Академический Документы
Профессиональный Документы
Культура Документы
Welcome
ITT Industries
2 4 October 2005
3
Fluid Technology Group
Fluid
Technology
3 4 October 2005
4
Advanced Water Treatment Group
Advanced
Water
Treatment Group
Biological
Aquious Disinfection
Treatment
Water Equipment
Sanitaire WEDECO
Technologies
ABJ C’Treat
Royce
PCI
Technologies
Hengtong Advanced
Water Treatment
Portacel
4 4 October 2005
WEDECO AG 5
WEDECO Structure
U
100 % UV-line of business
100 % 100 % 100 % Ozone 100 %
WEDECO AG Water WEDECO KATADYN WEDECO
Technology, Advanced UV Light WEDECO KATADYN
AG, Schweiz GmbH, Deutschland
Deutschland GmbH, Deutschland GmbH, Deutschland
WEDECO B.V. WEDECO KATADYN WEDECO UV Systems WEDECO VISA PCI WEDECO
Niederlande S.A., Frankreich Plc., Großbritannien GmbH, Österreich Inc.,USA
WEDECO Pty. Ltd. WEDECO Ltda. WEDECO WWT Ltd. WEDECO Ideal OZOMATIC
Australien Brasilien Neuseeland Horizons Inc., USA GmbH, Deutschland
WEDECO Ltd. WEDECO Tecnologie WEDECO Puro srl. WEDECO Rex S. A. WEDECO Ozotech Ltd.
Singapur Acque srl., Italien Italien Spanien Großbritannien
51%
WEDECO TRAILIGAZ
France
5 4 October 2005
6
What is OZONE?
Comparison of oxidants:
Molecular weight: 48 g/mol
Density @ 1013 mbar, 0°C: 2,14 kg/m³ - Chlorine 1,36 V
Max. limit for ambient level: 0,1 ppm - Oxygen (mol.)1,23 V
0,2 mg/m³air - Chlorinedioxide 1,27 V
Odor threshold: 0,01 ppm - OH radical 2,8 V
Redox potential: 2,07 V - Hypochlorite 1,49 V
Generator Generator
inlet outlet
Heat
Feedgas: Free oxygen atoms Product gas:
Oxygen molecules and Ozone-Feedgas mixture
oxygen molecules
7 4 October 2005
8
cooling 5 - 32 °C offgas
water
O3
air / O2
5,5 kV
feedgas ozone generator reaction tank
grounded
energy
(400 V)
8 4 October 2005
9
General Ozone Applications
Ozone Basics:
How it works in waste water !
10 4 October 2005
11
11 4 October 2005
12
APPLICATION EXAMPLES
Improvement of:
y BOD/COD-ratio
y flocculation / filtration
partial-oxidation
(cracking) Reduction of:
• colour
in industrial
Mineralisation of:
wastewater
y CKW´s
y Pesticides
complete
oxidation
End-of-the-pipe treatment:
• further COD reduction
Oxidation with OZONE for
• final desinfection
industrial wastewater treatment
12 4 October 2005
13
COD elimination by Ozone example
900 90
COD
800 80
COD elimination
700 70
500 50
400 40
300 30
200 20
100 10
0 0
0 500 1000 1500 2000 2500
Ozone dose [mg/l]
13 4 October 2005
14
Specific Elimination by Ozone example: toxic Kresol
16000 800
14000 700
12000 600
Kresol [mg/l]
COD [mg/l]
10000 500
8000 400
6000 300
4000 200
0 0
0 500 1000 1500 2000 2500
Ozone dose [mg/l]
14 4 October 2005
15
Ozone for COD reduction
15 4 October 2005
16
Ozone for specific elimination
Basic layout
oxidation loop for
waste water
treatment
17 4 October 2005
18
Design criteria
18 4 October 2005
19
Basic layout oxidation loop for waste water
treatment
Option:
Aeration of
biology
19 4 October 2005
20
Installation example
Scope included:
20 4 October 2005
21
Installation example
Scope included:
21 4 October 2005
22
Installation example
Scope included:
22 4 October 2005
23
PROJECT: KALUNDBORG
COD Removal
23 4 October 2005
24
- Kalundborg, DK -
25 4 October 2005
26
26 4 October 2005
27
Drinking Water Treatment
27 4 October 2005
28
Typical old design of DWTP
rawwater
Final desinfection
(Chlorine)
29 4 October 2005
30
Advanced DWTP
chemicals
Pre-oxidation
OZONE
rawwater
Final desinfection
Main-oxidation
UV / CHLORINE OZONE
rawwater
Final desinfection
Main-oxidation
UV / CHLORINE OZONE
31 4 October 2005
32
Pre-Ozonation
Pre-oxidation
OZONE
Applications:
¾1. Improving coagulation (impact on colloids and SS)
¾2. Iron & manganese oxidation
¾3. Taste and odor control
¾4. Color removal
¾5. Disinfection
¾6. THM pre-cursor oxidation
Pre-oxidation in combination with
Flocculation and/or Sandfiltration
32 4 October 2005
33
Pre-Ozonation
1. IMPROVED COAGULATION
33 4 October 2005
34
Pre-Ozonation
4. COLOR REMOVAL
– Color in surface water comes from natural
organic matters (humic, fulvic, tannic acids,…)
– These matters have often carbon-carbon
double bonds
– Ozone is known as strong double bond reagent
(POTABLE AND WASTE WATER)
36 4 October 2005
37
Pre-Ozonation
5. Disinfection
37 4 October 2005
38
Pre-Ozonation
5. Disinfection
Free Chlorine UV /
Chloramine Ozone
Microorganisms Chlorine dioxide Fluence
pH 8 - 9 pH 6 - 7
pH 6 - 7 pH 6 - 7 mJ/cm²
E.coli 0.034 - 95 - 180 0.4 - 0.75 0.02 8
0.05
Polio 1 1.1 - 2.5 770 - 3740 0.2 - 6.7 0.1 - 0.2 28
38 4 October 2005
39
Pre-Ozonation
6. THM´s (TroHaloMethanes)
39 4 October 2005
40
Pre-Ozonation
How ?
By replacing pre chlorination by OZONATION.
41 4 October 2005
42
Advanced DWTP with BAC
chemicals
Pre-oxidation
OZONE
rawwater
Final desinfection
Main-oxidation
UV / CHLORINE OZONE
42 4 October 2005
43
Main-Ozonation
Main-oxidation
OZONE
Applications:
¾ Reduction of dissolved organic material
¾ Taste and odor control (see pre-ozonation)
¾ Color removal (see pre-ozonation)
¾ THM-precursor oxidation (see pre-ozonation)
¾ Disinfection (see pre-ozonation)
43 4 October 2005
44
Main-Ozonation
44 4 October 2005
45
Treatment goals for Ozon
46 4 October 2005
47
WEDECO – MESSER
Keep it clear
and keep it
flowing
47 4 October 2005