Solutions 4

1
AITS-CRT-III-(Paper-1)-PCM(Sol)-JEE(Advanced)/15
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ANSWERS, HINTS & SOLUTIONS

CRT–III
(Paper-1)
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. C B C
ALL INDIA TEST SERIES
2. D C D
3. D C A
4. D C B
5. B D A
6. C D C
7. B C C
8. B A B
9. A, C, D B, C, D A, C
10. A, D A, B, C A, B, C
11. A, B, D A, B, D A, B
12. A, B, D A, B, C A, C
13. C B A
14. A B D
15. A D A
16. D C C
17. A A B
18. C B B
1. 4 2 0
2. 8 1 7
3. 1 3 3
4. 4 4 2
5. 8 2 2
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2
Physics PART – I
SECTION – A
1. Angular momentum conservation

v0
about the centre of the planet, v1
mv0  5 R sin   mv1R  R
v1  5 v 0 sin  -------(1) M
Energy conservation gives,
1 GMm 1 GMm
mv 0 2   mv12  ------(2)
2 5R 2 R
Solve equation (1) and (2),
  37
2. Assume a Gaussian surface to be a sphere of radius r and take limit as r  . The flux,
  q
 E.dA  0
q
 E.dA  0
a r /b q
lim 2
e  4r 2 
r  r 0
q
4a  lim e r /b 
r  0
q=0
5. The smallest angle of incoming beam should be greater than critical angle
of the medium.
The smallest angle incoming beam should be greater than critical angle of Ra 
the medium.
sin   sin c R
R 1

Ra 
a     1 R
R
amax 
2

 0i d   rˆ i  i
6. dB 
4 r 2
4r
   
 0 2 drˆ r  rdˆ   ˆ r  0 2 r d kˆ
4r
ˆ
Where ̂ r and   are unit vectors along radial and azimuthal directions
  i d
dB  0 kˆ
4 r
  i d
B   dB   0 kˆ
0 4  b 
a  
  
 i  b
 0 ln  1   kˆ
4b  a 
3
7. Since current leads the voltage

Hence circuit is capacitive.
8. For 1 mole gas,

PV = RT
PV 2  aR  constant
Compare with PV x  constant
x=2
R R
molar heat capacity of gas C  
 1 x 1
R
C 2   
 1
RT
Q  nCT  2   
 1
9. As the sand leaves the inner drum through the open holes, it does not 2
exert any force of the drum, angular momentum remains conserved.
At time t,
m1r12 0   m1  t  r12 0  m2  t  r22 2
1
tr12 0
2  r1
m2  t  r22
r2
The speed of inner drum does not change.
10. In first case, we can write torque equation about bottom point because it coincides with
instantaneous axis of rotation while in second case, you will write torque equation of centre of
mass.
11. V  A   5V
V  B   V  C   2.5V
V D   0
2
12. K  0.5     4cm


L   2cm
2
 L    4cm
3
L   6cm
2
 L  2  8cm
 v
13.     0.657m
2 2f
4
nv
14. f
2
n 1
V = 344
  0.657  0.035
f = 276.5 hz
15. Hf > Eb

6.6  10 34  103  1.6  1019
2
  1.6  1012 rad/s
F
16. a  0 cos t
m
eF0
v sin t
m
eF
v max  0
m
17. Here z is co-ordinate a+z z

  a  z  A
EA  0
0 E
S
0  a  z 
E
0
   0 0  a  z  a 0  a  z  
18.  dv     dr    a 0 dz  0 0 dz 
E
0 a2

0
SECTION – C
1. Initially,
0 A
C -----(1)
d
V0  Ed ------(2)
and Vf  Edf
4V0  E  d  x 
4Ed  E  d  x 
x
d
3
Volume = A(d + x)
Cd
=  d  x 
0
4x 2 C

90
5

2. V
R
1 1
R2
C
Q  CV 
R
1 1
R2
3. When switch is open

V1  V2  6V
V1  V2  3V
When switch is closed
V11  2V; V21  4V
V21  V2 43
 1
V1  V11 32
4. If length of side = 2a = 60  
2  1 cm
angular momentum conservation,
Mav 0  I 
Mav 0
 .....(1)
I
1 2
2

I  Mga 2  1 ......(2) 
2
I  Icm  M a 2  
8Ma2
 ....(3)
3
Solve these equation,
v 0  4 m/s
6
Chemistry PART – II
SECTION – A
O
1. Tollen’s reagent gives +ve test for H C OH not CH3COOH
.
2. Due to steric hindrance in II the loan pair e are not involved in resonance in I electron
withdrawing effect of NO2 is high.
3. 



O OH OH O
H
211
4. 83 Bi  Tl207  2 He 4 ;
81
total time = n  half life
moles of substance left after n halve.
initial moles 2
=  4  0.125
2n 2
moles of He produced
= 2 – 0.125 = 1.875
Pressure developed due to
1.875  0.0821 300
He =
100
= 0.4618 atm
2
K f  CH3 
5. K eq   ,  CH3   10 5 m
Kb C2H6 
5 2
1.57  103 10 
 , K b  1.57  107 L mol1s1
Kb 1
38
6. PH2 O  760  722  atm;
760
0.9
nH2O 
18
0.9 0.0821 300
V   760;
18 38
V = 24.63 L
7. KO2 has only unpaired e  remaining all are diamagnetic.
8. Both compounds resemble each other in solubility.
12. Order of reactivity towards E. A. substitution
7
 
N
N
H
d   G 
13. From equation above S =
dT
d  nFE  dE dE S
S  = nF  or    
dT dT  dT P nF
 dE 
14. H  nF   T  nFEcell
 dT P
 dE 
–218  1000 = 2  96500  300    2  96500  1.015
 dT P
 dE  4 1
   3.81 10 VK
 dT P
16. Mixture contains NaOH + ZnSO4

NaOH  ZnSO 4  Na 2 ZnO2  Na 2SO 4  2H2 O
so lub le
Na2 ZnO2  2HCl  2NaCl  Zn  OH2 

Zn  OH 2  2HCl  ZnCl2  2H2O
so lub le
18. O
Cl O C
H3C CH CH2 CH2 C Br
Zn Hg / HCl

H3CO H3CO
Cl
CH3
OH
AlCl

3
H3CO H3CO
Cl (A) H3CO
CH3
COOH
KMnO / 

4

H3CO COOH
SECTION –C
1. E 
hc

 
6.63  1034 J.s 3  108 m / s 
 3.055  10 8 m
–18
= 6.52  10 J.
8
3
EH 
4

2.176  1018 J 
–18
= 1.63  10
E = EH(Z)2
2
Z 
E


6.52  1018
4

EH 
1.63  10 18 
Z=2
2. 

Sb2S3  s   3H2  g 
 2Sb  s   3H2S  g
0.01  x 0.01  3x 2x 3x
3x = 0.005
H2 S  Pb2  PbS  2H
1.19
no. of moles of PbS formed =  0.005 moles
238
 0.005 
at equilibrium H2    
 250 
3
 0.005 
Kc    1
 0.005 
3.
O
B
O O
Metaborate BO2
B B
O O O
4. OH O OH
H3C C CH C H H3C CH2 C CH2 CHO
H CH3 H
OH OH
H3C C CH2 CHO H3C CH2 C CH CHO
H H CH3
5. C
A  CaC2 Ca
C
B = HC CH
C = HC CNa
D = HC C CH2 CH3
O
E=
9
Mathematics PART – III
SECTION – A
1. a1 = 1
1
a2 = 1 
2
1 1
a3 = 1  
2 3


1 1 1
a = 1     .....  ln2
2 3 4
      n
2. Given, sin    cos   
 2n   2n  2
            n
 sin2    cos2    2sin   cos   
2n
  2n
  2n
   2n  4
 n  n4
 1  sin     sin   
n 4 n 4

For n = 2, the given equation is not satisfied considering n > 1 and n  2, 0  sin    1
n
n4
 0 1  4 < n < 8
4
   tan x  1
3. g(f(x)) = tan  x   
 4  tan x  1
x 1
 g x 
x 1
 x  1
f(g(x)) = tan  
 x  1
x2 y 2
4. Locus of point of intersection of perpendicular tangents is director circle for   1 equation
a2 b2
of director circle is x2 + y2 = a2 – b2 which is real if a > b
5. Image of P in x-axis is (1, –2) y

(5, 3)
5 P(1, 2)
 Equation of reflected ray is (y – 3) =  x  5 
4
  
 5x – 4y = 13 
x
O Q(a, 0)
6. Radical centre of the circles described on the sides of a triangle y

Q(1, 0) S R(3, 0)
as diameters is the orthocentre of the triangle x x
 OS = 2 T
 1
ST  QS tan  
6 3
 1 
 Quadrants of T is  2,   P
 3 y
10
2
7.  Since, (4, –4) and (9, 6) lie on y = 4a(x – b)
 4 = a(4 – b) and 9 = a(9 – b)
 a = 1 and b = 0
 The parabola is y2 = 4x
2
Let the points R be (t , 2t)
4 4 1 2
1  1  125
 Area of PRQ = 9 6 1 = 5  t   
2 2  2 4
t 2t 1
1
 Area in largest when t 
2
1 
 Coordinate of the point R is  , 1
4 
8. f(x) is a decreasing function and for major axis to be x-axis

f(k2 + 2k + 5) > f(k + 11)
 k2 + 2k + 5 < k + 11
 k  (–3, 2)
x 7/6  x 5/6 x 7 /6  x5/6

9. 1/2 1/3
 1/2 1/3

x1/3 x 2  x  1  
 x1/2 x 2  x  1   1 
x 5 /6  x   1
 1 
 x 5/6  x   1
 x   x 
1
1 1/6
x2  1 
= 1/2 1/3
put Z   x   1 1
 1   1   x 
 x   1   x   1
 x   x 
After solving we get, P = 6, T = 2 and Q = 1
tan2 x
10. e sin 4xdx
Applying integration by parts
 sin 4xdx    e 
2
tan2 x
etan x
 2 tan x sec 2 x  sin 4xdx dx
1 tan2 x 1 2
 cos 4x   etan x tan x sec 2 x 2 2cos2 x  1  1 dx continue solving like this
2
= 
4
e
2 
   
11. Put z = cos x, dz = –sin x dx
t t 2
sin3 x 
f t    3 cos2 x 
dx    1  z2 z  3 dz

 
2 2
12. If a, b and c are odd integers then discriminant = b2 – 4ac  perfect square
 Roots are always irrational
If ac = 1  a = 1, c = 1 and b  3
 a, b and c = odd
 c(a – b + c) < 0  f(0) f(–1) < 0
   (–1, 0)
13.-14. Total points generated = 20

Two points can be selected in 20 C2  190 ways
(i) Number of points with all coordinates odd = 4
(ii) Number of points with x odd, y even = 6
11
(iii) Number of points with x even, y odd = 4

(iv) Number of points with both even = 6
 Required number of points = 4 C2  6 C2  4 C2  6 C2  42
42 21
(1) Required probability = 
190 95
(2) (x1  x2 and y1 = y2) = 2  5 = 10
10 1
Required probability = 
190 19
15. sin x + cos x = 1 + sin x cos x

t2  1
 t  1 (Let sin x + cos x = t)
2
2t = 2 + t2 – 1  t2 – 2t + 1 = 0
2
(t – 1) = 0  t = 1
 sin x + cos x = 1
  1
cos  x   
 4 2
 
x   2n 
4 4

x  2n 
4

 x = 2n or x = 2n + , n  I
2
16. sin4 x + cos4 x = sin x cos x

(sin2 x + cos2 x)2 – 2 sin2 x cos2 x = sin x cos x
1 – 2p2 = p ( sin x cos x = p)
(p + 1)(2p – 1) = 0
sin x cos x = –1 2 sin x cos x –1 = 0
sin x cos x = –1 sin 2x = 1
 
sin 2x = –2 (not possible) 2x = 2n +  x = (4n + 1)
2 4
 x    x   
17.-18. Graph of f  x   x-axis
 x    x   
y=1
y-axis
O    
SECTION – C
1. Let g(x) = (x + 1) p(x) – 1 ….. (1)

g(0) = g(1) = g(2) = ….. = g(11) = 0
 g(x) = kx(x – 1)(x – 2) ….. (x – 11) ….. (2)
Also, g(–1) = –1
1
 k
12
12
Now, from equation (1) and (2), we get

1
 x  1 p  x   1   x  x  1 x  2  .....  x  11
12
 p(12) = 0
n
2. C1, n C2 , nC3 an in A.P.
2n  n  1 n  n  1n  2 
n
2 6
 n = 2 or 7
Since n C3 demands that n should be  3 then n can not be 2
n=7
8
3. x0  2  y0  2
4
 Equation of the tangent is y  2x  6 which cuts x-axis at (3, 0)
Hence
 B  (3, 0) 
 AB  (3  2)iˆ  (0  2)jˆ and OB  3iˆ
 
 AB  OB  3
4. f(x) = –2 – 3x2 < 0  f(x) is decreasing

 f(f(f(x))) > f(f(–x))
 f(f(x)) < f(–x)  f(x) > –x
 30 – 2x + x3 > – x  x3 + x – 30 < 0
 (x – 3)(x2 + 3x + 10) < 0  x < 3
Positive values of integer x = 1, 2
x  sin y  2010
x  2010cos y  2009
5. substracting
sin y  2010cos y  1
 sin y = 1 + 2010 cos y
 
Possible if y   0  y 
2 2
 x = 2010 – 1 = 2009
 
2009  
 x  y   2
  2
1005 1005

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1

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. Angular momentum conservation

7. Since current leads the voltage

8. For 1 mole gas,

17. Here z is co-ordinate a+z z

3. When switch is open

7. KO2 has only unpaired e  remaining all are diamagnetic.

8. Both compounds resemble each other in solubility.

12. Order of reactivity towards E. A. substitution

16. Mixture contains NaOH + ZnSO4

Na2 ZnO2  2HCl  2NaCl  Zn  OH2 

H3C C CH2 CHO H3C CH2 C CH CHO

Mathematics PART – III

5. Image of P in x-axis is (1, –2) y

6. Radical centre of the circles described on the sides of a triangle y

8. f(x) is a decreasing function and for major axis to be x-axis

x 7/6  x 5/6 x 7 /6  x5/6

13.-14. Total points generated = 20

(iii) Number of points with x even, y odd = 4

15. sin x + cos x = 1 + sin x cos x

16. sin4 x + cos4 x = sin x cos x

1. Let g(x) = (x + 1) p(x) – 1 ….. (1)

Now, from equation (1) and (2), we get

4. f(x) = –2 – 3x2 < 0  f(x) is decreasing

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