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AN EQUATION TO RELATE K-FACTORS TO PRESSURE AND TEMPERATURE MARK L. McWILLIAMS, Chariton, W. Va ‘Molticomponeat fash and distlation compotations often require much time, particulary if many compo- nents are present. The design cr simulation of a multi- component distillation tower may require digital com- puter. 7 ‘These calculations must allow for variation in the Aistibution coeficients (K factors) with temperature and pressur.* However, while correlations for these varia. ons are available in chart and comograph fora, we ‘have not been able to find the corresponding equations in the conimon public lerature. ‘The following equation corelates K with temperature and pressure. It sin a form chosen to produce results accurate enough for chemical engineering courses in ‘hae rye cnc ct etc 2 eae enemas en eenue snametatvnenninncsenentenere RE colleges and univeits, bet it uml gies ets sit- able for indus aplicaon as well “Te general form ofthe repression equations: 09 = on( de) + on($) + ant + ons 4 eq Tan + an 0021+ on (5) +45 (4) 4+ oy PP + 9 CPP 07 (P) Where Ps presre, pea; and Tis temperature, *R. ‘A sepise maple nar reesson technique imple- mented in 4 ew sacl programing sem! vas ‘sed to determine th coetients in this equation. Daia ‘were entered into this digital computer program. A value of 0.001—represening the proportion of the sum of Values of the Coefficients Used % on os 4s tn itethane 6 o a 2 2050 Enylene ° ° ° ° 790608 Ebane e ° ° ° 790698 Propyene ° ° ° ° rare Propyene, 463024608 ° 0.00408 ° 1532456 Propane © o oO 7380658 Propane, 402.7000 ° 0 ° ees Iscbutane 11668460 ° ° 0 ° 7726865 Iscbutane, 11624520 ° ° .0014 ° 7osr2 Ieebutane, 11260740 ° ° ° ° razte Butane 12808870 ° ° ° 0 7.94966 Butane, ° ° s9sse7s— ~.02024 ° = 108.11067 Butane," ~ 12274060 0 ° ° ° 744621 Isepentane 148168300 0 ° ° . 750071 leopentane, ° soreness 8.15346 ° ° 5870558 leopentane, —_— 14357710 20 ° ° ° 738972 Pertane 1624851 0 ° ° ° ° 733128 mPertane, . — 16440840 a ° ° 0 ‘aszea0 mPentane, 14786830 0 ° ° ° 8.95724 exane ~a7Te9010 0 ° ° ° ‘oosres ‘texan, ° ° ° ootTe §— —0.0masses = 1582783 mHerane, = 17404820 o ° ° ° 67201 ‘miepiane 20138030 ° ° ° ° ‘ese mtiopiane, __~ 19848150 oo ° ° ° 29008 ‘Octane 0 “7646 81681 ° ° ° 2asast Octane, ssi07s = 60672266 ° ° 0 9.02579 ronare 2551060 o ° ° e ‘sees ecane ° — 7605705 ° ° ° va0054 erence sn tees eens reneesseetteminsetnt — Values of the Costicients Used For Standerd Compounde-Table It : Mean, Mabe of Farge ty tatty ty Ee Et Data Van 1 2 0 3aer ~osma 00 ass

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