Concentración (ppm) T %T A (-logT) A (2-log%T) log T

0 0
0.815 0.10 10 1.00 1.00 -1.00
0.671 0.20 20 0.824 0.699 -0.699
0.569 0.30 30 0.699 0.523 -0.523
0.46 0.40 40 0.523 0.398 -0.398
0.324 0.50 50 0.398 0.301 -0.301
0.245 0.60 60 0.301 0.222 -0.222
0.126 0.70 70 0.155 0.155 -0.155
0.057 0.80 80 0.007 0.097 -0.097
0.018 0.90 90 0.0220 0.0458 -0.0458

1.00
0.90
0.80
0.70
0.60
0.50
Transmitancia (T)
0.40
0.30
0.20
0.10
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Concentración (ppm)
 1.20
0.00
1.00 0 0.1 0.2 0.3 0.4 0.5
-0.20
0.80
-0.40
0.60
Absorción (A)
0.40 Log T -0.60

0.20 -0.80
0.00 -1.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Concentración (ppm) -1.20
Concentración (ppm

100
90 pendiente -96.512879928
80
f(x) = - 96.512879928x + 85.2272011737
70 R² = 0.9862007781
60
50
Transmitancia (%T)
40
30
20
10
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Concentración (ppm)
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Concentración (ppm)
 T %T log T 0,434/(T*logT) |0,434/(T*logT)|
0.0 0.0
0.02 2 -1.699 -12.8 12.8
CURVA D
0.05 5 -1.301 -6.7 6.67 14.0
0.08 8 -1.097 -4.9 4.95
0.10 10 -1.000 -4.3 4.34 12.0
0.20 20 -0.699 -3.1 3.10
10.0
0.30 30 -0.523 -2.8 2.77
0.37 37 -0.432 -2.7 2.72 |0,434/(T*logT)| 8.0
0.40 40 -0.398 -2.7 2.73
6.0
0.50 50 -0.301 -2.9 2.88
0.60 60 -0.222 -3.3 3.26 4.0
0.70 70 -0.155 -4.0 4.00
0.80 80 -0.097 -5.6 5.60 2.0
0.82 82 -0.086 -6.1 6.14 0.0
0.85 85 -0.071 -7.2 7.23 0 10 20
0.88 88 -0.056 -8.9 8.88
0.90 90 -0.046 -10.5 10.5
1.0 100 0.000
 CURVA DE CROWFORD
14.0

12.0

10.0

(T*logT)| 8.0

6.0

4.0

2.0

0.0
0 10 20 30 40 50 60 70 80 90 100
%T
Concentración (ppm) log C %T 100-%T
0
10 1.00 10 90.0 CURVA DE RINGBOM
9 0.954 20 80.0 100.0
8 0.903 30 70.0 90.0
7 0.845 40 60.0 80.0
6 0.778 50 50.0 70.0
60.0
5 0.699 60 40.0
50.0
4 0.602 70 30.0 100 - %T
40.0
3 0.477 80 20.0 30.0
2 0.301 90 10.0 20.0
1 0.000 100 10.0
0.0
0.20 0.30 0.40 0.50 0.60 0.70
log C
 CURVA DE RINGBOM
0
0
0
0
0
0
0
0
0
0
0
0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 1.10
log C
Intervalo de trabajo (ppm) concentración (M) Absorbancia T %T 100-%T
0.4 6.295E-06 0.201 0.629 62.9 37.1
0.5 7.868E-06 0.252 0.560 56.0 44.0
0.6 9.442E-06 0.302 0.499 49.9 50.1
0.7 1.102E-05 0.353 0.444 44.4 55.6
0.8 1.259E-05 0.403 0.395 39.5 60.5
0.9 1.416E-05 0.453 0.352 35.2 64.8
1.0 1.574E-05 0.504 0.314 31.4 68.6
1.1 1.731E-05 0.554 0.279 27.9 72.1
1.2 1.888E-05 0.604 0.249 24.9 75.1
1.3 2.046E-05 0.655 0.221 22.1 77.9
1.4 2.203E-05 0.705 0.197 19.7 80.3
1.5 2.360E-05 0.755 0.176 17.6 82.4
1.6 2.518E-05 0.806 0.156 15.6 84.4
1.7 2.675E-05 0.856 0.139 13.9 86.1
1.8 2.833E-05 0.906 0.124 12.4 87.6
1.9 2.990E-05 0.957 0.110 11.0 89.0
2.0 3.147E-05 1.01 0.098 9.8 90.2
2.1 3.305E-05 1.06 0.088 8.8 91.2
2.2 3.462E-05 1.11 0.078 7.8 92.2
2.3 3.619E-05 1.16 0.069 6.9 93.1
2.4 3.777E-05 1.21 0.062 6.2 93.8
2.5 3.934E-05 1.26 0.055 5.5 94.5
2.6 4.092E-05 1.31 0.049 4.9 95.1
2.7 4.249E-05 1.36 0.044 4.4 95.6
2.8 4.406E-05 1.41 0.039 3.9 96.1
2.9 4.564E-05 1.46 0.035 3.5 96.5
3.0 4.721E-05 1.51 0.031 3.1 96.9

pendiente 0.50357222
intersecto 0.00000000
mínimo error de T 37%
mínimo error de A 0.432
mínimo error de c (ppm) 0.857
 log c
-0.39794 1.600
-0.30103
1.400 f(x) = 0.5035722154x - 1.70930016567428E-16
-0.2218487 R² = 1
-0.154902 1.200
-0.09691 1.000
-0.0457575 0.800
-4.8216E-17 Absorbancia
0.600
0.04139269
0.07918125 0.400
0.11394335 0.200
0.14612804
0.000
0.17609126 0 0.5 1 1.5 2 2.5 3 3.5
0.20411998
Concentración (ppm)
0.23044892
0.25527251
0.2787536
0.30103 Curva de Ringbom
0.32221929 120.0
0.34242268
0.36172784 100.0
0.38021124 80.0
0.39794001
60.0
0.41497335 100-%T
0.43136376 40.0
0.44715803
20.0
0.462398
0.47712125 0.0
-0.6 -0.4 -0.2 0 0.2 0.4 0.6
log c
 Fe (ppm) Xi Absorbancia (Yi) Yi cal Yi-Yi cal (Yi-Yi cal)^2 Xi*Yi Xi^2
1 0.018 0.022 0.0201 0.0019 0.000004 0.00 0.000
2 0.057 0.071 0.0677 0.00330 0.000011 0.00405 0.003
3 0.126 0.155 0.1519 0.0031 0.000009 0.0195 0.016
4 0.245 0.301 0.297 0.0038 0.000015 0.0737 0.060
5 0.324 0.398 0.394 0.0044 0.000019 0.129 0.105
6 0.460 0.523 0.560 -0.03663 0.001342 0.241 0.212
7 0.569 0.699 0.693 0.0063 0.000040 0.398 0.324
8 0.671 0.824 0.817 0.00680 0.000046 0.55 0.450
9 0.815 1.00 0.993 0.00703 0.000049 0.82 0.664
10
11
SUM 3.285 3.99 3.99 0.0000 0.001535 2.233 1.83
PROM 0.365 0.444
pendiente 1.2206809266
intersecto -0.0018818716 1.20

1.00
f(x) = 1.2206809266x - 0.0018818716
0.80 R² = 0.9983807802

0.60
Absorbancia
0.40

0.20

0.00
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900
Concentración (ppm)
 Xi-Xmed (Xi-Xmed)^2
-0.347 0.120 N 11
-0.308 0.095 N-2 9
-0.239 0.057 ∑(Yi-Yical)^2/9 0.00017058
-0.120 0.014 Error típico (Sy/x) 0.01306047
-0.041 0.002 raíz ∑(Xi-Xmed)^2 0.79702698
0.095 0.009 Error pendiente (Sb) 0.01638648
0.204 0.042 N∑(Xi-Xmed)^2 6.987772
0.306 0.094 ∑Xi^2/celda M8 0.26249812
0.450 0.203 Error ordenada (Sa) 0.5123457
�=(0,3701±0,004783)𝑐+(0,01111±0,47
18)
0.000 0.635

mínimo error de T 37%

mínimo error de A (Yo) 0.432
mínimo error de c (ppm) 0.355
Por factor de dilución 2.5
0.89

00 0.800 0.900
 Error de la concentración (incertidumbre)
pendiente^2 1.49006192 pendiente^2 1.49006192
(Yo-Ymed) -0.011868
(Yo-Ymed)^2 1.409E-04 (Ymedia)^2 0.197
pend^2*∑(Xi-Xmed)^2 0.94656482 pend^2*∑(Xi-Xmed)^2 0.94656482
1/m 0.33333333 celda R4/ celda R5 0.20795207
1/n 0.09090909 1/n 0.09090909
1/m+1/n 0.42424242 suma celdas R6+R7 0.29886116
celda P4/celda P5 1.488E-04
celda P8+celda P9 4.244E-01
raiz 0.65145317 raiz 0.54668195
Sy/x/b 0.01069933 Sy/x/b 0.01069933
Error con réplicas (Sxo) 0.00697 Error sin réplica (Sxo) 0.00585
 MÉTODO 1 MÉTODO 2
Blanco Absorbancia Fe (ppm) Xi Absorbancia (Yi) Yi cal
1 0.018 0.022 0.0201
2 0.00400 0.057 0.071 0.0677
3 0.00700 0.126 0.155 0.1519
4 -0.00500 0.245 0.301 0.297
5 0.324 0.398 0.394
6 0.00500 0.460 0.523 0.560
7 0.00400 0.569 0.699 0.693
8 0.671 0.824 0.817
9 0.815 1.00 0.993
10 0.00700
promedio 0.003667
desv. Estandar (S) 0.0044572 pendiente 1.2206809266
3S 0.0134 intersecto -0.0018818716
LOD Señal 0.0170 Señal blanco -0.0019 x=0 ; y=A
Concentración (M)
2.48734E-07 ??? desv. Estandar (Sy/x) 0.01306047
Error tipico
Concentración (ppm) 0.014 3(Sy/x) 0.0391814019
LOD Señal 0.0373 ???
Concentración (M) 5.445186919E-07
LOD en ppm 0.0154997 Concentración (ppm) 0.0321 ???
RECUERDA
? QUE ESTE MÉTODO ES UN ESTIMATIVO, CUANDO NO HAY BLANCOS
2
Yi-Yi cal (Yi-Yi cal)^2
0.0019 0.000004 1.20

0.0033 0.0000109 1.00

0.0031 0.000009 f(x) = 1.2206809266x - 0.0018818716
0.80 R² = 0.9983807802
0.0038 0.000015
0.0044 0.000019 0.60
Absorbancia
-0.0366 0.001342
0.0063 0.000040 0.40
0.0068 0.0000463
0.20
0.0070 0.0000494
0.00
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900
0.001535 Concentración (ppm)

0.03040592 Calculada

HAY BLANCOS
 LOD=3SB/m
0.01095422

0.01095422 OK Metodo 3
18716

600 0.700 0.800 0.900

 [Cd] (M) [R] (M) Volumen inicial
1.25E-04 1.25E-04 10 Ml
Solución volumen Cd (mL) volumen R (mL) Absorbancia (390nm) Moles Cd Moles R
0 10 0 0.000 1.25E-06 0.00E+00
1 9 1 0.174 1.13E-06 1.25E-07
2 8 2 0.353 1.00E-06 2.50E-07
3 7 3 0.530 8.75E-07 3.75E-07
4 6 4 0.672 7.50E-07 5.00E-07
5 5 5 0.723 6.25E-07 6.25E-07
6 4 6 0.673 5.00E-07 7.50E-07
7 3 7 0.537 3.75E-07 8.75E-07
8 2 8 0.358 2.50E-07 1.00E-06
9 1 9 0.180 1.25E-07 1.13E-06
10 0 10 0.000 0.00E+00 1.25E-06
 XR X Cd [Cd] inicial [R] inicial
0.00E+00 1.00E+00 1.25E-04 0.00E+00 MÉTODO DE JOBS
1.00E-01
2.00E-01 0.800
3.00E-01 0.700
4.00E-01
0.600
5.00E-01
6.00E-01 0.500
7.00E-01 0.400
8.00E-01 Absorbancia
9.00E-01 0.300
1.00E+00 0.200
0.100
0.000
0.00E+00 2.00E-01 4.00E-01 6.00E-01 8.00E-01 1
XR
MÉTODO DE JOBS

01 4.00E-01 6.00E-01 8.00E-01 1.00E+00 1.20E+00

XR
[1,10 fenantrolina] (M) L
7.12E-04
1,10 fenantrolina (mL) Absorbancia 510nm moles L [L] diluiada a 25 mL moles Fe 2+
2.0 0.240 1.42E-06 5.70E-05
3.0 0.360 0.00E+00
4.0 0.480 0.00E+00
5.0 0.593 0.00E+00
6.0 0.700 0.00E+00
8.0 0.720 0.00E+00
10.0 0.720 0.00E+00
12.0 0.720 0.00E+00

Fe 2+
Volumen (mL) 2.0
Concentración (M) 7.12E-04
La solución se diluye a 25 ml
[Fe 2+] diluiada a 25 mL [L]/[Fe 2+]
0.00E+00 Métod
12.000

10.000

8.000

6.000
Absorbancia
4.000

2.000

0.000
0.00 2.00
 Método de Jones
12.000

10.000

8.000

6.000
ncia
4.000

2.000

0.000
0.00 2.00 4.00 6.00 8.00 10.00 12.00

[L]/[Fe 2+]