M122810
1. 3 P120309 4 C122903 4 M1220813
2 3 P120109 2 C121705 2 M120608
3. 8 P120307 3 C122607 3 M120608
4. 7 P120104 4 C121903 5 M120616
5. 1 P120212 4 C121405 8 M120807
6. 5 P120308 5 C122811 0 M120813
7. 8 P120309 2 C121504 0 M110610
8. 3 P120109 5 C124506 2 M113626
9. 4 P120307 5 C121804 4 M120323
10. 3 P120104 3 C122001 2 M120813
PT-1-(1719) (Paper-1) Set-A – PCM-14
HINTS & SOLUTIONS :
PHYSICS :
MORE THEN ONE CORRECT
 qE 
1. v 2 = v 02 + 2  0  x0
 m 
v = 2v 0
qE0 v0
an =
m v + v 02
2
x
3
v2 [m2 v 02 + 2qE0mx0 ] 2
R= = = 4 2 x0
an qE0 v 0m2
 (b) and (c)
2. (A) p.d. across each cell = VP − VQ

(B) If I is clockwise then E2 is supplying and for reverse case reverse is the answer.
(C) P.D. = E − ir (when battery supplies energy)
= E + ir (when battery consumes energy).
E − E2
By KVL i = 1 (Anticlockwise)
r1 + r2
E1r + E2r
 VP − VQ = E1 − i r1 =
r1 + r2
3. Work done by magnetic force on a charge = 0 in any part of its motion.

 ‘S’ is matching for all parts (i), (ii), (iii), (iv)
For loop 1 Iin = −i + i + i = −i   B.d = 0 (−i)
For loop 2 Iin = i − i + i = i   B.d = 0 (i)
For loop 3 Iin = −i − i + i = −i  B.d = 0 (−i)
(Note : That current will be taken as positive which produces lines of magnetic field in the same sense
in which d is taken)
 dq  2q Q Q
4. R  + =  q = (1 − e−2t /RC )
 
dt C C 2
dq Q −2t /RC
i= = (e )
dt RC
The charge on the first capacitor
Q
q' = Q − q = (1 + e−2t /RC )
2
 (a), (b) and (c)
5. v⊥ a  v.a = 0  6 + 4x = 0  x = –1.5
Further magnetic field is perpendicular to the plane of velocity.
So, magnetic field is along z-direction
Also work done by a magnetic force is zero i.e., kinetic energy of a particle remains constant if only
magnetic force is acting on it.
 (a),(c) and (d)
6. From Kirchhoff’s law

−6RI1 − IR + E = 0 .....(1)
−2R(I − I1 ) − (I − I1 )R − IR + E = 0
6R A3
I1
2R A2 R
I
E R A1
I
On solving I1 =
3
2I
I − I1 =
3
 Reading of A1 = I
2I
 Reading of A 2 =
3
1
Reading of A 3 =
3
 (a),(c) and (d)
8. Whole charge q given to shell A will appear on its outer surface. If a Gaussian surface is drawn within
material or shell B, net charge enclosed by it should be zero. Therefore, charge on its inner surface will
be –q. Let q be the charge on its outer surface then charge on inner surface of C will be –q and its
outer surface will be 2q + q as total charge on outer shell must be 2q.
Since shell B is earthed, its potential should be zero.
VB = 0 2q + q1
1  q q q q 2q + q 
0= − + − + q –q
1
40  2R 2R 2R 3R 3R 
4 q –q
Solving we get q = − q
3
So choice (a) and (b) is correct. A
Charge on outer surface of outer shell is 2q + q
4q 2q B
= 2q − = C
3 3
So choice (c) is correct.

Choice (d) is wrong obvious from above explanation.
 (a), (b) and (c)
10. In both case (b) and (d), Fnet = 0 so it passes the region undeviated.
 (b,d)
NUMERICALS :
 Q 
 /2 0  2 
(2R sin d)(R sin )2
 4R   Q
1. B=2 = 0
0 4R3 6R
or
PT-1-(1719) (Paper-1) Set-A – PCM-16
q QR2
M= (L)  M=
2m 3
and
   2M 0 Q
B= 0  3  B=
 4  r 6R
r
C
2. q' =  (4r 2 )dr = 2C(r 2 − a2 )
a
r
q + 2C(r 2 − a2 ) q
E= = constant  C =
40r 2
2a2
 q 
 q' = 2  2 
[(2a2 ) − a2 ] = 3q
 2a 
3.  = MB = 5 N − m

= = 10 rad / s2
I
4 
a =   R  = 8  m / s2
5 
4.
Mg
A
Qq 1
.
40 X2
f
N
Qq 1
. − f = Ma
40 x 2
2  2
f R =  MR2   = MR.(a)
 5  5
Qq
Solving f =
140 x 2
5. 10  10−3  9.9 = 0.1 i − 10  10−3 9 10mA
or I = 1A
0.1 0.9
A B C
6. gravity = B
l l
 mg   cos(60º) = BIl sin(90º) . This gives
2 2
mgcos ( 60º )
I=
lB sin90º
0 M
7. B= where M = I a2
4  R3
 Ia2  Ia2
 B= 0 3 = 0 3
4 R 4R
0Ia2
 dF = BI0dl = BI0 (Rd) = I0Rd
4R3
 dFx = dFsin
 II a2 sin  d
 dFx = 0 0
4R2
 II a 2
 Fx = 0 0 2
2R
and Fx = 0
 II a2
 Fnet = Fx = 0 0 2 = 8 newton
2R
8.
9. Hints/ Solution :
→ → →
B = B AB + BCD
10. Hints/ Solution :
 = IAB sin 
CHEMISTRY : (Paper - 1)
2. Iodoform reaction
O O O
+
NaOH+I2
CH3 − C − CH2 − CH3 ⎯⎯⎯⎯ → CH3 − CH2 − C − O−Na+ ⎯⎯→
H
CH3 − CH2 − C − OH
3.
CH − C  C− Na+
C C CH3 C C CH3
⎯⎯⎯⎯⎯⎯
3
SN
→ ⎯⎯⎯
S
N2
→
2 CH3I
- + (A)
O O Na OCH3 (B)
H2 ,P d −BaSO4
H H
CH3
CH3O (C)
4. CH3 − C − Cl gives substitution reaction with OH-
8. Claisen rearrangement.
10. Formic acid and Hemi-acetals give positive Tollen’s test.
Numerical :
3.
PT-1-(1719) (Paper-1) Set-A – PCM-18
OCH3 OH
⎯⎯⎯⎯
conc. HI
→ + CH3I
(1 mol)
OCH3 I
⎯⎯⎯⎯
conc. HI
(2 mol)
→ + CH3I
7.
O O OH CH3
CH3
O (1) CH−MgBr
OH (1) CH MgBr CH3
⎯⎯⎯⎯⎯ 3
(2) H+ / H O
→ ⎯⎯⎯⎯⎯ 3
(2) H+ / H O
→ OH
2 2
9.
−I2 −I2
CH2 − CH− CH2 ⎯⎯⎯ ⎯
3mol HI
→CH2 − CH− CH2 ⎯⎯ ⎯→CH2 −CH = CH2 ⎯1molHI
⎯⎯→CH2 −CH−CH3 ⎯⎯ ⎯→CH2 = CH−CH3 ⎯1mol
⎯⎯ ⎯
HI
→CH3 −CH−CH3
OH OH OH I I I I I I I
MATHS :
HINTS AND SOLUTIONS :
1.
 f(x) and g(x) are inverse of each other.
 y = min{fog(x), f(fog(x))2 (fog(x))3 ,...(fog(x))2011 }
 y = min{x,x2 ,x3 ,...x2011}
 Not differentiable at x = 0, 1 .
2. Put x = tan 
   −
 − sin−1  sin  ; 0
  2 2
f(x) = sin−1 sin = 
2 sin−1  sin   ; 0

  2  2
 −1
 ;−  x  0
f(x) =  2(1 + x )
2
1
 ;0 x
 2(1 + x )
2
1 −1
 f '(1) = ; f '( −1) =  (A) is correct
4 4
 
Range of f(x) = 0,  . Hence (B) is incorrect
 4
Also f '(x) is an odd function.  (C) is correct
f(x) 1  1 −1
lim   As, f(0+ ) = andf(0− ) =  = (D) is incorrect
x →0 x 2 2 2
3. (A) x  (−,0]
 
 ex  (0,1]  sin−1(ex )   0, 
 2
 f(x)sin−1(ex ) is one-one and onto both.
(B) f(x) = sgn(sin−1 | x | − cos−1 | x |)
f(− x) = f(x)  f(x) is many one
(c) f(x) = cos x
From the graph it is clear that f(x) is one-one and onto both.
(D) f(x) = ln{x}
Range of f is ( −,0)
 f is many one into
 1 h3
h2  p −  + + ....
+  2 3 1
4. g(0 ) = lim 3
; g(0− ) = ,g(0) = q
h→ 0 h 3
Now check the options.
5. Since, f(x) is continuous at x = 0, so
 1 + ax   1 + ax 
n n 1 + −1
 1 − bx   1 − bx 
Lim = 1  Lim =1
x →0 x x →0 x
1 + ax − 1 + bx
 Lim = 1 a + b = 1
x →0 (1 − bx)x
Now, f '(0) = 1
 1 + ah 
n
 1 − bh 
−1
 f '(0) = Lim h =1
h→ 0 h
By solving we get
b2 − a2 2
(a + b − 1)h + .h ...
 Lim 2 =1
h→ 0 h2
b2 − a2
 a + b − 1 = 0 and =1
2
 a + b = 1 and b2 − a2 = 2
b−a = 2
−1 3
a = ,b = Ans
2 2
6. We have f(2 – x) = f(2 + x)
Replacing x by 2 – x, we get
f '(x) = f(4 − x) …(1)
Put x = -4 in (1), we get
f(-4) = f(8)
on differentiating (1) w.r.t. x, we get
f’(x) = -f’(4 – x) …(2)
1
Put x = ,1,2 in (2) , we get
2
 1  7
f '   = 0 = f '(1) = f '(2) = f '   = f '(3)
 2  2
Now, consider a function y = f’(x)
1   7  7 
As f’(x) satisfy Rolle’s theorem in  ,1 ,[1,2], 2,  ,  ,3  respectively.
 
2  2 2 
So, by Rolle’s theorem, the equation of f’’(x) = 0 has minimum 4 roots in (0, 4)
/4
Now, consider I1 = 
− / 4
f(2 + x)sin x dx …(3)
PT-1-(1719) (Paper-1) Set-A – PCM-20
Applying king property, we get

/4 /4
I1 = 
− / 4
f(2 − x)sin( − x)dx = 
− / 4
f(2 + x)sin(x)dx
 I1 = −I1
Hence I1 = 0
2
Again, Consider I2 =  f(t)5cos t dt

0
Put 4 − t = y  dt = −dy
2
So, I2 =  f(4 − y)5cos (4 − y) ( −dy)

4
4 4
=  f(4 − y)5cos y dy =  f(4 − t)5cos t dt

2 2
2x 1 x−2
7. f (x) = 2 2
− 2
=
(log x ) (log x) 2(log x)2
f(x) > 0 for x > 2
and f(x) < 0 for x < 2
Hence (A), (D) are correct answers.
dy 3x 2 p2
8. = − 2 = − 2 (Slope of tangent)
dx 3y q
Since this is the line joining (p, q) and (a, b)
q−b p2
 =− 2 … (1)
p−a q
As these two points line on the curve.
p3 + q3 = a3 + b3 = k.
Hence p3 − a3 + q3 − b3 = 0  (p − a) (p2 + ap + a2) + (q − b) (q2 + bq + b2) = 0
q−b p2 + ap + a2
 =− 2 … (2)
p−a q + bq + b2
p2 p2 + ap + a2
From (1) and (2), =
q2 q2 + bq + b2
 p2 (bq + b2) = q2 (ap + a2)  pq (pb − aq) = − (p2b2 − q2a2)  pq = − (pb + aq)
b a
 + = −1 … (3)
q p
sin x − cos x
9. We have I =  ( sin x + cos x ) sin x cos x + sin2 x cos2 x
dx = cosec–1(g(x)) + c
− cos2x
I=  (1+ sin2x ) sin x cos x + sin2 x cos2 x
dx
Let 1 + sin2x = y
−dy
I= 
y y2 − 1
 I = cosec–1(y) + c
 g(x) = y = 1 + sin2x.
10. 4 − x 2 − x3  0 x  0, 1
And x  x
2 3
x  (0, 1)
 4 − x  4 − x − x  4 − x − x2
2 2 3 2
 4 − x 2  4 − x 2 − x3  4 − 2x 2
1 1 1
  
4 − x2 4 − x 2 − x3 4 − 2x 2
1 1 1
dx dx dx
  
0 4− x 2
0 4− x x 2 3
0 4 − 2x 2
 1
dx 
  
6 0 4 − x 2 − x3 4 2
INTEGER TYPE :
x
f(x) = lim  
(
tx 2 + x (t + 1)2t + 2 − 1  )
1.
t →0 
 dx
0 e− x .t 
x
 (t + 1)2t + 2 − 1
f(x) =  ex  lim x 2 + x  dx
0  t →0 t
(t + 1)2t + 2 − 1
Now lim
t →0 t
e(2t + 2) n(t +1) − 1
= lim =2
t →0 t
 f(x) =  e x (x 2 + 2x)dx = e x x 2
0
Now 2f(− | x |) = 1 ...(1)
x2 1
 |x|
=
e 2
x2
Let f(x) = ;x0
ex
(2x − x 2 )
 f '(x) =
ex
x(2 − x)
=
ex
 Number of solution of the equation (1) is 4
(x + 2)3 , −3  x  −1
2. Clearly, g'(x) = f(x)  2
 x 3 , −1  x  2
 g'(x) is a continuous function
PT-1-(1719) (Paper-1) Set-A – PCM-22
sign scheme of g''(x)

 g'(x) has a local maximum at x = -1 and local minimum at x = 0
Hence, g'(x) has two extremum points.
3. As y = f(x) is polynomial hence it is differentiable.

 f '(x) = k(x − 1)(x − 2)(x − 3)
f '(0) = −6k
6 = −6k  k = −1
Hence f '(x) = −(x − 1)(x − 2)(x − 3)
= −(x3 − 6x2 + 11x − 6)

 x 4 6x3 11x 2 
f(x) = −  − + − 6x  + C
4 3 2 
f(0) = 1 hence C = 1
 x 4 6x3 11x 2 
f(x) = 1 −  − + − 6x 
4 3 2 
Hence, f(2) = 1 – 4 + 16 – 22 + 12 = 3
4. f '(x) = x 4 − bx3 + (b + 1)x2 − bx + b

= (x4 − bx3 + bx2 ) + (x2 − bx + b)
= (x2 + 1)(x2 − bx + b)
Now f '(x)  0x R
 x2 − bx + b  0x R
   0  b2 − 4b  0
 b(b − 4)  0  0  b  4 .
sin x 1  sin x 
Since 0   xR  =0
 2 
5.
2 2
4 
 cos x 
similarly 
 2 
= 0 and 
0

sin x dx = 4 sin x dx = 8 .
0
6. f() = 
f(– ) = 2 – 
f–1() = 
f–1(2 – ) = – 
f–1(x) + f–1(2 – x) = 0  value of integration is zero.
  1 
n
  1+  
  1
n −1 
 n 
7. lim 1 − log  1 +   = lim 1 − log
n→   n   n → 1 
  1+ 
 n 

  1
n
 1 
= lim 1 − log  1 +  + log  1 +  
n→ 
  n  n  
  1  1 
n
= lim 1 + log  1 +  − lim log  1 +   = 1 + 0 – loge = 1 –1 = 0 .
n→ 
  n  n→  n  
 x + 59 
9. 3f (x) + 2f   = 10x + 30
 x −1 
For x = 7, 3f (7) + 2f (11) = 100
For x = 11, 3f (11) + 2f (7) = 140
Solving, we get f (7) = 4.
k
10. I1 =  xf ( x (1 − x ) ) dx
1−k
k  b b 
=  (1 − k + k − x ) f (1 − k + k − x ) (1 − (1 − k + k − x ) ) dx using  ( )
f x dx =  f (a + b − x ) dx 
1−k  a a 
k
I2
=  (1 − x ) f ( x (1 − x ) ) dx = I2 − I1  2I1 = I2 
I1
= 2.
1−k

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Advanced Paper 1 CTY 1719 AB Lot PT 4

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

CPT - 1 CODE:110662 PAPER - 1

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

(d) The net work done by the magnetic force to

(b) The charge on capacitor C1 at time t will be

(c) The charge on the capacitor C2 at time t will be

7. A metallic conductor of irregular cross-section is as shown

8. Figure shows three concentric thin spherical shells A, B and C of radii R,

4. Solid sphere A of mass M and radius R has charge Q at centre.

5. A miliammeter of range 10mA and resistance 9  is joined in a 9 ,10mA

8. The figure shows a network of five resistances and two batteries

9. A current I flows in a circuit shaped like on isosceles trapezium ABCD. A

1. In which of the following product is formed according to Hofmann’s rule ?

2. Which reagent(s) can be used in the conversion of 2-butanone to propanoic acid.

4. Which of the following will give Cannizzaro reaction ?

(c) Cl (d) HCHO

5. Pyrimidine bases present in DNA are

6. Acetaldehyde can be obtained from which of the following reactions ?

7. Which of the following compounds will give iodoform test ?

H3C C H H3C C CH3

H3C C Cl H3C C NH2

10. Which of the following compounds give positive Tollen’s test ?

(c) H3C CH OC2H5 (d) O

5. How many of the given compounds would give aldol condensation ?

C CH3 CHO CHO

Find out the value of ‘x’.

9. How many moles of HI reacts with glycerol to give 2-iodopropane ?

10. Lassaigne’s test is used for the detection of

3. Identify which of the following function(s) is (are) bijective ?

 f(t)5 dt =  f(4 − t)5 dt x

(A) Monotonically increasing in (2, ) (B) monotonically increasing in (1, 2)

(A) g(x) = 1 + sin2x (B) g(x) = 1 – sin2x

HINTS & SOLUTIONS :

2. (A) p.d. across each cell = VP − VQ

3. Work done by magnetic force on a charge = 0 in any part of its motion.

For loop 1 Iin = −i + i + i = −i   B.d = 0 (−i)

For loop 2 Iin = i − i + i = i   B.d = 0 (i)

For loop 3 Iin = −i − i + i = −i  B.d = 0 (−i)

6. From Kirchhoff’s law

So choice (c) is correct.

5. 10  10−3  9.9 = 0.1 i − 10  10−3 9 10mA

4. CH3 − C − Cl gives substitution reaction with OH-

10. Formic acid and Hemi-acetals give positive Tollen’s test.

HINTS AND SOLUTIONS :

Applying king property, we get

Again, Consider I2 =  f(t)5cos t dt

So, I2 =  f(4 − y)5cos (4 − y) ( −dy)

=  f(4 − y)5cos y dy =  f(4 − t)5cos t dt

Now 2f(− | x |) = 1 ...(1)

sign scheme of g''(x)

Hence, g'(x) has two extremum points.

3. As y = f(x) is polynomial hence it is differentiable.

= −(x3 − 6x2 + 11x − 6)

4. f '(x) = x 4 − bx3 + (b + 1)x2 − bx + b

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