1

91. A student performs experiments to obtain the

values of molar specific heat capacities at
constant pressure (C p) and constant volume

(Cr) for different gases or mixture of gases.

Which of the following set of values in
cal mo1-11C1 can be reliable ?

I I I I I I I V V
C p 3 5 1 0 4 5

C v 1 3 8 1 7

(1) All sets except V

(2) Sets I, II, III only
(3) Sets II and III only
(4) Set II only
92. 4 moles of mono atomic gas, 2 moles of
diatomic gas and 1 mole of triatomic gas
(7 = 4/3) all at room temperature are mixed
together. Quantity of heat energy required to
rise the temperature of mixture of gases by
10K isobarically is
SEC : SR 220 cal
(1) 110 cal (2) (3) 330 cal (4)
 420 cal temperature
93. 2 litre changes from
of N2 gas 127 °C to
initially at a,
pressure of 4001C .

105 Nnz has-2

Percentage

to double its change in

volume pressure of
isobarically. gas is
Quantity of (1) 30 % (2) 50
heat energy %
required is (3) 82.5 % (4)
100 %
(1) 850J (2)
700 J 95. Two moles
(3) 1400 J (4) of an ideal
2800 J gas is
carried
94. A triatomic
gas of y = along a
4/3 cyclic process
undergoes
a ABCA as
process C= shown. If
Cv - R
1200J of heat
during
which energy is
 withdrawn 96. Oxygen
(02) gas
from the gas
during the undergoes
a
cyclic
thermodyna
process, find
mic process
work done
as shown.
during the
Specific heat
process from
of the gas
B to C ?
during the
A
process A to
C
B is

sn. 500K -------

300K --------
A

Volume (V)
(1) - 2520J (2)
- 3520 J
(3) - 4520J (4)
- 6520 J
 D 0. Assume a
A
T diatomic gas
E
(considered
:
2 to be ideal) is
4
. used in a
0
9
carnot
. engine.
1
8 During
adiabatic
i 5p 0 ,,6,. B
expansion,
t
P
n
volume of gas
o

Ct becomes 32
times the
V0 3V0
Volume
volume it
1 has just
(1) 3R
(2) 23R

6 6 before
adiabatic
(3)
31R
(4) expansion
41R
—
14 begins.
14
 Efficiency of shown in the
the engine is figure. The
(1) 25 % (2) total heat
35 %
(3) 65 % ( 4 ) given to
7 5 ( Vo
the gas is
1. A
nearly (use In
diatomic 2 = 0.7) .

Pl. 8
ideal gas
undergoes
2Po
a -----------------
isothermal
thermodynami
Po--------------------- C
c change from A I
A to B and {
t

1 V
then from B to V 0 2I
/0
C according
(1) 25 17 (2) 1.4
to the P - V
0

P K,
o

diagram (3) 3.9 PoVo (4)

1.1 Polio
SEC : SR ELITE slowly to 1400gm
99. Steam at
of water at 16°C
100°C is added
until the
temperature of 101. Sixty
water is raised to percent of given
80°C . The mass of sample of oxygen
steam required to gas when raised to
do this is (Lv = 540 a high temperature
cal/gm) dissociates into

(1) 160 gm (2) atoms. Ratio of its

120 gm initial heat capacity
(3) 250 gm (4) of the sample (at
320 gm
constant volume)
100. A black
before
body calorimeter
. dissociation to the
filled with hot water
final heat capacity
cools from 60°C
of the sample after
to 50°C in 4 min
dissociation (at
and 40°C to 30°C
constant volume)
in 8 min. The
will be
approximate
(1) - 8
temperature of (2)
surrounding is —
25
(1) 10°C (2) 15°C 7 26
(3) 20°C (4) 25°C
10
 (3) —7 (4) —25 ABC is a
27 semicircle. The net
102. RMS work done in the
speed of a process ABC is
monatomic gas is 3 DATE:
increased to 2
times during an 24.09.18
adiabatic process.
Then the ratio of P (atm)
-- -I- A
initial volume to V(L-)
1 2
final volume will (1) zero
be
(2)
(1) 4
2 -7r atm - L
(2)
(3) - 1E- atm - L (4)
4 atm - L
(4)2/3 2
(3) 23/2 104._________________

(4) Six identical

8 conducting rods
103. In the P-V diagram are joined as
shown in figure shown in
figure. Points 27°C the rms
A and D are speed of the
maintained at molecules of a
temperatures certain diatomic
200°C and 20°C gas is found to be
respectively. 1930 m/s . The
The temperature gas is
of junction B (1) H2 (2) F2
will be _______________
(3) 0 2 (4) C/ 2
(in thermal steady
106. Three conducting
state)
rods of same
material and same
A B crosssectional area
C
D are shown in
200°C 20°C
figure.
(1) 120°C (2) Temperature of A,
100°C
D and C are
(3) 140°C (4)
80°C maintained at
0. At room 20°C, 90°C and
temperature of 0°C . The ratio of
 lengths of BD and heat flow in AB is
BC if there is no
c'r " . _ ri t'
A
8
C I
D / ' ,
2
(1) 7 — To
(2)
— 2T0 T
(1)
2 5
9
3 — 2 (2)
( ) (4) —
2
9 —5
2 ln 2 3
107. An ideal
(3) _______(4) —5
monatomic gas 41n 2 6
undergoes a cyclic 108. Volume
process ABCA as versus
shown in the temperature graph
figure. The ratio of two moles of
of heat absorbed helium gas is as
during AB to the shown in figure.
modulus of work The ratio of heat
done on the gas absorbed and the
during BC is work done by the
V
gas in process 1-2
2V0 -- 13, is
• Vo -- _A V 2.
/
C ,
 D
A
,
T
E
,
:
2
4.
0
1 9.
T 1
( 1)3 (2) 5/2 8
0. Three rods of
(3) 5/3 (4) 7/2 identical cross —
sectional area
and made from the
same material
form the sides of
an isosceles
triangle ABC
right angled at
B. The points A
and B are
maintained at
temperatures T
and -51
respectively in the
steady state.
Assuming that only
heat conduction
takes place
 temperature of a

L
s
point C will be
A ,
t
h
e
r
B c a
(1) 3T T t
______________
(2) i
+1 Nri-
o
+1
T T o
(3) __________(4) f
j- ( \h- —1) t
Nri —1 h
1 e
. s
I p
n e
a e
c d
e o
r f
t s
a o
i u
n n
g d
 9
a The molar heat
n capacity of the
d gas in a process
r given by PT =
o
constant is________
o
t (1)
(2) ——R (2 ) 3R
2 2
m 5R 7R
(3) — ( 4 )
e 2
a 111. A student records A
n
Q, A U and A W
s
for a
q
u thermodynamic
a cycle A --* B —>
r C —> A. Certain
e entries are missing.
s
Find correct entry
p
e in following
e options
AB
d BC
is CA
5
A W 40J 30J
AU -
50J
. A Q 150J
\I 10J
-- 1 7
HYDERA
 ( 1 ) WBC = 70 J (2) velocity of
A (kA = 130 J
the particle is
(3) A Um3 = 190J
(4) A UcA = - 160 J half its final
112. A body moves velocity
under constant
acceleration 113. A body
(1) average travelling along
velocity of a straight line
the particle is traversed one third
always zero of the total distance
(2) average with a velocity 4
velocity of
m/s . The
the particle is
remaining part of
always
the
greater than
distance was
its final
covered with a
velocity
velocity 2 m/s
(3) average
for half the time
velocity of
and with velocity
the particle
6 m/s for
may be zero
(4) average the other half of
 time. The mean relation, x = 6 +
velocity averaged 12t — 2t 2 . Here
over the whole x is in metre and t
time of motion is in second. The
(1) 5 m/s (2) 4 distance covered
m/s
by particle in first
(3) 4.5 m/s (4) 5 sec is
3.5 m/s
(1) 20m (2) 32 m
114. The position (x) (3) 24m (4) 26 m
of a particle

moving in a

straight line along

x axis is described

by the
 D position at time t
A
T = t after start of
o

E
: motion. Here, to
2 is
4.
0 (1) 4 s(2) (4 + 2-
9. 1 - 2 - )s
1
8
115. A point (3) (2 + 2,5)s

mass starts moving (4) (4 + 4,5)s

in a straight line 116. In a car

with contant
race, car A takes to

acceleration 'a'
time less to finish
from rest at t = 0.
than car B and
At time t = 2s, the
passes the
acceleration
finishing point
changes the sign,
with a velocity vo
keeping the
more than car B.
magnitude same.
The cars start
The mass returns
from rest and
to the initial
travel with
 constant upwards from the
accelerations al ground. When the
and a2 along a balls collide, they
straight path. are moving in
opposite directions
Then the ratio is
equal to and the speed of A
to
(1) is twice the speed
,2
(2) of B. At what
fraction of the
a
height of the
a
a 2 '2 building did the
2
a collision occurs ?
(3) Va i a 2 (4)2
(1) 1/3
a
117. Ball A is dropped (2)
from the top of a
2/3
building. At the
(3) 1/4 (4) 2/5 .

same instant ball B •

is thrown vertically
SEC : SR ELITE from point A at a
118. A
certain height from
particle is dropped
ground. It falls
freely and passes from a height of
through three 20m and it
points B, C and D rebounds to a
(in that order only) height of 5m
with BC = CD. after the
The time taken by collision.
the particle to Change in
move from B to C velocity of the
is 2s and from C to body
D is ls. The time during collision is_
taken to move (g =10ms ) -2

from A to
(1) 10 ms - 1
B is__(g. =10ms ) -2
downwards

(1) 0.5s (0) 10 ms - 1

upwards
(2)
( 1 ) 3 0 ms - 1
1.5 s u pw a r d s
(3) 0.75 s
(2) 30 ms - 1
(4) downwards

0.25 s 120. Star

0. A ball is ting from rest a
freely released particle moves
in a straight line from the top of the
with same tower with
some initial
acceleration velocity. The graph

a = {2 + t —2} of the distance(s)

s2
between the two

Velocity of stone varies with

particle at the time (t) as (before

end of 4s will either stone hits

be (1) 16 m/s the ground)

(2) 20 m/s

(3) 8 m/s (4) 12

m/s
0. One stone is
dropped from the
top of a tower from
rest and
simultaneously
another stone is
projected
vertically upwards
DATE: 24.09.18 t
(2)
122. Acceleration (a)
displacement (s)
graph of a particle
(1) moving in a
straight line is as
shown in the
t figure. The
initial velocity of
(0) the particle is zero.
The v — s graph of
the particle would
be (v is the
velocity when
t
the displacement
(1)
is s)
S
a
$
SEC : SR ELITE
(1)
v
 (2) (1) both d 1

and d will
2

decrease
s.
(0)
(0) None of (2) both d 1

these and d will

2

increase
123. Two holes of
(0) d will
1

unequal increase, d 2

will
diameters d decrease
1

(1) d will
1
and d (d >
2 1 decrease, d 2

will increase
d ) are cut in
2

metal sheet.

If the sheet is

heated
 D temperature.
A
T Let y is the
E coefficient of
:
2 volume
4
. expansion of
0 the liquid and
9
. a is the
1
8 coefficient of
124. A linear
horizontal expansion of
tube, open at the material
both ends, of the tube.
contains a Then the
column of correct
liquid. The relation is
length of this (1) y = a (2) y
liquid column = 2ct
(3) Y = 3a (4) y
does not = 0

change with 0. In a
 vertical U — equal to
tube t
containing a i
t2
liquid, the
two arms are
maintained
1.2 1
4-1 1 -1 2 1 2

at different (1) (2)

2 t 14
2 1 2
temperature 11111-
l2_ t2
s, t and t .
1 2
(3)
The liquid 1 -F1

columns (4)
in the two arms 1 2

have heights 4
and / 2
4+1 2

respectively. 12t1+1112
1t+ 1t 1 1 2 2

The 126. A solid whose

coefficient of volume does

volume not change
expansion of with
the liquid is temperature
 floats in a in the
liquid. For liquid. The
two different coefficient of
temperatures volume
t and t of the
1 2 expansion of
liquid, the liquid is

fractions f equal to
(1) fl -f2
and f of the
2
(2)

volume of the A- f2
f t , -
solid remain
2

t 2 f , t
submerged ,

20 HYDERA
SEC : SR ELITE coefficient of
(3)
linear
2•4
expansion a
—
just floats in a
7-2
liquid *whose
-—
f t + A/2)
2 i coefficient of
fti+f2t2 volume
127.. A solid with
 expansion is temperature
y . If the is v . If the
system is temperature
heated, the is doubled
solid will and the
in all oxygen gas
cases—
dissociates
(2) continue
to float in all into atomic
cases
(3) sink if y oxygen, the
> 3a
(4) sink if y < rms speed
3cc would be
128. The root
(l) (2) Viv
1)

mean square (3) 2v (4) 2-1 -

(rms) speed of iv
129. When an air
oxygen
bubble rises
molecules
from the
(0 )2 at a
bottom of the
certain
surface of a
absolute
lake, its
radius m
becomes (3) 70m (4) 80
m
double. Find 130. A spherical
the depth of black body
the lake, with a radius
given that the of 12cm
atmospheric radiates
pressure is 450W power
equal to the at 500K. If
pressure due the radius
to a column of were halved
water 10m and the
high. Assume temperature
constant doubled, the
temperature power
and disregard radiated in
surface watts would
tension be
(1) 30m (2) 40 (1) 225 (2)
450
(3) 900 (4) 131. One end of
1800 a uniform rod
of length lm
is placed in
boiling water
while its
other end is
placed in
melting ice. A
point P on the
rod is
maintained at
a cori§tant-
tc.rapeirattu--,
- of 800°C .
The mass of
steam
produced per
second is
equal to the (4)
mass of ice
mclted per
m
second. If
132. The power
specific latent heat
of steam is 7 radiated by a
times the specific black body is
latent heat of ice, P, and it
the distance radiates
of P from the maximum
steam energy
chamber must around the
be wavelength
1 1 X.
0 If the
(1) —m (2) —
7 8
temperature
m
of the black
(3) I9
body is now
changed so
10 m that it
radiates
 maximum constant
energy acceleration
around a of 2 m/s2 due
wavelength west. The
32 /4 , the distance
power covered by
radiated by it the particle in
will increase the fifth
by a factor of second of its
(1) 4/3 motion is
(2) (1) 0 (2) 0.5 m
16/9 (3) 2 m (4)
none of these
(3) 64/27 (4) 134. A particle
256/81
thrown up
133. A particle
vertically
has an initial
reaches its
velocity of 9
highest point
inis due east
in time t and 1

and a
returns to the
 ground in a constant force
further time on the particle
t 2 . The air opposite to its
resistance direction of
exerts a motion
4
SEC : SR ELITE .
U

(1) t1 > t2 (2)t i

.
%

= t2 •
A

.
,

135. A particle (A)

(3) t i < t 2 is freely released
from +IL ',0
(4) May be - -
(a) or (c) —
Ora TOV ....
- .

depending on —
?',74.T.thrii'Met
O.,: ratio of the re. After 'A' has
force of air descended by
resistPr::-,. to x metre,
61.e weight of another
particle (B) is
•
-

•
*
-
1
4
1
,
freely
1
,

t
1
1
released
%
,

1
7
,
1
from a point
 y metre finding the
below the top electron in
of the same dxy orbital is
tower. If they (1) along
the X-axis
reach the
(2) along
ground Y-axis
together
(3) at an
simultaneousl angle of 450
from its X
y 'h' is equal
and Y axis
to (4) along
X and Y axis
()
1

(x+y)2 ( 2 ) 137. Which

(x-42
4x 4x among the
(3) (x + y) 2
following
(4)

(x orbital has 2
—
4y 4y radial nodes

136. The and one

maximum nodal plane?

probability of (1) 2s (2) 3p

(3) 4f (4) 4p
138. If D
travelling at
A
T
same speeds E
which of the !
IA

following 139. The

wavelength oc
matter _- .•09.18
a spectral line
waves have
emitted by
the shortest hvd-
_.,ogen
wavelength
(1) Electron at
(2) Proton
(3) Neutron o
(4) He2+
m

in

m
o of
1
st
6

e
5
n
R
e
H. spectrum
r is
______________
g cm . The vaIue
of n2 is
et 1
5
ic R
(1) 3

s (2)
4
e (4)
1
ri 0. Which
of the
e
following set
s of quantum
numbers shy
 77; orbital of series of He
highest ion has
energy: frequency 02 ,
'

(1) then which of

4,/ = 0, =
0,s = +-
the following
(2)
2, / = 0,is correct?
0,s = +1(1) 1= 2
(3)
3,/ = 1, ( 2 ) = 4 2
1,s = + 1 —
2 (3) 2= 4 1
(4) (4) i= 2
3, 142.The
/ = 2,
1,
141. For the uncertainty in
Hydrogen position and
spectrum , velocity of the
particle are
last line of the
0.lnm and
Lyman series
5.27 x 10.27
has
m.s.'
frequency '0 respectively,
'and last line then the mass
of Lyman of the particle
 is: will be:
(1) 200kg (2) (1) Afg (2) 0
300kg
(3) (4) 3P,
(3) 100kg (4)
50kg 0. Energ
143. For an y of H-atom
electron with in the
n = 2 has one ground state
radial node is - 13.6eV,
and zero then the
nodal planes. energy in the
The orbital second
angular excited state
momentum of is:
the electron a2 HYDERA
SEC . energy of 2s orbital in
(2)
-3.4eVH , Li , Na and K is:
(3)-1.51eV (4) (1) E2,(H) > E2,
-4.53eV (Li) > E2,(Na) >
E2s(K)
145 Which among
(2) E2 (H) = E2,
the following is (Li) = E2s(Na) =
Es(K)
correct wrt
(3) E2,(H) < E2, (4) X,Y and Z
(Li) < E2,(Na) < 147. Two
E2s(K)
particles 'A' and
(4) E2,(H) < E2,
(Li) > E2,(Na) = 'B' have de
Es(K)
Broglie
146. The work
wavelengths 1
function for
nm and 5nm
metals X , Y and Z
respectively. If
are 1.92eV,
mass of 'A' is
2.0eV and
four times to that
5.0eV
of 'B', the ratio
respectively.
of velocities of 'A'
According to
and 'B' would be
Einstein equation
1) 5 : 1 2) 25 : 4
. the metal which 3) 20 : 1 4) 5 : 4
will emit 148. List — I List — II
(Electronic config)
photoelectrons for (Rules Violated)
A

a radiation of I
wavelength
I.H
4100A° is/are: und
's
(1) X only (2) X onl
and Y only y
(3) Y and Z only
 s only
B. 11.
The correct match
is
Pauli'
s
Hund'
s only
0.
III.Auf-bau ,
•
Pauli's
and
Hund'
s only

I [I

IV.Au
f bau
only
V.
Auf-
bau
and
Hund'
 D temperature
A (1) V (He) =
T V(Ar)
E:
24 (2) V (He) = 10
V(Ar)
.0
9. (3) V(He) =
18 3.16 V(Ar)
A CD (4) V(Ar) = 2.5
( 1 ) I I I V IV V(He)
(0) II I IV III 150. If Z is a
(2)III V compressibility
III
factor, van der
(0) I I I V I V
Waals' equation
149. Ar and He
at low to
are both
moderate
gases at room
pressure can be
temperature.
writtern as
How do the
(1) Z =,RT (2)
average
Z =1 a
molecular
pb
velocity of (V) VRT
11 b
their atoms (3) Z=1— —
(4) Z=
compare at this
1+
 RT RT (1) 4 : 1 (2) 2 : 1

151. A 1:2 (3) 8 : 1 (4)1:1

molar mixture 152. The

of He and CH 4 values of van der

is contained in a Waals constant a

vessel at 20 bar for the gass 02,

pressure. Due to N2, NH3 and CH4

a hole in the are 1.360, 1.390,

vessel the gas 4.170 and 2.253

mixture leaks L2atm mo1-2

out. What is the respectively. The

composition of gas which can

the mixture most easily be

effusing out liquefied by:

initially? (1) 02 (2) N2

(3) NH3 (4) CH4
SEC : SR ELITE °
327 C has a KE of
153. The K.E of N
'2x' joules. The
molecule of 02 is
latter sample
'x' joules at — contains
°
123 C. Another (1) N molecules
sample of 02 at of 02
 (2) 2N molecules door. There are 13
of 02
(3) N/2 equidistant rows of
molecules of 02
benches in the
(4) N/4
molecules of 02 classroom. The

154. In an atomic teacher releases

orbital, the + and N20 , the laughing
— sign present in gas, from the first
lobes indicates bench while the
(1) sign of the
probability student releases the
distribution
weeping gas
(2) sign of
charge (C6H110Br) from
(3) sign of the the last bench. At
wave function
which row will the
(4) presence or
absence of students start
electron
155. A laughing and
teacher enters a weeping
classroom from simultaneously
front door while a (atomic mass of
student from back Br=80)
(1) 7 (2) 10 developed if the
3 9
() (4) 5
156. A compound exists

compound exists as dimer to the

in the gaseous extent of 50% by

phase both as weight under these

monomer (A) conditions will be

and dimer (A 2 ) Sri Chaitanya

Page
The atomic mass
of A is 48 and
molecular mass of

A 2 is 96. In an
experiment 96 g
of the compound
was confined in a
vessel of volume
33.6 litre and

heated to 2730C.
The pressure
 D 0.03
A
T Y 6
E 0.032
:
Z 12
2
4 0.027
.
0 Which one of
9 these gases has
.
1 the highest
8 critical
(1) 1 atm (2) 2
atm temperature ?
1
(3) 1.5 atm (4) 4 ( )W (2) X
atm 3
( )Y (4) Z
157. The van der Waals 158. A gas such as
parameters for carbon monoxide
gases W, X, Y and would be most
Z are likely to obey the

Gas a(atm L
2 ideal gas law at
2 l
mor ) b (L mor ) (1) low
temperatures and
W 4 high pressures
(2) high
0.027 temperatures and
high pressures
X 8 (3) low
 temperatures and N :
low pressures 15/
(4) high
temperatures and ()
1

low pressures
159. Aromatic (2)

species a*

among
3
the ( )(4) All the above
followi 160. 2 - pentanone and
3-pentanone are
ng is (1) Chain
isomers
==
f \ (2) Tautomers
•
• (3) Metamers
· N ;N- (4) Positional
H isomers
SEC : SR ELITE C
H
' isomerism is 2
exhibited in (2)

C --\
CH 2 (0) CYN
(1)
CH 162. Maleic acid
2 and fumaric acid
(0) ___ are a pair of
(1) Optical
 isomers chiral
(2) Geometri carbon is
cal isomers
always
(3) Positional
isomers optically
(4) Metamer active.
s Statement –
163. Maximum
II :
number of
Stereogenic
structurally
carbon is
isomeric
always
alcohols
sp3
possible for hybridised.
C5H120 (1) Statement
-I is true but II
(1) 5 (2) 6 is false
(3 ) 7
(4) 8 (2) Statemen
164. Statement – t-I and II are
false
I : Organic
(3) Statemen
compound t-I and II are
with one true
(4) Statemen
 t-I is false II D
is true A
165. The T
E
:
I.U.P.A.0 2
4
name of .
0 0
11 9
.
0— C —
1
CH3 8
CH7 (0)Methyl bis
C- ethanoate
0C 2 H 5
(1) Ethyl
11
ethanoyl
0
oxyethanoate
, is
166. Optical
activity is
(1) Ethyl observed in
methanoyl (1) Malonic
methanoate acid (2) Malic
acid
(2) Ethyl – (3) Malei
c acid
bis (4) Meso
ethanoate – tartaric
acid
Sri Chaitanya Pag 167.
Cl
CI
 H4) H
OH
, 1 I HO
C2H5 OH
CH 3 CH3
C H3 a
n
H. d
C H3
a a
n r
d e
are a pair of
(1) Confo a pair of
rmational
isomers (1) Enant
(2) Chain iomers
isomers (2) Identi
(3) Positi cal
onal isomers compounds
(4) Identi (3) Dia
cal stereo
Compounds isomers
168.
CH3 (4) Positi
onal isomers
F1/.6 CH3
169. Tautomerism
His
: 6not observed in
(1) CH3-NO2 (2)
C6H5- CO -
. z z

C6H5
•
 (3) C6H5OH (4) 0
C .
H
3 E
C n
O o
C l
H
2 c
C o
O n
O t
C e
2 n
H t
5

i
1 s
7
l f
e o
a r
s 0
t
(1)
HYDERA

O h/
(
\/ c-F.T
2 _ _3
(4) —
) 171.
C

0 O

O
0
C
) U \
H
(3) 3
0 0
P
 _ C

O O

A= O
OH C

H H

O 3
H

C
O C
O
O
H
CO O
OH
H
OH

H t C __________OH
HO_______
B_ H CO
OC
O H3
Then correct
H
statement
regarding A, B
 1 1

and C is U
1 1
: . .
I r .

(1) A and B are T •

t r

enantiomeric pair
1 •
1 t
1

(2) B and C are (2) Racemic

identical
compounds mixture is
(3) A and B are
dia stereo optically active
isomers
(4) 'IV is a due to external
meso
compound compensation
172. Select the correct (3) Sec-
statement. butyl
(1) Meso
amine is
compound is
optically
optically
inactive
inactive due to
(4) All are
internal
correct
compensation
173. Most
stable
carbocation
among the
following is

CH2
 0 is
CH2 (1) —0 8
(2)
0 (C
H
o C-
3
3
(1)
(3) CH3 —(4) CD3
—
(2)
175. Most stable carbo
cation among the
CH3 following
is
CH2 CH2
0 0

0 0 N- H
(3)
(1) (2)
(4)
0
NO2

COOH
174. Group
that can cause (3) (4)
strong + I effect
SEC : SR ELITE o
176.
\ , \ i l
0 ® 0 o
 C - 0 bond

IP lengths
different, but in
are

s formate ion the

A=
C - 0 bond
lengths are same.
B= This is best
explained by

0 (1) Resonance
(2) Hyper
conjugation
(3) Reverse
hyper

A and B are the

1 conjugation
(4) Sterically
inhibited
resonance
178. Which of the
following is a temporary
two resonating effect
(1) Mesomeric
structures, then effect
their stability (2) Electromeric
effect
order is
(3) Inductive
(1)A>B effect
. (2)A<B (4) Hyper
(3) A = B conjugation
(4) 2A = B 179. Stable carbanion
177. In formic acid among the following is
 D
e A
(1) Ph 2 C H
T
° E
(2) Ph CH2 :
e 2
4
.
0
(3)

(
9
.
1
C 8
H 180. The correct order of
, — I effect in the
) following

C (R CH 3 )
. (1) —NR 2 < —
. OR < --F
.
1
(2) —NR 2 > —
3 OR > —F
O (3) —NH 2 < —F
(4) (CH3 )2 C H < —OR
(4) —NR 2 < —F
< —OR