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CHEMISTRY 9701/41
Paper 4 A Level Structured Questions May/June 2018
MARK SCHEME
Maximum Mark: 100
Published
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the
examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the
details of the discussions that took place at an Examiners’ meeting before marking began, which would have
considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for
Teachers.
Cambridge International will not enter into discussions about these mark schemes.
Cambridge International is publishing the mark schemes for the May/June 2018 series for most
Cambridge IGCSE™, Cambridge International A and AS Level and Cambridge Pre-U components, and
some Cambridge O Level components.
These general marking principles must be applied by all examiners when marking candidate answers. They should be applied alongside the
specific content of the mark scheme or generic level descriptors for a question. Each question paper and mark scheme will also comply with these
marking principles.
• the specific content of the mark scheme or the generic level descriptors for the question
• the specific skills defined in the mark scheme or in the generic level descriptors for the question
• the standard of response required by a candidate as exemplified by the standardisation scripts.
Marks awarded are always whole marks (not half marks, or other fractions).
• marks are awarded for correct/valid answers, as defined in the mark scheme. However, credit is given for valid answers which go beyond the
scope of the syllabus and mark scheme, referring to your Team Leader as appropriate
• marks are awarded when candidates clearly demonstrate what they know and can do
• marks are not deducted for errors
• marks are not deducted for omissions
• answers should only be judged on the quality of spelling, punctuation and grammar when these features are specifically assessed by the
question as indicated by the mark scheme. The meaning, however, should be unambiguous.
Rules must be applied consistently e.g. in situations where candidates have not followed instructions or in the application of generic level
descriptors.
Marks should be awarded using the full range of marks defined in the mark scheme for the question (however; the use of the full mark range may
be limited according to the quality of the candidate responses seen).
Marks awarded are based solely on the requirements as defined in the mark scheme. Marks should not be awarded with grade thresholds or
grade descriptors in mind.
state symbols 1
the sulfide ion is larger than the oxide ion / S2– larger than O2 / ionic radii quoted 0.184 nm and 0.140 nm 1
AND less attraction (between the ions)/bonds are weaker
mol–2 dm6 s–1 1
2(e) 2, 1, 3 1
2(f)(i) 2 1
2(h)(iii) SO3 + H2O → H2SO4 AND acid rain or consequence of this described 1
Ca2+ + 2e– → Ca 1
2 points = 1 mark
3 points = 2 marks
3(b)(iii) • metal / grey / silvery 1
• purple AND vapour / gas / fumes
• amount of melt decreases
0.06 / 0.02 = 3 ∴ Fe3+ or +3 or 3 1
2 points = 1 mark
3 points = 2 marks
4 points = 3 marks
5(a) 3s23p63d104s1 1
3s23p63d10 1
5(b) Cl-Cu-Cl 1
5(c) 1
5(f)(i) donates lone pairs / forms dative / co-ordinate bonds to (central) metal atom / metal ion 1
5(f)(ii) [Zr(C2O4)4]4– 1
6(a)(i) D 2-chloropropane 1
E hydrogen chloride 1
6(b)(ii) 1
6(b)(iv) 1
6
6(c) reactio
on with hot KMnO
O4(aq) 1
reactio
on with H2 + Ni, high
h pressure 1
6
6(d)
-H+
+ Products
NO2+
H NO2
correct intermediate 1
2nd cu
urly arrow from C-H
C bond into rin
ng 1
7(b)(ii) • propan-1-ol: O-H bond strengthened by positive inductive effect of alkyl group OR propoxide ion is destabilised by 2
positive inductive effect of alkyl group
• phenol: O-H bond weakened by negative inductive effect of ring OR phenoxide ion is stabilised by delocalisation of
oxygen lone pair into ring
• propanoic acid: O-H bond weakened by negative inductive effect of C=O OR propanoate ion is stabilised by
delocalisation of minus charge by C=O
1
add product of first step to phenol in NaOH
8
8(a) 1
correct ch elled only
hiral centre labe
*
O
OH
O O OH
C15H22O4
8
8(b) C15H222O4 1
8(c)(i) 1
8((c)(ii) CO2 1
oxidatiion / oxidative cle
eavage 1
8((c)(iii) CH3CO
OCO2H 1
9
9(a) C8H11O3N 1
9
9(b) yes, ass it has a chiral C atom 1
9((c)(ii) 1
OH
N2 1