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For – JEE (Advanced)
JEE-Chemistry
EXERCISE-01 CHECK YOUR GRASP
SELECT THE CORRECT ALTERNATIVE (ONLY ONE CORRECT ANSWER)
1. Which of the following equations represents a reaction that provides the heat of formation of ethane
(CH 3 CH 3 )?
(A) 2 C(s) + 6 H(g) CH3CH3(g) (B) 2 C(s) + 3 H2(g) CH3CH3(g)
(C) CH2 = CH2(g) + 2 H2(g) CH3CH3(g) (D) CH–CH(g) + 2 H2O(g) CH3CH3(g) + O2(g)
2. Which of the following equations represents a reaction that provides the heat of formation of CH3Cl?
(A) C(s) + HCl(g) + H2(g) CH3Cl(g)
(B) C(s) + 3/2 H2(g) + 1/2 Cl2(g) CH3Cl(g)
(C) C(s) + 3 H(g) + Cl(g) CH3Cl(g)
(D) CH4(g) + Cl2(g) CH3Cl(g) + HCl(g)
3. Use the given standard enthalpies of formation to determine the heat of reaction of the following
reaction:
TiCl4(g) + 2 H2O(g) TiO2(g) + 4 HCl(g)
o
H f TiCl 4(g) = –763.2 kJ/mole
H of TiO 2(g) = –944.7 kJ/mole
H of H 2O(g) = –241.8 kJ/mole
Hof HCl(g) = –92.3 kJ/mole
(A) – 278.1 (B) + 369.2 (C) + 67.1 (D) – 67.1
4. The heats of formation of CO2(g) and H2O(l) are –394 kJ/mole and –285.8 kJ/mole respectively. Using
the data for the follow i ng combustion react ion, calculate the heat of format ion of C 3 H 8 (g).
C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(l)
o
H = –2221.6 kJ
(A) 212.2 (B) – 143.3 (C) 185.4 (D) – 103.6
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5. The heats of formation of CO2(g) and H2O(l) are –394 kJ/mole and –285.8 kJ/mole respectively. Using
the data for the follow i ng combustion react ion, calculate the heat of format ion of C 2 H 2 (g).
2 C2H2(g) + 5 O2(g) 4 CO2(g) + 2 H2O(l)
Ho = – 2601 kJ
(A) – 238.6 (B) 253.2 (C) 238.7 (D) 226.7
6. Using the following information calculate the heat of formation of NaOH.
2 Na(s) + 2 H2O(l) 2 NaOH(s) + H2(g)
Ho = – 281.9 kJ
H of H 2O(l) = –285.8 kJ/mole
(A) – 141.6 (B) – 712.6 (C) – 426.8 (D) – 650.4
7. Using the following information calculate the heat of formation of CH4.
CH4(g) + 2 O2(g) CO2(g) + 2 H2O(l)
Ho = – 890.4 kJ
Hof CO2(g) = – 393.5 kJ/mole
Hof H 2O(l) = – 285.9 kJ/mole
(A) – 98.6 (B) – 65.5 (C) – 74.9 (D) – 43.5
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8. The heat of formation of CO2(g) is –394 kJ/mole and that of H2O(l) is –286 kJ/mole. The heat of combustion
of C2H4 is –1412 kJ/mole. What is the heat of formation of C2H4?
C2H4(g) + 3 O2(g) 2 CO2(g) + 2 H2O(l)
(A) +1360 (B) – 108 (C) + 52 (D) +108
9. What amount of heat energy (kJ) is released in the combustion of 12.0 g of C3H4?
(Atomic weights: C = 12.01, H = 1.008, O = 16.00).
C3H4(g) + 4 O2(g) 3 CO2(g) + 2 H2O(l)
o
H = –1939.1 kJ
(A) 725 (B) 504 (C) 783 (D) 581
10. The standard heat of combustion of solid boron is equal to :-
1 1
(A) H° f (B 2O 3 ) (B) H° f(B 2O 3 ) (C) 2H° f(B 2O 3 ) (D) H° f(B 2O 3 )
2 2
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∆ H° 1
∆ H° 1 ∆ H° 1 (∆ H° 1 − ∆ H° 2 )
(A) (B) (C) 2 − ∆ H ° (D)
2 2 + ∆ H° 2 2 2
24. From the following data of H, of the following reaction,
1
C(s) + O (g) CO(g) H = –110 kJ
2 2
C(s) + H 2 O(g) CO(g) + H 2 (g) H = 132 kJ
What is the mole composition of the mixture of steam and oxygen on being passed over coke at 1273K,
keeping temperature constant :-
(A) 0.5 : 1 (B) 0.6 : 1 (C) 0.8 : 1 (D) 1 : 1
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(A) H 2 (g) + I 2 (g) 2HI (g) (B) HCI (aq) + NaOH (aq) NaCl(aq) + H 2O (l)
(C) C(s) + O 2 (g) CO 2 (g) (D) N 2 (g) + 3H 2(g) 2 NH 3 (g)
16. H r of which of the following reactions is zero ?
(A) H 2 (g) 2H + (g) + 2e – (B) 2H (g) + aq 2H + (aq) + 2e –
(C) 2H (g) 2H + (g) + 2e – (D) H 2 (g) + aq 2H + (aq) + 2e –
17. H0f of water is –285.8 kJ mol –1 . If enthalpy of neutralisation of monoacid strong base is
–57.3 kJ mol –1, H0f of OH – ion will be ?
(A) –228.5 kJ mol –1 (B) 228.5 kJ mol –1 (C) 114.25 kJ mol –1 (D) –114.25 kJ mol –1
18. 4 grams of sodium hydroxide pellets were dissolved in 100 cm3 of water. The temperature before adding
the sodium hydroxide pellets was 25 degrees C, and after adding the pellets it was 35 degrees C. Calculate
the enthalpy change in kJ/mole of the reaction (Specific heat capacity of water = 4.2 J/K/g)
(A) 42 kJ/mole (B) 4.2 kJ/mole (C) 4200 kJ/mole (D) none
19. 50.0 mL of 0.10 M HCl is mixed with 50.0 mL of 0.10 M NaOH. The solution temperature rises by
3.0°C. Calculate the enthalpy of neutralization per mol of HCl.
(A) –2.5 × 10 2 kJ (B) –1.3 × 10 2 kJ (C) –8.4 × 10 1 kJ (D) –6.3 × 10 1 kJ
20. Which of the following statements is (are) correct ?
(A) the reaction between the strong acid and strong base takes place with the evolution of heat
(B) H neut. of weak acid/strong base is less than the H neut. of strong acid/strong base
1
C2H4(g) + H2O (g) ∆ H° = 45.54 kJ
C 2 H 5 OH (g)
2 CH CHO(g) + H (g)
3 2 ∆ H° = 68.91 kJ
if the molar ratio of C2H4 to CH3CHO is 8 : 1 in a set of product gases, then the energy involved in the
decomposition of 1 mole of ethanol is ?
(A) 65.98 kJ (B) 48.137 kJ (C) 48.46 kJ (D) 57.22 kJ
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Column-I Column-II
(A) Arrhenius equation (p) Variation of enthalpy of a reaction with
temperature
(B) Kirchhoff equation (q) Variation of rate constant with temperature
(C) Second law of thermodynamics (r) Entropy of an isolated system tends to
increase and reach a maximum value
(D) Hess's law of constant heat summation (s) Enthalpy change in a reaction is always
constant and independent of the manner in
which the reaction occurs.
3. Column-I Column-II
(A) S(g) + O 2(g) SO 2 (g) ; H (p) Heat of solution
(B) CH 4(g) + 2O 2(g) CO 2(g) (q) Heat of neutralisation
+ 2H 2O(l) ; H
(C) NaOH(s) + aq NaOH (aq) ; H (r) Heat of formation
(D) NaOH(aq) + HCl(aq) NaCl (aq) (s) Heat of combustion
+ H 2 O(l) ; H
1. Statement-I : Enthalpy of neutralization of CH 3 COOH by NaOH is less than that of HCl by NaOH.
Because
Statement-II : Enthalpy of neutralization of CH 3COOH is less because of the absorption of heat in the
ionization process.
2. Statement-I : Enthalpy changes are positive when Na 2 SO 4 .10H 2 O, CuSO 4.5H 2 O and salts like NaCl,
KCl, etc., which do not form hydrates are dissolved in water. But enthalpy changes are negative when
anhydrous salts capable of forming hydrates are dissolved in water.
Because
Statement-II : The difference in the behaviour is due to large differences in the molecular weight of hydrated
and anhydrous salts. The substances with larger molecular weights usually show positive enthalpy changes
on dissolution.
3. Statement-I : Heat of neutralisation of HF (aq.), a weak acid, with NaOH (aq.) is more than 13.7 kcal,
in an exothermic reaction.
Because
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Because
Statement-II : Enthalpy of formation and bond energy both involve the formation of one mole of HCl
from the elements.
Because
Statement-II : Gaseous molecules are far apart of each other due to less attraction.
Because
Statement-II : Enthalpy change is negative for the condensation reaction, H 2O(g) H 2 O(l).
7. Statement-I : As temperature increases, heat of reaction also increases for exothermic as well as for
endothermic reactions.
Because
Because
Comp rehensi on # 1
The industrial preparation of a polymer, PTFE, is based on the synthesis of the monomer CF2 = CF2, which
is produced according to reaction (i) below :
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(A) 69.9472 kJ/mol (B) 4054.375 kJ/mol (C) 139.8948 kJ/mol (D) 8108.750 kJ/mol
3. Given that the enthalpy of solution of the hydrated copper (II) sulphate is +11.3 kJ/mol, what is the
enthalpy of hydration of the anhydrous solid.
(A) 97.321 kJ/mol (B) –97.321 kJ/mol (C) –77.971 kJ/mol (D) 77.971 kJ/mol
Comp rehensi on # 3
The Born Haber cycle below represents the energy changes occurring at 298K when KH is formed from its elements
H
2K(s) + H2(g) 2KH(s)
v x
2K(g) + 2H(g)
w y z
+ –
2K (g) + 2H(g)
H atomisation K = 90 kJ/mol
Hionisation K = 418 kJ/mol
Hdissociation H = 436 kJ/mol
H electron affinity H = –78 kJ/mol
Hlattice KH = –710 kJ/mol
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(ii) Hi of K
2. Which of v to y is
6. On complete reaction with water, 0.1 g of KH gave a solution requiring 25 cm3 of 0.1M HCl for neutralisation.
Calculate the relative atomic mass of potassium from this information.
Tr u e / Fals e
1. F 2. T 3. T 4. T 5. T 6. F 7. F 8. F
9. F
F i ll i n t h e B lank s
1. exothermic 2. endothermic 3. heat of transition 4. +33 kJ mol–1
5. –18 kcal mol–1 6. –57.2 7. –110.5 8. –3 RT
Matc h th e C o lu m n
1. (A) - q, (B) - r, (C) - s, (D) - p, (E) - t 2. (A) - q, (B) - p, (C) - r, (D) - s
3. (A) - r, (B) - s, (C) - p, (D) - q
A s s er ti o n - R eas o n Q u es ti o ns
1. (A) 2. (C) 3. (C) 4. (A) 5. (D) 6. (A) 7. (D) 8. (B)
C o mp rehe ns i o n B as ed Q u e st i o ns
Comprehension # 1 : 1. (B) 2. (i) (B) (ii) (C)
C o mp re he n s i o n # 2 : 1. (B) 2. (A) 3. (C)
Comprehension #3 : 1. (i) H = (v + w + x + y + z) (ii) w/2 (iii) y/2 (iv) z/2
2. (i) y (ii) w
3. –124 kJ/mol 4. –62 kJ/mol 6. 39
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1. When 2 moles of C2H6 are completely burnt 3120 kJ of heat is liberated. Calculate the heat of formation,
H° f for C 2H 6. Give H° f for CO 2(g) & H 2O( l ) are –395 & –286 kJ respectively.
–1
2. The standard heats of formation of CH4(g), CO2(g) and H2O(l) are –76.2, –398.8, –241.6 kJ mol . Calculate
3
amount of heat evolved by burning 1m of methane measured under normal (STP) conditions.
2+
3. Calculate the enthalpy change when infinitely dilute solution of CaCl2 and Na2CO 3 mixed H° f for Ca (aq),
2– –1
CO 3 (aq) and CaCO 3(s) are –129.80, –161.65, –288.5 kcal mol respectively.
4. The enthalpies of neutralization of NaOH & NH4OH by HCl are –13680 calories and –12270 cal respectively.
What would be the enthalpy change if one gram equivalent of NaOH is added to one gram equivalent
of NH 4 Cl is solution ? Assume that NH 4OH and NaCl are quantitatively obtained.
5. The heat of solution of anhydrous CuSO 4 is –15.9 kcal and that of CuSO 4.5H 2O is 2.8 kcal. Calculate
the heat of hydration of CuSO 4 .
1 1
6. The heat of reaction H 2(g) + Cl 2(g) HCl(g) at 27°C is –22.1 kcal. Calculate the heat of reaction
2 2
at 77°C. The molar heat capacities at constant pressure at 27°C for hydrogen, chlorine & HCl are 6.82,
–1
7.70 & 6.80 cal mol respectively.
7. Calculate standard heats of formation of carbon-di-sulphide ( l). Given the standard heat of combustion of
–1
carbon (s), sulphur (s) & carbon-di-sulphide ( l ) are : –393.3, –293.72 and–1108.76 kJ mol respectively.
–1
8. The standard enthalpy of neutralization of KOH with (a) HCN (b) HCl in dilute solution is –2480 cal. geq
–1
and –13.68 kcal, geq respectively. Find the enthalpy of dissociation of HCN at the same temperature.
9. At 300K, the standard enthalpies of formation of C 6H 5 COOH(s), CO 2 (g) & H 2 O(l) are; –408, –393 &
–1
–286 kJ mol respectively. Calculate the heat of combustion of benzoic acid at :
(i) constant pressure & (ii) constant volume.
10. The heat liberated on complete combustion of 7.8 g of benzene is 327 kJ. This heat has been measured
at constant volume & at 27°C. Calculate the heat of combustion of benzene at constant pressure.
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–
11. If the enthalpy of formation of HCl (g) and Cl (aq) are –92.3 kJ/mole and –167.44 kJ/mol, find the enthalpy
of solution of hydrogen chloride gas.
12. 0.16 g of methane was subjected to combustion at 27°C in a bomb calorimeter. The temperature of calorimeter
system (including water) was found to rise by 0.5°C. Calculate the heat of combustion of methane at
(i) constant volume (ii) constant pressure.
–1 –1 –1
The thermal capacity of calorimeter system is 17.7 kJ K . (R = 8.313 mol K )
13. W hen 1.0 g of fr uctose C 6 H 12 O 6 (s) is burned in oxygen i n a bomb calorimeter, the temperature of the
calorimeter water increases by 1.56°C. If the heat capacity of the calorimeter and its contents is 10.0 kJ/°C.
Calculate the enthalpy of combustion of fructose at 298 K.
–1
14. The enthalpy of dissociation of PH3 is 954 kJ/mol and that of P2H4 is 1.485 M J mol . What is the bond
enthlapy of the P–P bond ?
15. Using the bond enthalpy data given below, calculate the enthalpy change for the reaction,
C 2H 4(g) + H 2 (g) C 2H 6 (g)
Data :
Bond C – C C = C C – H H – H
Bond Enthalpy 336.81 kJ/mol 606.68 kJ/mol 410.87 kJ/mol 431.79 kJ/mol
E 93
17. Find the enthalpy of S–S bond from the following data.
18. Calculate the electron affinity of fluorine atom using the following data. Make Born–Haber's cycle. All the
–1
values are in kJ mol at 25°C, H diss (F 2 ) = 160, H of (NaF(s)) = –571.I.E. [Na(g)] = 494,
The enthalpy of sublimation of Cs, enthalpy of dissociation of chlorine, ionization energy of Cs & electron
–1
affinity of chlorine are 81.2, 243.0, 375.7 and –348.3 kJ mol . The energy change involved in the formation
–1
of CsCl is –388.6 kJ mol . Calculate the lattice energy of CsCl.
20. The enthalpy of formation of ethane, ethylene and benzene from the gaseous atom are –2839.2, –2275.2
–1
and –5506 kJ mol respectively. Calculate the resonance energy of benzene. The bond enthalpy of
C–H bond is given as equal to +410.87 kJ/mol.
22. A bomb containing 5.4g of Al and 15.97g of Fe2O3 is placed in an ice calorimeter containing initially 8 kg
of ice and 8 kg of water. The reaction 2Al(s) + Fe2O3(s) Al2O3(s) + 2Fe(s) is set off by remote control and
it is then observed that the calorimeter contains 7.746 kg of ice and 8.254 kg of water. Find the H for the
above reaction.
23. A sample of the sugar Dribose (C5H10O5) of mass 0.727g was placed in a calorimeter and then ignited in
the presence of excess oxygen. The temperature raise by 0.910 K. In a separate experiment in the same
calorimeter, the combustion of 0.825g of benzoic acid, for which the internal energy of combustion is
3251kJ mol 1 , gave a temperature rise of 1.940K. Calculate the internal energy of combustion of
Dribose and its enthalpy of formation.
24. T he heat of combustion of formaldehyde (g) is 134 kcal mole 1 and the heat of combust ion of
paraformaldehyde(s) is 122 kcal per (1/n) (CH2O)n. Calculate the heat of polymerization of formaldehyde
to paraformaldehyde.
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1. For the reaction cis-2-butene trans-2-butene and cis-2-butene 1-butene, H = – 950 and
+ 1771 cal/mol respectively. The heat of combustion of 1-butene is –649.8 kcal/mol. Determine the heat
of combustion of trans-2-butene. Also calculate the bond energy of C=C bond in trans-2-butene. Given B.E
of C = O = 196, O—H = 110, O = O = 118, C—C = 80 and C—H = 98 kcal/mol respectively. Hv(H2O)
= 11 kcal/mol.
2. Using the data (all values are in kJ/mol at 25°C) given below :
(i) Enthalpy of polymerization of ethylene = – 72.
(ii) Enthalpy of formation of benzene () = 49
(iii) Enthalpy of vaporization of benzene () = 30
(iv) Resonance energy of benzene () = – 152
(v) Heat of formation of gaseous atoms from the elements in their standard states H = 218, C = 715.
Average bond energy of C—H = 415. Calculate the B.E. of C—C and C= C. [A : 331 and 590 kJ/mol]
3. Determine resonance energy of benzene [C6H6 ()] from the following information :
H°f of C6H6 () = + 49 kJ ;
H°f of C2H2 (g) = +75 kJ H°v of C6H6 () = + 45 kJ
B.E. C C = 930 kJ/mol ; C = C = 615 kJ/mol ; C — C = 348 kJ/mol
4. Consider the following thermodynamic data :
Enthalpy of formation of CaC2 (s) = – 60 kJ/mol ;
Enthalpy of sublimation of Ca (s) = 179 kJ/mol ;
Enthalpy of sublimation of C (s) = 718 kJ/mol ;
First ionization energy of Ca (g) = 590 kJ/mol ;
Second ionization energy of Ca (g) = 1143 kJ/mol ;
Bond energy of C2 (g) = 614 kJ/mol ;
First electron affinity of C2 (g) = –315 kJ/mol ;
Second electron affinity of C2 (g) = +410 kJ/mol ;
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1
589.7 kJ mol and 1145 kJ mol ; enthalpy of vaporization of bromine, + 30.91kJmol 1; dissociation
1
enthalpy of Br2(g), +192.9 kJmol1; electron gain enthalpy of Br(g), 331.0kJmol1; enthalpy of solution of
CaBr2(s), 103.1 kJ mol1; enthalpy of hydration of Br (g), 337 kJmol1.
1. If at 298 K the bond energies of C–H, C–C, C=C and H–H bonds are respectively 414, 347, 615 and
435 kJ mol –1 , the value of enthalpy change for the reaction : [AIEEE-2003]
2. The enthalpies of combustion of carbon and carbon monoxide are –393.5 and –283 kJ mol–1 respectively.
The enthalpy of formation of carbon monoxide per mole :- [AIEEE-2004]
3. Consider the reaction : N2 + 3H2 2NH3 carried out at constant temperature and pressure, if H and
U are the enthalpy and internal energy changes for the reaction, which of the following expressions is
true? [AIEEE-2005]
(1) H = U (2) H = 0
4. If the bond dissociation energies of XY, X 2 and Y 2 (all diatomic molecules) are in the ratio of 1 : 1 : 0.5
and f H for the formation of XY is –200 kJ mol –1 . The bond dissociation energy of X 2 will be :-
5. The standard enthlapy of formation (fH°) at 298K for methane, CH4(g), is –74.8 kJ mol–1. The additional
information required to determine the average energy for C–H bond formation would be:-
(2) The first four ionization energies of carbon and electron gain enthalpy of hydrogen
6. The enthalpy changes for the following processes are listed below : [AIEEE-2006]
Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard enthalpy of formation
for ICl(g) is :-
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7. (H – U) for the formation of carbon monoxide (CO) from its elements at 298 K is
(R = 8.314 J K –1 mol –1 ) [AIEEE-2006]
1 Θ Θ
1 ∆ diss H ∆
Θ
∆
Cl 2(g) 2 → Cl –(g) →
hyd H
Cl(g) →
eg H
Cl –(aq) [AIEEE-2008]
2
1
The energy involved in the conversion of Cl (g) to Cl –(aq)
2 2
Θ Θ Θ
(using the data diss H Cl2 = 240 kJ mol –1 , eg H Cl = –349 kJ mol–1, hyd H Cl − = –381 kJ mol–1) will be:-
10.
+
On the basis of the following thermochemical data : ∆ G f H ( aq ) = 0
0
( )
H 2 O( ) H + (aq) + OH – (aq) ; H = 57.32 kJ
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H 2(g) + O (g) H 2 O ( ) ; H = –286.20 kJ
2 2
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1 1
(A) C (diamond) + O 2 (g) CO 2(g) (B) H (g) + F (g) HF(g)
2 2 2 2
1
(C) N 2(g) + 3H 2(g) 2NH 3(g) (D) CO(g) + O (g) CO 2(g)
2 2
2. H° f for CO 2(g), CO(g) and H 2O(g) are –393.5, –110.5 and –241.8 kJ mol –1 respectively. The standard
enthalpy change (in kJ) for the relation : [IIT-JEE-2000]
(A) Zero
5. Diborane is a potential rocket fuel which undergoes combustion according to the reaction, [IIT-JEE-2000]
From the following data, calculate the enthalpy change for the combustion of diborane :
3
2B(s) + O (g) B 2O 3(s) ; H = –1273 kJ
2 2
1
H2(g) + O (g) H 2O(l) ; H = –286 kJ
2 2
H 2O( l ) H 2O(g) ; H = 44 kJ
6. Estimate the average S–F bond energy in SF 6. The H° f values of SF 6(g), S(g) and F(g) are –1100, 275
and 80 kJ/mol respectively. [IIT-JEE-1999, 2005]
7. From the following data, calculate the enthalpy change for the combustion of cyclopropane at 298 K. The
enthalpy of formation of CO2(g), H2O( l) and propene (g) are –393.5, –285.8 & 20.42 kJ/mol respectively.
The enthalpy of isomerisation of cyclopropane to propene is –33.0 kJ/mol. [IIT-JEE-1998, 2005]
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–1
8. Using the data provided, calculate the multiple bond energy (kJ mol ) of a C C bond in C2H2. That energy
–1
is (take the bond energy of a C–H bond as 350 kJ mol .) [JEE 2012]
–1
2 C(s) + H 2(g) C 2H 2 (g) H = 225 kJ mol
2 C(s) 2C(g) H = 1410 kJ mol –1
H 2(g) 2H(g) H = 330 kJ mol –1
(A) 1165 (B) 837 (C) 865 (D) 815
9. In a constant volume calorimeter, 3.5 g of a gas with molecular weight 28 was burnt in excess oxygen at 298.0
K. The temperature of the calorimeter was found to increase from 298.0 K to 298.45 K due to the combustion
process. Given that the heat capacity of the calorimeter is 2.5 kJ K–1, the numerical value for the enthalpy of
combustion of the gas in kJ mol–1 is [JEE 2009]
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