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MSDS

In accordance with NBR 14.725: 2014

Material Safety Data Sheet


Product:<<UL-MS TINTA LACRE>>
Review:<<01>> <<08/05/2017>>
<< DOCUMENT NOT CONTROLLED >> << ACTIVE>>

1– IDENTIFICATION
Product's Name: UL-MS TINTA LACRE

Internal Product Identification Code: PN - UL120/MS PINK – UL20/MS YELLOW

Recommended uses for the substance or Industrial Use


mixture:

Company Name: Mark Seal Sistema de Marcação Eirelli


Address: Av. Cillos 4242- Pq Universitário–Americana/SP
Telefone para Contato: (19) 3461-1432
Emergency telephone number: (19) 98719-0315
Fax: (19) 3461-1432
E-mail: sac@markseal.com.br
2. HAZARDS IDENTIFICATION
Chemical hazard class: Not classified as Dangerous

Classification System Used: Standard ABNT-NBR14725-Part 2: 2009-version


Corrected 2:2010. Adoption of the Globally Harmonized
System for the Classification and Labeling of Chemicals, ONU.

Other hazards which do not result The product has no hazards which do not result in
in classification: classification.

Appropriate labeling elements

Pictograms: Not applicable.

Word of warning Not applicable

Hazard statements: Not applicable.

Precautionary statements: P102 Keep out of the reach of children.


P234 Conserve only in the original recipient
P262 Avoid contact with eyes, skin or clothing.
P270 Do not eat, drink or smoke while using this product.
P501 Dispoe of contents/ container accordingly.With legislation

3 – COMPOSITION AND INFORMATION ABOUT INGREDIENTS


Ingredients or impurities that contribute ----
4 – FIRST AID ACTIONS
Inhalation: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If unwell, contact a POISON
CENTER or doctor. Take this MSDS.
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MSDS
In accordance with NBR 14.725: 2014

Material Safety Data Sheet

Contact with skin: Wash with plenty of soap and water. In case of irritation cutaneous:
Consult a physician.Take this MSDS.

Eye contact: Rinse cautiously with water for several minutes.


If contact lenses are worn, remove if present. If eye irritation occurs:
Consult a physician.Take this MSDS.

Ingestion: Wash the victim's mouth with plenty of water. If you feel unwell,
contact a POISON CENTER or a doctor. Take this MSDS.

Most important symptoms and No symptoms are expected after exposure to the product.
effects, both acute and late.

Notes to physician: If necessary, symptomatic treatment should include,


Especially, support measures such as correction of hydro electrolytic,
metabolic disorders, as well as respiratory care.

5- FIRE FIGHTING MEASURES

Extinguishing Media: Suitable extinguishing media: In case of fire use: carbon dioxide
(CO2), chemical powder, water in the form of haze.
Unsuitable extinguishing media: Avoid using water jet directly.

Specific hazards of the During combustion releases fumes containing monoxide and carbon
mixture or substance: dioxide, sulfur dioxide and nitrogen oxide.
Specific hazards related to the product are not expected during the fire.

Protective measures of Self-contained breathing apparatus (SCBA) positive compression and full
the firefighting team: protective clothing that provides protection against heat.
Containers and tanks involved in the fire may be cooled with
Water mist.

6 –CONTROL MEASURES FOR SPILL OR LEAK


Personal Precautions
For non-emergency staff; Remove all sources of ignition. Do not smoke. Avoid contact with the
product. If necessary, wear personal protective equipment as described in
section 8.

For emergency service Use complete EPI with protective gloves, safety shoes and suitable
personnel: protective clothing.

Environmental Do not allow product to reach sewage system.


Precautions:

Method and materials for Use natural barriers or spill containment.Absorb the spilled product with
containment and cleaning sand or other inert material and place in recipient for later appropriate.
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MSDS
In accordance with NBR 14.725: 2014

Material Safety Data Sheet


For final destination, proceed according to section 13 of this fispq
Difference in the action of
Big and small leaks There is no distinction between the actions of large and small leaks.

7– MANUSE AND STORAGE


Appropriate technical measures for handling

Precautions for Handle in a well ventilated area or with general local exhaust ventilation.
Safe Handling: Avoid contact with skin, eyes and clothing. Avoid breathing vapors or
mists of the product. Wear personal protective equipment as specified in
section 8.

Hygiene measures: Wash your hands well before eating, drinking, smoking or going to the
bathroom. Contaminated clothes should be changed and washed before
reuse.

Conditions of safe storage, including any incompatibility.


Condições de armazenamento seguro,incluindo qualquer incompatibilidade.
Prevention of fire and The product is not expected to present a fire or explosion hazard.
explosion:

Suitable conditions: Store in a ventilated place and protected from heat.

Materials for packaging: -----

8– EXPOSURE CONTROL AND PERSONAL PROTECTION


Control Parameters

Occupational exposure Not Established


limits:

Biological Indicators: Not Established

Other limits and values: Not Established

Engineering Control Provide mechanical ventilation and direct exhaust system to the outside
Measures: environment. It is recommended to make emergency showers and eye
washers available in the work area. Engineering control measures are
most effective in reducing product exposure

Personal Protection Measures

Eye / face protection: Specific safety goggles are not required, however, for personal safety and
prevention purposes, it is recommended that the goggles available in the
workplace should be worn when handling the product.

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MSDS
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Material Safety Data Sheet


Skin and body protection;

No specific skin and body protection equipment is required. However, for the sake of personal safety and
prevention, it is recommended that the approved protective clothing available in the workplace should be worn
during the handling of the product. Specific protection gloves, however, for the sake of individual safety and
prevention, it is recommended that the protective gloves available in the workplace should be worn when
handling the product.

Breath protection:

No specific respiratory protective equipment is required. However personal safety and prevention purposes, it is
recommended that the product is not handled in situations that allow free inhalation, except with the use of the
approved respiratory mask available in the workplace.

Thermal hazards: ----

9–PROPRIEDADES FÍSICAS E QUÍMICAS


Appearance (physical state,
shape and color): Liquid
Odor and Odor Threshold: Characteristic
PH: 8,5 - 9,0
Melting point / freezing Not available
point:
Initial boiling point and
boiling range:

Flash Point: Not available


Evaporation rate: Not available
Flammability (solid, gas) Not available
Lower / upper limit of
Flammability or Not available
Explosivity

Steam pressure: Not available


Vapor Density: Not available
Relative density: Not available
Solubility (ies): Soluble in water
Partition coefficient: n- Not available
octanol / water:
Auto-ignition temperature: Not available
Decomposition
temperature: Not available

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MSDS
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Material Safety Data Sheet


10– STABILITY AND REACTIVITY

Stability and reactivity: Stable under normal conditions of temperature and pressure. May react with strong
oxidants.
Possibility of hazardous
reactions: No dangerous reactions known. Incompatible Materials

Incompatible Materials: Strong oxidizing agents.


Hazardous Products No dangerous decomposition products known.
Decomposition:

11– TOXICOLOGICAL INFORMATION


Acute toxicity: Product not classified as acute toxic
Skin corrosion / The product is not expected to cause skin irritation.
irritation:
Eye damage The product is not expected to cause eye injury or irritation.
Severe / eye irritation;
Respiratory or skin The product is not expected to exhibit respiratory sensitization
sensitization: The product is not expected to be sensitive to the skin.
Mutagenicidade em
células germinativas: The product is not expected to show cell mutagenicity germinativas.

Carcinogenicity: The product is not expected to be carcinogenic to humans.

Reproductive The product is not expected to be reproductive toxicity.


toxicity:

Specific target organ


toxicity - single The product is not expected to show specific target organ toxicity - single exposure
exposure:

Specific target The product is not expected to show specific target organ toxicity - repeated exposure.
organ toxicity
- repeated
exposure:

Danger by aspiration: The product is not expected to be aspiration hazard.

12- TECHNOLOGICAL INFORMATION


Environmental effects, behavior and impacts of the product
Ecotoxicity: Not expected to be a danger to the aquatic environment.

Persistence / deg The product has no persistence and is considered to be rapidly degradable.
radability:Bio The product is not expected to have cumulative bio potential
accumulative
potential:

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In accordance with NBR 14.725: 2014

Material Safety Data Sheet


Mobility in soil: Not Determined.

Other adverse effects: No other environmental effects are known for this product.

13– CONSIDERATIONS ON FINAL DESTINATION


Recommended methods for treatment and disposal are

Product: They should be disposed of with hazardous waste in accordance with local
regulations. The treatment and disposal should be evaluated specifically for
each product. Federal, state and local laws should be consulted, as follows:
CONAMA 005/1993,ABNT-NBR10.004/2004 e ABNT-NBR16725.

Product remains: Keep product residues in their original containers and properly closed.
Disposal should be made as directed for the product.

14– TRANSPORTATION INFORMATION


National and international
regulations
Terrestrial Resolution n°420 Of February 12, 2004,The National Agency for
l: Land Transport (ANTT), Approves the Supplementary Instructions for the
Transport of Dangerous Goods Regulations and their modifications.

Number ONU: Not classified as dangerous for transport

Proper shipping name: N.A


Risk class
Sub-class of risk
main: N.A

Risk class/
Sub-class of risk
subsidiary: N.A

Number of Hazard: N.A

Packing group: NA

Waterway DPC:Diretoria de Portos e Costas (Ports and Coasts Directory)


(Transportation in Brazilian waters) Norma da Autoridade Marítima
(NORMAM) (Maritime Authority standard)
NORMAM 01/DPC: Craft Employees in Open Sea Navigation.
NORMAM 02/DPC: Inland Navigation Vessels
IMO–“International Maritime Organization). International Maritime
Dangerous Goods Cod (IMDG Code).

Number ONU: Not classified as dangerous for transport

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MSDS
In accordance with NBR 14.725: 2014

Material Safety Data Sheet


Proper shipping name: N.A

Risk class / N.A


Subclass of risk
Main

Risk class / N.A


Risk subclass
subsidiary:

Packing group: N.A

EmS: NA

Air: N.A

Number ONU: Not classified with the dangers o for transportation

Name Suitable
for shipment N.A

Risk class / N.A


Risk subclass
main:

Risk class/
Risk subclass N.A
subsidiary:

Packing group: NA

Danger to the The product does not present any danger to the environment
Environment :

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MSDS
In accordance with NBR 14.725: 2014

Material Safety Data Sheet

15 – REGULATORY INFORMATION
Specific Federal Decree No. 2.657 of July 3, 1998.
regulations for Law No. 2,305, of August 2, 2010 (National Policy on Solid Waste).
the chemical: Decree No. 7404 of December 23, 2010.
Ordinance n ° 229, of May 24, 2011-Alters Regulatory Standard n ° 26
Standard ABNT-NBR 14725-3: 2012

16 – OTHER INFORMATION
Important information, but not specifically described to the previous sections:

Hazard Classification of the chemical: Health: 1


Flammability: 0
Instability: 0
Specific: Not Rated

Classification system used: National Fire Protection Association: NFPA704.


Diagrama de Hommel:

1
0 0

Specific Hazard:No Rated

This MSDS has been developed based on the current knowledge of the chemical and provides information on
protection, safety, health and the environment.
It is advised that the handling of any chemical requires prior knowledge of its hazards by the user. It is up to the
user company to promote the training of its employees and
The risks arising from the product.

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MSDS
In accordance with NBR 14.725: 2014

Material Safety Data Sheet


Subtitles and abbreviations:

CAS – Chemical abstract Service


Ceiling – Valor Teto (Value Ceiling)
CONAMA– Conselho Nacional do Meio Ambiente
(National Council for the Environment)
DL50–Dose Letal 50% (Lethal dose 50%)
ONU–Organização das Nações Unidas
(United Nations Organization)
TLV–Threshold Limit Value

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