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ALL INDIA TEST SERIES

JEE(Advanced),2013
PART TEST - II (PAPER - 1 & 2 )
(9th December, 2012)

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QUESTIONS
\ ANSWERS & SOLUTIONS )
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ANSWERS, HINTS & SOLUTIONS
PART TEST - II
PAPER-1
Physics PART -I
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Physics PART -I
SECTION-A
Single Correct Choice Type
This section contains 9 multiple choice questions. Each question has four choices (A), (B), (C) and (0)
out of which ONLY ONE is correct.
1. In a certain region of space a unifonn and constant electric field and a magnetic field parallel to
4
each other are present. A proton is fired from a point 'A' in the field with speed v = 4 X 10 mls at
an angle of a with the field direction. The proton reaches a point B in the field where its velocity
makes an angle 13with the field direction. If s~na:=.J3 . Find the electric potential difference
• SIO 13
between the points A and B. Take mp (mass of proton)
19
1.6 x 10. kg and e (magnitude of = 27
electronic charge) = 1.6 x 10. C.

(A) 16 V (B) 16/3 V
(C) 90 V (0) 30 V
Sol. A
Work done by magnetic force is zero
. . 1 2 1 2
s2 from work energy theorem - mpYB :=- mpVA + q8 V.
;: 2';j: 2,). ,;
and simultaneously there is no change of velocity component along the direction of perpendicular .
tq,electric and magnetic field. >
v~ sina := VB sinl3
After solving !w = 16 Volt
2. A metallic disc of radius r is made .of a material of negligible R

resistance and can rotate about a conducting horizontal
shaft. A smaller non conducting disc of radius a is fixed
onto the same shaft and has a massless cord wrapped
around it, which is attached to a small object of mass m as
shown. Two ends of a resistor of resistance Rare
connected to the perimeter of the disc and to the shaft by
sliding contacts. The system is then placed into a unifonn
horizontal magnetic field B and the mass m is released.
Find the tenninal angular velocity with which the disc will
rotate finally.
1 .
= =
(Take r 10cm, a 2cm, R := 100 Q. B 0.2 T, m 50 gm, g = = = 10 m/s')
?
(A) 200 rad/s (B) 300 radls

(C) 100 rad/s (0) .10 radls
Sol. C
At tenninal stage, torque applied on the smaller disc by the rope = mga
2 .
current to the disc = Bwr (where (D is terminal angular velocity)

2R
B2 4
torque applied by magnetic field = _.Wf.
4R
~ 4
B"(J}r
So. -- :=mga
. 4R
ID == 100 rad/sec
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3.
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distance from each other and they are connected by a coil of
inductance L = 9mH as shown in figure. One of the spheres (say A) is imparted an initial charge
and the01her is kept uncharged. The switch S is closed at t = O. After what minimum time t does
the charge on the first sphere decrease to half of its initial value?
(A) 1t x 10-6 sec (B) 2: x 10--6 sec

4
(C) 2: x 10--6 sec (D) 2n x 10-6 sec
I
2
Sol. B
Angular frequency (f) of the LC oscillation = ~21T£ORL
required time is one fourth of the time period
4. A non conducting infinite rod is placed along the zcaxis: the
upper half of the rod (lying along z 2: 0) is charged positively
with a unifonn linear charge density +1. while the lower half (z <
0) is charged negatively with a unifonn linear charge density -
i.. The origin is located at the junction of the positive and
negative halves of the rod. A unifonnlycharged annular disc
(surface charge density: aD) ofinner radius R and outer radius
2R is placed in the x-y plane with its centre at the origin. Find
the force on the rod due to the disc.
(A) 2ao}.R
I
I
Co (i";
I
(C) ao/,R
I
Co
I
Sal. C
I The force on the rod due to the annular disc is equal and opposite to that on the disc due to the
I rod. We take an annular strip of radius r and width dr and find the force acting on it
I
I dF = (ao 21tr d)r -- i. = -
I.GO d
r
I 2m:or Co
I .. The force
F = ao/.
co.
J
2R
dr = aoi.R .
Co
- R
5. A insulating cylindrical rod of diameter d and length f. ( f. »d) has r

a unifonn surface charge density such that the electric field just
M.( )
.(.r;«\HO ..
outside the curved surface of the cylinder at point M is Eo. Find the < : ) p
electlic field. due to charge distribution at point P (r» 0. (
WE~ ~El~
o 2r2 0 4rL
~E~ ~E2ld
03r' 0 r2
Sol. B
--- 2" -E 0
21tl'od
i. = m:odEo .
_ todl
Sa Ep--- 2
, 4r
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6. Electric field given by the vector E =0 ~..Q.(xi
(
+ Yl) N/C is present in the
(o./l~
x-y plane. A small ring of mass M carrying charge +Q, which can slide
freely on a smooth non conducting rod, is projected along the rod from
the point (0, £) such that it can reach the other end of the rod.
(f, 0) x
Assuming there is no gravity in the region. What minimum velocity
should be given to the ring (in mts)? jf in S.1. unit QEo( =:8
M
(A) 2 (B) 3
(C) 2.5 (0) 3.5
Sol. A
E x2 E 2
For the electric field, V=:- +K
_0_ - ~
2£ 2£
QE £2 1 QE f2
from energy conservation - __ 0 - + k + _Mv2 =:- -' _0 . .:- x 2 +K
R 2 2 f. 8
v = 2 mts
2
7. One mole of an ideal monoatomicgas under goes a process V = aT . The temperature of the gas
increasesby 100 K. Which of the following is incorrect?
(A) the work done by the gas in the process is 200 R Joule
(B) the molar heat capacity for the process is 7R

.; 2
2
(C) for the process PT = constant
(D) for the process coe'tftcient of volume expansion is 'j' ;, ....~
T
Sol. C
R
For the process, P = -
aT
So, work done by the gas = 200 R Joule
. 3 RT 7R
For the process, molar heat capacity C = -R + -2aT = --
2 V 2
. ffi . 1 dV
Vo Iume expansIon coe rClent ",=' - -- = -T2
. V dT
8. A point source of heat of power P is placed at the centre of a spherical shell of mean radius R.
the material of the shell has thermal conductivity K. If the temperature difference between the
outer.and the inner surface of the shell is not to exceed T, then the thickness of the shell should
. not exceed
2 2
(A) 2nR KT (B) 4nR KT
P P
2 2
(C) nR KT (D) lIR KT
P 4P
. Sol. B
At equilibrium energy radiated by point source = heat conducted through the thickness of the
shell
9. Two infinite sheets carrying charge density +0 and -(J are arranged +XO .. -<)
perpendicularly as shown in the figure. Select the approximate electric
field lines for the charge system near the intersection .
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p,'jfS-PT -1I.{Paper-1)-PCM(S)~EE(Advanced)/1 ~. 7
(A) (B) +0
x
(C) (D)
Sot B
Tangent on the electric field lines give the direction of net electric field at that point.
Assertion -Reasoning Type

I
This $ection contains 4 questions n,mnbered 10 to 13. Each question contains STATEMENT-1
I'''!':' :i}':'.' .. ,':,'. '
(A~sertiOn) and STATEMENT-2 (Reason).. Each question has 4 choices (A), (B), (C) and (D) out of
which QNlYONE iscorrect.:;;:. i' -----t;y
10. A current of one ampere flows, through a wire made of copper and aluminium as shown in figure.
They have the same cross.section A.
STATEMENT-1 :
Some charge accumulates at the boundary between the metals.
and Cu
STATEMENT.2: 1A
According to Gauss's law, ~ E . (is = qenclosed for a closed surface.

.. Co
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
.Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement-lis True, Statement -2 is False.
(D) Statement-1 is False, Statement-2 is True.
Sol. A
Electric field inside copper and aluminium are different due to different resistivity. So, from
gauss's law the interface should contain some charge
11. 1 mole of an ideal gas is contained in a cubical volume V,

ABCDEFG at 300K. One face of the cube EFGH is made up of a
A
material which totally absorbs any gas molecule incident on it. At
any given time.
STATEMENT-1 :
The pressure of EFGH would be half that on ABeD.
and
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••••••••• -Of - , Wi,. lX "U i>Y ':f"UOY17&' i?
STATEMENT-2:
Gas molecules colliding with the wall EFGHare loosing ijs kinetic energy.
(A) Statement-1 is True. Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
Statement-1.
(C) Statement-1 is True, Statement -2 is False.
Sol. 8
In the figure shown a charged capacitor is being discharged by an p

12.
CJ
external load resistance Rl.
STATEMENT-1:
A magnetic field is not present at point P which is situated inside the
capacitor as shown in the figure.
and
STATEMENT-2:
From ampere's law, tS.d7 = f.Lo(ienclosed)' An ampere loop (circularin shape and parallelto the
plane of the plates) passing through P does not encloses any current.
Statement-1.
(8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(D) StatEfment-1 is False, Statement-2 is True.
Sol. D
13. STATEMENT-1:
In a black body radiation, energy is uniformly distributed in the radiation spectrum for all
wavelengths.
and
STATEMENT-2:
From Stefan - Boltzmann's law radiated energy from a black body is proportional to the fourth
power of its surface temperature in Kelvin.
Statement-1.
Statement-1.
Sol. D
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AITS-PT -1I-(Paper-1 )-PCM(S}-JEE(Advanced}/13
'90 n::tg- ( . - .•••,.,,0 .•..••):•••
Of xt 00' •
Comprehension Type
This section contains 2 groups of questions. Each group has 3 multiple choice question based on a
paragraph. Each question has 4 choices (A), (8), (C) and (D) for its answer, out of which ONLY ONE is
correct.
!
Paragraphfor Question Nos. 14 to 16
An engineer is instructed to design a tank to

mJasure the heat capacity of liquids. The tank
is designed and it consists 01 insulating walls of
negligible heat capacity, with a hole in the Immersion heaters
bottom, a drain plug fitted with a light rod to
co~er the hole, and 10 .eledric immersion
hebters each of 5 V0N. The tank has been
shown inthe adjacent figure. For testing, water
. is lfilled in the tank at 20°C and heaters are
SW1itchedon. After 15 hour of switching on the Drain plug
heaters water starts boiling at normal
at+osPheric 'pressure. The water is then Figure: Synthetic lubricating oil tank
re~laced by an equal volume of oil whose
boiling point is 220°C at normal atmospheric
prbssure and its specific gravity is 0.7. The
engineer reported that th~oil took 3.15 hour to
raise its temperature from 20° C to 60° C at
1 '. .
normal atmospheric pressur.e.

"/',
14. From the report of the engineer the specific capacity of the oil is approximately found out
(A) 60% of specific heat of water (B) 80% of specific heat of water
(C) 90% of specific heat of water (D) equal to specific heat of water
Sol. A
I The amount of oil in the tank is nearly, equal to
'1
Sol.
(A) 1.2 :x 103 kg
(C) 3.6 :x 103 kg-
8
(8) 5.7
(D) 4.8
x
x
10~kg
103 kg
16I 1
, 1\ is suggested that the air in the tank above the oil can be pressurized at 4 atm above normal air
pressure, which of the following is incorrect if pressure is increased to the suggested .value.
(A) The time required to heat the oil would be greatly extended.
(B) The drain plug would be more difficult to lift.
(C) Fluid velocity would be increased when the tank is drained.
(D) The tilT)e required to drain the tank would decrease.
I
Sol. A
I In case of water, (5x 10~ x 10 x 15x 3600 V x PIN X S.,y x (100 - 20) =
In case of oil, (5 x 1o~ x 10 x 3.15 x 3600 V x Po x So x (60 - 20) =
=
After solving SrlS.,., 0.6 and V x Po 5.7 x 10 kg
3
=
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10 AITS-PT -II-{Paper -1 }-PCM(S )-JEE(Advanced )/13
w 00CCiYt .
Paragraph for Question Nos. 11 to 19
A space shuttle is designed in such a way that magnetic force d

d
is used to reduce its acceleration during the landing of the
shuttle on a newly discovered planet. For this planet, it was
known that gravitational acceleration above the surface of the R
. B
planet is constant towards perpendicular downward to the
planet surface and is equal to g and the magnetic field B
~0-1g
produced by the planet is uniformly B and is directed parallel
to the planet's surface. There is no atmosphere above the x y
planet surface. The space shuttle is given such a shape, such
that it can be idealized like conducting disc of mass m. radius
R and thickness d (thickness d is much smaller than R) ,as nnnn7ne~aJlyjJY9J9)nnnn
shown in the figure. x and yare two flat surfaces of the shuttle. Neglect any type of eddy current
appeared during the motion.
17. The amount of charge induced on' flat surface (say x) of the shuttle during the falls in the
gravitational and magnetic field of the planet in terms of the shuttle speed v is
(A) conR2Bv (B) 2coR2Bv
3 2
(C) f-onRdBv (D) conR B v
d
Sol. A
19,~ The magnetic force acting on the shuttle during its fall in termSof the shuttle acceleration a is "
(A) conR2Bda' (B) conR2B2d? ~)_
(C) 2conR2B2da (D) conR3B2a
Sol. B
19. The acceleration of the space shuttle during the fall is

9 'g
(A) (B)
BconR2d B conR2d
2
1+----- 1--------
m m
2 2
(0) B £oTIR d
m
Sol. c
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AlrS-PT -II-{Paper-1)-PCM(S)-JEE(Advanced)/13 11
»Y"(" "PUG"i'frT': «x tttl!'ttt«<um Aynxt"X«fZ.,;.OX xm'M'dC'
SECTION - 8
Matrix. - Match Type

!hi1s section contai~s 3 questions. Each question contains ~atements given p q r
In two columns, which have to be matched. The statements 10 Column I are
lab:elled A, B, C and D, while the statements in Column II are labelled p, q, r, A
s ~nd t. Any given statement in Column t can have correct matching with B
ONE OR MORE statement(s) in Column II. The appropriate bubbles
co~resPOnding to the answers to these questions have to be darkened as c
illustrated in the following example:
If t~e correct matches are A - p, sand t; B - q and r; C - P and q; and D - s D
and t; then the corred darkening of bubbles will look like the following:
I .
1. Column-I contains some thermodynamic system and column-II contains its properties. Match the.
following columns.
Column -I Column-II
(A) Ametallic cube placed in open atmosphere, and (p) Work done by the system is
gets heated. from surrounding positive
1
_-IT.:
17_-_
r" --~
--rr. ~ i!~-
(8) --- ~ 2 ~-1l (q) Work done by the system is
~ 7.1IL ~:~ negative
a:- ~~
i~,'
:~ :;..::~
<::>-".- '0 - - -""--
~6-- -:-{;l:-S?-~
rrrr"FFFF: ~
.h The conducting cylinder, coptaining gas and
enclosed by a movable piston. The cylinder is
submerged in an ice water mixture. The piston is
quickly pushed down from position-1 to position-2.
1
I
I
1
i---
-~ 7: :-iI-
Increament in the internal.
(C) ~-- ~ 2~-d
-:l2 .. Y . -~_- (r)
II
energy is equal to the heat

_-_- :LILA. -_
-7\
17v.
-~
~ ~
I transferred to the system
-~
~ --A-.-- - --
-o~ I
-_:q.6"::-:-o.:-~-&
Iffffffff/:'
The conducting cylinder, containing gas and
I
enclosed by movable piston. The cylinder is
submerged in an ice water mixture. The piston is
very slowly pushed down from position-1 to
position-2.
p
(D)
p;O'''r (s) i
Increament in the internal
energy is less than the heat
transferred to the system
T0I2 To T
A monoatomic gas follows the given process. The
.
process 1 to 2 follows the thermodyn~mic relation
T<= Tg P.
(I) I Heat is transferred.
system.
into the
Po I
51 (A) -) (P, S, t) (8) ~ (q) (C) -; (q) (D) -) (q, t)

12
.•..
AITS-PT -1I-{Paper-1 )-PCM(S )-JEE(Advanced)113
2. Column-I contains some charged system and column-II contains its properties. Match the
following.
Column -I Column - II
ChargeSystem Properties
(A) z (p) Electric filled at the origin is zero
y
........
+
+ x
A ring placed in x-y plane symmetrically,

having equal and opposite uniformly
. distributed charge as shown in the figure.
(B) z y (q) Electric field at z-axis, Ez is along
positive z-direction for z>O and Ez is
along negative z-direction for z < 0
++;+++++
A s4'uare placed in x-y plane

symmeW~lIy, ~aving a~ternate positiv.e I
and negatIve umformly dlstnbuted charge r
on each side of the square as shown in
the figure.
(C) (r) Electric field at z-axis is along
positive x-direction
-+'~
p p x
';" p
Four identical dipoles placed symmetrically

with respect to origin in x-y plane as I
shown in the figure. f
(0) z XX (s) Electric potential at any point on z-
axis is zero
Electric potential at any point on z-

axis is some nonzero positive value.
Sol. (A) -~ (r, 5) (B) -)- (p, s) (C) -)- (p, q, t) (D) -)- (r, s)
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.,.trrCrtsx ( '« HC n' y,: 'OYr TN' OX! .>tr»'''X( 'oo'y' (X'" ""iX••.
)'SX»
3. Column-I contains some circuits and column -II contains some properties. In column-II current
signifies instantaneous current and potential difference refers instantaneous potential difference.
Column - I Column - "
Charge System Properties
(A) (p) In branch x. current varies
x~
E =&osin(rot)
A closely sep<;llratedconducting wire is
wrapped over an insulating cylinder. Wire
is connected to a resistance R and an
alternating source via a switch S. which is
closed at t = 0
"
(B) Between points a and b, potential

(q)
difference decreases always.
A charged metallic sphere of radius r is

earthed with a resi?tance R and a switch
S, which is closed at t =0.
l
x R I
(C) I (r) In branch x, current is constant
r ~ S
t-"NV\(\., -./
a I: b
An inductor L and resistor R is connected
I
to a cell of emf c and internal resistance r
= I
r~ ~
with a switch(s),which is closed at t 0
(D) I (s)
Between points a and b, potential
difference is constant.
I: -~ s
~1Vw..J
a b /
A circuit (used to measure an unknown
resistance) is in balanced conditions
(Galvanometer reads zero)
I
I (t) Rate of heat generation through the
resistor R is constant.
Sol. (A) ---')(p) (B) --+ (p, q) (C) ---')(P, q) (D) ---')(r, s, t)
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14 AIlS-PT -1I-{Paper-1 }-PCM(S)-JEE(Advanced)/13
•••
' 'm"" x. XQXtQ).,.m')Xi -,. y »
Chemistry PART - II
SECTION-A
Straight Objective Type
This section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1. The number of alkenes (open chain as well as cyclic) of six carbon giving same product with HBr
in presence of peroxide and absence of peroxide.
(A) 8 . (B) 6
~7 ~3
Sol. C
Me
o A
Et Et Me Me
\ / \ /
c=c c=c
/ \ / \
H H Me Me Me Me
o
Me
Et
H
/
\
c=c
/
\
H
Et
0(, .•...~1.;
-.
'.. C;., I
2. Diethyl ether is very less water soluble but Tetrahydrofuran is completely soluble due to
(A) Aromatic nature of tetrahydrofuran
(B) Due to Sp3 hybridisation of diethylether
(C) Flipping of ethyl group prevents H-bond in diethylether
(D) Diethylether stability in comparison of five membered ring intetrahydrofuran
Sol. C
3. Find out the correct match for the following compounds regarding their cis and trans configuration
(B) Sr
CHz
(C) (D)
. H
H
(E) ir--I~CH3
l~
H !
(F) f:):::jC~CH~
I
'.
-
'/
Sf H
(A) A - Cis, B -'-trans, F - Cis (B) A - Cis, B - Trans, E - Cis
(C) C - Cis, B - Cis. 0 - Cis (0) B - Trans, E - Cis, F - Cis
Sol. B
Because
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sax«<tuustoXt'tN<1t( nxr Cr"PDX ZX("lXl' . 'in xu
A - Cis, B - Trans, C - Cis

D - Trans, E.,.. Cis. F - Trans
4. Two drugs shown below are known as non-steroidal anti-inflammatory drugs (NSAIDS) taken
orally by the patient
F
\_---,. CH:;O
// \\ ! I!
(( \ . ./ ',:---CH- C-OH
~\- \ I
(Ansaid) (Mortein)
(I) (II)
Which of the following is true:
(A) I is more soluble in H20 than II (8) II is more soluble in H20 than 1
(C) Both are equally soluble in water (D) Both are insoluble in water
Sol. A
Because. of presence of F, it develops H-Bonding,
5. The amino acid produced when propanoic acid is subjected to the following sequence of
reagents.
(i) PBr3. Br2
(ii). H20
(iii): NH3 , .1
(A) Alutamic acid (B) Aspartic acid
(C) Valine,,, (D), Alanine
S I. o .
oII PSr,
°II °II
H~.,C-CH2-C-OH
-~~) H.•C-CH-C~Sr H"C-CH-C-OH
- 6,: - I - I
Sr 8r
NH;o ,-'
, R
H.•C-CH-C-OH
- I
NH2
6. Find the correct statement:

(A) 2, 4-pentanedione exists more as enol content in hexane than inwater
(B) 2,4-pentanedione exists more as enol content in water than in hexane
(C) 2,4-pentanedione is equally stable in water and hexane in keto form
(D) 2,4-pentanediene exists mainly as keto form in water than in hexane
S ,I. A
Due to intramolecular H-bonding.
7. Among the compounds:
H,)'CH, (i)
The correct order .of pKa values are:
&(ii) NO:
Ph-OH
(iii)
(A) IV < III < II < I (B) IV < I < II < III
(e) IV < II < III < I (D) IV < III < I < II
s ,I. C
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16 AITS-PT -11-( Paper -1 }-PCM( S)-JEE(Advanced)/13
NrMtN . iXCO"
OH
r6l pKa=835
N02
Ph-OH pKa = 9.98
o
II
H3C-C-OH pKa=476
8. In the reaction sequence:

OTs
, OH
co
X & Yare:
CH3
1. X
2 lsCl,pyri<jne
~
~_: .' '-6uOK/HluOH) y
(A) o (B) o
cD 0s0 •. ~
V
m
. H
(C) (0) OH
Sol.B
6J H'
OH
m-CPBA.
CH-.)
co
, OH
0.0,
~fOt-.yo'O"y.at.o~
.Cb lsCtiP)
TOS)1ahor: a: I~S- hr.deted OH 0'0 •.•;::.
(r'o~t~ o
CD - '
0-8u-'
'-BuOH
cL>
9. The relative reactivities of compounds A, Band C with HBr is
ICH-.) ICH-.) ICH-
.)
H~C==C H-C==C H.C==C
L \ '\ L \
OCH3 CH3 CH2-O-CH:;
(Ai (8) (C)

(A) A > C > B (B) C > A > B
(C) B > A > C (0) A > B > C
Sol. 0
tn fact this is the order of stability of carbocation fanned after attack of etectrophile H- .
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Reasoning Type
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-l (Assertion)
an~ ST ATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY
O~E is correct.
I
N-2 is better nucleophile than N-1 arx:JN-3

o. STATEMENT-l: In the cytosine
and
H3C~I. (111)~:~
STATEMENT-2: In the thymine . lG~!./"" & cytosine, N-2 of cytosine is better
N 0 nucleophile than N-2 of thymine.
H .
(A) Statement-l is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-l.
(B) Statement-l is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-l.
(C) Statement-l is True, Statement -2 is False.
(D) Statement-l is False, Statement-2 is True,
B
N
/ 1"'-
Statement 1, compare basicity of I in same molecule while in second statement the basicity
is compared between two different molecules.
In cytosine lone pair of N-2 is not in conjugation while lone pair of N-l and N-3 in the same are
participating in mesomerism, In thymine lone pair of both N-l and N-2 are taking part in
mesomerism.
OH
STATEMENT-1:
and
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18 AllS-Pl -1I-(Paper-1 )-PCM(S)-'JEE(Advanced )/13
. "00:(( Of (0" "pi "," "e". - J'St'»Y . 'n>pXX"9"Q' XPX( nxsnnroxt •••••
sttZP' "r?ifSY" ::-oXTa".a: ?X'S"y,.>.it. xxtrnnj .•••.••
w X ?xt»»XX .•••:st«tr:MCJ(CCC' y<t"tox'»?t:.yNi"'(QQ: XYiX 'X:C:C:ftrtriXf!"'''''''''' pxa' Y »YQ1"QXJXf'"
OH
STATEMENT-2:
OH
-~
/ etc.'--
STATEMENT -2:
(A) Statement-l is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-l.
(8) Statement-l is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-l.
(D) SV~tement-l is False. Statement-2 isTrue.
Sot. A
12. STATEMENT-l: Cinnamaldehyde cannot go self aldol condensation.

and
STATEMENT-2: It does not have a-hydrogen.
Statement-l.
(8) Statement-l is True, Statement-2 is True; Statement-2is NOT a correct explanation for
Statement" 1.
Sol. C
In Cinnamaldehyde (PhCH = CH - CHO) there is no acidic a.-hydrogen.
. -
e.g. PhCH = CH - CHO~PhCH = C~ CHO
The carbanion is not sufficiently stabilized .
. 13. STATEMENT-l: When mixture of 1 mole of benzaldehyde and 1 mole of cyclohexanone is

treated with semicarbazide. semicarbazone of cyclohexanone precipitates first and finally
precipitate of semicarbazone of benzaldehyde is formed. I
and
STATEMENT-2: Initial one is kinetically controlled product and the other one is
thermodynamically controlled product.
(A) Statement-1 is True, Statement-2 is True; Statement-2' is a correct explanation for
Statement-l.
(8) Statement-l is True, Statement-2 is True; Statemenl-2 is NOT a correct explanation for
Statement-l.
(D) Statement-1 is False. Statement-2 is True.
Sol. A
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.III~
I
I 19
~ITS-PT -110{ Paper -1 }-PCM(S)-JEE(AdvancedV13
. .,.m roxaxz
,
}
>
Comprehension Type
I .
Tlhis section contains 2 groups of questions. Each group has 3 multiple choice question based on a
P1aragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
cprrect. .
(yellow precipitate)
I
1 (C,:,03J "0:,0. !ekO o,~ • C
0,
Zn,HzO
)8+0
Jleasant smell)
1.CH.o,O-Na~
2. CH3 - Br(1eq)
E
1.
HO, H;:0
.1
) F 1 OK" (excess),~ ) G
-CH~
2 K"
.:',
14. Compound C is
(A) . (BY
(C) (D)
srI. I
B
15. Compound j is
o 0
II 1/
H-C-C-CH -CH-C-O-CH
.> 2 I 3 (B)
(A) CH3
CH.O
3 o
II 1 11
~C-C~-C-?-C-O-C~ (D)
(C)
CH3
I
SFI. D
16. Compound B is
I
I
(A) It is pleasant smelling, red coloured liquid
(B) Sold in paint stores for general clean up work
(C) It is less volatile than water
(D) All the above
I
I
Sol. B
I
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)y -,:" 7
AITS-PT -1I-(Paper-1 }-PC M(S)-JEE(Advanced)/13
o
--
(C)H~C-y=CH-t-eH3. "
CH~
o 0
~; l!
(D}H,C-C-C-H (ElHoC-C--CH-C-O-CH
, _! 3
" II II
o 0 CH3
o o
H II
(F)H~C-C-CH2 (G) HO-C-CHo
I I •
CH3 CH3
o o o 0
II II II II
(H) CI-C-CH (I)H,C-O-C-CH3 (J) H C-CH -C-O-CH-C-O-CH
3 2 I 3
I 2
CH3 H,C
o
CH3CO H+ E (KM~O.
a.dation A[C H ]
9 12
H,!3eq)
Pd-C)
[
B C9H~6
]
j. aq, H2S04
HgS04
C+D
(isomeric ketohes) .
o
II
H2C-C-OHO
O
'If E __ II
T-CH2-
I
CH C II
CO'
2- H2- 7- H
and compoundC gives positive iodoform test
OH
Compound B is
(A) CH3 (8)
O-CH2CH2CH'
(D)
Sol. C
18. Compound C is
(8)
(A) Q-CH'CH2CH2CH,
(C) (D)
Sol. D
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A ITS-PT .1I-{Paper.1)-PCM(S )-JEE(Advanced)/13 21
y 'OT' yy n . Y Y -C"fPtSfU' "5st"'Ptt'tttt:CWetSXt" 'itp(«<< 't<MWtidttSlXtro>X W OJ » '0 'ON 'W rt(ii'(C''',wti rtxAX#U((t<M '0 y,o,."X"to"o •. x,
19.
(B)
(0)
Sol. A
Solution for the Q, No. 17 to 19.
o-CH2-CH2-CH2-CH3
(B) \
\
o i~
0-
I
(C)
11
CH2CH2C-CH3
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22 AITS-PT -"-(Paper~ 1)-PCM(S)-JEE(Advanced)/13
0.
<mormon 'cxmttt'PttYd'tt'H
SECTION-B
(Matrix Type)
This section contains 3 questions. Each question contains statements given p q r s
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
sand t. Any given statement in Column I can have correct matching with
A@)00@Et9
ONE .OR MORE statement(s) in Column II. The appropriate bubbles B0~@00)
corresponding to the answers to these questions have to be darkened as
c@@(00)
If the correct matches are A - p, sand t; B - q and r; C:.- p and q; andD - s D (~)0)0@@
and t; then the correct darkening of bubbles will look like the following:
1. For each of the statements in Column I, choose a substituent from Column II that fits the
description,for the compound.~z
Column..J Column-II
(A) Z-donates electrons. inductively, but does not donate or (p) -OH
withdraw electrons by resonance
(B) Z-withdraws electrons inductively and withdraws (q) -Br
electrons by resonance
(C) Z-deactivates the ring towards electi'ophile and directs (r) -O-R
ortho, para positions
(D) Z-withdraws electrons inductively but donates electrons (s) -Et
by resonance and activates the ring.
(t) -N02
I Column-II
I (p)
i
I
!~~!X
rOT n .i.
! ~ . CD3
(q)
(r)
~CH'
I
.d-iH
I (s)
!
I
i,
~o
! (I) N(CH3h(OD) ....•

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A\TS-PT -1I-Waper-1t-PCM(S)..JEE(Advanced)113
23
...."T.,.'=' mnxT'X'$'Q) , »w rat X'OO'ti'c,.tnn>
Sol. A ~ s; B ~ r, t; C ~ q; 0 ~ p, t
I Cope elimination (a typical syn-:elimination)
General mechanism:
R1
04.1+
"
$~~' /
C/
II
c
"
+
3. Match the following:

Column-I (Monocyclic species where I Column-ll (Properties)
all carbon atoms are part of cycle)
(A) CgHg' (p) Contains 2, n-electrons
(B) C9H~ (q) Contains 6, n-electrons
(C) C4H~' (r) Contains 8.n-electrons

Contains 10,n-electrons
.
(D) C 4H~' (s)
(t) Aromatic in nature
Sol. A ~ s, t; B ~ r; C ~ p, t; D ~ q, t
(A) (B)
. '.,
(C)
W
. 0
8
(D)
.~
[]V
r>.
[]0 e
I
-.1.,I' ',"Ju'
'. '. :...
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24 AITS-PT -f1-(Paper-1 }-PCM(S)-JEE(Advanced)/13
p' '( Y«'=,(Y"c»»neooz "y;"."tC" ••«t1)YOT'-CiNfd't<t'tt'Xit -'O?T'"rtrtOXxit ""oxt»" 'ttf)Y-O .,...,.-Y'r:XtYXf'i ••"
SECTION -A
This section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B),
(C) and (0), out of which ONLY ONE is correct.
1. px + qy =
40 is a chord of minimuml.~n~th of the circle (x - 10)2 + (y - 20i = 729. If the chord
passes through (5, 15). Then (p2013+ q'o,) is equal to
(A) 0 (B) 2
2014
(C) 22013 (0)2
Sol. o
-£=-1:::>p=q
q
Now, 5p + 15q = 40 :::>p + 3q = 8 :::>p = q = 2
2.
1 mt2 503t
-=-=-----
1 -1 2:.:2013m
1 503t
m=--- m=--
=>
e' 4026
/4026 ')1/3
:::> t = -1--
\ 503
:. Only one common tangent
3. The number of ordered pairs (x, y) satisfying Ixl+ IYI

~
= 3 and sin( 2x
\3
2
! j
= 1 is/are
(A) 7 (B) 8
(C) 9 (0) 10
Sol. B
i '\
sinl2x2
,3 /
1=1
3
=> x2 = 2(4n+1) for n = 0, 1 only
f3 '15
=> x = :t~2 ' :t~-2- and for each x, there are two values of y .
:. The number of ordered pairs =8
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AilS-PI -1I-{Paper-1 )-PCM(S)-JEE(AdvancedV13 25
.r' nXS?Xii '••nxsn ?Z>'tf •••••., .. )>>
4. If the asymptotes of the hyperbola (x + y + 1/ - (x-y - 3)2 = 5 intersect at A and the coordinate
axis at Band C, then the equation of the circle passing through A, Band C is
(A) 4(x2 +y2)~4x+6y+3 == 0 (6) 4(x2 +y2)-4X+y ",0
(C) x2 + l -x + 2y == 0 (D) none of these
Sol. C
Centre of rectangular hyperbola is (1. -2)
:. Equation of Asymptotes are x = 1, Y =-2
Radius of circle = J5 .
2
5. Let PQRS be a square with length of the side 10. The points A and 6 are taken on the side PQ
and C is taKen on the side RS. Then the circumradius of the triangle ABC can be
(A) 3.1 (6) 4.2
> (C) 5.5 (D) 8
Sol. C
Let M be the circumcentre
Now MA + MC ~ AC ~ SP = 10
:. The minimumvalue of circumradius = 5
Now a circle through PQRS has the radius 5.J2 and the points P,- Q, R lie on or inside the-square
:. 5:0:: radius s s.J2
6. In triangle ABC with A as obtuse angl,~_,AD and AE are median and,.\,,~ltitude respectively. If
~AD == IDAE == IEAC , then sin3 A cos A equals

," 3 3(.
3
3a3
(A) 3a
64b2c (6) 128b2c
3 3
(C)3a (D) _ 3a _
256b2c 512b"c
Sol. 6
Clearly triangle ADC is isosceles. A
=:. AD = AC = b
=:> DE = CE ~ ~
4
!
Now sin3 A cos ~ == sin2 A 2sin A cos A
3 3 2 3 3 3
1 . 2 A . 2A B C
= -Sin -sln- D E
2 3 3
= "2
1 (EC')2
b;
(BE}
I,AB
1
== "2'16b2
a2 3a 1 3a3
'4'c == 128b2c'
7. If sin" (x2 + y2) + tan" Jy2 - 2 + sec"(x - 2)= K has no solution. then exhaustive range of K is
( 1 1'
(A) (-1,1) (6) 1--'==,
\ --/2
-1
.J2)
(C) R (D) none of these
Sol. C
x2 + y2 ::; 1, lYI:?.J2 and Ix - 21 ~ 1
No such (x, y) exists
:. K E R
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26 AITS-PT -II-(Paper-1 }-PCM(S)-JE E(Advanced)113
'O"LSlf ••' "q •.••••••.•
•Y" "r - - -0- X'X """""'J)YW'O ea:c
8. =
P is a point '{' on the parabola y2 4ax and PO is a focal chord. PT is a tangent at P and ON is a
normal at O. The minimum distance between PT and ON is equal to
'1\
(A) 0 (B) ,j1+e + ~1+e al J
2 )3/2 . j--z
( (D) a-v1+ t
(C) a t +1
e t2
Sol. C
P(at2, 2at) , o( t~, _ t ,

2a1
Equation of tangent PT is ty = x + at"

Equation of normal at
2
a
is xt - yt3 - a - 2ae =0
:. PT II aN
4 2
d = l-at - a - 2ae 1= ah + 1)3/2
,)t4 + t6 t2
9. The area enclosed by the curve max {Ix - 11,WI} = kis 100, then I<.is equal to
WS ~8
(C) 10 (D) none of these
Sol. A
Area enclosed by the region Y
D C
ABCD =
2k' 2k Y =k
=> 4k~ 100 =
k=S "
=-1<.
A BY
x=1-k x=k+1
Reasoning Type
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion)
and ST ATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY
ONE is correct.
. ab - rr .
10. STATEMENT 1: In tnangle ABC, 12 == R .
r3
STATEMENT 2: In any triangle ABC. _a_ = _b_ =._c_ = 2R

. sinA sinB sinC
(A) Both the statements are true and Statement 2 is correct explanation of Statement 1.
(B) Both the Statements are true and Statement 2 is not the correct explanation of Statement 1.
(C) Statement 1 is true and Statement 2 is false.
(D) Statement 1 is false and Statement 2 is true,
Sol. o
ab = 4R2 sin A sin B
rh = 4R2 sinAsinBcos2 ~
2
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•
10Ts-P1 -'HPaper-1 l-PCM(S)-JEE(AdvancedV13 27
1.- ST~TEMEN~1: If xox:::l are the 1::9th of the segments of the focar":~:':~"~:IiPse
latus rectum is given by 2(x). Then major axis of the ellipse cannot exceed 2.
whose
STATEMENT 2: Semi latus-rectum is the HM between the segments of the focal chord.
(B) Both the Statements are true and Statement 2is not the correct explanation of Statement 1.
r
(D) Statement 1 is false and Statement 2 is true.
D
2x{x}
Ix) = -- => [xl = 1
x+ {x}
I
b2
=> -=1
a
=> a(1 - e
2
) = 1 => 2a > 2
STATEMENT 1: The normals at the ends A and Bof a focal chord of the parabola y2 = 4ax meet
l•
I
the parabola again at C and D respectively then AB = 3CD because.
STATEMENT 2: The normal at 't,' meets the parabola again at 't2' then 12 = -t, - 3...
t,
(A) Both the statements are true and Statement 2 is correct explanation of Statement 1,
(C) Statement 1 is true and Statement 2 is false. .
A
.
Let A = (at , 2at),
2
B=
(a12' - 2a'
-t )
Also normal at A meets the parabola at C

., (2' 2 2' ' /
'(1 "2 '1 ")
... c=lai-t--) ,2a(-t--lJand.D=la!-+2tl.2al-+2tl
... t . \ L \ ~t } t /.
1 STATEMENT 1: In any triangle ABC. the minimum value of cot2 A + cae B + cotL C is .J3 .
STATEMENT 2: y = cot x is a concave downward curve in 10, n).
Sol. C
I' Comprehension Type
p~ragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer. out of which ONLY ONE is
I .
ct;>rrect.
R:ead the following write up carefully and answer the following questions:
Bly taking B(-3, 0) and C(3, O),triangles PBC of perimeter 16 are constructed. If S is the locus of incentre
of triangle ABC, then
11 , Equal.ion o! S is
1
(A) x< + 4yl = 4
2
(B) Xi + 4/ 9 =
I {C)x +4l=12 (D) none of these
SOl. B
As ID -.LBC
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.".@ "UWttrfPY X HlOO' )'
w-N .x nY' ytm-.;
Now x = BD - BO = 5 - b ~ b = 5- x
".C=10-b=5+x
----------
Now /j = ~8(8 - 6)(8 - 5 + x)(8 - 5 - x)
(8y)2 = 16(3 + x)(3 - x)

~ x +
2
4l = 9
. 15. A ray emanating from (- 3;3 . 0) is incident on the curve S at P whose ordinate is %. The
equation of the reflected ray is

(A) 4x + 313y = 12 (B) 4x - 3.)3y = 12.)3
(C) 8x + 313y = 1213 (D) none of these

Sol. C
Equation of s is x2 + 4y2 = 9
p;: (0. ~I
2/
313 \
Foci are ( :1:-. -.0
2 )
I
Equation of the reflected ray is 8x + 3.J3y = 1213
16. Twoc:perpendicular tangents to S inter-sect at O. then 1001 is equaf to (@ being origin)

~
(A) }..;~
?}2 (B) . J5 ";'.~
c
(C)~-j3 (0) none of these
2
Sol.
Paragraph for Question Nos. 17to 19

Read the following write up carefully and answer the following questions:
let 0(0, t) is a variable point andR = (3, 0). PO is drawn perpendicular to RO to meet the variable line y =
2t in P. let S represent the locus of P.
17. The equation of S is
(A) xy =4 (B) r\ x-~Y

2)
+(y-3i = 19
x2 y2 .
(C) y2 = 12x (0) -+-- = 1
3 6
Sol. C
Equation of PO is Y - t = ~(x - 0)
t
.'. Coordinates of P = (.~. 2t]

3 /'
.... locus of P is y2 = 12x
18. The chord x + y = 1 cuts the curve S in points A and B. The normals at A and B intersect at C. A
third line from C cuts the curve S normally at O. Then the coordinates of Dare
(A) (3, ~) (B) (0, 0)
(C) (6. -3) (D) (12, 12)
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taN we 'xh Yilt- 'OX xrtYrr »nW)' r( tT'l'C"..-' '(
-
Sll. D
Let A : (3m~, - 6~), B': (3m~, - 6m2), 0: (3m~, - 6111:3)
A and B lies on x + y = 1
... 3m~ -6m1 =0 and 3~ -6m2 =1
:. m; - m~ - 2( Ill, - m2) = 0
Ill, + m2 = 2 ~ --m3 = 2
:. Coordinates of 0 are (12; 12)
How many nonnals can be drawn from the point (.J37, -10) to s
(A) 1 (8) 2
(C) 3 (0) infinite
Sol. C
As h > 2a :. 3 nonnals can be drawntos
SECTION-B
(Matrix Type)
Ttlis section contains 3 questions. Each question contains statements given p q r s

in Itwo columns, Which have to bematched. The statements in Column I are
la!,)elled A, 8, C and 0, while the statements in Column II are labelled p, q, r,
s ~nd 1. Any given statgmentin Column I can. have cOJrect matching with
ACB900@E!9
ONE OR MORE statement(s) in Column II. The appropriate bubbles B 0 ~"'EfD.0c)
coirresPOnding to th~ aQ~wers to these questions have 19 be darkened as
illustrated in the foHowing example:
c Ci)~{~) 0 C0
I .
If the correct matches are A - p, sandt; B - q and r; C - P andq; and 0 - s
~jd t:then the correct darkening of bubbles will look like the following:
D~00CDCD
1.
(A) ~ (r). (Bl-~ (r) (C) ~ (p) (D)~ (q)

2
The 4 points of intersection lie on 2x + 12x - By + 26 = 0 (by adding)
Which is a parabola with vertex = (-3, 1), S = (-3, 2) and directrix y = 0
(A) A = 0, 8 = 0; g = 3, f = -2, c = 13 ~ g + f + c = 14
(B) a=-3,p=2:. a2+132+1=14
(C) Required sum = sum of these points from y = 0 = sum of the ordinates of these points
These points of intersection also lie on l-
20y + 59 0 =
:. Sum of ordinates = 20 (By subtracting)
Since these points lie on a circle and hyperbola so we get a pair of points with same ordinates.
Hence sum = 40 .-
(0) As SG SP 5 = =
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>"'»'»»X!Xft -t,::,,:,:.:y-< - "«"(tOX' rtf"" n»?i -((crt')Xi .rxrn stX'RiYY' ••••
-,,-
2. Match the following Column-I with Column-II
(A) Let P be any point on the parabola = 8x between its vertex and (p)
positive end of latus rectum. If 5 be the focus and Nbe the foot of
perpendicular from 5 to tangent at P. then possible integral values
of area of triangle PN5 is
(8) A chord is drawn from a point A(1, a) to the parabola = 4x which l (q) 4
cuts the parabola at P and Q such that AP'AQ = 31al. then 'ex' can
take the values
(C) A trapezium is inscribed in the parabola = 4x such that its l (r) 8
diagonals pass through the point (1, 0) and each has length 25 . If
4
the area of trapezium is A then 16 A is equal to

25
(D) Normal to the parabola yl. = 4x at points P and Q of the parabola (s) 12
meet at R(3, 0) and tangents at P and Q meet at T (a., 0), then
area of the quadrilateral PTQR is equal to
Sol. (A) ~ (p) (B) ~ (p. q) (e) ~(s) (D)~ (r)
(B) Equation of the line thro (1, a.) is x -1 = Y.- a = r . It meets the parabola at P and Q
cosO SIOO
~ (rsinO + o} = 4r(.rcos6 + 1) ~ r2 sin2 H + 2r(tsinO ""t2cose) + (a2 - 4) =0

~ Ap x AQ == 1a.
sin
2
-2 41,~3lal
e'-
~
la31al41 -
2
-- 2
sin e:s; 1 ~ (Ial + 1)(10.1- 4) ~ 0 ~. lal ~ 4
(C) The diag0!lals arc the focal cords of the parabola R
PF 1 + t< a (say) = =
1 1 5
:. -+-----=1 = a=-. 5
a 25/4-ex 4
= -.5 1 + ex2 5
Fora =- = I = :i~1
442
For ex = 5. t = :i2
50 P = l' ~,
4
11.) R = (4, 4), 5 = (4, -4), Q = Q == (~,
.4
- 11
i
5
.', Area of Irep = -75

4
2
(D) If P(a1 , 2at) then
Q = (af, -2at) ~ a = -at2
For R, t :t1 = x
ATt=1,a=-1 (a,O)
:, PM = 2at =2
~ RT= 4
Area of quadrilateral = i (i;.-.

x 4 x 2) = 8 sq. units
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J
.A,ITS-PT -1I-(Paper-1 )-PCM(S)-JEE(Adv anced)f13 31
'XrX!xtrnMmO'MO ex cu- O':Cr1N('Xi'.,':'"A «, ",:p:,'lt:»- . "af ¥ YU»?X»XUC"!'WQ
3. Match the following Column-I with Column-II
2
(A) If the cirde x + y2 - 4 X - 6y + k =0 does not touch or (p) (-1,3)
intersect the axes and the point (2, 2) lies inside the
cirde, then k can lie in the intervallintervals
(B) If the line 3x + ay - 20 =0 cuts the circle x2 + y2 = 25 (q) (-:Y:, -3)v( 4, x,)
at real, distinct or coincident points, then a belongs to.
(C) If the point (2, k) lies outside the circles
(r) (~J:.,-,j7Jv[ -fi,oo)
x2 + y2 + X - 2y - 14 =0 and x2 + y2 = 13, then k
belongs to the interval
(D) If the point (k + 1,k) lies inside the region bounded by (s) (9, 12)
the curve x = ~25 - y2 ,thenk belongs tothe interval
(A) ~(q. r, s) (B) ~ (r) (e) ~ (q) (D)~ (p)
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o
o
.•... FIITJEE .JEE[AdvancedJ.20 13
a.
....o ANSWERS, HINTS & SDLUTIONS
e
M
PART TEST . II
'<:t
o PAPER.2
NN
a. <r-
Oo Physics PART -I
"-N
e
.- W :i;:j:;.:[:;'
..,';f::;j::i.'
;;::! ;:;;lf:8:i:;::.:.:":::.:
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..:;:::::'.•:.::..
:'::::O':: .. :.:i.::,..:.:.:;:;.:: ...
~W
-I :.;.s~.:;~~r:'::;:
..;::~:;.!'i~~T:t~:;
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O
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0.-
..- •
1 0 C A A
0-
•....e 2. 0 C B A
e .-
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E e ~ A A C 0
ns0
L. .-
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5. A ADD
o 0
L. Q)
0.- 6. A A 0 C
E Q)
o (/) 7. B A A C
0_
:n ns 8. C o .. A B
u
(1) .•••
ns 0
.•.. 9. C o A A I
1::N
0;1;
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-
Cl>06
E~
10.
11
12.
A
B
A
o
A
B
B
A
o
A
o
A
1 !
::J e
.- ns
13. o A A B !
~o:: 14. A A A A
~o C
15. B C B
u~
e a..
C'O
o 16. o o o o i
(/)..-
E
C'O
e
.-
17. A A A A i
1...0)
18. C B C B
g>t.D
1...
0..0
••.•.
19. o o o o
EO (A) ~ (r) (A) ~ (5) (A) ~ (5) (A) ~ (5)
ON (B) ~ (r)
00. (B) ~ (p) (B) ~ (r) (B)~ (p)
L. 0 1 (C) ~ (q)
~ •.... (C) ~ (5) (C) ~ (q) (C) ~ (q)
!!! .S (0) ~ (q) (0) ~ (p) (0) -4 (r) (0) ~ (p)
UlO
(A) ~ (5) (A) ~ (5) (A) ~ (r)
Er--.
I...
2.
(~)
(B)
~
~
(5)
(p) (B) ~ (p) (B) ~ (r) (B) ~ (p)
I
I
(C) ~ (q) (C) ~ (5)
~
0)
e
o
(C)
(0)
~
~
(q)
(r)
(C)
(0)
~
~
(q)
(r) (0) ~ (p) (0) ~ (q) j
(A) ~ (5) (A) ~ (r) (A) ~ (r) (A) ~ (5)
I
.J
E (B) ~ (p) (B) ~ (p) (B) ~ (p)
3. (B) ~ (r) \
o
I... (C) ~ (q) (C) ~ (5) (C) ~ (5) I (C) ~ (q) I
LL
~_-lJ0) ~ (p) (0) ~ (q) (0) ~ (q) i (0) ~ (r)
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2 AilS-PI ~II-{Paper -2)-PCM(S }-JE E(Advanced}/13
I
I
Ohemistry PART - II
:><::>:')--i~it.wll.)-; ••
~~-;i9~':
1. B A B
2. C B o
3. 0 C o
4. D.- B C
5. B B B
6. B o A
7. C D- B-
8. B C C
9. A B B
10. B A o
11. I;A o A
I 12. A B
]A
I
113.
t 14.
t .
I 15. -1:
~
I
17.
I 18.
o
B
A
B
A A
I
A
A
-,
19 A 0 A o I
I
1 . 1
I
(A) --) (p, r, s, t) (A) --) (q,f, t) (A) --) (r, 5) (A) --) (q, r, t)
(B) --) (q) . (B) --) (r) (B) --) (p, r, s) (B) --) (r)
1.
(C) --) (p, q) (C) --) (p, s) (C) --) (5, t) (C) --) (p, s)
(D) --) (q) (D) --) (q, s) (D) --) (q, 5) (D) --) (q, s)
(A) --) (r, s) (A) --) (r, s) (A) --) (q, r, t) (A) --) (p, r, s, t)
I (B) --) (p, r, s) (B) --) (p-, 5)
I 2. (C) -~ (s, t) (C) --) (5, t)
f, (B) --) (r)
(C) --) (p, 5)
(B) --) (q)
(C) --) (p, q)
i
I (D) --) (q, s) (D) --) (q, 5) (D) --) (q, 5) (D) --) (q)
r- (A) --) (q,r, t) (A) --) (p, r, 5, t) (A) --) (p, r, s, t) (A) --) (r,s)
I
I (B) ~ (r) "(B) --) (q) (B) --) (q) (B) --) (p, r,s)
I 3.
I I (C) --) (p, s) , (C) --) (p, q) (C) --) (p, q) (C) --) (5, t)
!
I
I (D) --~ (q, s) I (D) --) (q) (D) -~ (q) (D) --) (q, s)
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AIJS-PT -1I-(Paper-2)-PCM(S)-JEE(Advanced)113 3
'N:fXttt:IJX )'C(<<m'm- •. ,'(X'X>"(iX'
QillN~'::".:;::;.':m9V>."
1. C 8 8 8
2. 8 8 8 A
3. 0 8 8 o
4. A 8 8 8
5. 8 8 C C
6. 8 A 8 8
7. 8 0 o B
8. 8 8 A 8
9. 8 C 8 8
10. 8 D o A
11. 0 A 8 o
~!~":.~
12. A
-;'.\';
0 o 8
13. 0 1
8 A '0 I
I
----1_
14. 0 iA o IA
: 15. A
;
;
iB fA
-----i 8 !
I
16.
17. A
B 10
I
10
I
8
A
I~
o
J
118. B IA 8 A
19. 0 IB o 8
(A) -" (s) (A) -" (q) (A) -" (p, r) (A) -" (q)
(B) ----)-
(q) (8) -" (p) (8) -" (p, q) (8) -" (p)
1.
(C) -"(r) (C) -" (r) (C) -" (q, r, s) (C)-" (r)
'" (D) -" (q) (D) -" (s) (D) -" (p, q, s) (D) -" (5)
~
rl
(A) -" (p, r) I (A) -" (p, r) (A) -" (q) (A) -" (s)
(8) ~ (p, q) I (8) -" (p, q) (8) -" (p) (8) -" (q) I
'. 2.
(C) ~ (q, r, s)
(D) -" (p, q, s)
I (C) -" (q, r, s)
(D) -" (p, q, s)
(e) -" (r)
(D) -" (s) (C) -" (r)
(D) -" (q)
(A) -" (q) (A) -" (s) (A) -" (p, r)
II (A) -" (s)
(8) -" (p) I (8) -" (q) (8) -" (q) (8) -" (p, q)
f 3.
I
(C) -" (r) I (C) -" (r) (C) -"(r) I (C) -" (q, r, s) i
i
~.
(D) -" (s) _~) -~ (q)
I
(D) -" (q) I (D) -" (p, q. s) I
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(om- 'X xt"t •••»'tNZXP"COCX ?"tC'1'o' )"'C' xr:?O'OO°rONt"PCl
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''''''''1 1. •
1
~"YSICS -PART -.
SECTION-A
. Single Correct Choice Type
Th1issection contains 9 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
oul of which ONLY ONE is correct.
2. In the figure Box-1 contains one capacitor and one resistor

Box-2 contains 1 inductor and one resistor
R, =
resistance in Box 1
=
R2 resistance in Box 2
1
Power factor of Box 1 = -r
--/5
Vosin(rot)
1
Power factor of Box 2 = - r=
'0/5
. 1
Power factor of Box 1 + Power factor of Box 2 = ----,=
--/2
' •.
Power factor of Box 3 = -----,=1
.J2
Resistance of Box 3 R, + R2 =
'a
Current I = sin(wt + ~)
On the basis of above mentioned information pick the incorrect option from below:
(A) ~ =3 (B) Z3 = 4.i2R2 (Impedance of box 3)

Rz
(C) 1= Vo sin(Cilt) (D) (j! = (2n + 1)n, where n may be some integer.
4Rz
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AITS-PT -1I{Paper -2)-PCM(S )-JE E(Advanced)/13 5
.,- '-XC»",,"Q)xo'o" . mau' 'ECN xn»o trC»'O'scxtcO?'Q$dutttt<:SOXK#t c O"'UXZX'"Ztf oOtCr" xt xtO'TS"'tA'N
Sol. 0
2 1
1 1
Box 1: 1
--
ffiC1 '
1/roC,
-=2
R,
4>,
" "
R,
Box 2: R2
wL1 = 2
Rz "
'. "
" 4>
rol,
,sOx 1 + Box 2
"--1 - rol,
ffiC1 =1
R1 +Rz
=:> 2R, ~ 2R2 = R, + R2
=:> R, = 3R2
For Box 3:
Impedance of Box 1 + Box 2 = (R, + Rz)12 = 4--J2 R2, phase angle is 1t/4
Impedance of Box 3 = 4--J2 R2, phase angle is -n/4
.'4,~,
~\~ Current in Box 1 + Bo~ 2 = I, = ':J. sin(wt ~ ~)
4",2Rz 4
. Vo . ( 1t \1
Current In Box 3 = 12 = r;:; SIAl wt - -
4",2R2 \ 4;
, = I, + '2 = 4RVo sin( t)(J)
' 3 Vosinffit
Impe d anceo f B ox 1 +, B ox 2 +. B ox = ---= , 4R'
2 an
d'
IS
..' t
resistive In na ure '
Phase angle is zero,
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6 AITS-PT-U~Pape~-2)-PCM(S)-JEE(Advanced)/13
':Ct »yt:M: Xi » nx t,'.,{x
•••. ..••••
::.:.)Ym it O'
3. In the figure, OA and OB are two uniformly charged y

wires, placed along x and y axis respectively. The unit
vector in the direction of field at point (0, 0, -Y3L) is
(A) -11 + 4} - 313k L -40 -
144
A
(B) -11 - 41 + 313k x
144
L
(C)-1i+4 1
ffi
(D) -11 :=1~
.J2
Sot A
- -- E.i +--k
E=
E13. - 2Ey3k
~. + 2Ej" . -11+41-3J3i<
2 2 :. E = .J44
y z
4E E
z x
"r" .•
4. In the figure, A, B, C and D are four concentric

spheres of radius a, 2a, 3a and 4a and contain.
charges +3q, +6q. -9q and +12q respectively. In the
beginning switches 81 and 82 are open. After earthing
the sphere C, Ilq1 amount of charge flows from the
sphere C to the earth. If the sphere B is also earthed,
then Ilq2 amount of charge flows from the sphere B to
the earth, the value of IIlq1 I is equal to

I tiq2 I
(A) 1
(B) 3/5
(C) 2/3
(D) 1/2
,!!!!,!!!!!!,!!!!!!!!!!!!!!!!!!,!!!!!!!!,!!!!!!!!,!!!!!!!!!!!!!!!!!!!!!!!!!!!!,!!!!!!!!,!!!!!!!!!!!!!!!!!!,!!!!!!!!,!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!,!!!!!!!!!!!!!!!!,!!!!!!!!!!!!!!!!!!!!!,,,,,_'!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!:l!!:!!!!:!!!=!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
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AilS-PI -1I-(PaPef -2)-PC M(S )-JEE(Advanced)113 7
XC"! 'XStTf D'1 00?tt2N xt .. ":«00
Sol. A 12q
_1_ [3q
4m::o 3a
-+ 6q -+ ~
3a 3a
+ 12q -I =
4a J
0
= q, = -18q
~~q11= 9q
1
41tco
[3 q• q2
3a + 3a + 3a + 4a
q3 12q 1 0
J=
12q
_1_
4m,o •2a
[3 q + q2 + ~ + 12q]
2a 3a 4a
= 0
Solving
q2 = -3q
l~q21= 9q
I ~q2 I = 1
I L\q, I
5. A charged particle having charge q and mass m is projected into a region of uniform electric field
of strength Eo, with velocityVo perpendicular to Eo' Throughout the motion apart from electric
force particle also experiences a dissipative force of constant magnitude q Eo and directed
opposite to its velocity. If I Va 1= 6 mis, then its speed when it has turned through an angle of 90°,
is equal to
(A) 3 m/s (8) 5 m/s
(C) 4 m/s (D) 2 m/s
Sol. A
Consider the situation when particle has
turned through an angle of <jJ
dv = _ qEo [1- sin$]

dt m
dvx
---- _qEo[1 . ",]
-Sin,;,
dt m
~ dv = _ dvx
dt dt
qEo
.~ v = -vx + C
~ v = vo -- Vx = vo - v sin q,
~ v = --~ =~ := 3 m/s
1+sin~, 1+1
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6. A uniformly conducting wire is bent to form a ring of mass 'm' and radius 'r', and the ring is placed
on .a rough horizontal surface with its plane horizontal. There exists a uniform and constant
horizontal magnetic field of induction B. Now a charge q is passed through the ring in a very small
time interval Llt. As a result the ring ultimately just becomes vertical. Calculate the value of g
(acceleration due to gravity) in terms of other given quantities. Assume that friction is sufficient to
prevent slipping and ignore any loss in energy.
(A) ~ (:r r (B) ~-q-

6 m2r
2 2B2
2 (q B r)
2 2
(C) 1t --
2m
Sol. A
Angular momentum, (~mr2)(!)=

\2
r
.
ldt = f .dqdt nr Bdt
2 == q1tr2B
For the ring to become vertical,

1(3
-
2 2
-mr 2\1
j
2
ill = mgr
.
I.e. g=-
1t 2( --Iq B,2
r
3 m/
A nQn-conducting wire is bent into a semi-circle of radius R and a

chafg'e + Q is uniformly distributed o:~er it as shown in the figure.
+0
Find ithe ratio (~: J of the potential (VA) to the magnitude of the. :0 ',A
B+ .
-------,--------e .
electric field (E~, both evaluated at the other end A of diameter AB + : :EA, VA
that bisects the wire (as shown in the figure)
(A) R (B) 2R
(C) R In (1+12) (D) 2R In (1+ 12 )
Sol. B
,
. 1 dq
E = I---coso.
4ns r2 ,.
v= r_1~dq; where r = 2R cos 4>
+,
o
o . 4m:o r
+
,
,
, I
8. In the figure ABCDEFA is a closed conducting wire loop. y
The part AFE is a portion of an ellipse,

2
X2 +
4a a
y;
~
= 1and
BCD is a portion of the ellipse

x2 y2 X x
-+-=1
9a2 4a2
A uniform magnetic field
B == Bok. exists in this region. If the frame is rotated about
the y-axis with a constant angular velocity 'r.:)". The
maximum emf induced in the loop is,
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AITS-PT -Ito{ Paper -2)-PC M(S)-JE E(Advanced)113 9
YN ",,:,,:,:,w «ttaNtriX "1YN ' .••••Nf( "#(" 'zrtP>tr" 'itttM trcox'
1UJ.) Boa2
(A) _ (B) 1tlJ)Boa2
2
2
(C) 21tCl)Boa (D) 1.S1troBoa2
Sol. C
a, = 2a
a? 3a =
Area of wire frame
n(a2b£ - alb,) 2
-----=21ta
2
<\l =
21tBoa2 cos(lJ)t}
C = - dljl = 2ll:(J)Boa2sin (rot)

dt
peak emf = 211lJ)80a2
9. In the figure 8" B2 and 83 represent uniform

time vaJ)'ing magnetic fields in three different
infinitely long cylindrical regions with axis
passing through P, Q and Rand
perpendicular to the plane of the paper.
PQR is an equilateral triangle of side 4"';3 r,
where r is the radius of each cylindrical
region (r = 1m). The magnetic inductions
vaJ)' with time t as B, A+ at, 82 = A - bt =
and B3 = A + ct. Here a = 2 Testa/s, b = 2
Teslals and c 1 Tesla/s and A is a =
constant with dimensions of magnetic field
and 't' is time. The induced electric field
strength at the centroid of the triangle PQR
is,
-
,,'S
(A) --VIm
8
1 '
(B) - V 1m
8
(C) .../13 VIm

8
(D) zero
Sol. C
The contribution due to anyone the
cylinder .
P <- - - ~~.
4J3r - - - - - - -3>
0...
--------------------__.j.?9 Q
':- __ EZ~OO E, _'-:'
IE 1=~ldBI = CldBI = !ldBI ,"4 - 4 '
2x dt 8r dt 8 dt , r, . . " - r ,,
" '....,' ,.
, - E'
", O.
IE,I =!V
4
1m , ,
3,
, ,,
IEzl = 1/4 VIm
IE 1 = 1/8 VIm
\
-, ...
:4r /
,,
3
(directions as shown in the figure)
,
,
'",
.
' I
,
,
1- - -. ,,'13
IE, + E2 + E31 = 8 VIm ~
R E3
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10 AITS-PT -11-( Paper -2)-PC M(S ).JEE(Advanced)/13
C)'t'fM nrx
Assertion - Reasoning Type
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1
(A~sertiOn) and STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (0) out of
I
whlich ONLY ONE is correct.
101 STATEMENT-1:
I A constant potential difference is maintained between the inner and
outer surfaces of an annular homogenous and isotropic conducting
sphere of inner radius 'a' and outer radius'b'. The drift speed of
charge carriers (Le. , electrons) decreases, with increase in distance
from the centre.
and
STATEMENT-2:
As we move away from the centre, the electric field decreases in magnitude. .
(A) Statement-1 is True, Statement-2is True; Statement-2 is a correct explanation for
Statement-1.
(B)Statement-1 is True, Statement-2 is True; Statement-2is NOT a correct explanation for
Statement-1.
(0) Statement-1 is False, Statement-2is True.
50[1. A
11 STATEMENT-1: .
In the circuit shoWh in the figure initially S~ is closed and S? is-
R
open. After some time, S2 is closed and S1 is opened
simultaneously. The ammeter reading shows a sudden change.
l,
and
STATEMENT-2:
By Faraday's Law,
em = - d<p, A-.
. dt 't'
= magnetic flux, !:"., = Induced emf
(A) Statement-1 is True. Statement-2 is True: Statement-2 is a correct explanation for

Statement-1.
Statement-1.
(0) Statement-1 is False, Statement-2 is True.
I
5011. B
12 STATEMENT-1:
The adjacent figures shows two thermally
mCompressed
insulated vessels having equal volumes and monoatomic
containing monoatomic and diatomic ideal gaS€s ideal gas 5
separated by a stopper, which prevents the mole 400 K
gases from mixing with each other. If the stopper ~
is removed and the gases are allowed to mix,
the final equilibrium temperature is 525 K .
and
STATEMENT-2:
Total energy of the system is conserved.
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,,'.oco'.aws."Q"C)$Jaxst. nt<' tr'C'tt1 NXitirUR"'#wtrrstn' rtti,u"'ttXtl"i sur'
(A) Statement-' is True, Statement-2 is True; Statement-2 is a correct explanation for

Statement-1. •
Statement-'.
(C) Statement-' is True, Statement -2 is False.
(D) Statement-1 is False, Statement~2 is True.
Sol. A
13. STATEMENT-1:
A metallic sphere 'A' has radius R and a concentric hollow
metallic sphere B has radius 3R. The space between them is
filled by an annular dielectric of dielectric constant 2K and
radius R (inner) and 2R (outer) and another dielectric of .
dielectric constant K and radius 2R (inner) and 3R (outer). No
charge is deposited at the common interface of the dielectrics ..
and
STATEMENT-2:
Asper Gauss's law ~E.dS = ~E,(Symbols have their usual
meanings}
(A) Statement-' is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) St'!t~ment-1 is True, Statement-2is. True; Statement-2 is NOT a Gorrect explanation for
. Stafem.ent-1. 'r: ','i.~
(C) Stat.ement-1 is True, Statement -2 is False.

(D) Statement-1 is False, Statement-2 is::1"rue.
Sol. D
Comprehension Type
paragraph. Each question has 4 choices (A), (B), (C) and. (D) for its answer. out of which ONLY ONE is
correct.
Paragraph for Question Nos. 14to 16
Four large metallic plates of area A each are kept parallel to I K,

each other with a small separation between them, as shown in
the figure. A cell of emf V is connected across the two
outermost plates through a switch K1. The two inner plates are
similarly connected with a cell of emf 2V through a switch K2•
1 2 3 4
Initially, both switches ar.e open and the plates, starting from left
to right (i.e., number 1 to 4) are given charges Q, 2Q, -2Q, -Q .
respectively. Now answer the following questions.
14. The charge appearing on the outer surface of plate -1, when switches K1, K2 are open
(A) zero (B) Q
(C)-Q (D) -3Q
Sol. A
When both switches are open,
Charge on outermost surface =
(net charge on system)!2
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12 AITS-PT -IIi Paper -2)-PCM(S)-JEE (Advanced)/13

I
15.
(A) 0+(EoA1V
.
If K1 is closed and K2 is open, the charge appe~ring on the right surface of plate-2 is
.
.
.
. (B).(EoAI~+30
2 \d;4 d)42
, \
(C) (COA)V_S (D) 30
,d 4 2 2
Sol. B
When K1 is closed and K2 is open V
..9!.. + ~ +~ =V , where Co = eoA
Co Co Co12 d
For plate 2,q - q1 = 20
Solving the above equations, we get
q-
_ (coA)V-+-30
-
o q -q o
d 4 2
16. If both switches are closed, the charge appearing on the plate 4 is
(A) (C~A ) V (B) 0 + C~A (~) .

2t7.
(C) 0 - COA"( V'l

d 2.)
(D) (EoA Y V'j
d )" 3 j
I
Sol. D
When both switches are closed. V
-~+2V--q-=v
Co Co/2
._ _ CoV _ (eoA l(V\)
~,q---l-)'-
3,d/\3 ..
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AIlS-PT -Iii Paper -2)-PCM(S)-JEE(Advanced)/13 13

ret ~ "«ftt0 *UU,wuttrrrt 'fd'" x'i(Mn)Xf«tt«W<Oittr( xt"oxrm»»x
A calorimeter of water equivalent 250g contains a block of ice

at -1 Dec in which there is a solid conducting ball whose steam
water equivalent is 50g: The mass of ice is 800 g. 150g of
e
steam at 1000 is added to the calorimeter and the system is
isolated from surroundings. calorimeter
Given
Specific heat of water = 1 cal/g/oC
Specific heat of ice = 0.5 cal/g/OC
Latent heat of fusion of ice = 80 callg
Latent heat of vaporization =
540 cal/g .
Answer the following questions based on the infonnation above.
17. Amount of water in the container, when equilibrium has been established, is
(A) 950g
(Bl800 9
(C) 150 9
(0) cannot be calculated from the information given
SoJ; A
18. Equilibrium temperature of the system is

(A) Dec (B) 10QoC
(C) 20CC (0) 30i'it
Sol. C
19. The density of the material of the ball at O"C is Ip6(O°C)}is equal to density of \'fater. Also PB
varies with temperature as PB (Gec) = PB (O°C) x 1-~) r\ 200/

Ignore the expansion of water and any
. .
pressure changes with temperature. After thermal equilibrium has been reached, the fraction of
volume of the ball in air in the calorimeter equals.
1 3
(A) 20 (8) "2
(C) ~ (0) ~.
10 10
Sol. D
•
;\~
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I SECTION ~ B
I Matrix - Match Type

T~is section contains 3 questions. Each question contains statements p q r s
gi~en in two columns which have to be matched. Statements (A, B, C,
D) in column I have to b~. matched with statements (p, q, r, s) in A@D~Q)@D
column II. The answers to these questions have to be appropriately
btbbled as illustrated in the following example.
B0@)@~
. If ~he com~ct match are A-p, A-s, B-q, B-r, Cop, C-q and O-s, then the
c@D~Q)0
correctly bubbled 4 x 4 matrix should be as follows:
....l..... . . ....•......................
00@C0C¥J
1. Column-I contains some thermodynamic system andj:X)lumn-1I contains its properties. Match the
following columns.
Column - I Column - II
(A) A steel rod is clamped at its two ends and rests (p) 400
on a fixed horizontal base. The longitudinal
strain developed in the rod when temperature
rises to 50°C is - 3.6 x 10'4, and the temperature
coefficient of linear expansion of steel is 1.2 x
10,5 fc. Find the temperature at which rod is in
relaxed state
(B) Six hundred mole of a gas undergoes,a process (q) 27

5 2
P = 7 x 10 N / 01 "
iii 2 +Y..._3
4m
where V is volume in 013 When volume of the
gas is 20 01\ its temperature in Kelvin is
approximately equal to
(C) A block of mass 100 gm slides on a rough (r) 20

horizontal surface of zero heat capacity, When
the speed of the block decreases from 10 m/s to
o
5 mIs, its temperature rises by O.2S C. The heat
capacity of the block in joule/c,C is
1
(0) P(N/m ) (s) 15
C
5 ..
3 x10
isoczj0riC
proc.ess isothermal
process
10:J A
-:; t isobaric 'B
process
T 600 T (Kelvin)
If two moles of a gas consisting of 1 mole of He
and 1 mole of H2 undergo a cyclic process
A ~ B~ C ~ A as shown in the,figure the total
work done in the cycle is -600Rln[9/e] The
temperature T in DC is
(A) ~ (r) (B) ~ (p) (C) -) (s) (D) ~ (q)
AITS-PT -"-(Paper -2)-PCM(S )-JE E(Advanced)/13 15
r-m»>"''i''''X'CfO'«t O'tSXtUQ'ffi)'Z • WiN OD'Xsturp un (0"«("(( XI » .fPCt?SZ yuxtrn
2. Match the following columns.

- Column-I Column-II
(Temperature T in steady
state)
(A) A B C (p) sooe
~ __ 2_K_O 3_Ko__ ~ __ 6_K_o __ I

100.C T 10.C
Three homogenous thermal resistors A, Band e,

each of length I.. cross-sectional area A and thennal
conductivity 2Ko. 3Ko and 6Ko respectively are joined
in series such thatthere is one dimensional heat flow
from left end(temperature 100°C) to the right end
(temperature 1Q0C). T is the temperature of the
interface between resistor Band in the steady e
state.
(B)
A spherical annular thennal resistor of thennal

conductivity K and inner and outer radii 2R and SR
respectively, is in steady state with its inner surface.
maintained at 100°C and its outer surface maintained
at 10°C (heat flow is radially outwards). The
temperature of the concentric spherical interface of
radius 3R in steady state is T. .
(C) (r) Issoe
I
, _-- .
'<!SH."?:--/
~
.100.C
. • 2R :
~
. T •.
A cylindrical and thennal resistor of inner radius R

and outer radius 8R is in steady state with its inner
surface maintained at 100°C and its outer surface
maintained at 10°C(heat flow is radially outwards).
The temperature of the co-axial cylindrical interface
of radius 2R in steady state is T.
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16 AilS-PI ~1I-{Paper-2}-PCM(S)-JEE(Advanced)113
tttMvtN . 'or" COMCN
ttt"""n?i
(D) A • 2l l
6R b
R
100°C 10°C
T
A homogeneous thermal resistor whose outer
surface is the frustom of a solid cone, has the two
base radii as 6R and 3R respectively and the
perpendicular distance between its, two bases is 3L.
The two bases are maintained at 100cC and 10°C. In
the steady state(heat flows from left end to the right .
,
II
end) the temperature of the interface at a distance of
2L from the left end is T. Assume that L is very large
in comparison to Rand the lateral surface of the
cylinder is thermally insulated from the surroundings.
FindT.
Sol. (A) ~ (s) (B) ~ (p) (e) ~ (q) (0) ~ (r)
J. Column-I contains some physical systems and column-II contains its properties. Match the
following columns.
ci:: I Column - I Column - II ~."
I (A) A metallic solid sphere of mass 5 kg and radius 2 (p) 60
I
;: I m is freely rotating about its diameter with
angular velocity 00 =
2 rad/s. The coefficient of
thermal expansion of the sphere isa
4
10. fc. =
If temperature increases by 20°C. the % change
in angular velocity of the sphere is
(B) A metallic sphere of emissivity 0.8, radius 4 m (q) I' Zero
and at a surface temperature of 600 kelvin is
emitting radiation. If half of the metallic sphere is
covered by some opaque material and the
surface temperature increases to [600 (5/2) 1!4}
kelvin, the % change in power emitted is
(C) A metallic hollow spherical shell is placed (r) 25

concentrically with a spherical shell of double the
radius. The inner sphere is given a charge q
while the outer sphere is given a charge 4 q.
Now the two sphere are connected together by a
metallic wire. The % change in charge on the
outer surface of the outer sphere is .
(D) Dielectricof (s) 0.4
' q~. ~2 ~' ~t~c=c~n$tant
C ~ . ~~ .
~ V q2 V
Situation -1 Situation-.2
Two identical air capacitors 1 and 2 of
capacitance C each are connected in series and
/
a potential difference V is applied across the
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AITS-PT -1I-(Paper-2}-PCM(S}-JEE(Advanced)/13
'OX' iXS(
17.
combination as shown in the figure. q1 is the

charge of capacitor-1 in situation-1. When a
dielectric of dielectric constant 4 is inserted into
capacitor-2, a charge q2 flows through the battery
in the circuit as shown in the figure in situation-2.
Find q2 x 100.
q1
Sol. (A) -t (5) (8) -t (r) (e) -t(q) (D) -t (p)
(A) ~MR200 = ~MR2(1+ae)2oo

5 5
())= ())o (1 - 2aO)
[
(r)'- 000] x 100 = (2aO)IOO= 0.4 %
())o
(B) P, = aA!,:600 4
P2 = (crN2)f:600 (5/2) = 5/4P,A
P2 - P1 x 100 = 25%
P1
(C) % change is zero .
.~
&
~:J.~:J
4CV 7CV 3CV eV/2 eV/2 4CVl5 4CV/5
(D) q2 = -5- - "2 = 10
q2 x 100 = 60% .
q,
Yv Yv qz
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18 AITS-PT-IHPaper-2)-PCM(S)-JEE(Advanced)/13
'»'"r:=,.w>~a= xa .•••.
«" .,?OO'nxrro-.
.>. -an" •...,.-."'rtf xr .otc ••••• '( xooa »xi rrt . 'tiC"'
qneml8try PART - n
5ECTION-A

I
T~iS
I
section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (8),
(q and (D), out of which ONLY ONE is correct. . . _
1. How many total stereoisomers do the following compounds have?

, ., ,H ,
0,0 CO 0/
(:
(~) (B) (C) ! (0) (E)
I
W 4 3 2 o 1 2
(B) 3 4 2 4 o 2
~ 3 4 4 2 2 o
Sol.
I B
(A)
(D)
c'-. ,
4 3
, 0 2 2 o
o r
.~
~
il (~
!
~
11
(8)
, t
'.
1
,
0.,0./ 0 .'0
,.--V" 1
,
...
(C) OH OH
"
(D)
l, c , ,
(E)
oo
None
1 t
(J o I
(F) Enantiomeric pair
!!!!!!!'!!!~!!!!!!!!!!!!''!!!'!!!! __ '!!!!!!!!!~!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!i!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!'!!!
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AITS-PT -IIi Paper -2}-PC M(S}-JE E(Advanced}/13 19
)'ct we xc m»> )7'rr ) 0'0'" t:er:rmxcoXf f
2. How many products will formed by reaction:
(,)0£°4
ii)p..;iHSO~
(A) 4 (8) 3
(C) 2 (D) 1
Sol. C
Two -OH groups, above and two below the plane.
3. Which of the following will not exhibit geometrical isomerism:
(A) (8)
(C) CO (D)
Sol. o
(A) I) < I L >-<J

In A and 8 there is hindered rotation about central. bond between two rings.
'M
,
(6) M ,00
<>=<1
CI
I
r' Cl
In (C) compound exist in two form cis and trans.
(C) H . H .
. Cb'OOCb H H
In case of (D) on rotation conformer will develop instead of geometrical isomer.
4. In the reaction:
~CI-~P,
N
H
Product P, should be:
(A) (8)
~CI
H
(C) (D) CI
(J H
Sol. o
C/1S ~\-..~
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J
5] In the followin
20 AITS-PT -1I-(Paper-2)-PC M(S )-JE E(Advanced)/13
table the value of di ole moments (in Deb e are as follows

"urn l""'f'rTM""»")
X CH;,X CH2X2 CHX3 __ ~

F a, a2 a3 i
CI _b,___ ~ C3
--------j
I
Br __ c_,_ C2 C3
I d" d2 d3
The correct relation among a" a2. a3, b" ~.~. Ch C2.C3and d" d2• d3 are
(A) a3> a2 > a,. b, > ~ > be. (B) a2> a,> a3, b, > ~ > b3.
(C) C, > C2> C3.d2> d, > d3 (D) C, > C2> C3,b2 > ~ > b,
S I. B
X CH;,X CH2X2 CHX3
F 1.82 1.97 1.65 .
CI 1.94 1:60 1.03
I
!
Br 1.79 1.45 1.02
I I 1.64 1.1 1.00
i
l
C~W"M rti
N.........•..
\-_ ..•.....
--------
N
consists of three fused chair conformations. If 11.67gms of the above
compound undergoes acid catalysedhydrolysis
grams of water for complete hydrolysis:
(At. Masses: C - 12. N -14. H - 1)
it requires how many
~N~
(A) 5 '.' (B){9

(C) 15 (D) 10
Sol. B>
It is urotropin and its reaction with water is
(CH2)EN. +6H20~4NH:o + 6HCHO
7. In the cyclization reaction given below, the most probable product of the reaction
Sr
~ .A.~ /OH ~ ...•Product is

HO" ~
(A)-
HO~
0 (B)
(D)
o ---/
0,>--- OH
(C) HO~
<)--J0H
c
Br /\8
~ i
Na-H:
. O-H -----
HO~'.../~)
I..OH group nearer to Br is more acidic}
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• UC"tUr'tDON'U"''' 'XP"t x "wm)'
("tlXtW,.ur'w ••••••••••..
8_ In the reaction
,. &',(2 &q) ,. Br,!2&q) ) P
h,. hv
2. hydrolysIs 2 hydrolysis
and
°
yOEt
~"OEt 1. EtONalEIOH
;: ~so. (dOl)
l
(Compound
Q
with six momb&'&O nng)
°
(2 mole)
-*
" then P+Q 00-(0'0005) lFinalproduct
-'!.
Then final product is:
(8)
(A)
o
o
(C) o (D) o
ever)
Sol.
* o
rA-(CHO
i(')!
~ CH3
N /-----..:,
I
l\..-!J..
i'
~"""'CH--Br
,CliO
.I
Br
(X::-:(P)
o o
o~
EtO
Et :lo
.
H)lr+
~OEI
H~ 'V II-
0
OEt Et~: Na-
EtOH
8
d
EtO
EtC o~:
:
8
o
" /
)7° q 'Q
EtO-C
COO:O
diI H.SO~
l
o
C-OEI
It eOOH o
o (O!
(t3-ketoacidj
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.c>: o
:OW
••
(excess\
, J
••
o
This compqpnd may further )'
(
\ undergo tautomerism to give
~
OH
9. A Na) B ~HO.03) 2C~. 2CH3COOH.;. 2C02

[HydJOcarbon J liquid. NH3 .. -
Then compound A, is
(A) colourless liquid (B) less volatile than water
(C) orange red gas (D) non-aromatic compound
A
g (A)
Na/NH",
(8irc" ,.duct""') .)
o (6)
1.0:.
2.H,O
) H~C
I
" \
COOH
COOH
~ CHJCOOH + CO,
Compound A is benzene which is colourless liquid .
.i
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,.oo.••••••
zw ••••) .•.•,'''S(). "tUffi' q ) nrxx W-P- 'Wi watt s >WtP»>' xt 'c'o'r"d>' Wetc
Reasoning Type
and STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY
ONE is correct.
10. ST ATEMENT -1: Acetaldehyde reacts with alkaline solution of sodium nitroprusside to give red
colouration.
and
STATEMENT-2: Acetaldehyde is good reducing agent.
(A) Statement-1 is Tru~, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Slatement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(D} Statement-1 is False, Statement-2 is True.
Sol. B
11. STATEMENT -1: Ortho iodobenzoic acid is strongest acid among ali ortho halobenzoic acid.
and
STATEMENT-2: Iodine exerts maximum ortho effect so the acidic strength increases.
(A) Statement-1 is true, Statement-2 is True; Stafement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True'>Statement-2 is True; Statement-2is NOT a correct explanation fof;;"
Statement-1.
Sol. A
12.
"
Sol.
CH-i
Ph-S
/'" CH2
I
OH
S is a better nucleophile than 0 atom and act as neighbouring group participant.
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••• ' _.l
24 AllS-PT -II-(Paper -2)-PC M(S )-JE E (Advanced)/13
.. 1' -" "OX"n- .••.. "lUX' '0"' ••.1.%<9( ro- )'yrtSO((((("UO"Uz'y-xrx»XftYn>xp Y M"
13. STATEMENT -1: Generally esterification reaction of carboxylic acid and alcohol is carried out in
acidic medium while esterifIcation reaction of acid chloride and ~Icohol is carried out in basic-
medium.
and
STATEMENT-2: In acid chlorides and alcohols reaction, HC! is released which can be neutralized
by base.
Statement-1.
(B) Statement-1 is True, Statement-2is True; Statement-2is NOT a correct explanation for
Statement-1.
(D) Statem-ent-1 is False, Statement-2 is True.
Sol. A
Comprehension Type
p1ragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
. c~rrect. .
\lli'hen wate~ is added&)to an alkene no re.~ction takes place, because there is no electr~phile present to
s~art a reactton by addmg to the nuCleophilic alkene. The O-H bond of water are too strong. .
CH;, - CH = C~h + ~O----4 X
If however, an acid (H:eS040r HCI) is added to the solution, a reaction will occur because the acid
provides an electrophile.
T le second order rale conslanl (M-Sec -') lor acid calalysed hydration at 25.C is give n lor each 01 Ihe
fdllOwing a!kenes:
I H3C
I \
i C=CHz
/
H
Compound P Compound Q Compound R Compound S CompoundT
FRateconstant: K, K2 K3 K.
1 k. Which is more reactive between (Z)-2 butene and (E)-2 butene towards hydration
(A) (E)-2-butene (B) (Z)-2-butene
(C) Both are equally reactive (D) Both are inert towards hydration
Sol. B
(E) isomer is more stable hence more free energy of hydration required.
15. Correct relation between rate constants:

(A) K3 < K1 < K:e< ~ < Ks (B) K2 < K1 < K3 < ~ < Ks
(C) K3 < K1 < K2 < Ks < ~ (D) K3 < K1 < K2 < ~ < Ks
Sol. A
(A) due to relative stability of carbcation formed.
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AITS-£'T -1I-{Paper-2)-PCM(S )-JE E(Advanced)/13 25
xa,m- "wA!tX «Utt
16. Amongthe given compounds Q, R. Sand T which has maximum number of planes of symmehy
(A) Q (B) R
~S ~T
Sol. 0
There are three planes of symmetry for compound T
H,C
•• \
i
: j
CH,.,
Xl plane _..... /YC\ ....
H,C l CH3
xy plane
yz plane
Compound (A), which can be distilled in high vacuum, gives positive test with Br2/H20, but does not react
with Na metal in ethereal solution, but compound (B) and(C) gives H2(g) with sodium metal.
Compound (A) undergoes following sequence of reactions -
I ":," .C
[AJ LOA/H, )B
B;HsITHF
~~2eq)
,I H;0210H'
Products
:;-
, 1two structural iSQrnersl
_ ve "-£:''''''k .«": C ~ - ve iodoform test

i : £'{Y. r /fr,.
17. Compound 'A' should be:

(A) ~OH
(8)
Y V
/-'-',,-,/OH A
n y::=
(D) CHO
(C) ~ -
::::::....
H,C--O/~
OH' \
OH i
Sol. B
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26 AITS-PT -11-( Paper -2)-PCM(S )-JEE(Advanced)/13
"'toon) . 07"
'~~"_Q»Y Compound '8'

I (A) k OH
r 11
~OH
/A.."
(C)
Compound 'C' is:

(A) OH (8)
OH
(C) (D)
~.
.. ,~)
~/O"
:',-. HO - /I
I
~
Sol. A
Siolution for the Q. No. 17 to 19.

C1oH1602(A}
Degree of unsaturalion =
10 + 1- 16 = 3
2
Compound does not react with Na metal, so it does not contain acidic groups like - C- OH , - OH
o"
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AIlS-PT -II-(P aper -2}-PCM(S )-JEE(Advanced)/13 27
>¥tOO'dOZY' l'O' < tiN - • $Mte::e<i dX»X r' if
SECTION-B
(Matrix Type)
This section contains 3 questions. Each question contains statements given p q r

in two columns, which have to be matched, The statements in Column I are
labelled A. B. C and D, while the statements in Column II are labelled p, q, r,
A(f£j0C0@@
ONE OR MORE statement(s) in Column II. The appropriate bubbles B0@~0Q)
. illustrated in the following example: c@»~00Q)
If the correct matches are A - P. sand t; B - q and r; C - P and qi and D- s D~00@9QL)

Column-I Column-ll
(A) .HCOOH (p) Decarboxylates on heating
(B) CH3COOH (q) Reacts with Br2/P
(C) (r) With Tollen's reagent gives silver mirror
~o 0
( r-g~OH
"----', c',
o
(D)
~.,
~CHj-' "
-C-OH
(s)
.
Decarbonylates
heating with H2S04
(removal of CO) on
(t) Reduces HgCI2
Sol. A ~ p, r, s, t; B -~ q; C ~P. q; 0 ~ q

Column-I Column-II
(A) CH;; - CH2 - CH2 - NH2 (p) Treatment of NaN02, HCI gives N-nitroso
yellow liquid
(B)
(q) Treatment of NaN02, HCI gives
diazonium chloride
(C) H3C-N-CH3
(r) Treatment of CH3 - I (excess) followed by
I
CH3 AgOH; heat gives alkene
(D) Ph - NH2 (s) Treatment of HCI, heat gives non-volatile
salt
(t) Cannot form H-bond with each other
Sol. A~ r. s; B ~ P. r. s; C ~ S. t; 0 ~ q, S
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28 . AtTS-PT-IHPaper-2)-PCM(S)-JEE(Advanced)/13
)' . iY '." )"ITrtO)))'"" Xi' >tt»>" .•yX a c-mx-xnn
'tXt.,. X••. )P' Xd"YO ••• iOYWt Tt >-trw 'X xa rom'ox iX' ?ttCX¥&»y-"

-Column-l I Column-ll
(A) PMMA (p) Thermosetting polymer
(B)
(C)
Orion
Bakelite I (q)
(r)
Thermoplastic polymer
Addition polymer
-'.
(D) Dacron
I I
(s)
(t)
Condensation polymer
Brittle
Sol. A --) q, r, t; B --) r; C --) p, s; 0 --)q, S
PMMA Polymethylmethacrylate coacH:;

.... I ".
i -r:]
\
CH2
CH-j/ n
i
Orion Polyacrylonitnle CN
CH2
-{j CH3/ n
Bakelite Phenol formaldehyde OH OH
CH2 CHz
Dacron Polyethylene
tetraphthalale
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nxp)"l?CtX $"'NCXt UftturC'Xfrrrnxtr "((dts (t'XttfrtttC'YtttsXtW«(it "':'"xcoxurrrr ••
Mathematics PART -III
SECTION-A
This section contains 9 muhiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct ..
1. Normals PO, PB and PC are drawn to the parabola y2 = 100x from the point p = (a, 0). If the
triangle aBC is equilateral, then possible value of 'a' is
(A) 150 (B) 250
(C) 350 (D) 450
Sol. C
IPBC = ~ ::::> t1 = 2-!3

6
Equation of nonnal at B is y = -t1x + 2at1.+ at~
y =2.J3x+4-!3a+24.J3a
It passes through (a, 0)
P{CJ.,O)
:. 0 = -2../3a + 4'-'2 (25)+ (24../3)25.
" 0 = -V3CJ.+ (4-!3)(503)+ (24..)3)503

=a = 350 C
x2 y2
2. If 'd' be the length of perpendicular drawn from origin to any normal of the ellipse - +- =1
25 16
then 'd' cannot exceed
1
(A) "2 (B) 1

Sol. B
Equation of nonnal is 5x sec 8 ~ 4y cosec 8 =9
d= 9 9
,/25sec2 e + 16cosec2e .J25tan 2
8 + 16cot2 0 + 41
e + 16cOt2 e ~ .J25 x 16
2
Now. 25tan
. 2
::::> 25tan2 e + 16cot2 (1 ~ 40 ::::> 25tan2 (1 + 16coe (1 + 41 ~ 81
::::> d~1
- od.Jx 3x2 - 6x + 13 - .Jx + 5x2 +41 is

4 4
3. The maximum value -
W2 ~3
~4 ~5
Sol. D
/(2)2 -2 12221
1V x -2 + (x ~ 3) - '.j{x + 2) + X I
Le., IJ(y - 2)2 + (x -.:3)2 - ~(y + 2)2 + x2 i

Here y = x". If P(x, y) be any point on the parabola, then IPA - PBI ::;AB
Where A(3, 2), B{O, -2)::::> AB = ,/9 + 16 = 5
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?'N-"'X'""""""" mtenm >X"""OX( .,.to,.
»"(' ••• >X«Y' my YfW XI»?
If tan-1A=tan-1(A2 +n)+~ is satisfied by atleast one integral value of A in [0, 2J. Then the
4
possible integral values of 0. is/are
(A) -1 (B) 1
(C) 0 (D) 2
~~S.ot A
0. = 1- ~ - A 2 which gives 0. = -1 only

A+1
.22
.. 5'..
~;-. ' . ,If from a point (1, 0.) two tangents are drawn on exactly one branch of the hyperbola ~ ~~ = 1,
. . ."
then '0.' belongs to
(A) (-1, -~)

(C) (!,
,2
11 >
(D) none of these
~:Sol. B
Two tangents can be drawn if the. point lies between the
asymptotes OAand OB
x
The asymptotes are y = :t-
2
x
C = ( 1;
.
-I
1\
2/
=:;.. D =
(;.'. 1 \
, 1, ..- J
\ 2>
1 1\
=:;,o.E ( --,-l
\ 2 2;
1! . a-c
6. In acute angle triangle ABC. r = r..,+ r-. - rl and B > -. Then -- completely lies in
. " ~ 3 b
(A) f!. ~') (B) (~. ~)\

!\34) 32
(C)r~.~\)
\2 2
(D>f~,~'l
\2 3;,
Sol. B
r = r2 + r3- rl
/1 /1./1 n
~ -=--+-----
s s-b s-c s-a
a-cEl/~ 1'1
.. b 3')
x2 y2
7. If the curve - + - = 1 and (x - 20)2 + (y - 20)2 = ~ intersect each other orthogonally at a
400 100
point (20 cos e, 10 sin G), then
. G 1 o 1
(A) cot "2 = J2 (B) cot- =-
2 2
l)
(C) cot~ = 100 (D) cot- = 20
2 2
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)- J'Y'n xum". :, Y...:Qu»»>YC" ••••
Sol. B
(20 20) lies on x(20cos8) + y(10sinO) =1
, 400 100
=> cos
. "1
e + 2 Sin b =
.
=> Sin
e = ---
1- case
=> cot- = -
0 1
2 2 2
x2 y2 - - 1
8. An ellipse 2 + -2 = 1 and the hyperbola XL - yL :: intersect orthogonally. It is given that-the
a b 2
2
eccentricity of the ellipse is reciprocal of that of hyperbola, then a 2 is equal to
b
(A) ~ (B) 2
. 2
(C) ~ (0) 4
4
Sol. B
Ellipse and hyperbola are confocal
:. (:t ae, 0) (:t 1, 0) =
=> a = ../2 and e = .~
,.,12
2 . 2
:. equaticmof the ellipse is ~ + 'L = 1
2 1
/it:." _ :'5~:, ,~"
9. A tangent 'at the point P(20, 25) to a parabola intersects its directrix at (-10, 9)". If the focus of the
parabola lies on x-axis, the numbers of such parabolas are
(A) 1 (8) 2
(C) infinite (0) none of these
-Sol. B
Let S= (a, 0) P(20, 25)
As PS.l as
::~;> 9 =-1
20 - a -(10+ a)
=>a=5
Let the slope of the "directrix be m x
Equation of directrix is y - 9 = m(x + 10)
Now 120m- 25 + 9 + 10ml = ,.'225 + 625
Jm +1 2
2
=> 25m - 480 m - 297 0 =
It gives two distinct values of m.
Hence two parabolas
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1- 'W)Y).'i'Q"'ttO"O"XOO :fzro/,....oo.w.,.ve."'tiX'l"t'
Reasoning
32
'"XXf')"yart=
Type
AITS-PT -1I-{Paper-2)-PCM{S)-JEE{Advanced)/13
XY.•.•(O'''O y' -#0"10".,.......,.....-.
ahd STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY
qNE is correct.
1h. STATEMENT 1: If C.I. with least absolute value is a root of the quadratic equation a:x2 + bx - a == 0,
where a > Oand b < Othen sec{coc1(tanex}-tan.1(cota)} =-1
- b
STATEMENT 2: For the quadratic equation ax" + bx + c = 0, sum of the roots = -- and product
a
c
of roots = -
a
(B) Both the Statements are true and Statement 2is not the correct explanation of Statement 1.
Sol. S .
2
The roots ofax + bx - a = 0 are negative reciprocals of each other.
:. aE (-1,0)
Now tan(eos.'a) = -TI + coC1(tan a)
1 1
.~,;.sec[ cot- (tancx)- tan. (cota)] ""secTl=-1
11. STATEMENT 1: The area of a triangle whose vertices are the incentr~, eireumcentre and centroid
oithe triangle whose sides are 18 em, 24 em and 30 em is equal to 3 em2 because.
STATEMENT 2: Centroid divides each of the medians in the ratio 2: 1.
(A) Both the statements are true and statement 2 is correct explanation of Statement 1.
(B) Both the Statements are true and Statement 2 is nol the correct explanation of Statement 1.
(C) Statement 1 is true and Statement 2 is false. .
Sol. D
The triangle given is right angled
Take a triangle with vertices (0, 0), (18. D), (0,24).
Centroid (6, 8) =
Circumeentre (9, 12) =
=
6 rs::::> r 6 =
So ineentre (6, 6)
SO area of the required triangle = ~ x 2 x 3 = 2 em'.

;
1t 2 2
12. STATEMENT 1: If 0 < 0 < - , then ecosec
2(J
sin 8 + esec
2 -
t' . cos e > e2 because.
2
STATEMENT 2: AM of positive numbers is always greater than or equal to their GM.
~!!!!e!!!!!!!!!!!!!!!!!e!!!!!!!!e!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!!!!!!'!!!O!'!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!!!!!"""_!!!'!!!!!!!'!!!!!!!!!!!!!!!!!!!!!!!!e!!!!!!l!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
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AITS-PT -1I~Paper-2}-PCM(S)-JeE(Advanced}/13 33
caxu"mWUscet (cm»xtC~««xt'1 »yt
Sol. A
AM~GM
=:> ecoseclesin2 e + esec'e . cos2 e ~ 2~eoosec2e"sec2
6. (cOS2 esin2 e)
= 2~ellSin'ecos'e . (cOS2 esin2e)
= e2/sin226.sin28
Now consider f(x) == xe2/

x2
which c1ear1yis decreasing in (0, 1)
:. f(x) > e2
13. STATEMENT 1: There exists atleast one solution of the equation

2
20[x - x ~ 5} + 10[ x - ~] == 1+ SO(cosx) (where [.J denote greatest integer function).
STATEMENT 2: If x E R. then x = [xJ + {x} where {x} denotes the fractional part of x.
• (A) Both the statements are true and Statement 2 is correct explanation of Statement 1.
(B) aoth the Statements are true and Statement 2 is not the correct explanation of Statement 1.
(0) Statement 1 is false and Statement 2 is true.
Sol. D
RHS is always an odd number. So no solution.
Comprehension Type
. .~ .~
'i~This section contains 2 groups":ibfquestions. Each group has :fmultiple choice question based~';on a
paragraph. Each question has 4 choices (A), (B), (C) and (0) for its answer, out of which ONLY ONE is
torrect. l: t ;'
Paragraph for Question Nos~ 14 to 16
Read the following write up carefully and answer the following questions:
A normal to the parabola at a point A on the parabola whose equation is yL 2013x cuts the axis of x at =
N. AN is produced to the point B such that NB = !AN. Now answer the following questions.
2
14. If two more normals to the parabola yL = 2013x pass through B, then they are
(A) coincident (B) inclined at ~

4
(C) indined at ~ (D) inclined at ~
6 2
Sol. o
Equation of normal through A is
A(am~, --2am)
y == mlx-2aml-a~
:. N(2(2013) + 2013m~, 0)
If B = (h, k), then k = 2013 ml
K
But mlm~m~
~ ~
= :.---
2013
=:> m~m-
< ~
= -1 x
:. Normals are inclined at right angles B
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"'ehsite: 1J.'Illnf'.fi~t/t?'!.~.fX)rn .
34 AITS-PT -IHPaper-2)-PC M(S)-JEE(Advanced)/13
. . .• >:Cb,.. ••»')').'>X'O.Sr.T
i
I
15. If C is a point on the parabola l = 2013x such ,that 10CN =:= ~ (0 being origin), then projedion of
I
:
CN on x-axis is equal to
(A) 2013 (B) 2013

2
Sol. A
If C ==(at2, 2at), equation of CN is
y-2at= -~(x-at2)
2
::::::>N==(at2+4a,0)
:. Projedion of CN on x-axis = ON - OL = 4a = 2013.
16. If the nonnals through" any point of the parabola y2 = 2013x, cutthe line 2x - 2013 = 0, in poi!1ts
whose ordinates are in AP, then the slopes of these normals are in
(A) AP (B) GP
(C) HP (D) none of these
Sol. B
.
'S 0 Ivmg th e equation
. 0fl'nonna With ,x = -2-'
2013 th'e or d'mates are --4-'
2013 m 3
1
2013 3
::::::> ---m2
4
2013 3
::::::> ---m3.
4
As the ordinates are in AP
... m13 +1Tl33 ==
2m3
2
But ml + m3 =- m2
Solving we get m~ ==m1m3
Riead the following write up carefully and answer the following questions:
2
The
I
ellipse whose equation is given by x + 4/ = 4 is rotated about origin through a right angle in its own
plane. The tangents at any point A on the ellipse before and after rotation intersect at P(o., B)
Nbw answer the following questions.
I
1if . The locus of P is symmetric about
(A) origin (B) the line y = x
(C) the line y = 2x (D) the point (1, 1)
A
If (0. + f3f = 3, then (0. - (3)2 equals

(A) 2.J5 -1 . (B) 2M-1
(C) J1O-1 (D) none of these
Sol. B
1!:}. Which of the following pairs of points lie on the locus of P

(A) (0, '/'3) and (0, - -J3) (B) (0, ,/5), (0, -13)
(C) (0, .J5) and (1, 1) (D) none of these
5'01. 0
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L
AITS-PT -II-( Paper -2)-PCM(S)-JE E{Advanced)/13 35
iYtlF1W XYtC'"it iXO""t'Yi"'XS
»W "N
0- '0)'="""'"00'(
17.-19. Equation of any tangent before rotation is

XCOSa+ ysina. = ~4cos2a + sin2 a. ..... (1)
Equation of the tangent after rotation is
J '" '"
-xsina + ycosa == ,14cos~ a. + sin~ u. ..... (2)
Solving (1) and (2) we get
(x2 +y2 l =4(y+a)2 +(y-xi

or (y+x)2+(y-xf ~16(Y+X)2 +4(Y-X)2
SECTION-8
(Matrix Type)
This section contains 3 questions. Each question contains statements given. p q r

in two columns, which have to be matched. The statements in Column I are
labelled A. B, C and D, while the statements in Column II are labelled p, q, r,
A~00@@
ONE OR MORE statement(s) in Column II. The appropriate bubbles B0(V@00
c ~.<W>000
If the correct matches are A - p, sand t; B - q and r; C - P and q; and D - s
D~00(@)@
........:.~9Jt.t~...;;U{ ....
(A) Locus of centre of circles touching circle + - 4x - 4y (p) Straight line
2
= 0 internally and x + y2 - 6x - 6y + 17 0 externally is =
(B) The locus of the point (3h - 2, 3k) where (h, k) lies on the (q) Circle
2
circle x + y<- 2x - 4y - 4 0 = :
(C) . Locus ~f ce~tre of circle touching two circle XL + / + 2x
o and Xi + t- =
6x + 5 0 externally is I
(r) = I Hyperbola
(D) The extremities of a diagonal for a rectangle are (0, 0) and (s)
(4,4) .. The locus of the extremities of the other diagonal is
I Ellipse
Sol. (A) ~ (5) (8) ~ (q) (C) ~ (r) (D)~ (q)
, (A) _ 2n
If cos--cos--cos--
4n 6n 1998n
...... cos--
-k
= 2 ,then
()
k+1
.
IS
(p) 2
1999 1999 1999 1999
divisible by
(B) If (1+tan10)(1+tan20) .... (1+lan450) = 2Jl then (n+1) is divisible (q) 3
by
(C) The points (0, 0), (a, 11) and (b, 37) are the vertices of an (r) 5
equilateral triangle then 'ab' is divisible by
(D) tancos-' sintan.-'I-( 1 is divisible by J (s) 7

.. ,,42,
Sol. (A) ~ (p, r) (8) ~ (p, q) (C) ~ (q, r, s) (D)~ (p, q, s)
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36 AilS-PI -'.-(Paper -2}-PCM(S}-JE E(Advanced )/13
(A) Let a = ~ and P denote the desired product

1999
Let Q = sinasin2a .... sin999a then
2999pQ:= (2sinacos a)(2sin2acos2a) .... (2sin999acos999a)
= sin2asin4a sin1998a
= (sin2asin4a sin998a)[ -sin(2n -1000a)][ -'-sin(27t -1002a) J....[- sin(21t -1998a)]
:=sin2asin4a sin998asin999asin997a .... sina = Q
999
It is easy to se that Q :;:.0 hence the desired product is P := T ~ k + 1':=1000
Hence P, Rand T are correct options
(B) '(1 + tankO)(1 + tan( 45 - k)O):= 1+[tankO + tan(45 - k)OJ + tanka tan(45 - k)o
:=1tan45° [1-tankO tan( 45 -kt]+ tanko tan(45 - kt = 1+tan45° =2
Hence (1 + tan10)( 1+ tan 44° ) ...(1 +tan22° )(1+ tan 23° )(1 + tan 45° )
~223
~ n+1:= 24
Hence P, Q and T are correct options
(C) Let 0 :;;(0,0), A :=(a, 11) and B:= (b, 37) and M be the mid point of segment AS
(a+b \,
~M=1-,241
\ 2 )
Now OM l- MA and IOMl = J3IMAI
.-,-. a - b .... ----.)3 ..
..Because AM=--i-13j if follow that OM=13"'3i+~(a-b)j
. 2 2
. a+b. - J3 . ..
Hence ~-'+24j=13"'3i+-(a-b)j
2 2
a+b. ~. a-b ;
.~ --:= 13./3 and -- = 8,/3
. 2 2
= a = 21.)3 and b = 5-8 ~. ab:= 315
Hence Q, Rand S are correct options.
(D) Because cos. 1.

SlOB = -71 - 0 and
.
tan -: - (n e = -- 1
'J' n
for 0 < 0 < -, we have for any x> 0 ,
2 \2 tanO 2 .
t ancos -1'
smtan
2
-1
x = t an - - t an x. = -1
/ X
l')1 '.1)
~ tancos-1 sintan-
1
( 1 ..
42
) = 42 l
Hence P, Q and S are correct options.
3.. Match the following:
Calufiiri~J: .<i ....•..
.cO:)9.tfi.n~n'.'••:....
"
X + cos"y ,; (). ..... (p) a square
(q) a circular arc
sin"x + cos" y + cos'\ (xy) =~
2
sec"x + tan"y = 0 (r) part of a rectangular hyperbola
a pair of lines
(D) tan"x2 + cor' y" =: .::'. . (s)
2 I
Sol. (A) --'t (q) (8) .~ (p) (C) ~ (r) (D)-~ (s)
Use formula for at:jdition of inverse trigonometric functions.

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L I :-'.

ALL INDIA TEST SERIES

(9th December, 2012)

I. FIITJff .Ltd:, F1ITJEE House. 29.A. Kalu -Sarai, San'apriya

Mathematics PART - III

(A) -) (p) (A) -) (p) (A) -) (q. r.s) (A) -) (r)

electronic charge) = 1.6 x 10. C.

2. A metallic disc of radius r is made .of a material of negligible R

(A) 200 rad/s (B) 300 radls

current to the disc = Bwr (where (D is terminal angular velocity)

(A) 1t x 10-6 sec (B) 2: x 10--6 sec

5. A insulating cylindrical rod of diameter d and length f. ( f. »d) has r

(B) the molar heat capacity for the process is 7R

Assertion -Reasoning Type

According to Gauss's law, ~ E . (is = qenclosed for a closed surface.

11. 1 mole of an ideal gas is contained in a cubical volume V,

In the figure shown a charged capacitor is being discharged by an p

Paragraphfor Question Nos. 14 to 16

An engineer is instructed to design a tank to

normal atmospheric pressur.e.

I The amount of oil in the tank is nearly, equal to

Paragraph for Question Nos. 11 to 19

A space shuttle is designed in such a way that magnetic force d

19. The acceleration of the space shuttle during the fall is

Matrix. - Match Type

energy is equal to the heat

51 (A) -) (P, S, t) (8) ~ (q) (C) -; (q) (D) -) (q, t)

A ring placed in x-y plane symmetrically,

A s4'uare placed in x-y plane

Four identical dipoles placed symmetrically

Electric potential at any point on z-

(A) (p) In branch x. current varies

(B) Between points a and b, potential

A charged metallic sphere of radius r is

Straight Objective Type

A - Cis, B - Trans, C - Cis

6. Find the correct statement:

7. Among the compounds:

8. In the reaction sequence:

OCH3 CH3 CH2-O-CH:;

(Ai (8) (C)

N-2 is better nucleophile than N-1 arx:JN-3

12. STATEMENT-l: Cinnamaldehyde cannot go self aldol condensation.

. 13. STATEMENT-l: When mixture of 1 mole of benzaldehyde and 1 mole of cyclohexanone is

Paragraph for Question Nos. 14 to 16

Paragraph for Question Nos. 17 to 19

Solution for the Q, No. 17 to 19.

description,for the compound.~z

! (I) N(CH3h(OD) ....•

3. Match the following:

(C) C4H~' (r) Contains 8.n-electrons

Mathematics PART - III

Straight Objective Type

3. The number of ordered pairs (x, y) satisfying Ixl+ IYI

:. The number of ordered pairs =8

~AD == IDAE == IEAC , then sin3 A cos A equals

P(at2, 2at) , o( t~, _ t ,

Equation of tangent PT is ty = x + at"

STATEMENT 2: In any triangle ABC. _a_ = _b_ =._c_ = 2R

Also normal at A meets the parabola at C

I' Comprehension Type

Paragraph for Question Nos. 14 to 16

(8y)2 = 16(3 + x)(3 - x)

~ __ 2_K_O 3_Ko ~ 6_K_o __ I