‘Vie 7, 61-68 2018) OL: 10 soTaWits20185761-68 Antioxidant activity, phenolic compounds and colour of red wines treated with new fining agents (6D, Dussan/N, Live Lem VV. Corea! an RA. Pano "Vine sd Oey Deine Unive Apia Scie and Vein Meine lan a eh Br a, Agata Chenin Dope Summary Nowadays the larifeatio and stbiiztion ofr ines generally done with conventional ning en, Tike bentonite and ecivated coal Which pone «majo? ‘hallenge to environmental securiy and wate ‘gemen, Thi stimulated the use of many new tech igus in order to lscoveralteraatve tly {hat don't have negative inuence ot colo, phevole perimental materia from Nort-East Ro ‘ras tned with mesoporous materials, Denote and {vated con. Discriminant analysis cased "Cab- “rnct Sauvignon’ wines according tothe diferent fs. {ng agents bse on ttl ptypheneli compounds and eit Alternative Ot phenol content of ed wins in cotrst to etat- ‘cal and bentonite teatents tha an conduct fo Snettpng characteristic. Mesoporous materia ae Preferable and could be Porphenai conpoanes, ovo nti ein da cle, reduction Color and tiny are among the most ipo struts sited wih high quate wines, Sich se Sor characteris are append by consumes and con tribute sivey tothe pressing decison. Furthermore, red wines contain a number of polpherelic compu tic determine other reer feneralspet sch a eringen,bitemest and mouhfer. These compounss ape the amount properes of wine, isuesing "her poten heh fet (De a 2015) yb ing fe rd seavenging activity aswell as a rtetive Activity against arises, coronary hea dlease (ins eal 200) orig cancer el wowth Zak est of iro Cit, Se ta. 2008). The content of phenolic composition in wine lepends on he variety sb imate, as well a. the oe oop! practices applied for winemaking, erietion, abliion iments, peg ens ease conditions (KO ago af 2012) ‘Wine stblizaten and caicatan 6 normally ob- ‘aloe afer winemaking duo chemical and physical pe oem ht determin the precio of ensable com unde and the seimenation ofthe hzy piles, The ral clean roces in ation beng slow. my ‘ot be enogh for proper erty and aio he wine ‘This neptve sperm wines imps at heya of poor ‘uted coal recorded ves smong 379 % and $7.2 ‘Nanamterls used ath hips dose dono seem 49 ‘esuiable for red wine ing de tthe ow reduction oF ‘vine bi pI vals varied in oction of fing get appli in ‘he ierval 3253.38. Ping get i change i ean the aol dearer of the wines rent so). egisering a vale around 13.2% (o) Fig etmek creased rable ait and in a eer exe the ve ale aii Tn. 2) The highest irences fn thi ast Parameter were observed in wins teed with MCMEAI fnomateral independely ofthe doves nee. Bentonite ‘tu activated coal showed the same Behavior, Regards lng teats, SBA eaorateril st 6 ad 10g L Showed the highest redaci ‘Total antionidant activity and total polyphenolic compounds: The tl polyhe- ‘aicompounds (TPC) of red wines determined ty the 2ymate method varied roo 134.1 86mg estechin {0531653 106 mgcatechin Lin Fig 2 canbe cleaiy ‘sen that in genera the feet lag agent appli n- s | : v3 < ‘ é Fig. 2 Tol pple ompounds (TF), expres ila feat eet (il a alain ey (TAA ecresed ws milinlr Wl emp) tf wr er exer wi nol aad coal (CA) Bete (0) themes ater he ig ma! teeth oe ned) Dios les inde ip ees 954 Emcee ein TP vats ilewat capt itso pic loess 95 ose leeln TAA os,Red wines tested witha Sing agents “s ced decreas of te ol polypence content present in wines, sinifean cone redutnof wl payee. role compound war observed for SBAcIS nd raged ecween 235% (SBA 6) and 293 M6 SBA 10) flowed by MEM tht ranged from 3.196 (CM 2) r0 164% {MM 4 ie espet othe conc vart. The aeorgin ‘nth mesoporous mater an be abt tthe pres. fence ofthe nal props an the vast felecrone ‘ofthe phenyl ngs may enhance the eration wi Si (OH group. Fo activaed coal and temonte a sinieant “TrCedctionoceuted aswel 37.54 fr ava oa {2 g Land 16.79 for bene at? 3 Fr th ol antxidar activi (TAA). SBA-LS and rT were closely ranked acording he obalne re Sul obo eases, the percentage males decrsted om 112941024454 (SBA-15)andrespecney, om 69910 25,1 SU (KITS) As amb see Fig 2, be most porn “ecreses of aout stv were corded fer et ‘mens ith 2 gL of activated coal sad? gL tone ‘ach reament redicing With 26.154 and $3.3 he com {ene when compared wh onl var, ‘song conelaton Between th toxin atv ‘iy and tal pyphenolic compounds was found fr ed nes in this Sud, with a cretion ecient oF 29, (Gig 3). The canbe atte to» point rl of Dlyphenol inthe anos action any ete authors ave ben als repre avery hgh degee of conelaton ‘eon fol polyphenols content nd tx ati fred wines (Yoo ef of 2011). The noxdat aiviy of ‘ed wins eine depend gre exten he A ‘nolconten but iasoinuncedy te relive mounts te dvdulRavanolFinsg apes are a i ferent o the peal compotion epi in f- ‘anol monomers and ers. Cosue (2007) epred ha some ing peta protest gelatines) ave 2 Slee acton, precipitating high} plymerzed abd ight glloynted tain fom se wines. Thiscan be sen- ‘rt currents tha ne a sketve con of ese pours material on invita phenolic ompastin and encom these individ! campos conte it ‘rious modalities othe ed wie ation acti Discriminant analy (OA), asa mincing iscrinina techie implemented for Sng t= far combination of esures, which characteris fps Ines wo of mote clases of objet. The et icrimiant faetion CF) acount for 39.86 ofthe wl dsp ‘sth coreltin of 976, which messes te ssition Among the discriminant sores andthe ous. The seo Aisriminat anton (2 accounts for 10.14 96 fhe o- tl variance wih eapoiealeoeltion of 0836. Fig Sows the dtbton of rel wie ened wih aout fning agent et diferentconcentaon sng al ope role compounds ad eal antxidan acy a pare {es TPC and TAA pei to dilate song wines ‘sbjeted to mesoporous maria, Destonie and acted {Sh SBA-IS and served oa wae sted fate et ‘ofthe coordi, which cole wi he highest ‘etaied quantity of al plypenai compounds tn an ‘xian acti. The lation of CMA ad KITS in ‘herit part, which oppose to the ote fing ages indicates that they weaned be lowest oan of TPC and TAA, Colour properties: Coleris one ofthe prin: ciplatettes fa wine oa i repre ve fcr Torte choles of enrimers Ini ead sour tudes an bet hlpal too in enalopel pate nthe reso ton ofthe pel characteris a wie Red wine colour are ifunced by te content in phenolic compounds an derivate pets nano "ani, Also, the colours depend on the copigmentation ‘Phenomena and pl of wine (Boutros 2001) Chemist race, dere of tnaston and lees of antsy: sae me meng ip 3: Simple repens beeen wl ppl conpond an tl niet acy of ws aoa veda CA) sd Bente) Tamanho eh Single se id gL“ G.D Deseret a. ie om | Bowe ‘sone ne Fi 4: Dri sass sig potent compounds nl nent vy cashing aria of wines fer ‘came wi sro ted Cu (CA) nd Beant (Tenure fing maa nee eo ed moray cetue me cheomatie propre of youn ed Wines and athe formation of derivative pigment “ab 2 sows the chromate parameter of ‘abort Sauvignon tesa wins The jr fing stents pple led t nolo ites decrease when compared {the contol wes. A sage exention was observe or ‘he samples tented wih MCM 10 Acne oa an ber ent have an inporant impacto th cou of ewes ‘Ta, 2) tet rites a gly. Redaction of elou iment (036% for MCM 2 ap 0416s fr SBA) was secompanid by inceucs of aap (Sts or SRA open 5 fr SBA) tee ‘vies cried wih mesporse sca material, Al, an be noted tha dimiton in coor nena (143% for Bentonite at gL up 48% for activated coal at e 2 5am of clr paneer obine fe eames with toner ava (CA ad Berne (BT mbes sere ing mata ne herd gC 2.51 was accompanied by a orl decrease (62 % for bentonite a Lup to 208% fr ated la 15eL). Hseand hrm parameters aio deceased orvrits ‘rested with npomterals, and an nerese For stated ‘al ed bentonite samples was observed. The cont ty behavior wine samples ed wih diferent estments ‘Sauter pros fhe igh arian of penal pole “The iets of yellow re nd ue colo (ter ance t 20a 20m an 620m) ceased Cosy in cvated coal and bernie variants In conta wi incressed in wines toate wih acne coal and keto ie when compared with mesoporous mater vars (Fig 3) A hlerrhial eater says wa ed 0 group soem 2 E [ éRed wines wat with new fining agents o the wine samples scoring to thir colour prope (Fie 5) Inte clstering betmap we can nae» eat hangs of colo profes hat occured in clad wines ih fren tetmens. Colour parameters wee grouped stow man clases. Cate represented activated col and bene ints an cluster 2 nclaées mesons ‘tae and cael wines sample Conca Nanomaterlwesteats imine win iy in ‘Cabumet Sgn’ wheres KIT and MCMCt1 have shownteterNTU aes, Faiag agen rosie difeens ‘nga on the wal polypenlc compounds andthe to stoidant act, ering varous fence othe Cslourof he wie Among mesoporous nts SBA-13 ‘educed signer the TPC and TAA. Mesa, at ‘ated eal nd enone presented the songs enol oF enolic cones om all sud vari Alri Ing agents mesoporous materia, have less pact on the colour and jolie conten a ed wines in cont sctvted cal nd bentonite reatmets that an conduc 0 ‘nsatihng chimeric. Taking i coment gate impact of bert onthe event andthe Aliminton of inporan vi compounds ed wines, Ineoporocs mars are prefeble and could be ano ‘soto dsr for polyphenali compounds. mledgements ‘is per var cri oak he fame of OV Re serch Gt Weare ae gra he Oslo Ress (Cer omnin Sedo Bre uma: 20 Ati phen nd toned mit dik mena en to te ‘201 Acme pnp of mo ‘tical on ob) a Wee ae nA At Act tn 0:2 At 1K 10 pe nan ef ed re ‘stipes nasa 8 Hal Mas ht sa Siac ON Cha Ma ME Dime 0 Cont A080 fc lt Sy ee ‘sD Pa, RA: Pt Lin em 38 "Gs pense poe nw ae pers vay mm ee ep i gramanice te iaeieeetencnsaree oe iSite aaa xanga ie Kot ge Hare 67 Seen a ‘Atorpion of pent nd ohiepert on rice ary wh err ae one sae See ne Eanes perone eae ae eee ae rains atta atta sagt ate foie atone wines irate Sees Ente, pasoeacee omeere eae ogee meen Aotierniemeees on eee LENSES onc citi teeta occoaccnnirieee et acre tae Ghee mee eae eect arta Fa pare ler ete erent Saeccactmnna rane Lie cael tere sneer area ot nae maraeo 6.0. 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