1 2 3 4 5

Compound Formula % mol Peso molecular Pc

kg/kmol bara
1 Methane CH4 16.0 46.0
2 Ethane C2H6 30.1 48.7
3 Propane C3H8 44.1 42.5
4 i-Butane C4H10 58.1 36.4
5 n-Butane C4H10 58.1 38.0
6 i-Pentane C5H12 72.1 33.8
7 n-Pentane C5H12 72.1 33.7
8 Hexane C6H14 86.2 30.3
9 Heptane C7H16 100.2 27.4
10 Octane C8H18 114.2 24.9
11 Nonane C9H20 128.3 22.9
12 Decane C10H22 142.3 21.1
13 Acetylene C2H2 26.0 61.4
14 Ethylene C2H4 28.1 50.4
15 Propylene C3H6 42.1 46.0
16 1-Butene C4H8 56.1 40.2
17 1-Pentene C5H10 70.1 35.6
18 1-Hexene C6H12 84.2 32.1
19 Benzene C6H6 78.1 49.0
20 Toluene C7H8 92.1 41.1
21 m-Xylene C8H10 106.2 35.4
22 o-Xylene C8H11 106.2 37.3
23 p-Xylene C8H12 106.2 35.1
24 Water H2O 18.0 220.6
25 Ammonia NH3 17.0 112.8
26 C. Monoxide CO 28.0 35.0
27 C. Dioxide CO2 44.0 73.8
28 Hydr. Sulfide H2S 34.1 89.6
29 Hydr. Chloride HCl 36.5 83.1
30 Hydr. Bromide HBr 80.9 85.5
31 Nitrogen N2 28.0 34.0
32 Oxygen O2 32.0 50.4
33 Air Mixture 29.0 37.7
34 Hydrogen H2 2.0 13.1
35 Chlorine Cl2 70.9 77.1
36 Bromine Br2 159.8 103.0
37 Helium He 4.0 2.3
38 Neon Ne 20.2 26.5
39 Argon Ar 39.9 49.0
 6 7 8 9 10.0000 11.0000 12.0000
Tc �c zc � Ai Bi Ci
K kg/m3
190.6 162.7 0.286 0.01
305.3 206.7 0.279 0.10 9.0435 1511.4000 -17.1600
369.8 220.5 0.276 0.15 9.1058 1872.5000 -25.1600
407.8 224.4 0.278 0.18
425.1 227.9 0.274 0.20 9.0580 2154.9000 -34.4200
460.4 235.8 0.270 0.23
469.7 230.5 0.270 0.25 9.2131 2477.1000 -39.9400
507.6 232.3 0.266 0.30 9.2164 2697.6000 -48.7800
540.2 234.1 0.261 0.35
568.7 235.0 0.256 0.40
594.6 232.8 0.255 0.44
617.7 230.6 0.254 0.49
308.3 232.5 0.268 0.19
282.3 214.1 0.281 0.09
364.9 227.5 0.281 0.14
419.5 232.8 0.278 0.18
464.8 239.4 0.270 0.24
504.0 241.8 0.267 0.29
562.1 305.1 0.268 0.21
591.8 291.6 0.264 0.26
617.0 283.1 0.259 0.33
630.3 286.9 0.264 0.31
616.2 280.9 0.259 0.32
647.1 322.0 0.229 0.34
405.7 235.0 0.242 0.25
132.9 296.7 0.299 0.05
304.2 468.2 0.274 0.22
373.5 346.0 0.284 0.09
324.7 450.1 0.249 0.13
363.2 809.1 0.283 0.07
126.2 314.0 0.289 0.04
154.6 436.0 0.288 0.02
132.5 316.6 0.313
33.2 31.4 0.305 -0.22
417.2 571.8 0.276 0.07
584.2 1183.8 0.286 0.13
5.2 69.9 0.302 -0.39
44.4 483.9 0.300 -0.04
150.9 535.6 0.291 0.00
VARIABLES
Presión (MPa) 0.6
Temperatura(K) 313 R
fracción vapor(V_F) 0.0950606642 cm3*MPa/mol*K
volumen

Composición zi peso molecular Pc(bara) Pc(MPa)

Ethane 0.5 30.1 48.7 4.87
Propane 0.25 44.1 42.5 4.25
n-Butane 0.3 58.1 38 3.8
n-Pentane 0.2 72.1 33.7 3.37
Hexane 0.2 86.2 30.3 3.03

Cálculo de z
multicomponente beta gama
A= 0.2761704655 -0.9690161132 0.2113226881
B= 0.0309838868
Solución de la ecuación cúbica

Raíces
q 0.0338915737

r -0.0033543108

UNA RAÍZ

sign r -1

Z1 Err:502

TRES RAÍCES
Ɵ 2.1383939923

Z1 0.0444542348
Z2 0.6708035267
Z3 0.2537583517
 8.314

Tc(K) w k alpha TR a b
305.3 0.1 0.5261668 0.98685561 1.02522109 596956.272 40.5496827
369.8 0.15 0.5999058 1.09828584 0.84640346 1116926.32 56.2817502
425.1 0.2 0.6722952 1.19993113 0.73629734 1803512.64 72.3597613
469.7 0.25 0.743335 1.29170895 0.6663828 2672638.04 90.1530194
507.6 0.3 0.8130252 1.37966669 0.61662727 3707994.1 108.359902

delta
-0.0075670886

q3-r2 2.767777468E-05
tres raíces

Zlíquido 0.04445423
Zvapor 0.67080353
 MATRIZ A
A B comp. 1 comp 2 comp 3 comp4 comp5
0.0528914 0.0093494132 0.052891399 0.07234792 0.09193341 0.11191386 0.13182061
0.09896168 0.0129767066 0.0723479212 0.09896168 0.12575185 0.15308226 0.18031187
0.15979446 0.0166837632 0.0919334143 0.12575185 0.15979446 0.19452356 0.22912456
0.23680054 0.020786299 0.111913858 0.15308226 0.19452356 0.23680054 0.27892159
0.32853494 0.0249842027 0.1318206084 0.18031187 0.22912456 0.27892159 0.32853494

MATRIZ B
comp. 1 comp 2 comp 3 comp4 comp5
0.0093494132 0.01101474 0.01248933 0.01394058 0.01528357
0.0110147443 0.01297671 0.01471395 0.01642369 0.01800591
0.0124893313 0.01471395 0.01668376 0.0186224 0.02041643
0.0139405774 0.01642369 0.0186224 0.0207863 0.02278879
0.015283574 0.01800591 0.02041643 0.02278879 0.0249842
Ai Bi Ci Ki Antoine VF_ANTOINE Sumatoria Fugacidad Vapor
9.0435 1511.4 -17.16 8.524103984 0.2193301303 8.9134E-05 1.1285846893
9.1058 1872.5 -25.16 2.24496591 0.2783048534 1.0015859309
9.058 2154.9 -34.42 0.625590096 -0.1164682697 0.8882795
9.2131 2477.1 -39.94 0.191993823 -0.1750464866 0.7864179447
9.2164 2697.6 -48.78 0.061727038 -0.2060310929 0.6967123214
Fugacidad liq Ki Peng Robinson Pmmix
5.0365759799 4.4627364056
1.9090618976 1.9060390513
0.723164207 0.8141178616
0.2777710113 0.3532104184
0.1083121431 0.1554617878