Urea Unit Process Book

PETRO VIETNAM
. PHU MY - FERTILIZER PROJECT
UREA
UNIT 20
2200MTPD
UREA UNIT
PROCESS BOOK
Volume 1
MErI
Rev. 0
Feb, 20112
Chemical and Fertilizer Plants Division
CUSTOMER JOB UNIT No.
PETROVIETNAM 810312 20
PLANT LOCATION
~11iI1iil1ii1ilIPllr@@mltii PHU MY - FERTILIZER PROJECT SPC No. ZA-E-6019
i
PROJECT I UNIT Rev.
2200 MTPD UREA PLANT sh1of22 0
UREA UNIT
PROCESS BOOK
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JOB UNIT No,
810312 20
SPC No. ZA-E·6019

Rev.
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I I I
INDEX
VOL.1
1. Generals
1.1 Design Basis
1.2 Process Description
1.3 Equipment list
1.4 Production and Consumption Figures
1.5 Electric Load list
1.6 Effluent Data
1.7 General Requirement for Piping
1.8 Special Requirements for Instrumentation
2. Balances and Process flow diagrams
2.1 Process Flow Diagrams
2.2 Material Balances
2.3 Steam Balances
2.4 Cooling Water Balances
VOL.2
3. Piping & Instrument Diagrams

4. Equipment Process Specifications
5. Instrument Process Specifications
5.1 Interlock system
5.2 Control Valves
5.3 Safety and thermal Relief
5.4 Instrument Data Sheet
Form code: MDTGG,QUA.0005 Sh. 01JRev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
This document is the property of Snamprogetti who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
sh30f22 oI I
I I I I
1. Generals
1.1 Design Basis
Please see SPC. W RA-E-6000 rev. 1 hereafter attached.
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook,doc
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PLANT LOCATION
PHU MY - FERTILIZER PROJECT SPC No. RA - E - 6000
PROJECT I UNIT Rev.
2200 MTPD UREA PLANT Sh1of6 oI 1 I I I
I I I I
DESIGN BASIS
FOR UREA UNIT
;/J .nI 1 I .. k»I

Revised on sheets 3 and 6 where marked <1 > 17/01/02
o Issue RICCARDI RICCARDI 10107101
Form code: MDT.GG.QUA.0004 Sh. 01iRev. 3.96 File code: spcjobve.dot Data file: designbasis.doc
This document is the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNIT No.
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SPC No. RA - E - 6000

Rev.
Sh2of6 0 1 I I I
1. Design Basis for Urea Plant
1. 1 Plant Capacity
The Urea Unit has a nameplate capacity of 2200 MTPD of prilled urea.
The Urea Unit is anyhow designed for the production of not less than 2385 MTPD of prilled
urea.
The Prilling Tower and annexed finishing sections is designed for the production of 2640
MTPD of prilled urea.
<1> The design stream factor of Urea Unit is 8000 hours per year.
The turndown ratio of Urea Unit is from 50 to 100% of the nameplate capacity during special
conditions of operation of the Unit.
1.2 Climatic Conditions
Temperature dry bulb avg. 26.9°C

dry bulb min. 18°C
dry bulb max. 35°C
Relative humidity avg. 82 %
min. 28%
max. 99%
Barometric pressure avg. (monthly) 1011.2 mbar
Min. (monthly) 1002 mbar
Max. (monthly) 1016mbar
1.3 Raw Materials Characteristics
Urea Unit is designed on the basis of the following characteristics of raw materials:
Carbon Dioxide from Ammonia Unit to Urea Unit
Composition (on a dry basis): C02 99 %vol min.

Inerts 1 %vol max.
Water saturated
Pressure 0.18 barg
Temperature 45°C
Pressure at discharge of C02 Compressor 157 bar g
Ammonia
Composition: NH3 99.8 %wt min.

H20 0.2 %wt max.
Form code: MDT,GG,QUA.0005 Sh, 01/Rev. 3.96 File codespcjobve,dot Data file; designbasis,doc
This document is the property of Snamprogetti who will safeguard ils rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312 20
SPC No. RA - E - 6000

Rev.
Sh 3 of 6 oI 1 I I I
I I I
Oil 5 ppm wt max.

Pressure 24 barg min.
Temperature 25'C (ammonia from Ammonia Unit)
-33'C (ammonia from Ammonia Storage Tank)
1.4 Utilities and Chemicals Characteristics
Urea Unit is designed on the basis of the following characteristics of utilities and chemicals:
Steam
Pressure (bar Q) Temperature ('C)

Normal Design for Normal Design for
mechanical mechanical
calculation calculation
HiQh Pressure Steam (HS) (1) 38.2 44 370 420
Medium Pressure Steam (MS) (2) 23.5 28 325 370
Medium Pressure Saturated Steam (MSS) (3) 21.8 28 219 244 <1>
Medium-Low Pressure Saturated Steam (MLSS) (3) 4.9 7.1 158 190
Low Pressure Saturated Steam (LSS) (3) 3.4 6 147 180
NOTES:
(1) From Battery Limits for Urea Hydrolyzer consumption
(2) From C02 Compressor Steam Turbine for Urea Unit process consumption
(3) Inside Urea Unit Battery Limits
Fouling Factor for steam 0.000086 m 2,CIW
Cooling Water
River Cooling Water is used for Final Process Condensate Cooler only.
Fresh Cooling Water from a closed circuit is used for all other exchangers in Urea Unit.
Fresh Cooling Water is cooled by heat exchangers with River Cooling Water.
A) RIVER COOLING WATER
Pressure operating supply 4 bar g

design 6 bar g
Temperature supply 34'C
return 42'C <1>
design
2
Fouling Factor 0.000344 m ,CIW
2
0.0000516 m ,CIW overall for plate heat exchangers <1>
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve,dot Data file: designbasis.doc
JOB UNIT No.
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B) FRESH COOLING WATER
Pressure operating supply 5 bar g

design 7 barg
Temperature supply 37'C
return 46'C
design 75°C
Fouling Factor 0.000086 m2,CfW
Flushing Condensate
Pressure bar g) Temperature eC)

Normal Design for Normal Design for
mechanical mechanical
calculation calculation
LP Flushina Condensate (LW) (1) 9 12 120 150
MP Flushing Condensate (HW) (1) 22.5 32 120 150
Cold MP Flushino Condensate (1) 26 32 50 150
HP Flushing Condensate (KW) (1) 175 194 120 150
NOTES:
(1) Inside Urea Unit Battery Limits
Demi Water from B. L.
Pressure normal 9 bar g

design 13.5 bar g
Temperature normal 45'C
design 75'C
Conductivity <0.2 Ils @ 25'C
PH 6.5+7
Chlorides <0.1 mgll
Nitrogen
Pressure operating 7 bar g

design 11 bar g
Temperature operating 10+20'C
design 60'C
Form code: MDT.GG.OUA0005 Sh. 01/Rev. 3,96 File codespcjobve,dot Data file: designbasis,doc
This document is the property of Snamprogettl who will safeguard its rights accordinQ to the civil and penal pn;lVisions of the law,
JOB UNIT No.
810312 20
SPC No. RA· E· 6000

Rev.
Sh50f6 oI 1 I I I
I I I I
Instrument Air
Pressure operating 7.5 bar g

design 11 bar g
Temperature operating 45'C
design 75'C
Dew Point at condition ··25'C
Plant Air
Pressure operating 8 bar g

design 11 bar g
Temperature operating 45'C
design 75'C
Sulphuric Acid
Composition: H2S04 98 %wl min.

H20 balance
State liquid
3
Density 1840 kg/m
Solidification point -1.9'C
1.5 Product and Recoveries
A) PRODUCT
Prilled urea produced by Urea Unit at nameplate and design capacity will have the following
characteristics:
Nitrogen content 46.3 %wl min.

Biuret content 1.0 %wl max.
Moisture content 0.4 %wl max.
Prills Size Distribution 90 %wl min. between 1.4 mm and 2.8 mm
Prills Size Distribution 2 %wl max. below 1 mm
Prills Temperature 65'C max. at nameplate capacity only
B) RECOVERIES
Process Condensate from Urea Unit to B.L.
Form code: MDT.GG.QUA.0005 Sh. 0i/Rev. 3.96 File codespcjobve.dot Data file: designbasis.doc
JOB UNIT No.
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Composition: NH3 3 ppm

Urea 3 ppm
Water balance
Pressure normal 3 bar g <1>
design 7 bar g <1>
design 120'C
Steam Condensate from Urea Unit to B.L.
Pressure normal 5 bar g

design 10 bar g
design 120'C
Form code: MDT.GG,QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: deslgnbasis,doc
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JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
Sh4of22 0 I I
I
1.2 Process Description
Please see SPC. N"ZA-E-6003 rev.O hereafter attached.
Form code: MDT,GG,QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Oata file: ureaunitprocessbook.doc
PLANT LOCATION
~lrn~IiililIPllr@~@ltlt" PHU MY" VIETNAM SPC No. ZA-E-6003
PROJECT I UNIT Rev.
FERTILIZER PROJECT Sh 1 of 13 0 I I I
I I I I
PROCESS DESCRIPTION
-
FOR UREA UNIT
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JOB UNIT No.
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SPC No. ZA-E-6003

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The Urea Unit is characterized by the following main process steps:
a) Urea synthesis and NH 3, CO 2 recovery at high pressure;
b) Urea purification and NH 3, CO 2 recovery at medium and low pressures;
c) Urea concentration;
d) Urea prilling;
e) Waste water treatment.
The urea production unit is also provided with the following:
f) Auxiliary installation;
g) Steam networks;
h) Flushing networks.
a) Urea synthesis and NH 3, CO2 recovery at high pressure
Urea is produced by synthesis from liquid ammonia and gaseous carbon dioxide.
In the Urea Reactor, R-1001, the ammonia and carbon dioxide react to form ammonium carbamate,
a portion of which dehydrates to urea and water.
The reactions are as follows:
2 NH3 + CO 2 ++ NH2 COONH 4
NH2 COONH 4 ++ NH CONH + H 0

2 2 2
=
In synthesis conditions (T 188+190°C, P = 152+157 bar g.), the first reaction occurs rapidly and is
completed, the second reaction occurs slowly and determines the reactor volume.
The fraction of ammonium carbamate that dehydrates is determined by the ratios of the various
reagents, the operating temperature and the residence time in the reactor.
The mole ratio of ammonia to carbon dioxide is around 3.3 +3.6
The mole ratio of water to carbon dioxide is around 0.5+ 0.7.
The liquid ammonia feed to Urea Unit, coming from the relevant Ammonia Unit, is filtered through
NH3 Filters, FL-1002 NB, then enters into NH3 Recovery Tower, T-1005, and is collected in the
Ammonia Receiver Tank, V-1005. From V-1005 it is drawn and pumped to about 22 bar g pressure
by means of Ammonia Booster centrifugal Pump, P-1005 NB. Part of this ammonia is sent to
Medium Pressure Absorber, T-1001, the remaining part enters the high pressure synthesis loop.
The ammonia to the synthesis loop is pumped by H.P. Ammonia centrifugal Pump, P-1001 NB, to a
pressure of about 220 bar g. Before entering the reactor, the ammonia is heated in the Ammonia
Pre heater, E-1007, and used as propelling fluid in the Carbamate Ejector, J-1 001, where the
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carbamate coming from the. Carbamate Separator, V-1001, isprope:\Ied up to the synthesis
pressure.
The liquid mixture of NH 3 . and carbamate enters the urea reactor bottom where it reacts with the
carbon dioxide compressed feed.
The carbon dioxide feed, drawn to the Urea Unit battery limits, from the rel.evant Ammonia Unit, at
0.18 bar g pressure and 45'C temperature, enters the CO2 Compressor, PK-1 001, and leaves it at a
pressure of about 157 bar g.
A small quantity of air is added to the carbon dioxide feed at the PK-1001 suction in order to
passivate the stainless steel surfaces of H.P. loop items, thus protecting them from corrosion due to
both the reagents and reaction products.
The reaction products leaving the reactor flow to the upper part of Stripper, E-1001, which operates
at about 147 bar g. It is avertical in-tube falling film decomposer in which the liquid is distributed on
the heating surface as a film and flows by gravity to the bottom. In practice it is a vertical shell-and-
tube exchanger, with the heating medium on the shell side, and liquid upper head onthe upper tube
sheet specially designed to permit the uniform distribution of urea solution. In fact, each tube has an
insert-type distributor (ferrule) designed to put the feed uniformly around the tube waU in·film form.
The holes of the ferrule act as orifices and their diameter and liquid head control theflbw rate. As
the liquid film flows, it is heated and decomposition of carbamate and surface evaporation occur.
The carbon .dioxide content of the solution is reduced by the stripping action oUhe ammonia as it
boils out of the solution. Thevapour formed (essentiaUy ammonia and carbon dioxide) are removed
by flowing to the top of the tube. The carbamate decomposition heat is supplied .by means of
condensing steam at about 21.. 8 bar g (saturated).
The mixed stream of overhead gases from the Stripper, and the recovered solution from the bottom
of Medium Pressure Absorber, T-1001, enter the Carbamate Condensers, E-1005 AlB, where
except for incondensable gases, is condensed and recycled to the Urea Reactor, R-1 001, by means
of Carbamate Ejector,. J-1 001.
Condensing the process gases at high pressure (about 144 bar g.) permits the production of
saturated steam at 4.9 bar g. in the shell side of 1st Carbamate Condenser, E-1 005 A, and at
3.4 bar g. in the shell side of 2nd Carbamate Condenser, E-1005 B.
From the top of the Carbamate Separator, V-1001, come out the incondensable gases consisting of
inert gases ( passivation air plus inerts with CO 2 from B.L.) containing a little quantity of NH3 and
CO 2 , which are sent directly to the bottom of the Medium Pressure Decomposer, E-1002.
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b) Urea purification and NH 3, CO, recovery at medium and low pressures
Urea purification and relevant overhead gases recovery take place in two stages at decreasing
pressure, as follows:
1st stage at 19.5 bar g. pressure;

2nd stage at 4.0 bar g. pressure.
It is pointed out that the exchangers where Urea purification occurs are called decomposers
because in these apparatuses the residual carbamate decomposition takes place.
1ST PURIFICATION AND RECOVERY STAGE AT 19.5 BAR G. PRESSURE
The solution, with a low residual CO 2 content, leaving the bottom of the Stripper, E-1001, is
expanded to the pressure of 19.5 bar g. and enters the upper part of Medium Pressure
Decomposer. This item is mainly divided in three sections:
top Separator, V-1002, where the released flash gases are removed before the solution
enters the tube bundle;
in-tube falling film type Decomposer, E-1002A1S, where the carbonate is decomposed and
the required heat is supplied by means of condensing steam at 4.9 bar g. (in the upper part
of the shell, E-1002A) and cooling of steam condensate directly flowing out of the Stripper
Steam Condensate Separator, V-1009, at about 22 bar g. pressure (in the lower part of the
shell, E-1002/S).
urea solution Holder, Z-1002, where the 1st stage's purified urea solution at 60+63 wt% is
collected.
The NH3 and CO2 rich gases leaving the top separator, V-1002, are sent to the shell side of the
falling film Vacuum Preconcentrator, E-1004, where they are partially absorbed in aqueous
carbonate solution coming from the recovery section at 4.0 bar g.
The total heat from the shell side, due to condensation/absorption/reaction of reagents, is
removed by evaporating urea solution, coming from the 2nd purification step, up to 84+86 wt%,
thus allowing a considerable saving of L.P. steam in the 1st vacuum concentration stage.
From the Vacuum Preconcentrator, E-1004, shell side the mixed phase is sent to Medium
Pressure Condenser, E-1006, where CO 2 is almost totally absorbed and condensation/reaction
heat is removed by cooling water coming from Ammonia Condenser, E-1009.
The mixed phase effluent from E-1006 flows to the Medium Pressure Absorber bottom, T-1 001,
where the gaseous phase coming up from the liquid phase enters the rectification section. This
is of bell-cap trays type and performs CO 2 absorption and NH3 rectification.
The trays are fed by pure reflux ammonia, in order to balance the energy entering the column,
and to remove residual CO 2 and H2 0 contained in the rising stream of gaseous ammonia and
inerts.
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Reflux NH3 is drawn from the Ammonia Receiver, V-1005, and sent to column by means of
Ammonia Booster Pump, P-1005 AlB.
A gaseous current of saturated ammonia and inert, with a few ppm of CO 2 (20-100 ppm)
residue, comes out the top of the rectification section, it is partially condensed in the Ammonia
Condenser, E-1009. From here two phases are sent to the Ammonia Receiver V-1 005.
The uncondensed stream, saturated with ammonia, leaving the V-1005, rises along the
Ammonia Recovery Tower, T-1005, where an additional amount of ammonia is condensed by
means of the descending liquid ammonia stream coming from the Urea Unit B.L.
The gaseous stream leaving the T-1005 top, rises along the Medium Pressure Ammonia
Absorber E-1 011, where its residual ammonia content is drastically reduced by means of
countercurrent stream of an ammonia water diluted flow which absorbs gaseous ammonia. As
the ammonia in the gas phase is absorbed, heat is generated which increases the temperature
of descending liquid, thereby tending to impede further ammonia absorption. To maintain the
temperature at a favorable level a coaling water flow is provided in the shell side of E-1 011.
The M.P. Inerts Washing Tower T-1003, connected to the upper part of E-1011, consists of
three valve trays where the inert gases are submitted to a last washing step by means of the
pure water addition. Here the ammonia content of gas raising stream is minimal and
consequently the temperature is less sensitive to absorption heat. Finally the inerts are
collected to the vent stack.
From the bottom of E-1011 the NH3 - H2 0 solution is recycled back to the Medium Pressure
Absorber, T-1001, by means of the centrifugal pump P-1007 AlB.
The T-1 001 bottom effluent is recycled, by means of H.P. Carbonate Solution centrifugal Pump
P-1002 AlB, to the synthesis recovery section after pre-heating in the tube side of H.P.
Carbonate Pre heater, E-1013. In this exchanger the shell side heating fluid is the process
condensate from the bottom of Distillation Tower, T-1002.
2ND PURIFICA TlON AND RECOVERY STAGE A T 4. 0 BAR G.
The solution, with a very low residual CO2 content, leaving the bottom of the M.P. Decomposer
is expanded to the pressure of 4.0 bar g. and enters the upper part of Low Pressure
Decomposer. This item is mainly divided in three sections:
top Separator, V-1003, where the released flash gases are removed before the solution
enters the tube bundle;
in-tube falling film type Decomposer, E-1003, where the carbonate is decomposed and the
required heat is supplied by means of condensing L.P. steam at 4.9 bar g. (saturated);
urea solution Holder, Z-1003, where the 2nd stage's purified urea solution at 69+71 wt% is
collected.
The gases leaving V-1003 are firstly mixed with the vapors coming from rectification section of
the Distillation Tower, T-1002, and subsequently sent to shell side of H.P. Ammonia Preheater,
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E-1007, where they are partially condensed. The condensation heat is recovered on tube side
where the H.P. liquid ammonia (feed to urea reactor) is preheated.
The E-1007 shell side effluent is sent to L.P. Condenser, E-1008, where the remaining NHa and
CO 2 vapors are totally condensed. Condensation heat is removed by cooling water flowing in
the tube side.
The carbonate solution at the exit of E-1008 is recovered into Carbonate Solution Accumulator,
V-1006. From here the carbonate solution is recycled back to the M.P. Absorber bottom, T-
1001, by means of centrifugal pump, P-1003 AlB, through the shell sides of Vacuum
Preconcentrator, E-1004, and then M.P. Condenser, E-1006.
One little part of the low pressure carbonate solution is used also as reflux into rectification
section of Distillation Tower, T-1002.
The V-1006 is designed with a Low Pressure Inarts Washing Tower, T-1004, in order to help
the pressure control of 2nd recovery stage. T-1004 is connected to the upper part of E-1012
where cooling water is provided to remove the absorption heat.
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c) Urea concentration section
The urea solution leaving the bottom of L.P. Decomposer is expanded to the pressure of 0.33 bar
abs. and enters the upper part of Vacuum Preconcentrator. This item is mainly divided in three
parts:
top Separator, V-1004, where the released flash gases are removed before the solution enters
the tube bundle. Vapors are extracted by 1st Vacuum System, PK-1003;
intake falling film type Concentrator, E-1004, where the low residual carbonate is decomposed
and water is evaporated. The required heat is supplied by means of partial condensation (in the
shell side) of overhead gas coming from the M.P. Decomposer;
bottom liquid Holder, Z-1004, where the urea solution at 84+87% wt. is collected.
The urea solution leaving the Vacuum Preconcentrator Holder, Z-1004, is sent by 85% Urea
Solution Pump, P-1006 AlB, to the bottom of 1st Vacuum Concentrator, E-1014. It operates at the
same pressure (i.e. 0.33 bar abs.) as E-1004 tube side.
Saturated steam at 3.4 bar g is supplied to the E-1014 shell side to concentrate the urea solution
flowing in the tube side.
The mixed phase coming out from the process side of E-1014 enters the 1st gas-liquid Vacuum
Separator, V-1014, from where vapors are again extracted by the 1st Vacuum System, PK-1003,
while the urea melt (- 95 wt%), by gravity flow, enters the bottom of 2nd Vacuum Concentrator, E-
1015, operating at a pressure of 0.03 bar abs.
Saturated steam at 3.4 bar g. is supplied to the E-1015 shell side to concentrate the urea melt
flowing in the tube side.
The mixed phase coming out from the process side of E-1 015 enters the 2nd gas-liquid Vacuum
Separator, V-1 015, from where vapors are extracted by the 2nd Vacuum System, PK-1004, while
the urea melt (- 99.75 wt%) is sent to prilling section.
"-"
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d) Urea prilling
The melted urea leaving the 2nd Vacuum Separator Holder, Z-1015, is sent to the Prilling Bucket Z-
1009 AlB by means of centrifugal pump P-1 008 AlB.
Droplets of molten urea from the prilling bucket fall along the natural draught Prilling Tower, Z-1008,
and solidify and cool while encountering a countercurrent air flow.
Some residual ppm of free ammonia are contained in the urea melt coming from the Holder Z-1015,
and could be released to the atmosphere, entrained by the cooling air flowing through the Prilling
Tower.
In order to reduce its emission, a 98% sulphuric acid solution is taken from relevant storage tank,
TK-1005, and injected in the melt by means of proportioning pump, P-1020 AlB, at the suction of P-
1008 AlB pump. In this way H2S04 reacts with NH3 giving ammonium sulphate, which mixes and
solidifies togheter with the urea product.
Solid prills are collected at the centre of Prilling Tower bottom by means of the conical double arm
Rotary Scraper, Z-1007, and through a conical hopper, they fall onto Prilling Tower Belt Conveyor,
N-1001.
The screen Z-1012, downstream of N-1001, removes any urea lumps or agglomerates which are
discharged directly and dissolved in the underground Urea Close Drain Tank, TK-1003, through
Urea Recycle Belt Conveyor N-1 002.
Finally the urea product is sent to B.L. by the Product Belt Conveyor N-1003.
N-1003 is provided with a weight sensitive single bridge type scale, W-1001.
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e) Waste water treatment
This section provides conditions to process the water containing NH 3-C0 2 and urea coming out of
Vacuum Systems, so as to have an almost NH 3-C0 2-urea free process condensate to be sent to
B.L.
The process water containing NH 3, CO 2 and urea, coming from the Vacuum Systems, is collected in
the Process Condensate Tank, TK-1002, together, if necessary, with the drain waters accumulated
into underground Carbonate Close Drain Tank, TK-1004, and fed to TK-1 002 by means of pump P-
1016 NB. From TK-1002 the process condensate is pumped, by means of P-1014 NB, to the upper
part of Distillation Tower, T-1002.
Before entering the column the process condensate picks-up heat from:
• the purified condensate leaving the bottom of distillation column itself, by means of 1st
Preheater, E-1016;
the steam condensate at 120°C, leaving the Steam Condensate Accumulator, V-1010, by
means of 2nd Preheater E-1017.
The Column T-1002 is provided with 55 trays and it is divided into two main portions by a chimney
tray perched between the plates numbered (from the bottom) 35 and 36.
Column process conditions are:

• pressure (bottom/top): 4.7/4.2 bar g.;
temperature (bottom/top): 157/130 °C.
The condensate from the chimney tray is drawn and pumped, by centrifugal pump P-1 015 NB, to
Urea Hydrolyzer, R-1002, where process conditions are suitable to decompose urea into CO 2 and
NH 3. R-1002 itself behaves as a reactor and live steam is added so as to provide enough heat to
decompose urea.
Hydrolyzer process conditions are:

pressure: 34.3 bar g.;
temperature: 235°C;
live steam available at S.L.: temp. 370°C, press. 38.2 bar g.
The outcoming vapors from the Hydrolyzer as well as the vapors from the top of the Distillation
Tower are mixed with the L.P. decomposer overhead gas, upstream of E-1 007 for heat recovery.
The hydrolyzed condensate leaving the bottom of R-1002, after decreaSing its temperature when
passing through Hydrolyzer Preheater, E-1018, enters the Distillation Tower immediately under the
chimney tray, where the final NH3 and CO2 stripping takes place. Steam (at a press. 'of 4.9 bar g.),
injected directly into the Column bottom, provides the necessary stripping driving forces.
The purified process condensate leaves the column bottom at 157"C is sent to S:L: after cooling to
45°C by means of :
• H.P. carbonate preheating in E-1013;
distillation tower feed preheating in E-1016;
final cooling by river cooling water in E-1024, Purified Condensate Cooler.
JOB UNIT No.
810312
I 20
SPC No. ZA-E-6003

Rev.
Sh 100113 oI I I
I I I
The contaminants (Le. NH3 -C0 2 -urea) in this treated water are reduced to few ppm and it's easy to
foresee convenient utilization due to its good characteristics.
During start-up and section upsets the processed condensate is recycled to the Process
Condensate tank, TK-1002, until it contains the specified ppm of NH3 and urea.
JOB UNIT No.
810312 20
SPC No. ZA-E-GOO3

Rev.
Sh 11 of13 oI I I I
I I I I
f) Auxiliary installations
To make the Urea unit operation easier, the following auxiliary installations have been provided:
Urea Solution Tank TK-1001

Tank TK-1001 is used to collect both the 70+75% urea solution in case of concentration section
failure, and urea melt in case of prilling section failure.
In the same tank it has also been envisaged to recover the urea solution coming from Urea
Close Drain Tank, TK-1003, after being filtered through Filters FL-1001NB.
The urea solution contained in TK-1001 can be heated by means of LP. saturated steam.
Urea Solution Recovery Pumps P-1009 AlB

This pump takes the urea solution from TK-1001 and recycles it to 1st Vacuum Concentrator E-
1014.
Urea Close Drain Tank TK-1003

The buried tank TK-1003 is used both to collect urea solution drains and to dissolve lumps by
means of Stirrer Z-1011. The immersed pump P-1019 NB permits to send back the urea
solution to the Urea Solution Tank TK-1001. The duty required for the urea lumps dissolution
and the heating of the urea solution is provided by means of direct injection with 3.4 bar g
saturated steam.
JOB UNIT No.
810312 20
SPC No. ZA-E-6003

Rev.
Sh 12of13 oI I I I
I I I I
g) Steam networks
Five steam networks are provided in the Urea unit area:
H.P. steam network (HS) at p = 38.2 bar g. T = 370°C;
M.P. steam network (MS) at p ,= 23.5 bar g. T =325°C;

M.P. saturated steam network (MSS) at p'" 21.8 bar g. T = 219°C;
• M.L.P. saturated steam network (MLSS) at p= 4.9 bar g. T =158°C;

L.P. saturated steam network (LSS) at p= 3.4 bar g. T =147°C.
H.P. steam network at p =38.2 bar g and T = 370°C

The steam of this network is used to drive the CO 2 Compressor, PK-1 001, by means of CO 2
compressor driver Steam Turbine.
The steam of this network is also used for Urea Hydrolyzer R-1002.
M. P. steam network at p = 23.5 bar g and T = 325°C

The steam of this network is withdrawn from steam turbine. It is used to feed the saturated
steam network at 21.8 bar g.
M.P. Saturated steam network at p = 21.8 barg. and T = 219°C

This steam is obtained by desuperheating of e)(traction steam from CO 2 compressor driver
Steam Turbine. It is used in the Stripper E-1 001 and for L.P. steam boosting, when necessary.
The condensate coming from Stripper is collected in the Stripper Steam Condensate Separator,
V-1009, and utilized in the lower part of M.P. Decomposer, E-1002 B. From here the subcooled
condensate is sent to shell side of 151 Carbamate Condenser, E-1 005 A.
• =
M.L.P. saturated steam network at p 4.9 bar g and T = 158°C
The steam of this network is produced in 1st Carbamate Condenser E-1005 A or it is obtained
by boosting the 3.4 bar g steam, by means of 21.8 bar g. steam. It is used in the upper part of
M.P. Decomposer, E-1002 A, in L.P. Decomposer, E-1003, and also injected into the bottom of
Distillation Tower, T-1002.
Should the M.L.P. steam be in excess, the extra steam produced would be reinjected into the
CO2 compressor steam driver turbine.
• =
L.P. Saturated steam network at p 3.4 bar g and T 147"C=
The steam of this network is produced in 2nd Carbamate Condenser, E-1005 B, and it is
utilized in the following equipment or services:
1st Vacuum Concentrator, E-1014;

2nd Vacuum Concentrator, E-1015;
1st Vacuum System, PK-1003;
2nd Vacuum System, PK-1004;
steam tracing;
JOB UNIT No.
810312 20
SPC No. ZA-E-6003

Rev.
Sh 130113 oI I I
I I I
. flushing.
The steam condensate coming from L.P. networks and from tracing are collected into Steam
Condensate Receiver, V-1010, operating at a pressure of about 1 bar g and temperature of 120'C.
The flash steam rises along the countercurrent packed Steam Recovery Tower, T-100S, where it is
condensed by a descending subcooled condensate quench, recirculating at a temp. of 45'C. That
condensate is first cooled in E-1017, where heat is recovered by preheating the process water
solution to Distillation Tower T-1 002, and finally in E-1023 by C.w.
The condensate collected in the accumulator V-1 01 0 is returned to battery limits by means of
centrifugal pump P-1013 AlB, performing also the level control of Condensate Accumulator itself.
An adequate steam let-down system assures that M.P.,M.L.P. & L.P. steam networks remain under
pressure control during normal operation or partial/total urea unit upset, start-up and shut-down
conditions.
h) Flushing networks
Three flushing networks have been provided in the Urea unit operating at the following pressures:
very high pressure flushing (KW) p = 175 bar g.;
high pressure flushing (HW) p = 22.5 bar g.;
low pressure flushing (LW) p = 9.0 bar g.
KW flushing is used in urea synthesis and H.P. recovery stage.
HW flushing is used in the M.P. purification and recovery stage.
Low pressure flushing is used in the remaining parts of the urea unit.
The condensate at 120'C, from the receiver V-1 01 0, is used to produce all the above mentioned
flushings. The centrifugal pump P-1010 AlB is provided for HW flushing and also, after pressure
reduction, for LW flushing. Cold flushing condensate at 50'C is also provided by the cooler E-1010.
Reciprocating pump, P-1 011, downstream and in series with P-1 010 AlB, is used to produce KW
flushing.
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
8h50122 0 I
I
1.3 Equipment list
Please see SPC. W ZA-E-6001 rev.2 hereafter attached.
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve,dot Data file: ureaunitprocessbook.doc
This document is the property of $namprogetti who will safeguard its rights according to the civil and penal provisions of the law.
PETROVIETNAM 810312 I 20
PLANT LOCATION
PHU MY - FERTILIZER PROJECT SPC No. ZA-E-6001
PROJECT / UNIT Rev.
2200 MTPD UREA PLANT Sh 1 of 5 oI 1 21
I I I I
EQUIPMENT LIST
-
FOR UREA UNIT
, ,i ' ~ "
"'". -
II
/.J-, rdx ([J X
2 Revised where marked <2> on sheets 3 ZaW'.JIIl<O """tt9) 'S06ttO 14f02/02
1 Revised where marked <1> on sheets 2, 3, 4, 5 Zamblanco Scotto Scotto 04/02102

0 Issue RICCARDI RICCARDI 11/07/01
Form code: MDT.GG.QUA0004 Sh. 01/Rev. 3.96 File code: spcjobve.dot Data file: eq~lIst.doc
JV" UNIT No.
810312
I 20
SPC No. ZA-E-6001

Rev.
Sh 2 of 5 0 1 2 I I
I
GENERAL NOTE: All equipment tag numbers to be prefixed by 20
Item No Description
<1> Deleted
HEAT
EXCHANGERS E-1001 Urea Stripper
E-1002NB Medium Pressure Decomposer [Assembly with Z-1 002N-1002]
E-1003 Low Pressure Decomposer [Assembly with Z-1003N-1003]
E-1004 High Pressure Carbonate Preheater
<1> Deleted
51
E-1005 A 1 Carbamate Condenser
nd
E-1005 B 2 Carbamate Condenser
E-1006 Medium Pressure Condenser
E-1007 Ammonia Preheater
E-1008 Low Pressure Condenser
E-1009 Ammonia Condenser
E-1010 Flushing Condensate Cooler
E-1011 Medium Pressure Ammonia Absorber [Assembly with T-1003]
E-1012 Low Pressure Ammonia Absorber [Assembly with T-1004]
E-1013 Vacuum Preconcentrator [Assembly with Z-1004N-1004]
E-1014 1st Vacuum Concentrator [Assembly with V-1014]
nd
E-1015 2 Vacuum Concentrator [Assembly with Z-1 015N-1 015]
51
E-1016 1 Distillation Tower Preheater
nd
E-1017 2 Distillation Tower Preheater
E-1018 Hydrolyzer Preheater
E-1023 Steam Condensate Cooler
E-1024 Purified Condensate Cooler
FILTERS AND
SCREENERS FL-1001 NB Urea Solution Filters
FL-1002 NB Ammonia Filters
Form code: MDT.GG.QUA.0005 Sh. 01/Rev, 3-.96 File codespcjobve.dot Data file: eq-listdoc
JOB UNIT No.
810312
I 20
SPC No. ZA-E-6001

Rev.
Sh 3015 oI 1 I 2
I I I I
Item No Description
EJECTOR J-1001 Carbamate Ejector

J-1002 Steam Ejector for T-1002
MATERIAL HANDLING
AND CONVEYING
<2> N-1001 Prilling Tower Belt Conveyor
<2> N-1002 Urea Recycle Belt Conveyor
<2> N-1003 Product Belt Conveyor
PUMPS P-1001 AlB High Pressure Ammonia Pumps

P-1002 AlB High Pressure Carbonate Solution Pumps
P-1 003 AlB Medium Pressure Carbonate Solution Pumps
P-1005 AlB Ammonia Booster Pumps
P-1006 AlB 85% Urea Solution Pumps
1'-1007 AlB Ammonia Solution Pumps
P-1008 AlB Urea Melt Pumps
P-1009 AlB Urea Solution Recovery Pumps
P-1 01 0 AlB Steam Condensate Flushing Pumps
P-1011 High Pressure Flushing Pump
P-1013 AlB Steam Condensate Pumps
P-1014 AlB Distillation Tower Feed Pumps
P-1 015 AlB Hydrolyzer Feed Pumps
P-1016 AlB Carbonate Close Drain Recovery Pumps
P-1 019 AlB Urea Close Drain Pumps
P-1020 AlB Sulphuric acid Pumps
<1> Deleted
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobv9.dot Data file: eq-list.doc
This document is the property of Snamprogetti who will safeguard its rights according to the civil and penal provisions of the law
----
JOB UNIT No.
810312 20
SPC No. ZA-E-6001

Rev.
Sh 4 of 5 o 1 I 2
I I
Item No Description
PACKAGE UNIT PK-1001 C02 Compressor

PK-1002 NB Stripper Passivation Air Compressors
st
PK-1003 1 Vacuum System
nd
PK-1004 2 Vacuum System
REACTORS R-1001 Urea Reactor

R-1002 Urea Hydrolyzer
SILENCERS SL-1001 CO 2 Vent Silencer

SL-1002 Medium Pressure Steam Silencer
SL-1003 Low Pressure Steam Silencer
COLUMNS T-1001 Medium Pressure Absorber

T-1002 Distillation Tower
-.- T-1003 Medium Pressure Inerts Washing Tower [Assembly with E-1011]
T-1004 Low Pressure Inerts Washing Tower [Assembly with E-1012]
T-1005 Medium Pressure Ammonia Recovery Tower [Ass, with V-1 005]
T-1006 Steam Recovery Tower [Assembly with V-1010]
STORAGE
TANKS TK-1001 Urea Solution Tank
TK-1002 Process Condensate Tank
TK-1003 Urea Close Drain Tank
TK-1004 Carbonate Close Drain Tank
<1> Deleted
Form code: MDT.GG,QUA0005 Sh. 01JRev. 3.96 File codespcjobve,dot Data file: eq-lIst.doc
JOB UNIT No.
810312 I 20
SPC No. ZA-E-6001

Rev.
Sh 5 of 5 oI 1 I 2 I I
I I
Item No Description
VESSELS V-1001 Carbamate Separator

V-1002 Medium Pressure Decomposer Separator [Ass. with E-1 002/L-1 002]
V-1003 Low Pressure Decomposer Separator [Ass. with E-1 003/L-1 003]
V-1004 Vacuum Preconcentrator Separator [Assembly with E-1013/L-1004]
V-1005 Ammonia Receiver [Assembly with T-1 005]
V-1006 Carbonate Solution Accumulator
st
V-1014 1 Vacuum Separator [Assembly with E-1014]
nd
V-1015 2 Vacuum Separator [Assembly with E-1015/L-1015]
V-1009 Stripper Steam Condensate Separator
V-1 01 0 Steam Condensate Accumulator [Assembly with T-1 006]
V-1011 Blow-down Holder
st
V-1012 1 Vent Stack Holder
nd
V-1013 2 Vent Stack Holder
V-1028 M.P. Decomposer Steam Condo Separator
V-1029 L.P. Decomposer Steam Condo Separator
st
V-1030 1 Vacuum Concentrator Steam Condo Separator
nd
V-1031 2 Vacuum Concentrator Steam Condo Separator
<1> V-1040 Sulphuric Acid Accumulator
MISCELLANEOUS Z-1001 Prilling Tower Lift

Z-1002 Medium Pressure Decomposer Holder [Ass. with E-1 002N-1 002]
Z-1003 Low Pressure Decomposer Holder [Assembly with E-1003N-1003]
Z-1004 Vacuum Preconcentrator Holder [Assembly with E-1013N-1004]
Z-1005 Carbamate Mixer
Z-1007 Rotary Scraper
Z-1008 Prilling Tower
Z-1009NB Prilling Buckets
Z-1 01 0 Prilling Buckets Support
<1> Z-1011 Urea Close Drain Tank Stirrer
Z-1012 Urea Lumps Separator
nd
Z-1015 2 Vacuum Separator Holder [Assembly with E-1015N-1015]
SCALE W-1001 Weighing Machine
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve-dot Data file: eq-Ustdoc
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
sh6of22 oI I I I
I I I I
1.4 Production and Consumption Figures
Please see SPC. N° ZA-E-6662 rev.O hereafter attached.
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
PLANT LOCATION
Sl'Ismprogettl PHU MY - FERTILIZER PROJECT SPC No. ZA-E-6662
PROJECT I UNIT Rev.
2200 MTPD UREA PLANT Sh 1 of 2 0
EXPECTED CONSUMPTION & PRODUCTION FIGURES
RAW MATERIALS AND CHEMICALS
2200 MTPD 2385 MTPD OTHERS

LOAD LOAD
flmmonia (as 100%) 51792 kg/h 56146 kg/h
f::arbon Dioxide (as 100%) (1) 66892 kg/h 72517 kg/h
~ulphuric Acid Sol. (at 98% cone,) 188 kg/h 203 kg/h
UTILITIES

LOAD LOAD
Fresh Cooling Water (L\T -8,8'C) 6901 m3/h 7483 m3/h
~iver Cooling Water (L\T=8'C) 300 m3/h 325 m3/h
Flectric Power (2) 2300 kWh/h 2500 kWh/h
~,p, Steam (3) (39,2 bar abs; 3200 kg/h 3470 kg/h
370'C)
fIA,P, Steam (4) (24,5 bar abs; 50970 kg/h 55230 kg/h
325'C)
Passivation air (5) 413 Nm3/h 449 Nm3/h
Plant Air -.""",--~-~--"---~.,,,"".~ ---"~~ ..
600 Nm3/h
(discontinuous
( . ":,;,,';;<,, ;,;',c::", 0 S.p,A. as a peak)
.
I'litrogen
----
~j':',.,.;,
i
-,..
I .f' W'r " ". ':'~ , E!i\\\d'

.~"
"','
~~ AI.
"
,;~..
$ " n
.. - .. _-" _. __. ,---
,H9 ~
.
f't\ '" \-! .) .q
!'. b
600 Nm3/h
(discontinuous
as a peak)
bemi Water
I , , ,
,
30 m3/h
I
'"
I tJ
~-, ,
I
.
~:::"l El~
(discontinuous
as a peak)
PRODUCTS AND RECOVERIES

LOAD LOAD
Urea Product 91666 kg/h 99375 kg/h
Steam Condensate (6 bar abs; 28433 kg/h 30851 kg/h
45'C)
Process Condensate (4 bar abs; 52981 kg/h 57384 kg/h
45'C)
{'j! ill- fiL j....vI

0 Issue co semra scona 06/11/01
",. .
ThiS document IS the property of Snamprogettl who will safeguard Its rights according 10 the ciVil and penal provisions of the law.
Snamprogettl JOB UNIT No.
810312 20
SPC No. ZA-E-6662

Rev.
Sh2of2 0 I
I
NOTES:
(1) At C02 Compressor discharge on a dry basis.

(2) Estimated power consumption at shaft. Final consumption is depending on efficiency of
selected pumps. The figure is not including consumption for lighting, air conditioning and
instrumentation.
(3) For Hydrolyzer.
(4) From C02 Compressor Steam Turbine Driver extraction.
(5) Injected upstream of 1st Stage of C02 Compressor in order to have a 0.25%vol.
concentration of oxygen in the C02 feed stream. The figure is excluding passivation air
required for stripper bottom injection.
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 FHe codespcjobve,dot Data file: expec-01.doc
This document is the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
sh7of22 oI I I I
I I I
1.5 Electric Load List
Please see SPC. N° ZA-E-6015 rev.1 hereafter attached.
Form code: MDT.GG.QUAOOOS Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
This document is the property of Snamprogetti who wi!! safeguard its rights according to the civil and penal provisions of the law.
Rev. Desctiptlo n Prepared Checked Approved Date CUSTOM ER JOB UNIT No.
0 Issue ZAMBIANC O scono SCOTTO 11110/01 PETROV IETNAM 8jQ312 20
1 Revised where marked <1> on sheets 5 6.7 ZA¥'!!)\,NCO S~O
Jicq,no 04/02/02
~
PLANT LOCATI ON
f/L.- iliA :J...k.A. PHU MY - FERTILI ZER PROJEC T SPC.No . ZA-E-6015
"' PROJEC T/UNIT Rev.
2200 MTPD UREA PLANT Sh ... ,.L. of......~.... OJ I I I
I
ELECTR IC LOAD LIST (1)
a b I c I d I e I f I 9 I h I i j k I m I
TO BE COMPLE TED BY: PROCESS DEPART MENT
n 0
I p I q r I s I t
ENGINEERING DEPARTMENT ELE DEPART MENT (2)
I DRIVEN MACHINE OR OTHER USER DATA
ELECTR IC USER DATA
I
D"iy Type of Raqulred power
Type of Special Coupling Angular SpeCial Supply. Shape Rated No. of
• T,. Type ServIce Feeding Control data velocity data ed by power poles
m Type Houf51 Notes
PNP KWU PN (3) KWN
Year (kW) {kWJ {kWJ ",,11.
P-1001 A CENTR.
PUMP
H.P. AMMON IA
PUMP
C 8000 N KlB MAIEA 1315 - "~:.:-"
","""""...-_~v> """""",,,,-~.,,",,
:t,:. i..:·i'::tf 'fie; ~Jii ,:t;i:~ s. '.A.

-"--- .-.
(kW)
CENTR.
P-1001 B
H.P. AMMON IA R N KlB ~.- .•. ... - -- -- - . -- ..
,
.~-~".-
PUMP r 1"'.(
t ~n
PUMP MA/EA ~ "l~~~
. ~; I"
'c. ~ f"JT, :U
P·1002 A CENTR.
PUMP
H.P. CARBO NATE
SOL. PUMP
C 8000 N KlB
MA/EA
535 \ .lUi '.->:
I~ j •r~j L. ~
I"L rr
~.-
.-- I-- , •
P-1002 B CENTR. H.P. CARBO NATE R N
'~'~:C:' ::: ;; i l.....".,'.
.~1.~
.
P-1003 A
PUMP
CENTR.
PUMP
SOL. PUMP
M.P. CARBO NATE C BODO N

KlB
K
MA/EA
! ."dIe 'i:':o:"-~"~! ....-... "':---.
".~ r~-r-~'1-TQ
E;/,-\:
:~';-;:;'; .,1
SOL. PUMP B4.4
P-1003 B CENTR. M.P. CARBO NATE

PUMP R N K
SOL. PUMP
CENTR. AMMON IA C BOOO
P-1005 A
PUMP BOOSTE R PUMP E/R K 49
NOTES: (1) For the form use see the INSTRUCTION sheet
8 of 8 (MDT.ELES Y.13 J
(2) ELE Identifies Electrical departmen t
(3) rad/s '" rpm x 0.1047 • rpm '" rad! s l( 9.5493
This document IS the property of Snamprog ettl who will safeguard Its nght according 10 the CIVil
and penal provIsions of law.
Form Code: MDT,ELESY.13 Sh. 01fRav.2.92 Form File: ESY13F1E.MDT Dala File:
Sn~
JOB UNIT No,
810312 20
SPC .No. ZA-E-6015
,,
Rev.
Sh., ...~ ... oL ...~ ... o, 1 I I
I
a b
TO BE COM PLE TED BY:

c I d
PROCESS DEP ART MEN T
I e
., f -r 9 I h
II i I j I k I
ELE CTR IC LOA D LIST
I m r n I D
I p q r s
, I
t
ENGINEERING DEP ART MEN T
I ELE DEP ART MEN T (2)
DRIVEN MAC HINE OR OTHER
, USER DAT A
ELECTRIC USE R DAT A
Duly
Type of Type of Required powe r
• T.g Typ. Servi ce Suppl y
Speci al Coupling Angu lar Speci al Supp ly- Shap e Rated No, of
Contr ol data velocIty data edby
on Type Hour s! P""'" poles
PNP KWU PN (31 KWN Notes
Year
(kWl ('WI (kW)
CENTR. radls
P.l0 05 B AMM ONI A R (kW)
PUMP EIR K
BOO STE R PUMP
P-l0 06 A CENTR. 85% URE A C 8000 N K

PUM P SOL . PUM P 24
P·l0 06 B CENTR. 85% URE A R N K

PUM P SOL PUMP
P-l0 07 A CENTR. AMM ONI A SOL . C 8000 N K

PUM P 6.8
PUMP
P-l0 07 B CENTR. AMM ONI A SOL. R N K

PUMP PUMP
CENTR.
P-l0 08 A URE A MEL T PUMP C 8000 N
PUMP K 86
CENTR.
P-l0 0B B PUMP URE A MEL T PUMP R N K
NOTES: (1) For the form use see
the INSTRUCnON sheet 8 of 8
(MDT .eU:S Y,13)
(2) Elf identI fies Electr ical depar
tmen t
(3)ra dls .. rpm x 0.1047 " rpm "" rad/S x 9.5493
This document IS the property of

Snam proge tll who win safeguard Its right accor
ding 10 the CIVil and penal prOVisions of the law.
Form Code: MOT.ELESY.13 Sh.
02IRev.2.92 Form File; ESY13F2E.MDT Data Ale:
HA16607-a
JOB UNIT No.
810312 20
Snampmgettl SPC.No. ZA-E-6015
Rev.
Sh., ...~, ... of......~ ...

01 1 I I I
I I I I
II I I
ELECTRIC LOAD LIST (1)
I m I n I p q r 5 I I
a b I c d e f 9 h i j k I 0
ENGINEERING DEPARTMENT ELE DEPARTMENT (2)

TO BE COMPLETED BY: PROCESS DEPARTMENT
DRIVEN MACHINE OR OTHER USER DATA ELECTRIC USER DATA

I
RequIred power Coupling Angular Speclal Supply- Shape Rated No, of

t D"1y Type of Type of Special
velocity data ed by power poles
• T.g Type Service
Type Hours!
Supply Control data
PNP KWU PN (3) KWN
Notes
m
Year (kW) (kW) (kWJ rad/s (kW)
CENTR. UREA SOL. D 6000 N K 7.4

P-l009 A PUMP RECOV.PUMP
CENTR. UREA SOL. 0 6000 N K
P-1009 B 7.4
PUMP RECOV.PUMP
CENTR. STEAM CONDo C BODO E1R KIA 47.6
P-1010 A PUMP FLUSH. PUMP
CENTR. STEAMCOND. R E/R KIA
P-l010 B PUMP FLUSH. PUMP
RECIPR. H.P. FLUSHING D 4000 E K 57.5 5B.7
P-l0l1 PUMP PUMP
.
CENTR. STEAM CONDo C N K 24.4

P-l013 A
PUMP PUMP
BODO
NOTES: (1) For the form use see the INSTRUCTION sheet 8 of 8 ( MDT.EL.ESY.13)
(2) ElE identifies Electrical department
(3)radls'" rpm x 0.1047 • rpm = rad/s x 9.5493
This document is the pro perty of Snamprogetb who wlll safeguard Its nght according to the CIVil and penal provIsions of the law. Form Code. MDT.ELESY.13 Sh. 02lRev.2.92 Form File: ESY13F2E.MDT Data Fde: HA16607~7
JOB UNITNa.
8103j2 2Q
Sriamprogetti SPC.No. ZA·E·6015

Rev.
Sh., ...~. ... of... ...~, .. 01 I J 1
a b I c I d I e f 9 h
I i j k I
ELECTRIC LOAD LIST (1)
m n a p I q r I s I t
TO BE COMPLETED BY: PROCESS DEPARTMENT ENGINEERING DEPARTMENT ELE DEPARTMENT (2)
I DRIVEN MACHINE OR OTHER USER DATA ELECTRIC USER DATA
I Duly Required power Coupling Angular Special Supply- Shapll Rated NO,of
Type of Type of Special
velocity data ed by power poles
• T'9 Type Service
Type HoursJ
Supply Control data
PNP KWU PN (3)
KWN Notes
m
Year (kW) (kW) (kW) radls (kW)
CENTR. STEAMCOND.
P.1013 B R N K
PUMP PUMP
P-1014 A CENTR. 0I5T. TOWER

C 8000 N K 34.6
PUMP FEED PUMP
CENTR. DIST. TOWER

P-1014 B R N K
PUMP FEED PUMP
CENTR. HYDROLYZER KlB
P-1015 A C 8000 N 148.5
PUMP FEED PUMP
CENTR. HYDROLYZER
P-1015 B R N KlB
PUMP FEED PUMP
VERTICAL CLOSE DRAIN
P-1016 A D 8000 E KlA!B 1.7
PUMP RECOV.PUMP
VERTICAL CLOSE DRAIN

P-1016 B D 8000 E KlA!B 1.7
PUMP RECOV.PUMP
NOTES; (i) For the form use see the INSTRUCTION sheet 8 OF 8 (MDT.ELESY.13)
(2) ELE identifies Electrical department
e3J radfs '" rpm x 0.1047 • rpm '" rad/a x 9.5493
This document IS the property of Snamprogetti who Will safeguard Its nght accordtnglo Iha cIvil and penal proVIsions of the law. Fonn Code: MDTEL.ESY13 Sh, 02fRev.2.92 Form Fde. ESY13F2E.MDT Data File. HAr6607·8
JOB UNIT No.
810312 2Q
Snamprogetti SPC.No. ZA-E-6015
Rev.
Sh, ....~. 'n OL ...~." 011 I L~
I I I I
ELECTRIC LOAD LIST (1) .

r
a b c I d I e I f I 9 I h I i I j k I I m n I 0 I p I q r I s I t
TO BE COMPLETED BY: PROCESS DEPARTMENT ENGINEERING DEPARTMENT ELE DEPARTMENT (2)
I DRIVEN MACHINE OR OTHER USER DATA ELECTRIC USER DATA
t Doly Required power CoupUng Angular Special Supply- Shape Rated No,of
Type of Typo of Special
velocity data edby power poles
• T•• Type Service Supply Control d.ta
(3) KWN
Notes
Type Hoursl PNP KWU PN
m
Year (kW) (kW) (kW) radfs (kW)
DOSING. SULPHURIC C 8000 N KIA

P-l020 A 0.2
PUMP ACID PUMP
P-l020 B DOSING SULPHURIC R N KIA

PUMP ACID PUMP
VERTICAL UREA CLOSE
P·l019 A 0 8000 N KlA/B 3
PUMP DRAINPUMPS
VERTICAL UREA CLOSE 0

P-l019 B 8000 N KlA/B 3
PUMP DRAINPUMPS
RECIPR. E-l001 PASS. C 8000 N KlB

PK-l002 A 25
COMPR. AIRCOMPR.
 RECIPR. E-l00l PASS. R

PK-l002 B N KlB
COMPR. AIRCOMPR.
NOTES: (1) For the form use see the INSmUCnON sheet 8 OF 8 (MDT.EL.ESY.13)
(2) ELE Identifies Electrical department
(3) radls = rpm x 0.1041 - rpm = redls x 9.5493
Th)S document IS the property of Snamprogetti who will safeguard Its fight according to the cIVil and penal provISions of the law. Form Code: MDT.ELESY.13 Sh. 02/Rev.2.92 Form Fila. ESY13F2E.MDT Data Fila. HA16607·9
JOB UNIT No.
~1Q312 20
~
SPC.No . ZA-E-6015
Rev.
Sh ... ,.~ ... d .....8.... 011 I
I I
a b I c d I I I
I ELECT RIC LOAD LIST (1)
e f 9 I h i j k I m n I 0 I p I q r I 5
I t
TO BE COMPLETED BY: PROCESS DEPARTMENT
ENGINEERING DEPARTMENT ELE DEPARTMENT (2)
I DRIVEN MACHINE DR OTHER USER DATA
ELECTRIC USER DATA
t
Duty Required power Coupling
Type of Type of Special Angular Special Supply· Shape Rated No. of
• T•• Type Service Supply Control data
velocity data ad by power poles
Typ. Hours! KWN Notes
m PNP KWU PN (3)
Year (kW) (kW) (kW) rad/s (kW)
 BELT PRILLING TOWER C
N·1001 8000 N KlB
CONVEYOR BELT CONVEYOR 5
 BELT UREA RECYCLE N K
N·1002 C 8000
CONVEYOR BELT CONVEYOR 3
 BELT PRODUCT N

N·1003 8000 KlB
CONVEYOR BELT CONVEYOR C 10
Z·1001 LIFT PRILLING TOWER D

LIFT 400 E K 10
Z·1007 SCRAPE R ROTARY SCRAPER 0 8000 N KlB 10
ROTATING C N
Z·1009 A PRILLING BUCKET 8000 KlCIB
BUCKET VSD 3
Z·1009 B ROTATING PRILLING BUCKET C N

8000 KlCIB VSD 3
BUCKET
NOTES: (1) For the form use see the INSTRUCTION sheet
a OF 8 (MDT.EL-ESY.13)
(2) ELE identifies Electrical departmen t
131 radls" rpm x 0.1047 • rpm;; rad/s x 9.5493
This document IS the property of Snamprog etti who Will safeguard liS nght according to the clvd and penal proVIsions of the law. Fonn Code. MDT.ELES Y_13 Sh. 02/Rev.2.9 2 Form File: ESY13F2E_MDT Data Flte. HAt6607·9
JOB UNIT No.
Snamprogettl 810312 ;10
SPC.No. ZA· E·6 015
Rev.
sh.... T ... Of......~ .•.. 0/1 / / I
I
a b
L c d I e f 9 h
I ELECTRIC LOAD LIST (1)
I I
TO BE COMPLETED BY:
j j I k I m n 0 p I q I
PROCESS DEPARTMENT r 5 I t
ENGINEERING DEPARTMENT
I ELE DEPARTMENT (2)
DRIVEN MACHINE OR OTHER
USER DAT A
I ELECTRIC USER DAT A
D"/y
Type of Type of Requ ired powe r
• T'9 Type Servi ce
Speci al Coup ling Angu lar Speci al Supp ly- Shap e Rated No, of
Suppl y Contr ol data velocity
m data edby powe r
Type Hours ! poles
PNP KWU PN 1'1 KWN Notes
Year
(kW) (kW) (kW)
<1> PRILLING BUCKET racUs
Z-1010 SUPPORT D IkWI
4000 N K
SUPPORT
2
Z-1011 MIXER UREA SOLUTION
TAN K STIRRER D 6000 N K 3
HV- l0l0 MOTORIZED AMMONIA
VALVE D 4000 E K1B/C
TO J-l0 0l
2
HV- l007 MOTORIZED E-l0 0l BOTTOM
VAL VE D 4000 K1B/C
E 2
HV-1021 !MOTORIZED V-l0 0S BOTTOM D 4000 K1B/C
VAL VE E 2
NOTES: (1) For the form use see

the INSTRUCTION sheet 8 OF 8
(MDT.ELESY.13)
(2) ELE idenU fies Elect rical depa
rtmen t
(J)ra dls"" rpm x 0.1047 •
rpm "" (adts x 9.5493
This document IS the property of

Snam proge tti who Will safeguard Its ngh/ accor
dmg to the Civil and penal provIsions of the law.
Form Code. MDT.ELESY.13 Sh. 02lRe
v.2.92 Form Fila, E8Y13F2E.MDT Data F~e. HA16607·9
--- -
810312 I 20
SPC No. ZA-E-6015

Rev.
0 1 I
I
Electric load list
INSTRUCTION FOR THE USE OF THE FORM MDT.EL.ESY.13
REMARKS: These instructions shall not be attached to the form used for the transmission or information.
TAG = Item identification code (eJ. MP101A)

TYPE Construction type (e.g. centrifugal pump. mill)
SERVICE = Item function (e.g. sea water pump)
DUTY TYPE C for Continuous duty, always operates when the plant is operating
D for Discontinuous duty, runs casually when the plant is operating
for Intennittent periodic duty, operates with an runnjng~shutdown cycle defined by a
cyclic duration factor
S for Seasonal summer duty
W = for Seasonal winter duty
R = for Stand~by machine or user
HOURSIYEARS running hours per year (to nearest 100 hours).
TYPE OF SUPPLY N for Normal supply, stops in case of normal supply interruption
RI... sec. when reacceleration is required foHowing normal supply interruption to restore plant
operation 1 maximum interruption period
5/... sec. = when no break or reacceleration is required for safety reasons following normal
supply interruption/maximum interruption period
E = under preferential power
TYPE OF CONTROL K for local control, near the user
(one or more of the following) C for remote control, distant from the user
A = for automatic conlrol, actuated by process Instrumentation
B when [ock~oul and I or permissive start functions are provided
SPECIAL DATA VSD = when variable speed drive is required
(one or more of the following) LS = when a motor with ~ 94 rad/s (900 rpm) is required
MA when there are auxiliary motors
EA when there are auxiliary equipment other than motors
PNP = Maximum preliminary extimated absorbed power (shaft power)

KWU = Item absorbed power at the heaviest foreseen operating conditions of the plant as a whole (the value
shall be as accurate as possible)
PN Minimum rated power of the motor or other electric user, including oversizing (e.g. API)
KWN Rated output (rated power) at the design operating conditions such as environmental conditions,
electrical feeding, operating conditions, etc.
For motors KWN is the mechanical power available at the shaft and stated on the rating plate.
COUPLING B by belt
R by gear box
o by direct
ANGULAR VELOCITY At the motor shaft (tacking account of the coupling type e.g. gear box)
SPECIAL DATA AT = when axial thrust to the motor is transmitted
(one or more of the following) TH = when heat transfer to the motor is provided
=
SUPPLIED BY NOT = electric user (e.g. motor) is not purchased by ELE Department
YES electric user is purchased by ELE Department
SHAPE"
63
W1M 1001
65
[JH
1M 3001
V1
Iii --
1M 3011
V3 1= j=
F i---"""
' - '--
1M 3031
V5
[ill3 QH
1M 1011
V6
1M 1031
0
OTHER
Form code: MDT.GG.QUA0004 Sh. 01/Rev. 3.96 File code: spcjobve.dot Data file: el.10.doc
This document Is the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312 20
SPC No. ZA·E-6019

Rev.
sh8of22 oI I I
I I I I
1.6 Effluent Data
Form code: MDT,GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
This document is the property of Snamprogettl who wi!! safeguard its rights according to the civil and penal provisions of the law.
------
PLANT LOCATION
~lrnSIi11ilIPlIr@~mtltU PHU MY - FERTILIZER PROJECT SPC No, ZA-E-6661
PROJECT 1 UNIT Rev.
2200 MTPD UREA PLANT sh1of7 0 1
EFFLUENT DATA
/#:. /UJ,.
•
"I,..
1 Revised on sheets 5, 6 and· 7 where marked <1 > fZAMBIANCO SCOTTO -S)XJTTO 17/01/02
0 ISSUE ZAMBIANCO SCOTTO SCOTTO 05/12101
This document IS the property of Snamprogettl who will safeguard Its rights accordi~g to the civil and penal prOVISions of the law.
JOB UNIT No.
810312
I 20
SPC No. ZA-E-6661

Rev.
Sh 2 of 7 oI 1 I I I
I I I
Foreword
The purpose of this specification is to summarize gaseous and liquid effluents

from urea plant in order to give adequate information to design the effluent
treatment system.
Figures are related to the actual revision of Petrovietnam Project datasheets and
based on Snamprogetti experience in similar plants.
It's a matter of fact that effluents treatment unit should be designed taking in
consideration not only a normal operating case but also particular cases of plant
upset.
Please find here in after a few tables in which are summarized the most
representative cases of liquid and gas effluents from urea plant divided in
continuous, discontinuous and emergency emissions.
A table showing the significant cases among all the predictable scenarios of
contemporaneous events has been redacted. It is showing the scenarios sorted
out from process considerations and previous operating experience.
Form code: MOT.GG.QUA.0005 Sh. 01/Rev ..3.96 File codespcjobve.dot Data file: effiuentdata.doc
J
JOB UNIT No.
810312 20
SPC No. ZA-E-6661

Rev.
sh3017 oI 1I
I I
1. LIQUID EFFLUENTS
CONTINUOUS LIQUID EFFLUENTS

DESCRIPTION FLOWRATE COMPOSITION TEMPERATURE PRESSURE
WWTProcess H20 contaminated by
Condensate to B.L. 54 m3/h max. 5 ppm of 45'C 3 bar (g)
ammonia and urea
Steam Condensate to B.L. 31000 kg/h H2O 45'C 5 bar (g)
DISCONTINUOUS LIQUID EFFLUENTS

DESCRIPTION EMISSION FLOWRATE COMPOSITION TEMP. PRESS. DURATION
CAUSED BY OF
DISCHARGE
WWT Process Process upset H20 contaminated by
Condensate 54 m3/h 400 ppm of NH 3, 40C 45'C 3 bar (g) 8 h max.
to B.L. ppm of urea and 1
ppm of ammonium
sulfate
Steam Exchanger 31000 kg/h H20 with 45'C 5 bar (g) 10 h max.
Condensate tube rupture contamination
to B.L. depending on where
exchanger tube
rupture occurs.
Carbonate Synthesis 3.2 m3 /h 40%wt NH3, 10%wt 42'C 3.8 bar 24 h max.
Solution from loop drain CO 2 , 50%wt H,o (g)
Carbonate after a long
Accumulator shut-down
Ammonia from Carbamate 2.1 m3/h NH3 25'C 18.5 bar 24-36 h max.
Ammonia formation in (g)
Receiver the ammonia
receiver
Urea-carbonate Sampling 2 m3/h Urea, Carbonate Amb. Atm. About five
solution from (10 samples solution (according minutes Once
sample about 200 IIh to the process point). per day
connection each))
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: effluentdata,doc
ThIs document is the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312
I 20
SPC No. ZA-E-6661

Rev.
Sh 4 of 7 0 1 I
I I
EMERGENCY LIQUID EFFLUENTS

EMISSION DURATION
DESCRIPTION CAUSED BY FLOWRATE COMPOSITION TEMP. PRESS. OF
DISCHARGE
TK-1001 Prilling section 42 m"lh 80% urea solution 110°C Atm. 1h
overflow upset during
urea sol. Tank
high level
recovery
TK-1002 Contemporary 60 m3/h H20 + 5% NH3 45°C Atm. 1h
overflow not availability of
P-1014NB
TK-1004 Contemporary 16 m3/h Carbonate solution 60°C Atm. 1h
overflow not availability of (typical 20% NH3,
P-1016NB or 10% C02, 70%
TK-1002 full H2O)
2. GASEOUS EFFLUENTS
CONTINUOUS GASEOUS EFFLUENTS

DESCRIPTION FLOWRATE COMPOSITION TEMPERATURE PRESSURE
M.P. Section vent 700 Nm3/h 3%vol NH3, 13.7% H2, 50°C 18.5 bar (g)
14.2% 02,10.6% CH4,
58.5% Inerts (water satured)
Vacuum package 80 kg/h Air with max. 1 kg/h of NH3 50°C Atm
vent
Exast air from 763000 Nm3/h Air with 35 mg/Nm 3 of urea 45°C Atm
Prilling Tower and 30 mg/N m3 of NH3
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File cOdespcjobve.do! Data file; effluentdata.doc
This document Is the property of Snamprogetti who will safeguard its rights according to the civil and penal provisions of the law
JOB UNIT No.
810312 20
SPC No. ZA-E-6661

Rev.
Sh 5 of 7 0 1
I I I
DISCONTINUOUS GASEOUS EFFLUENTS

DESCRIPTION EMISSION FLOWRATE COMPOSITION TEMP. PRESS. DURATION OF
CAUSED BY DISCHARGE
L. P. Section L.P, WWT 2500 kg/h NH3 45°C 1 bar (g) 30 minutes
vent section (high frequency)
instability
M.P. Section H.P. synthesis 2500 Nm 3 /h 70%vol NH3, 50°C 18.5 bar 2 hours
vent loop instability 30%vol Inerts (g)
(water satured)
M.P. section C02 compo 1270 Nm"lh (1) 3%vol NH3, 50°C 18.5 24 hours
vent Out of spec. 32.5% H2, 11 % bar(g)
02, 5.9% CH4,
47.7% Inerts
(water satured)
H.P. section H.P. synthesis 4000 kg/h 73%wt NH3, 155°C 145 bar 2 hours
vent loop instability 1%wtC02, (g)
1%wt H2O,
25%wt Inerts
WWTduring Drainage of 10000 kg/h 42%NH3,15% 130°C 4 bar (g) 24 hours
plant shut-dowr the synthesis C02, 43% H2O
loop
WWTduring V-1006 very 10000 kg/h 42%NH3,15% 130°C 4 bar (g) 2 hours
process upset high level or C02, 43% H2O
WWT
instability
Atmospheric High ammonia 1500 kg/h NH3 45°C 1 bar (g) 30 minutes
tanks in content
overpressure
Vacuum Gas blow 580 kg/h Air with 500 50°C Atm 5 minutes
package vent through L.P. kg/h of NH3
section
<1>
(1) This case considies the maximum flowrate of H2 due to max concentration in C02 stream (1%
voL) and maximum flow of 02 due to max. concentration in C02 stream (0.35% voL).
Form code: MDT.GG,QUA0005 Sh. 01/Rev. 3,96 File codespcjobve.dot Data file: effluentdata,doc
This document is the property of Snamprogetti who will safeguard Its rights according to the civll and penal provisions of the law,
JOB UNIT No.
810312
I 20
SPC No. ZA-E-6661

Rev.
sh6of7 0 1 I I
I
EMERGENCY GASEOUS EFFLUENTS
<1>
DESCRIPTION EMISSION FLOWRATE COMPOSITION TEMP. PRESS. DURATION OF
CAUSED BY DISCHARGE
Exaust air from Loss of 763000 Nm3 /h Air 45'C Atm 30 minutes
Prilling tower Vacuum contaminated
And with 50
Operator mg/Nm3 of urea
mistake and 100
mg/Nm3 of
ammonia
In addition please see PSVs datasheet SPC. SA-E-6800 & SA-E-6801

The following cases have to be considered as contemporaneous opening of PSVs considering the
composition at the normal conditions as reported in the material balance.
(1) Loss of level in E-1005A

PSV-1013 and PSV-1014
(2) CW failure
PSV-1019, PSV-1022 and PSV-1032
3. CONTEMPORARY EVENTS
DISCONTINUOUS LIQUID EFFLUENTS: POSSIBLE CONTEMPORARY EVENTS

DESCRIPTION (Cause) QUANTITY COMPOSITION 1 2 3 4
WWTProcess H20 contaminated by 400 ppm of x
Condensate to B.L. 54 m3/h * 8 h NH 3 , 400 ppm of urea and 1 ppm
(Upset) of ammonium sulfate
Steam Condensate to 31000 kg/h * 10 h H20 with contamination depending x
B. L. (Exchanger tube on where exchanger tube rupture
rupture) occurs.
3
Carbonate Solution from 3.2 m /h * 24 h 40%wt NH 3 , 10%wt CO 2 , 50%wt x
Carbonate Accumulator H2 O
(Drainage)
Ammonia from Ammonia 2.1 m3/h * 24-36 h NH3 x
Receiver
(Drainage)
Urea-carbonate solution 2 m3/h * 5 minutes per day Urea, Carbonate solution x x
from sample connection (10 samples) (according to process points)
Form code: MoT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: effluentdata.doc
JOB UNIT No.
810312
I 20
SPC No. ZA-E-6661

Rev.
Sh 7 of 7 oI1I I
I I I
DISCONTINUOUS GASEOUS EFFLUENTS: POSSIBLE CONTEMPORARY EVENTS

DESCRIPTION (Cause) QUANTITY COMPOSITION 1 2 3 4 5 6
L.P. Section vent (L.P, 2500 kg/h * 30 minutes NH3 x X X
WWT section instability)
M.P. Section vent (H.P. 2500 Nm3/h * 1 hour 70%vol NH 3, 30%vollnerts x
synthesis loop instability) (water satured)
H.P. section vent (H.P. 4000 kg/h * 2 hours 73%wt NH 3, 1%wt CO" 1%wt x
synthesis loop instability) H20, 25%wt Inerts
WWT during plant shut- 10000 kg/h * 24 hours 42%NH 3, 15% CO" 43% H2O x
down (Drainage of the
synthesis loop)
WWT during process 10000 kg/h * 2 hours 42%NH 3, 15% CO 2 , 43% H2O x x x
upset (V-1 006 very high
level or WWT instability)
Atmospheric tanks in 1500 kg/h * 30 minutes NH3 x x x
overpressure (High
ammonia content)
Vacuum package vent 580 kg/h * 5 minutes Air with 500 kg/h of NH3 x x x
(Gas blow through L.P.
section)
<1>
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: effluentdata.doc
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
sh90f22 oI I I I
1.7 General Requirement for Piping
Please see SPC. N° GA-E-6667 rev.O hereafter attached.
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
PLANT LOCATION
~lliltmlfi1illPlli'Ci>§JJ~tin PHU MY - FERTILIZER PROJECT SPC No. GA-E-6667
PROJECT I UNIT Rev.
2200.MTPDUREA PLANT sh1oi6 0
. . .
........
..'
GENERAL REQUIREMENT FOR PIPING
~\
''''''''~---: ~ "~~"~
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I
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A (\
f/7) llA. (J... ')..vv
0 ISSUE I~CO SCOTTO S!'OTTO 12111101
Rev. Descriotlon Preoared Checked Aoomved Date
Form code: MDT,GG.QUA0004 Sh, 01/Rev. 3.96 File code: spcjobve.dot Data file:
pipingrequfrement.doc
JOB UNIT No.
810312 20
SPC No. GA-E-6667

Rev.
Sh 2 of 6 oI I
I
FOREWORD
The purpose of this specification is to give some general requirement for the
piping design of the urea plant. The indications reported are in accordance with
the characteristics of the process fluids themselves, the tendency to crystallize of
the urea and carbonate solutions, and the long experience of Snamprogetti in
the design and operation of the plants.
The deviations from the general prescriptions have to be discussed case by case
with the Licensor in order to prevent/avoid unexpected modifications to be
realized at site.
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File {;odespcjobve.dot Data file:
pipingrequirementdoc
This document Is the property of Snamprogeffi who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312 20
SPC No. GA-E-6667

Rev.
Sh 3 of 6 oI I
I I I
1. All notes indicated on P&IDs must be strictly followed.
2. P&IDs issued for the Process Design Package have to be completed during
Basic and Detailed Engineering phases. Configuration of the PDP is only the
minimum requirement from the process design point of view.
3. Where it is indicated "slope", it's necessary to assure the maximum slope

avoiding line pocket or horizontal line and to run the pipe line as straight as
possible from the origin point to the final destination of the interested line.
Self draining of process pipe should be ensured.
Some critical points are listed here below:
a. P-1002A1B suction/discarge line

b. P-1003 AlB suction/discharge line
c. P-1006 AlB suction/discharge line
d. P-100S AlB suction/discharge line
e. P-1009 AlB suction/discharge line
f. T-1001 drain line to V-1006
g. E-100S outlet line to V-1 006
h. E-1001 vapour line to E-100S A.
i. E-100S B outlet line to V-1001
j. V-1001 bottom line to J-1001
k. HP vent line to MP decomposer holder.
I. Stripper and all decomposers urea solution outlet line
m. Return line from prilling tower three way valve to T-1001 where no
pocket or horizontal pOints are allowed.
4. Where it is indicated "min", or "minimum distance" the length of the interested

pipe as to be kept as short as possible in order to prevent dead zone where
crystallizzation is very likely to occur with consequent plugging problems leadinto
to plant shut down or even emergency situations.
S. Vacuum systems PK-1003 & PK-1004 shall be positioned at min 11 m from the
top of TK-1 002 and balance legs to TK-1 002 shall have maximum slope.
6. All steam traps shall be sized and designed during detailed engineering phase in
function of the discharged steam condensate flowrate. Floating type steam trap
are suggested for continuous service and thermostatic type for discontinuous
service (steam jacketed lines).
7. On H.P. loop angle valves plug direction must be according to P&ID indication.
S. The second block valves located on the discharge of P-1001 AlB pumps and
indicated on P&ID P-41 shall be installed on reverse position in order to avoid
H.P. liquid seepage to the stand-by pump when the main one is running.
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file:
pipingrequirement.doc
JOB UNIT No.
810312 20
SPC No. GA·E·6667

Rev.
Sh 4 of 6 0 I I
I I
9. All instruments connections on urea or carbonate services shall be located at

minimuin distance from the process pipes in order to minimize stagnant zone.
This concept is applicable where diaphragm typeihstruments are not used,
10. Connection of lines of small diameter to the main process lines (washing
connections) of HP process piping shall be realized utilizing the special lens
gaskets according to SP std. TB-5002. This is to avoid to punch HP loop piping
as much as possible and having the washing connection at minimum distance
from the block element.
11. All the washing connections (LW, HW and KW) shall be realized respecting the
distances and configuration indicated on P&ID P-53.
12. Line from urea reactor R-1001 to urea stripper E-1001 has to be designed
avoiding pocket or horizontal pipes. Slope shall be in direction from R-1001
outlet nozzle to E-1001, urea solution inlet nozzle. The location of R-1001 outlet
butterfly valve shall be at about 2 meters from E-1001 inlet nozzle to avoid the
flashing of the solution in the nozzle itself.
13. Expansion joints are normally provided at the following point in order to avoid
piping compensation loops that might create dead points where crystallization
can occur:
a. P-1006 AlB suction line

b. P-1008 AlB suction line (on this line no filter has to be provided)
c. Line connection from V-1014 to PK-1003
d. Line connection from Steam booster ejector of PK-1004 to the main
condenser.
14. Urea melt three way valves system (HV-1032A and HV-1032B) shall be located
on the top of prilling tower inside the buckets room.
15. Install drain at all lowest line point. All drain points of carbonate or urea solution
lines shall be provided with washing connections and relevant drain as shown on
P.&I.D. P-53.
16. Install all valves in accessible and approachable point for operation. Platforms
shall be adequate to allow easy operation and maintenance.
17. All instruments and vessels level connections shall be approachable for
operation and maintenance.
18. Equipment and operating points shall be provided with gangways and all the
necessary inspection facilities. In particular all the weep holes of Reactor R-
1001, Stripper E-1001 Carbamate separator V-1001 ans Carbamate Condensers
E-1005 AlB shall be easily inspectionable.
Form code: MDT,GG.QUAOOQ5 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file:
plpingrequirement.doc
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JOB UNIT No.
810312 20
SPC No. GA-E-6667

Rev.
Sh 5 of 6 0
I I
19. CO2 compressor discharge line to Reactor R-1001 and urea melt line in between
V-1014 and E-1015 shall have the elbows of long radius type (R=5DN).
20. PSV connected to process lines shall be located as close as possible to the
protected vessel and the connecting line shall be as short as possible avoiding
pocket and horizontal pipe. For H.P: loop PSV special pieces are provided in
order to flange the safety valve directly on the process pipe. In the other sections
spool pieces shall have minimum length in order to prevent dead pOints with
consequent plugging and dangerous consequences.
21. Blow down lines and branches have to be always flushed with low-pressure
steam in order to prevent crystallization. Moreovere the slope of the piping shall
be always toward the BD header and finally to the separator V-1011. 8elf-
draining pipes has to be provided.
22. Reduction shall be eccentric type rather than concentric one.
25. Plug valves with included washing connection on carbonate and urea solution
lines shall be installed according to the following sketches, thus to allow washing
of the process line when the main valve is opened.
upstream normal downstream

washing operating washing
process process process process

process process --..1--+--......
condensate condensate
condensate (normally closed;
it may be opened)
Exception has to be made for suction and discharge valves of P-1006A1B and
P-1008A1B that shall be assembled in such a way that entrance of washing
water to the process is avoided any time the main valve is opened. That is to
prevent product quality deterioration. The assembly of the above mentioned
valvesshall be as per the following sketches:
Form code: MDT.GG.QUAD005 Sh. 01/Rev. 3,96 File codespcjobve.dot Data file:
pipingrequiremen1.doc
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JOB UNIT No.
810312 20
SPC No. GA-E-6667

Rev,
Sh 6 of 6 oI I I
I I I
upstream normal downstream

washing operating washing
condensate
(it may not be opened, condensate
condensate nor leak into the process)
The reason for this difference is the following. In the first case the possibility
to inject condensate has to be ensured when the process fluid is flowing,
while inthe second one the condensate should never be injected when in the
line the process fluid is flowing and condensate leakage into the process line
must be avoided,
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file:
pipingrequlrementdoc
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JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
Sh 100122 0 I I
I
1.8 Special Requirements for Instrumentation
Please see SPC. N' SA-E-6666 rev.O hereafter attached.
Form code: MDT.GG.QUA0005 Sh, 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
PETROVIETNAM 810312 \ 20
PLANT LOCATION
~l1i1il1lfi1ilpllr«li!\lJ~tiH PHU MY - FERTILIZER PROJECT SPC No. SA-E-6666
PROJECT I UNIT Rev.
2200 MTPD UREA PLANT Sh 1 of32 0
SPECIAL REQUIREMENTS FOR
INSTRUMENTATION IN UREA PLANTS.
I-""··-·. ·""-·. · ·-·. -·. . --.

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n o' n
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This document Is the property of Snamprogettl who will safeguard Its rights according to the civil and penal provIsions of the law.
-----
JOB UNIT No.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 2 of 32 oI I I
I I I
CONTENTS
1. GENERAL 4
1,1, Scope and field of application 4
1,2, Reference codes and standards 4
2. PROJECT 5
2,1, Operating conditions 5
2,2. Instruments defined for UREA SERVICE 5
2.3, Construction devices 5
3. FLOW RATE MEASUREMENT 6

3.1. General 6
3,2, Ammonia flow rate measurement 6
3,3, Carbamate measurement 6
3.4. Other flow rate measurements 7
4. PRESSURE MEASUREMENTS 9
4.1, General 9
4,2. Pressure measurement in the vacuum separators and reflux
drum of distillation column 10
4,3. Pressure measurement in the hydrolyser 10
5. LEVEL MEASUREMENTS 13
5,1. General 13
5,2, Stripper level measurement 13
5.3. Level measurement in the carbamate separator 14
5.4. Level measurement in medium and low pressure decomposers 15
5,5, Urea level measurement in the vacuum evaporator 23
5.6, Other level measurements 25
5,7, Level transmitters, radioactive type 25
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
This document is the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law
JOB UNIT No.
810312 I 20
SPC No. SA-E-6666

Rev.
Sh 3 of 32 0 I I
I I
6. TEMPERATURE MEASUREMENTS 28
6.1. General 28
7. CONTROL AND MOTORIZED VALVES FOR "UREA SERVICE" 29

7.1. Control valves 29
7.1.2. Design 29
7.2. Motorized valves 30
8. SAFETY VALVES FOR UREA SERVICE 31

8.1. General 31
8.2. Design 31
9. ANALYZERS 31
9.1. Analysis of 02 in C02 31

9.2. Analysis of conductivity in steam condensate 32
Form code; MDT.GG,QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file; sae6666,doc
This document is the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law,
JOB UNIT No.
810312 20
\
SPC No. SA-E-6666
Sh 4 of 32 o, , ,,
Rev.
,
,
1. GENERAL
1.1. Scope and field of application
The purpose of this document is to act as a guideline for the selection of instrumentation for
Urea plants under Snamprogetti licence.
The solutions proposed are the result of experience gained over the years.
1.2. Reference codes and standards
- STD.TB.5002 Urea Materials
- SPC.CR.UR.510 General Specification - Austenitic steels for Urea plants,

high pressure section
Form code: MDT.GG.QUA.OOOS Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
..... ~., ,~v.
810312
I 20
SPC No. SA-E-6666

Rev.
sh5of32 oI I
I I
2. PROJECT
2.1. Operating conditions
The selection of instrumentation for Urea plants shall take into account the characteristics of
the process fluid that is particularly aggressive and the tendency of the lines connecting the
instruments to the process (primary) to get plugged.
Urea plants have been classified, for the purposes of explosion hazards, as non hazardous,
except for the top of the prilling tower; this area is classified as Zone 2.
Electrical equipment enclosures may therefore be waterproof except for those of the
instruments mounted in the prilling tower top which may be explosion-proof or intrinsic safety
type.
Instruments mounted on the field shall not contain copper or copper alloys due to the
presence of ammonia vapours and urea dust in the plant atmosphere. However, copper
material can be accepted only in case the interested part cannot be in contact with an
atmosphera of ammonia vapours.
All instrument tubings, air supply and pneumatic signals, including compression fittings,
shall be made of stainless steel.
The electric contacts of sensors installed in the plant shall, whenever this is possible or
applicable, be immersed in inert atmosphere.
When electronic circuits are to be erected on site, they shall be treated with suitable
protective paint.
Instruments shall be installed in positions where there is no possibility of process fluid leaks.
2.2. Instruments defined for UREA SERVICE
2.2.1. The suggestions of this design practice should be followed for the selection of instruments
defined for UREA SERVICE. In the case of pressure and temperature instruments, account
should also be taken of the requirements of Snamprogetti standard STD.TB.5002.
2.2.2. The material to be used for instruments and valves on high pressure UREA SERVICE shall
conform to the provisions of Snamprogetti specification SPC.CR.UR.51 O.
2.3. Construction devices
It has been endeavoured to overcome the difficulty of the corrosive action exerted by
carbamate and urea by utilising corrosion resistant material, whenever possible, or by using
installation techniques aimed at preventing corrosion. In particular stagnant zone has to be
avoided to the maximum possible extent in order to prevent corrosion and/or clogging
phenomena.
The solutions indicated in the following pages propose the most commonly adopted methods.
Form code: MOT.GG.QUA.0005 Sh. 01/Rev. 3,96 FHe codespcjobve,dot Data file; sae6666.doc
This document is the property of Snamprogettl who will safeguard its rights according to the eMI and penal provisions of the law.
JV~ UNII NO.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 6 of 32 oI I
I I
3. FLOW RATE MEASUREMENT
3.1. General
The indications of the P.&I.D. shall be followed

Orifice plates will be used wherever this is permitted by the process fluid and process
operating conditions.
Some solutions for cases in which orifice plates cannot be used or where they raise particular
installation difficulties are indicated below.
3.2. Ammonia flow rate measurement
Mass flow meter instrument must be used for flow rate measurement of ammonia feed to the
urea plant.
3.3. Carbamate flow rate measurement
3.3.1. Application
Flow rate measurement of carbamate coming from absorption column T-1001 that is being
sent to the H.P. carbamate condensers by centrifugal pumps.
When centrifugal pumps are used, carbamate flowrate measurement is made by a magnetic
flow meter mounted at the suction of the pumps. The installation of this instrument shall be
such to avoid stagnant liquid during shut down conditions. In fact the liquid might crystallize
affecting the correct operability of the instrument.
3.3.2. Instrument type
Measurement is made by means of magnetic flow meters.

The minimum characteristics of these instruments are:
lining : Teflon reinforced with stainless steel mesh

electrodes material : titanium or other materials provided they have been
experimented by the Vendor.
protection class : IP65
automatic zero calibration
outlet signal : 4-20 mA, galvanically insulated
precision : ± 1% of the end of scale value
body material : stainless steel
transmitter : programmable microprocessor based
erection : preferably vertical with a top to bottom fluid direction.
Note: Care should be taken to ensure that the line is cleaned by hot water or steam having a
maximum temperature equal to or less than the value that can be withstood by the
magnetic flow meter lining.
Form code: MOT.GG,QUAOOQ5 Sh, 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
NO UI'II' , ''\I~.
810312
I 20
SPC No. SA-E-6666

Rev.
sh7of32 oL I I I
I I I
3.4. Other flow rate measurements
3.4.1. The flow rate measurement of C02 to urea reactor is made by means of a nozzle or orifice
plate installed on the compressor delivery line, at the following conditions:
temperature : about 1200 C

pressure : 160 bar
Consider that under this conditions CO 2 has not to be treated as a perfect gas.
It is suggested to install the differential pressure transmitter at higher level than the process
line on separate pole, and being at minimum distance from the process line itself.
3.4.2. Flow rate measurement of ammonia sent to the reactor
When centrifugal pumps are used, flow rate measurement of the ammonia sent to the
reactor is made using a nozzle or orifice plate.
To safeguard integrity, centrifugal pumps shall be provided with a recycle loop assuring a
minimum flow rate through the pump even when the plant is running at a reduced charge.
The protection circuit is ensured by measuring the flow rate on the pump suction by means of
an orifice device recycling if necessary a certain quantity of ammonia.
Great care should be taken in the choice of recycle valve in view of the pressure differential
to be obtained (pump delivery pressure of 230 bar, suction pressure of 20 bar).
The appropriate valves are multistep type (MASONEILAN, FISHER, PARCOL). Cage type
valves are absolutely unsuitable.
NOTE: The following provisions shall be followed for erection:

any reductions upstream and downstream control valve shall be concentric type
- a section of straight line shall be maintained downstream control valve for 6-10
diameters in order to mitigate the vibration phenomena.
3.4.3. Flow rate measurement of water with small percentages of carbamate or urea
The measurement, if required, is made by orifice plate where the connection branches to the
differential pressure transmitter are flushed with water or low pressure steam.
Preference is given to steam flushing since it dissolves any carbamate that may have
deposited.
A typical diagram of the installation is shown in FIG.1.
Form code: MDT.GG.QUA,0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
JOB UNIT No,
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 80132 oI I I I
I
FLOW RATE MEASUREMENT OF WATER WITH SMAll PERCENTAGES OF

CARBAMATE OR UREA
1'2"xl0nw
" /
"2";.-: 1 Orrlll
10mn 10m'11
1Umll
10rrm
lJUTE (1)
MADIFOLO
f"'Hffi'lW'-
L---~~-v/r-+n~I~
IDSTRUMElOT " STEAM QR
F [L TER COO[[lEDSATE
WATER
NOTES:
1- Restriction orifices will be used when steam is used with steam flushing
- FIGURE 1 -
Form code: MDT.GG.QUA.OD05 Sh. 01/Rev. 3.96 File cOdespcjobve.dot Data file: sae6666.doc
JOB UNIT No.
810312
I 20
SPC No. SA·E·6666

Rev.
Sh 90.32 oI I I
I I
4. PRESSURE MEASUREMENTS
4.1. General
Gauges, pressure transmitters, and pressure switches mounted on lines containing

carbamate or urea shall be provided with a separation diaphragm and with capillaries.
These shall be flexible type and protected by stainless steel sheathes.
Instrument calibration shall be made taking into account the plant operating temperature.
For reliable operation, the instruments shall be, mounted on vibration free supports.
4.1.1. High Pressure section
Connections : instrument connections shall be according to Snamprogetti standard

STD.TB.5002.
Body material: the body material shall be according to ASTM A 182 F 316L "Urea Grade".
Material of the diaphragm: the material shall be 25Cr -22Ni - 2Mo alloy according to
SPC.CRUR510.
Tests and analyses on the materials : the tests and chemical analyses required for the
material with which the diaphragm and parts wetted by the process fiuid are fabricated shall
be carried out according to the requirements of SPC.CRUR.510.
The corrosion test (Huey test) is carried out separately for:
a) the material of parts wetted by the process fluid (a portion of the material used for
construction is used for making the specimens required for the performance of the
corrosion test)
b) the sheet steel for construction of the diaphragm (a portion of the sheet steel is used for
the performance of the corrosion test)
c) welding of the diaphragm to the sensor body. Since the Huey test is a destructive test it
obviously cannot be performed on the instrument being fabricated. The purpose of the
test is to ascertain that the welding method employed guarantees the integrity of the
mechanical characteristics of the material.
The test procedure consists in preparing a sample consisting of sheet steel and a
specimen and then in welding the edges of the sheet steel to the specimen so as to
avoid infiltration of sulphuric acid (that is used in the corrosion test) under the
diaphragm, since this would compromise the successful result of the test.
The test consists in ascertaining the magnitude of the corrosion that has occurred.
It is clear that the tests are rather costly and therefore tests a) and b) can be carried out for
lots of material which will be punched if the test is successful. The costs can therefore be
spread over several material supplies.
The welding (diaphragm to separator body) of all finished parts shall be subjected to the
liquid penetrant test.
Form code: MDT.GG.QUAOD05 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
JU~ '''v,
I
VI'IIII
810312 20
SPC No. SA-E-666S

Rev.
sh100132 oI I I I
I II I
4.1.3. Medium and low pressure sections
Connections: instrument connections shall be according to Snamprogetti standard

STD.TB.5002.
Material: the body and diaphragm material shall be AISI 316L.
Tests and analyses of materials : the body and diaphragm shall be subjected to the
mechanical tests and chemical analyses required by ASTM.
4.2. Pressure measurement in the vacuum separators
Measurement is made by means of a pressure transmitter flushed with instrument air

because the process connection is made at the top of the vessel where gas is found.
A typical sketch of the installation is shown in Figure 2.
4.3. Pressure measurement in the Hydrolizer
As described in paragraph 4.2.1. but, in this case, flushing is made using the medium
pressure steam available in the plant.
A typical sketch of the instillation is shown in Figure 3.
Form code: MOT.GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
JUB UNII NO.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 11 of32 oI I I I
I I I I
PRESSURE MEASUREMENT IN THE VACUUM SEPARATORS
, .. lOS TRUMEOT
j?
1~1]
j';,"x1onn "<"x\mrn
II~'" . . . .'.0<""..-...... OlO.,0'"". ...ctxl

l/{
I
--~ /
10lffn
r11-(
AIR FILTER
REGULATOR
JOSTRUM80T
AIR
NOTE:
1. The instrument shall be installed in a higher position than the vessel pressure connection.
- FIGURE 2 •
Form code: MDT.GG.QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
JU~ UI'IIII"'U,
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 12 of32 oI I I
I I I
PRESSURE MEASUREMENT IN THE HYDROLYZER
'" '! , !"'~1 0"""

o~------------------'~
I,~ ~ 1'2'
~~
T
1 10r(][TI
STEAM TRAP
M.P. STEAM
NOTE:
1. Restriction orifice to be sized for each project
- FIGURE 3 -
Form code: MDT,GG.QUA.0005 Sh. 01/Rev, 3.96 File codespcjobve.dot Data file: sae6666.doc
This document [s the property of Snamprogettl who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNII NO.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 13 of 32 oI I I
I I I
5. LEVEL MEASUREMENTS
5.1. General
Some solutions are proposed below for the measurement of fluids whose characteristics
have particular installation requirements such as line washing or the use of instruments with
operating principles differing from those normally utilised.
5.2. Stripper level measurement
5.2.1. Application
Continuous measurement of the stripper bottom level (E-1 001).
Two types of level meters have been experimented over the years:
a) Differential pressure transmitter: This meter measure the pressure difference of the liquid
head assuming the density to be constant; the connection lines to the instrument are
flushed with water.
The main components of the flushing circuit are:
2 No,Pumps, one in operation and the other standby stating up on failure of the first one,
controlled by a pressure switch
flow rate: 50 I/h
delivery pressure: 200 bar g
set pressure of PSV: 220 bar 9
4 No Dampers of 1 litre
flushing fluid: hot water
filters: 30 micron
restriction orifices
rotameters, with built-in needle valves, of 60 I/h (Fischer and Porter model 10 A
1227 N or equivalent).
The connection pipes and fittings shall be in AISI 316.

b) Radioactive transmitter: This meter measure the residual radiation that is not retained by
the process fluid whose level is to be measured.
A typical feature of these instruments is that they have a high time constant (to diminish
the radioactive activity of source) so that the indication of the instrument does not
faithfully reproduce rapid variations in the process. They are however acceptable for level
control. The instrument requires practically no maintenance and once installed its
residual radioactivity at a distance of about 1 m is practically nil. The supplier shall in any
case check whether it is necessary to install a lead protective screen. The screen cannot
cover the weep inspection holes on the HP equipment
An advantage of choosing radioactive instruments is that the purge and associated
pumps are not required. A greater knowledge of these instruments, which involve
practically no radiation risks and are easy to install, is resulting in their being increasingly
used.
A typical sketch of such an installation is given in Figures 5 and 6.
This document 15 the property of Snamprogetti who will safeguard its rights according to the civil and penal provisions of the law.
JV. UI'IIII'IU.
810312
I 20
SPC No. SA-E-SSSS

Rev.
Sh 14 of 32 oJ. I I I
I I I
Anotherveryimportant aspect that should be taken into account are the national and
international standards for the use and transport of radioactiv.e material.
Furthterinformation on the subject is given inChapter 5.7.
Notes: 1) Radioactive level transmitter must be used for stripper level measurement.
2) Differential pressure transmitter will be used when it is not possible to install

radioactive level transmitter due to local laws of end user.
5.3. Level measurement in the carbamate separator
5.3.1. Application
Continuous measurement of the carbamate level in the carbamate separator (V - 1001).
a) Displacement level transmitter with displacer mounted inside the vessel.

The main instrument characteristics are:
m: torque tube and internal displacer

material:
• all parts in contact with the process fiuid shall be AISI 316 L according to
specification SPC.CR.UR.510.
• torque tube arm, knife, and displacer suspension shaft shall be made of
titanium;
• torque tube in AINSI 316 L
• displacer with teflon and titanium rings
heating of torque tube chamber: by steam and jacket having connections y."
ANSI B1.20.1 NPTF-3000#
washing with water of torque tube: 1/2" ANSI B1.20.1 NTPF-3000#

connection.
The installation is shown in Figure 7.
NOTE: When the plant instrumentation is electronic, it is recommended to request a

pneumatic transmitter if qualified vendors do not have the electronic version.
b) Radioactive transmitter: see point 5.2.2.b and Chapter 5.7 for greater details.
The installation is shown in fig. 8-9.
Note: 1) Radioactive transmitter must be used .for level measurement in the

carbammate separator.
2) Displacement level transmitter will be used when it is not possible to install

radioactive level transmitter due to local laws of end user.
This document is the property of Snamprogettl who wilt safeguard its rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312
I 20
SPC No. SA·E·6666

Rev.
Sh 15 of 32 0 I I
..
I
5.4. Level mea!i.Urement in medium andlo\\(; prl!ssure decOmpo$ers·
5.4.1. Apr!lications
Continuous measurement of the Urea level in rnedium and low pressure decornposers.
For this measurement two types of level meters have been experimented over the years:
a) Capacitance probe transmitters with radio frequency peramplifier: this solution prevent
process material build-up, is widely used and gives good results.
Capacitance transmitter shall be used when downstream Urea Plant there is the priJIing
unit.
Further details are given at point 5.5.2.
b) Differential pressure transmitters with steam flushing: the pressure difference of the liquid
head is measured assuming the density to be constant.
This is a simple and reliable solution. shall be used when downstream urea plant there is
the granulation unit.
Form code: MOT.GG.QUAoao5 Sh. 01JRev. 3.96 File codespcjobve.dot Data file: sae6666.doc
JOB UNII NO.
810312 20
SPC No. SA-E-6666

Rev.
~~16Q!32 ,,~od',...-':1'-++--1
-,'.
STRIPPERLE'ilELME~SUREMEI\,IT(E"1(JO~)
" ~
'"
·,:t
'-
~
ul ~\ "/X1/~ "
.-- .... -..

AuTOMATIC START
1,2'
fl STAO~-BY
AO[b ALARM
PUMP
~~
,~
L~ " "2"~
L
<-
? 'r "I
I
/
RES TF! reT I 00
ORl~lCE
I,!,
i1
?l~:~~·~f?it-\~fEE!Et~
(U,MPEOER
/[ I,t
[ I,{
RESTRICTIOO
ORIFICE
IDS TRUMEDT /'
"
PUMP
200 bar
FILTEIl ~
COO{]EDSATE
WATER
- FIGURE 4 -
JOB UNII NO.
810312 I 20
SPC No. SA-E-SSaS
Sh 17 of32 oI
Rev.
I , ,,
I I
TYPICAL INSTALLATION OF STRIPPER RADIOACTIVE PROBE (E-1001)
E-101
MATERIALS LEGEND
CD
M\
\.0
SHELL ; CARBOD STEEL
IOOER LIDIOG :
CMiaOO STEEL + 25/22/2 Cr/Ni/Mo
1
CD BOTTOM : CARBOD STEEL
8) [SOLATIOO : ROCKWOClL
® Bllom rLAOGE : CARBOO STEEL
"'; /;;;;.> SUPPORT FOR RA~IOACTIVE LEVEL
F'ROBE HOLmER WELL

SEE ffiETAIL FIG,S
- FIGURE 1) -
Form code: MDTGG,QUA0005 Sh. 01/Rev. 3.96 File codespcjobve,dot Data file: sae6666.doc
"U~ un"
I
''1V.
810312 20
SPC No. SA-E-6666

Rev.
Sh 180132 oI I
I I I I
TYPICALDETAI~ OF PROBE HOLDER WELL

(REFERENCE ONLY)
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JOB UNIT No.
810312 20
SPC No. SA-E-6666

~ev.
[OLE T
·'tAOS! 81.20,1~[IPT/F
3000'"
HEATIOC STEAM
","ADS! Bl.20.1.-{]PT/F
3000#
- FIGURE 7 -
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 Fite codespcjobva.dot Data fife: sae6666.doc
JOB UNIT NO.
810312 I 20
SPC No. SA-E-6666

Rev.
Sh 20 of32 oI I I I
.....
I I
TYPICAL INSTALLATION OF RADIQACTIVEPROBE FOR CARBAMAtE SEPARATOR V-1001
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GETAll FIG.9 MATERIALS LEGENI!.
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(:0 SHELL: CARB.STEEL/SOra" THICK,
CD IOOER LIDiO!) AIS] 3lb/Sewn THICK.
P1IP? SUPPORTS FlIR RMfrlUACTIVE LEvEL
- FIGURE 8 -
This document is the property of Snamprogettt who will safeguard its rights according to the civil and penal provisions of the law.
JOB UNII NO.
810312 20
SPC No. SA~E-6666
044.3
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060.3
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05" 150"RF
- FIGURE 9 -
JOB
I
UNII NO.
810312 20
SPC No. SA-E-6666

Rev.
Sh 22 of 32 0 I I
I
LEVEL MEASUREMENT IN MEDllJi\IIAND LOW PRESSURE DECOMPOSERS,OTHER UTILITIES
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MErnIUM PRESSuRE STEAM

NOTE:
Restriction orifice to be sized for each project
- FIGURE 10 -
Form code: MDT.GG.QUA0005 Sh. 01/Rev, 3.96 File codespCjobve.dot Data file: sae6666.doc
JOB UNII NO.
810312 20
\
SPC No. SA-E-6666

Rev.
Sh 230132 oI I I I
I I I I
5.5. Urea level measurement in the vacuum evaporator
5.5.1. Application
The choice of the instrument depends on the type of process that is used to obtain the
finished product.
Three processes are used industrially: prilling, granulation and crystallisation.
In the case of prilling, urea in the vacuum evaporator must contain a very low percentage
of moisture, which is ensured by full vacuum system.
For level measurement in the evaporator, the choice of a capacitance probe is
compUlsory.
Some details about probes are given in paragraph 5.5.2.
5.5.2. Instrument with capacitance probe
This measurement is based on the principle of the capacity that is established between the
two electrodes.
Information to be given in the technical specification:
Type of sensing element: capacitance

Probe/insulation material:Stainless Steel/ TEFLON
Preamplifier: Radio frequency (R.F.)
Zero and range adjustment
Outlet signal: 4-20 mA floating
Execution: IP 55
Erection type: vertical, from bottom
Connection to Vessel as per line specification
Electrical connection: y," or 3/4" ANSI B1.20.1 NPFT
Operating/environmental condition
Level range/probe length
The instrument shall be immune to electrostatic discharges
Possibility of build up on the probe by process fluid
This document Is the property of Snamprogetti who will safeguard its rights according to the civil and penal provisions of the law
JOB UNIT No.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 24 of 32 oI I
I I
TYPICAL INSTALLATION OF LEVEL CAPACITANCE PROBE
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Form code: MDT.GG.QUA.0005 Sh, 01/Rev. 3,96 File codespcjobve.dot Data file: sae6666,doc
ND ...... ,. uv.
810312
I 20
SPC No. SA-E-6666

Rev.
..... sn?50132
..........
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5.6. Ottler level measllr.;lrt.enti;
5.6.1. Applications
a) MEldium prElssure absorber column bottom (T·1001)

b) Carl10nate solution tank (V-1 006)
c) Waste water collection tank
d) Urea solution tank (TK-1001)
Measurements are made by a transmitter indicating the differentialpressurEl determined by

the liquid head (the density of which is assumed to be constant) that is established between
the lower and the upper nozzle of the vessel where level measurement is desired.
Since the process fluid contains dissolved carbonates andlor urea, which may cause
sla9gingl plugging, the connection lines between the instrument and the vessel shall be
washed by steam.
Typical installation is shown in Fig.10 for measurements under a) b) d).
For measurements under c), the typical installation shown in Fig.i0 can be used. In this case,
only the lower connection of the tank will be flushed by steam.
The.tank is atmospheric and it is not necessary to connect the transmitter (minus side) to the
upper part of the same.
NOTE: For the same measurements, washing can be made with condensate water, but
steam is preferred. In any case it must be ascertained thatthe pressure of the fluid
used is always higher than the vessel pressure.
5.7 Radioactive level transmitter
5.7.1. Guide to the preparation of the purchase specification (FOR REFERENCE ONLY)
a) Major characteristics of the receiver instrument
manual compensation of decay

automatic compensation of decay
linearization of the signal
self-diagnostic
possibility of generating several alarm thresholds with relay output
output signal: 4 - 20 mA (galvanically insulated)
alarm for rupture of the source, if rod type
precision: 2-3% of the range
measurement indication: in mm or % of the range
the scintillation counter must be insensitive to temperature variations or provided with
a com pensator
automatic electronic calibration.
This document is the property of Snamprogettl who will safeguard its rights according to the elvil and penal provisions of the taw.
.Utl VI,." ... u.
810312
I 20
SPC No. SA-E-6666

Rev.
5h260f32 oI I I I
I I I I
b) Elements to be considered for the selection of the source:
1) type and dimensions of the vessel, thickness/types of the material between the probe
and the external surface of the vessel
2) thickness and material
3) position in which the probe will be installed (whether inside or outside the vessel)
4) thickness and density of insulation, if any
5) measurement range
6) density and other characteristics of the process fluid
7) density of the gas above the process fluid, and relevant operating conditions
8) velocity of change in the level of the fiuid to be measured (see Note)
9) operating temperature of the detector
10) temperature of the cooling water that becomes necessary if the detector exceeds the
maximum permissible temperature
11) environmental conditions, execution of field mounted electrical apparatus, area
classification, etc.
12) request details on the type of fastening of the detector outside the vessel; calculation
of radiation intensity at 1 m distance from the vessel; check the necessity to install a
protective shield for personnel protection according to the regulations in force.
Note: The fluid level variation velocity is important especially in the cases in which level control
is required. In fact the scintillation counter is selected on the basis of the velocity of
variation. In other words, a more sensitive counter will be chosen for control, and a less
sensitive one when indication only is required.
c) Information to be provided by the Supplier with his bid:
1) a statement that the equipment he intends to supply complies with the regulations in
force in the country of installation
2) a list of all documents that are necessary to obtain the various authorizations: for use,
transportation, etc.
3) dimensions, weights of the radioactive source with its protective container for
shipment, and of auxiliary equipment
4) instructions for transportation, storage and installation of radioactive sources
5) list of international! national codes and standards met by the Manufacturer, and of
those to be complied with by the user
6) cost for transportation and, alternatively, addresses of approved carriers
7) characteristics of the radioactive source and maximum emission in the surrounding

area
Form code: MDT. GG. QUA.0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
This document is the property of Snamprogettl who will safeguard Its rights according to the civil and penal provisions of the law.
JOB UNIT NO.
810312 20
\
SPC No. SA-E-6666

Rev.
Sh 270/32 0 I I
I I
8) technical description, consumption, utilities required
9) list of inspections/ tests required by law to be made by the Manufacturer and/or by

official agencies
10) instructions and everything necessary to define the adjacent zone in which the
radioactive source is installed; measurements to be taken
11) construction details for the installation of the probe inside the vessels, taking into
account the weight and possible emission of radiation
12) list and quotation of monitors, badges to be provided to the maintenance personnel
13) other useful information.
5.7.2.2. Codes and Standards
(MINIMUM REQUIREMENTS)
The implementation of radioactive sources, the field of application, inspection and testing,
transportation, installation, methods of utilization, are governed by strict standards which are
apt to safeguard the health of the population and of the operators using these substances.
These standards are issued by international organizations such as IAEA (International
Atomic Energy Agency) and by the country in which the equipment will be installed; other
reference standards are U.S.N.R.C. (United States Nuclear Regulatory Commission).
Form code: MDT.GG.QUAo005 Sh. 01/Rev: 3.96 File codespcjobve.dot Data file: sae6666.doc
JOB UNIT No.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 28 of 32 0 I I
I J
6. TEMPERATURE MEASUREMENTS
6.1. General
The temperature will be measured by standard thermocouples
6.1.1. The thermowells for "UREA SERVICE" installed on the high pressure circuit shall be
fabricated in accordance with the following standard:
STD.TB.5002 for high pressure service to be installed on piping with line specification
"SPECIAL LENS UREA GRADE"
STD.TB.5002for high pressure service to be installed on equipment
The thermowell material shall be ASTM A 182F316L in accordance with Snamprogetti

specification SPC.CR.UR.510.
6.1.2. For "UREA SERVICE", M.P. and L.P. networks, the characteristics of the
thermowells to be provided are standard: they are threaded, with subsequent seal welding,
for piping, and flanged for equipment.
6.1.3. Measurement of reactor lining temperature
A thermocouple shall be provided, without a thermowell, suitable for detection the

temperature of the reactor internal lining. The thermocouple shall be equipped with a spring
to ensure proper contact of the element with the lining.
Form code: MDT.GG.QUA.D005 Sh. 0i/Rev. 3.96 File codespcjobve.dot Data file: sae6666.doc
This document is the property of Snamprogettl who witl safeguard its rights according to the civil and penal provisions of the law,
JUB UN\I fIIO.
810312 20
\
SPC No. SA-E-6666

Rev.
Sh 290f32 oI I I I
I I I I
7. CONTROL AND MOTORIZED VALVES FOR "UREA SERVICE"
7.1. Control valves
7.1.1. General
The valves described hereafter are included in the "UREA SERVICE" category. The materials
and tests for high presslJre valves shall conform to the requirements of SNAMPROGETTI
specification SPC.CR.UR.510; connections shall conform to the piping specifications and,
where applicable, to SNAMPROGETTI standard STD.TB.HPU.5002.
7.1.2. Design
a) Construction
The major elements characterizing the valves for "UREA SERVICE" are:
-materials: these must be adequate for urea and carbamate fluids

-connections: these must be obtained directly on the single piece that constitutes the
valve body, in order to keep down both weight and cost (since this is valuable material)
-shape of internals: it must not leave dead zones. Dead zones are a cause for corrosion;
carbamate intensifies its corrosive action particularly in these zones owing to the failure of
oxygen protection (passivation).
Owing to the oxidizing property of 02, the air admitted into the process creates a surface
which is more resistant to corrosion.
Note 1: Due to the great importance of the valves for "UREA SERVICE", only
Suppliers of proven experience shall be used for reliable plant operation.
Note 2: Valves on urea high pressure circuits may cause noise; the only remedy
consists in insulating the valves and the lines on which they are installed.
Valve internals are designed to satisfy severe operating conditions to the
detriment of noise.
Note 3: The commercial material HVD1 is produced at present by the German firm
GUSTAV GRIMM; in accordance with DIN designation it is defined as:
X 5 Cr Ni Mo Cu 25 8
Its composition is:

C= 0.10%
Si= 1%
Mn= 2%
Cr = 25 - 27%
Ni = 7.5 - 9.5%
Mo= 2 - 3%
Cu = 1 - 2%
JOB UNIT No.
810312 20
\
SPC No. SA-E-6666

Rev.
Sh 300132 0 I
I I
b) Installation
The inlet of process fluid into angle valves (from the bottom or the side) will be as
recommended in the following pages; different .solutions may be adopted for plant
requirements, after agreement by the PIPING department. However, the necessary
. information shall always be provided to the Supplier.
7.1.3. Notes on other valves installed in the urea plant
a) CO, vent valve
It is important that this valve has no leaks; any leaks will reduce production.
In the case of non-optimal conditions of plant operation and C02 vent to the atmosphere,
ice will form at or near the seat/plug (due to C02 expansion) resulting in improper closing.
The valve shall be cage type with jacketed body to permit heating; care shall be taken not
to oversize the valve because sudden discharge of great amounts will affect the proper
operation of the compressor.
Required seal class: IV minimum according to ANSI 8-16.104.
b) Ammonia recycle valves and carbamate recycle valve
These valves are necessary when centrifugal pumps are used in H.P. ammonia and
carbamate loops. Avoid oversizing to obtain proper operation at minimum flowrate
(overflow of excess flowrate).
The seal class required for ammonia recycle valves is class IV, according to ANSI 816.104.
c) Three-way switch valve for liquid urea to Drilling tower or recovery tank.
The valve is diverter type.

Material of body and internals: AISI 316L.
In case of air failure: the way to the recovery tank opens.
Jacketed body is required.
Seal class: IV according to ANSI 816.104
This class reduces the possibility of seepage between the seat and the plug, which cause
grooving from crystallization phenomena.
7.2. Motorized valves
7.2.1. General
The provisions for control valves under paragraph 7.1.1. shall apply.
7.2.2. Design
7.2.2.1. Sizing
The size of the body shall be the same as the line diameter. The actuator shall be sized for
the process conditions, operating time, and supply voltage
7.2.2.2. Construction
Valves will be constructed in accordance with the standards mentioned in the piping
specifications.
This document is the property of Snamprogettl who wi!! safeguard Its rights according to the civil and penal provisions of the law.
JOB UNIT No.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 31 of32 oI I
I I
8. SAFETY VALVES FOR UREA SERVICE
8.1. General
All valves that belong to the "UREA SERVICE" category have the same characteristics,
except for rating which will conform to the piping specification requirements.
8.2. Design
8.2.1. Sizing
Sizing will be in accordance with the codes and standards required by the project (API/
ASME).
8.2.2 Installation
There must be no dead zones between the valve body and the process line (forged block for high
pressure loop).
Nozzle must be connected directly on process line by lens gasket and stud bolts.
Intermediate spool piece is not allowed
8.2.2. Construction
For valves in urea and carbamate service at high, medium and low pressure, the construction
material of the plug and seat must be HDV1. Under normal operating conditions, the process
fluid is not in contact with the body, which can therefore be AISI 316. Only under discharge
conditions, the process fluid is in contact with the body; for this reason, washing downstream
of the plug is provided.
Inlet connections shall conform to piping specifications and, where applicable, to
SNAMPROGETII standard STD.TB.5002 (high pressure side).
9. ANALYZERS
The analyses that are made in the urea plant are very limited due to both the plant inherent
characteristics and the difficulty to be carried out (e.g. analysis of treated water).
The following analyses are normally provided:
• Analysis of 02 in C02
• Analysis of conductivity in steam condensate
• Analysis of the presence of urea/ammonia in the process treated water (normally not
required).
9.1. Analysis of 02 in C02
The function of oxygen in the urea plant is to passivate the metal surface wails, thus reducing
the process fluid corrosion. It is however essential that the oxygen amount be limited,
because in the plant there are components such as hydrogen and methane, which may
cause hazardous conditions in certain ratios; hence the need for oxygen measurement. The
operating principle is based on the paramagnetiC effect of oxygen.
The measurement range is 0 - 1%.
Form code: MDT.GG.QUA0005 Sh. 01/Rev. 3.96 File cOdespcjobve.dot Data file: sae6666.doc
.vo UI~I' '''v.
810312
I 20
SPC No. SA-E-6666

Rev.
Sh 32 of 32 oI I I I
I I I
9.2. Analysis of conductivity in steam and process condensate
The measurement of conductivity aims to check the presence of ammonia or C02 in the
condensate in the case of exchanger tube rupture.
Typical applications are in the steam condensate at plant outlet. on the carbamate
condensers and in the process condensate stream leaving the plant.
Form code: MDT.GG,QUA.0005 Sh. 01/Rev. 3.96 File codespcjoblle.dot Data file: sae6666,doc
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
Sh11 of 22 oI I I I
I I I I
2. Balances and Process flow diagrams
2.1 Process Flow Diagrams
Please see SPC. W GD-E-6002 rev. 1 hereafter attached.
Form code: MDTGG.QUA.0005 Sh. 01/Rev, 3.96 File codespcjobve.dot Data file: ureaunitprocessbook,doc
7 I
PI<-lOOl SL -1001
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PHU MY - FERTILIZER PROJECT

2?OO MRPD UREA PLANT
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PETROVIETNAM COMM. - Job 810312
PHU MY - FERTILIZER PROJECT REvJSICM: 0 I

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This dOCUMent is the property Qf' SnCMprogetti, mho .ilt so.f'egua.rd its rights according to the civil o.nd pel"lc\ pr"ovisions of the lo.m. ~ PROCE SS FLOW' DIAGRAM ~~~:;':,'~y"'"
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PETROVIETNAfvl COMM. - Job 810312

PHU MY - FERTILIZER PROJECT l
R(VISIONt f-0+-l I-++H++-IH
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MTPD UREA PLANT
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~ L.P. DECOMPOSITION AND SCALA - Scale
w
..J
RECOVERY SECTION r;:s:~~~ or
DOCUMento oi propriet(r SNAMPROGETTI. La. Societo: tutelel"'o: i propl"'i di",itti il"l sedeo civile e peno.le Q terMini di tegge.
t
This dOCUMent is the pt'operty of SnoMprogetti. 111'10 ..itt so.fegoord its rights o.ccording to the Civil end peMl provisiOt'lS of the lo. •. ;: PROCESS FlO\J DIAGRAM =-~:~!'';.....
P 7 ~ i' I I
V-1030 [-1014 V-IO;4 V-1031 [-1015 V-1Cl3 PK-1OO3 PI< -1(J()4

1st VACUUM 2 .... VACUUM
I" VACUUM 1st VACUUM 2nd VACUUM 2"" VACUUM I" VACUUM 2nd VACUUM
STEAM CONDo CONCENTRATOR SEPARATOR STEAM CONDo SEPARATOR SYSTEM
CONCENTRATOR SYSTEM
SEPARATOR SEPARATOR
1·- f-n
CV
Ic- r'
I
II
\-4-,,---,
r,
-'1
,._
UREA SOL.
fROM P-I006A1B
>
UREA SOLUT.
TO TK-IOOI
<
>
(
Jl +
I
I
UREA SOLUT.
fROM P-I009MB ,. P-I014 AlB P-10l6 AlB Ti< -1004
) >>-------__
11>'
UREA MELT PROCESS CONDo DISTILLATION TOVER CARBONATE CLOSE CARBONATE CLOSE
PUMPS TANK FEED PUMPS DRAIN PUMPS DRAIN TANK
> > ~
SuI rUI"'ic o.eld FrOM B.L.
(» I 05/021112 ••,.;s........ _ ...... (I) "" ..... ts , .,.. 5
• • ,108101 • - I ......
.. ~ I :-
V-I040 P-I020 AlB

~lril®lml;Q)J(©~®lQt" GD-[-6002
SULPHURIC ACID SULPHURIC ACID
ACCUMULATOR PUMPS
PETROVIETNAM COM!!. - Job 810312
- •- •- PACKAGE <TO BE DEFINED AFTER VENDOR SELECTION) ~~---------------------------------------------t~~-L~-L~~LL~
~ VACUUM CONCENTRATION AND SCALA - SeQ\"
SOSTlTulSCE 1..
W PROCESS CONDENSATE RECOVERY SECTION In t"ftP'o.C:."'nt oF'
~.O.CUMento di p,..~p,..jetQ· SNAHPROGETTI. La Societe' tutelero.' j pl"'Opri di,..itti in sede Civile e penale 0. tel"'l"Jini ali tegge. ..J SOSTITulTO DAL
IflIS docul"lent is the at .ho .R( its rights to the civil a.~d pena.t of the lO-'II. ..... PROCESS FLO'" DIAGRAM Rl1Pio.c,", 10)'
J I
lK -1001 Z-1008
UREA SOLUTION PRILLING TOIJER
TANK
t r£
UREA MELT
2>=RO=M==P~-)~~0_8
__
A/_B.______________ -1~r-______________________________----------------------i----i~ Z-lDHl
PRILLING BUCKETS
SUPPORT
D- rD
UREA SOLUT.
FROM P-I006 AlB
> ) 2-1009 AlB 2-1001
PRILLING PRILLING TOIJER
BUCKETS LIFT
/'
Z-1007
c- UREA SOLUT.
TO E-l014 ROTARY
< < SCRAPER
>-----'-..t,~ j L--_---..,
Z--1012
UREA LUMPS
B- b-",---"-----'-
()
I
, / !
..I.. ~
SEPARATOR
~y~============SJ--~~~--~>===>
PR1LLED UREA
TO STORAGE
rJ
N-1002 N-lOOi \./-1001 N-I003

UREA RECYCLE PRILLING TOVER IJEIGHING PRODUCT BELT
BELT CONVE YOR BELT CONVEYOR MACHINE CONVEYOR
__+-~~~~~~~-r~.~'~~"S~"~~~'~M_~_._._<_"_~__~
r-~I ___ 5______________~),(~
ts_"_'_'~
__
P-lO09 AlB FL --1001 AlB P-1019 AlB Z-1011 Tk-1003 o 07108101 (MISSIQN( ~ Issut' ~ RICCARDI RtCCMDI
UREA SOLUTION UREA SOLUTION UREA CLOSE UREA CLOSE UREA CLOSE
A- RECOVERY PUMPS FILTERS DRAIN PUMPS DRAIN TANK DRAIN TANK -A
STIRRER GD-E-6002
PETROVIETNAM COM!!. - Job 810312

PHU MY - FERTILIZER PROJECT R(VISI!JN£ 0 1
H-++H-++H-I R.visioo'!
~ 2200 MTPD UREA PLANT
~ ~----------~~~~~~~--~~~~-=~~~-----------t~SC~A~L~A---~S~C-Q~te~~-L~~-I
w PRILLlNG SECTION SOSTITUIsa: Il

d I" "~QC.M"t 0'
Docur'lento eli pl"'op"'ieto.~ SNAMPROGETTI. Lo. SocietQ~ tutelero: i prOpl"'i di,.+tti in seole ciyite e pennte a terr'lini di legge. .... PROCESS FLOW DIAGRAM SO$TlTUITO ....
Rf'j:Ilo.cf'd by
This docul"IE"nt is the property of' $nnl'loprogetti, .1'10 .ill soFegUQr"cI its rights Qccording to the civil. Qnd penal provisions of the lo. •.
7 I I
[ -1017 T-1002 R-I002

2nd DISTILLATION DISTILLATION UREA HYDROL YZER
TO [-1007 TO~ER PREHATER TO~ER
AMMONIA PRE HEATER
E- -E
FROM P-!013
L)==~>---------------------~
D- -D
TO E-I023 -
< -
FROM E-1013 ,-9 1
) )--------_.. --------
-! 2 ,I I
V~ •
f-I _ _ ......:..,M"'.L"'.P.:...-"S:.;.TE",Ac.::M.c....<:II:II
~. !
~ASTE ~ATER ~
j
• I
l
c- -c
!i
P-I~--------I~.:. C- .~-. ~I
'II
~
F)ROM
TO E -1013
""I
f -............. ,._
...__
,....
i
,~:--_________~~.'--------I-----------.,.i---~I----------------------------------------------~~~--C-ON-D-E-NS-A-T~~[T=O==B.~L.)
C~. ~
<:II
I
I I
r PURIFIED PROCESS
B-
< ( ~.-.~.-t2 t......... _ ..__1
1-'
[-1016 [-1024 P-101SA/B [ -1018

1st DISTILLATION PURIFIED HYDROLYZER HYDROLYZER
TO~ER PRE HATER CONDENSATE COOLER rEED PUMP PREHEATER
scotti Sci t.
o 07108.1'01 OtlSSIONe: - IsS\H' RICCARDI RIC-CAROl
~y~~o
~~;~ ~:: DtSCRI210NE ~ Dncl"iption p,. .. LATO
A_
1-'
GD-E-6002
PETROVIETNAM COMM. - Job 810312

gm~--------~~~--~-=~-==----=--------------~~~~~~-L~~L1
SCALA - SCQle
tD PROCESS CONDENSATE TREATMENT SQSTITUISCE u.
W
PROCESS FLO'" DIAGRAM
In "f'PIGc:~t 0'
DoclJf'lento di proprieta.· SNAMPROG£TTI. La Socie'tQ' tuteler"Q.· j propri cU,.itti in sede civile e pE'l'Ia.le Q terMini di legge. ;:! SQSTlTu!TO _
RiI'~o.cfl'd lDy
This docul"lent is the proper"ty of Sno.nprogetti, _no .ill sQFeguQr"cI its rights Qccording to the civil Qnd penQ\ proviSions of the lo. •. La.
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
Sh 12 of 22 0 I
I I I I
2.2 Material Balances
Please see SPC. N° ZA-E-601 0 rev. 1 hereafter attached.

Form code: MDTGG.QUA.0005 Sh, 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunftprocessbook.doc
Rev, Description Prepared Checked Approved
o ISSUE Date
RICCARDI CUSTOMER
1 RICCARDI 09/08/01
Revised where mark <1> Zam}l.!'.M'o JOB : UNIT No.
~ I f"'Mcotto 05/02102 PETROVIETNAM
810312
~ ~j\ SnSJrnpmgettl PLANT LOCATION 20
PHU·MY. FERTILIZER PROJEC
T SPC.No. ZA-E.6010
PROJECT
2200 MTPD UREA PLA NT
MATERIAL BA LAN CE · UREA Sh 1 of 10 . Rev. 1
UN IT·C 02 COMPRESSION SEC
NUMBER TION (2200 MTPD)
STREAM 1 _. -+_ _2_ _--+---::-=---::-3__ _ j-...---._ 4 _____ 5
NAME
C02 to Svnt. Sect.
..c.. _ ._ -+ __._c6c_..._. ....JI_ _ _.:...
7 ..._ .-j-....._ _B_ _ _
10 COMPONENTS M. W. kg/h wt% kg/h wt% kglh wt% kglh wt% kglh wt% kglh wt% kglh wt% kglh wt%
...!.~--··-·-----·....
,f----If----f---
+-·-+---+---j-
111 ---- --_ . --- ... .J- ·:; - · - j - - - - - -... .1-- --.
12 I (INERTS)
::- -1 I- --+ --. -j. ... --- ..j ... ..- -+ --- -I- --. --.. ..... .-.- - f-- -.-- +-- -... .... j-..
~ (Nm3/h) (Nm 3/h)
--+ _- -.. ..t --- l-. -.. . - - - j - - - - t -..- -
-+ -- -,e -- -- - - - -
TOTAL FLOW RATE 464 (Nm3Jh) (Nm3lh) !Nm3 /h) . - ---
(kgJh) 1--._._...L__ _ -+_._----".._. __1-'6"'68",9"'2....l_1~0~0,."'00~%~----L. (Nm 3/h)
--......
(Nm3lh) (Nm3Jh)
VOLUMETRIC FLOW RATE
TEMPERATURE
(m3/ h) 11-.__ _~--.-+---
.----+---=-21'-'7-'-'
,1"'8-.- __ __ _.. __
_ _ L. _ _._.t -._ _
._ ...... ...
L ___ .__ ~L--t_-....L.--
(deg 'C)
120 ._ 1- --- .-- --.
PRESSURE
(bar abs. )
. _ _ _ . __ .__ _ )--- ._ .•.__ .. __._ - __ __.__ __ - -
_ ..
158,00 ------t----.---
PHYSICAL STATE .
II" -- '.L .-. -+ -.- __.~ __ ._ _ _..._ _ _ _ _. _..•
_ _ _.._ _------j
DENSITY -,G"-A,,,S:......_.+-_......__ _._
(kg/m3) _ _ _ _ _ .. ...__ _.... ..._ .-.
AV. MOLECULAR WEIGHT
+-_ __ __
._+-_~3"'08:....._~ _ _
_ _ _ _._f -.-. ..-- -.
.- ..... ..• - .... .- - - - - . . . . . l - - . - -......- -
(kg/kmol) -. -+ -- -- -- .- +- -- -- -.._
44,00
- - - - . - - \-- . . _. __ __ _
1-__ _._._ _ _+-._ _ -- --
t- -- .- -- + -- -- ..- - . - . -.. -- .- -+ -. -- -- .- -t
1- --- --- -...-.1 --. -....-- -.-
.- -- .- -- .
., FIGURES INDICATED IN THE MAT
-- -- -.- -.- .- . - - - . _..
ERIAL BALANCE ARE THOSE EXP
ECTED AND MAY BE AL TERATED
$ NOT CONSIDERED FOR MATERIA
L BALANCE OF THE STREAM;
IN ORDER TO ACHIEVE THE REQ
UIRED PLANT PERFORMANCE
This document is the property of snam

progf lttl who Will safeguarrJ Us tights
Bccordlng to tha civil and penal provIsions of the
la
, '
......
~'~-""--.~..,.-
'--" ...-,.... --~
~~!,:~:;:';~.?"~~~Jr(l'll.k";jl:.h·!HHt c> It
;
"
-- -- -- -- "- CUSTOMER
CO
J ~
N~r
hrDEN'TI Al JOB: UNIT No,
SnamprogeHi PETROVIETNAM
810 312 20
f' PLANT LOCATION
I
-------~
~-"""="~~~::::~I:"·l;
TE'~"J ~ PHU-MY. VIE TNA M
., 'A~~~.~~~_
.
MA TER IAL BA LAN CE · URE A
PROJECT
FER TILI ZER PRO JEC T 8h2 0f 10
SPC . No. ZA- E-6 010
Rev. I
UNIT-H.P. SYN THE SYS SECTIO
STR EAM
NUMBER 11 N (2200 MTP D\
12 13
NAME C02 to Reactor 14 15
Reactor Outlet 16
10 COMPONENTS
M.W kglh
Stripper SoLOutlet Stripper Vapours -- \ - - '
HP Carbonate Reo. . 17 18
wt% HP NH3 to Elec t
1-1 - NH3
17
"oIh wt% kalh wt% kg/h wt% kolh
VaD, from HP Sec t Carb,Rec. to R-l0 0l
2 ._. 84119 31.18% 52844 25,11%
wt% "Oil, wt% kalh wt%
--.-:-- \;02 _, 44.._ ,._.6 689 2 100,00%
31275 52]0 % 34149 46.64% 75796
kalh wt%
_ .. c3__ UREA 39448 14.62% 14838 99,87% 5198 94.06%
-~------------. 60
j..---- 91592
7,05%
2i~ 41.47% 15277 20.87% .- -- 60226 47.4
,1%
-
4 WATER --- -- 33.95% ! - - - - -- -- -
91592 \-.43.52.'l6. 164 2.97%
.a~ ._ --- 31.27%
--~--
... . 18
-. 5
~-
FORMALDEHYDE f--. - - -
54651 -- -- -
20,26% -. -- f--- --51196 -
24.32%
1- -'_ -
L....... __
3455
30 r-_~'.az.'l6. 1-_ 2378Z, 32,4~ ..•- 95 f - - - - - p-- --- -
6 SULPHURIC ACID +, -_ .- c..•._ _ _ /--- -'-- - -- - --0.13 -- % 164 2.97% r' 27078
--. - C': ':-- . 98
_. - ._ -_ . ,._•.._-r-- -21.3
-2%-
7 AMM.SULPHATE ..~ _ _ .' - _ _ _c.. -·- · ._ -- -- -
8
1~.
-- . - f-. _- - ' - - . - -_.,_._-- 1-- -_. - -- --- "-" -
-- -- -- -- -- '-- -_ .- - _. - - - - - I--. 1-- -._ - . ' - r- -- --
--
9 _._
--- -_ ._- -_ . -- .,-- '
-- -. -
-- - -
10
'--. --- .'- - -.-- - - . -
' - ' - -f - - -
-- ~- ---- -- _. _- - -- --
11
. __ ...
. --. --- --. - -- -- -,,
- ' - - ,..- --- -
_. - -- -- -- -'- f-- ._ - ._-
- 1-- -_.
- - -- -'- -- -- -._ -- - - - . - .-. -.- c,_ _ _ .
•. .-. _- - ...
.
--
.
~"-'
_. _. -
-,--- -----
~--.-
12 (lNERTS) -'- "--

~-
8 464 (Nm 3lhl

~-
r-- --- . - - - - - f--~ -_ ._ - I---~- ._ -- ---~-
TOTAL FLO W RATE

(kglh) 66892 100.00%
484 (Nm31h) 23 (Nm3Jh) 471 (Nm3/h)
269810 (Nm3/h) (Nm3/h)
-- -- ._ -- _. _- -
VOLUMETRIC FLO W RATE 100.00% 210470 100.00% ...5.9.a~ 100, 471 (Nm31h) (Nm3/h)
(m31h) 217.18 00% ....E3.!.3_ 100.0~ __75891 100,00% 5526 100,00%
TEMPERATURE ---~--
- 221.55 539.45. __ _ 127027 100.00%
(deg 'C) 78.72
PRESSURE -_ ._ -- - 1-.
. 120 188 204 190
-~.-~-
--
_... .1£ .23__ _ 56.39 137,33
(bar abs.) 105
PHYSICAL STATE
157.00
--- -- .. 152.80 148.00 ·14 8,0 0--- - f-~..-il.L_" 155
.-. 155
154.00
_
-,,~--
/----"----" -... 220.00
1--- -. GAS
-
-~---
MIXED LIQUID f--. .. 146.00 146.00

DENSITY (kg/m3) -- -- .
GAS . LIQUID .-.
308 LIQUID GAS
950 LIQUID
W. MOLECULAR WEI GHT (kglkmol) 44,00 -- _ _. 125 <'': ._ 930 515
f-. 25.93 26.93 22,90
I- 98 925
1--- --. 19.91 --
.,
17.00 17.34
1---- _. . 21.35
.
"- -- - - . - . - - - - -- -- -- - j.-.
FIGURES INDICATED IN THE MAT
-- ~--.----
-"-.,,--
ECTED AND MAY BE ALTERAT

ED IN ORDER TO ACHIEVE THE
8 NOT CONSIDERED FOR MATERIA
L BALANCE OF THE STREAM; REQUIRED PLANT PERFORMAN
CE
This dOcument Is the property 01 snam

progsu, who will sfJJfeguarri Its rights
aOOMilng (0 the civil and penal provtl$/ons o( the
law.
;
e-:i;"""'",{·,;;~;·r.·,";"'w;!:tH 0 A
._---,----_..-._.- "
- CUSTOMER JOB: UNIT No,
Snamprogetil CO~f~'?:DENTI
'~;H>' r Al PLANT LOCATION
----.-
T'-'~';"I \ L'oEA
. . ~=,..~::'~~:'<-:.,~~,.=- .' ;. .~ , - I
FERTILlZE.R PROJECT
PROJECT
PHU·MY, VIETNAM SPC. No. ZA·E·S010
Sh30f 10 Rev. I
0 MATERIAL BALANCE· UREA UNIT-H.P. SYNITHESYS SECTION (2200 MTPD)
NUMBER 19 20 21 22 23 24 25 26
._---,.
STREAM NAMI;: NH3 and Carbamate Pass. Air to Stripper
iD COMPONENTS M.W. kglh wt% kglh wt% kglh wt% kalh wt% kg/h wt% kg/h wt% kolh wt% kolh wt%
1 NH3 17 136022 67.03% ..-
. _.
2 CO2 ... 44 39723 19.58% .. _ .
---.
__._,.-.-- •.
L-.
.
.
. ..• - .. -
. _ - . - - . _.. - - " - - " - " . - _._-
3 UREA 60 ..- - _ . - 1--.- - - - I--. . -_.-
-------- --. . ---- ~.-.
. - _ . - ---"'''.- - -
-, ..
4 WATER 18._ 27173 13.39% .---'-
5 £QRMALDEHYDE 30 ..• . - .... ,,-~- - ....- '''-- - ' - ' - ..... _ ..-
6 SULPHURIC ACID 98 /-----
. _. 7 ~MM. SULPHATE 132
. - f - - - - 1-. -- - - - - - /--- .. _ 1 - - - \---..
.
-'- ._-_. f - - - . -
.-
8
. - 1-. f - - . - •. _-'--- _._. /---•.. .1-----
.- _
9 f-...- -.
- ---- 1--..._ ..-
---'".
10 1-----.
....
. ..-
...•
. .".. _ _ -_
_- --_._. ._ _
. ..- ... 1-._....
__
_.
.--. "-
'- - -... ----

-.~--.-
......1.1..... -".-~,,-
' - - 1---. . ... _ ' - - . _ - .. ..... .... - . . . . ..•.- . - - -... - -... ..-
,
12 (INERTS) ~ (Nm31h1 30 (Nm31h) (Nm31h) (Nm31h) (Nm3/h) (Nm31h) (Nm31h) (Nm3/h)
,TOTAL FLOW RATE (kg/h) 202918 100.00% . I .L_~ I I I .• -
VOLUMETRIC FLOW RATE (m3/h) 1---. 248.98___ f--.. _ - .
" - - " - . ,,_. . ._-.
TEMPERATURE (deg ·C) 125 AMBIENT .. .- ..... - - - . - -_...._'. .
•. .. -
PRESSURE (bar abs.) 157.00 . . ATM
- ..•- _ . _ - - -. _ . _ - , . .. "-
PHYSICAL STATE LIQUID GAS . - _.--. .---~.- ..- - - - - _..-
DENSITY (kg/m3) 815 . ---"'-"'--"
-.,~ 1--._'--, -.
AV. MOLECULAR WEIGHT (kglkmol) ._.- 19.49 ---_..., - - - - - - ..-
__ _.... ... •.. ...:.. _. -._-" ._"
...
f--.-.,-- ...-
...- . - _ . _ ' - "
",_ -_
.. .. _ •. _ ..... .
... ~-.-
..._'.-
0 FIGURES INDICATED IN THE MATERIAL BALANCE ARE THOSE EXPECTED AND MAY BE ALTERATED IN ORDER TO ACHIEVE THE REQUIRED PLANT PERFORMANCE
~ NOT CONSIDERED FOR MATERIAL BALANCE OF THE STREAM
This dOCument Is the property of snamprogettl who will safeguard Us rights accorrJIng to the eM and penal prov(s/ons Of the law. File: BlLMATacJd2200Jev1.XLS
·-~fJ;~~~',;,;'.'1.'_
l'~\;;,,_•.~;:
,~; '"
,:::",·iii:·-::-'· '"', .
-. CUSTOMER
Sn sm pro ge tti
CONfiDENTIAL
-- -- - PLANT LOCATION
PETROVIETNAM
JOB:
810312
UNIT No.
20
:
TE "'I 'I....... \,...,.. ~«. ~
"',= """ .........-""~~~...,,-...........

I. ~
, . , - . . -....... -
l'... r':;:'.. != A PROJECT
PHU·MY. VIETNAM
.
SPC:::. No. ZA·E·6010
0 FERTILIZER PROJECT
MATERIAL BALANCE -ljR EA UNI Sh4 of 10 Rev. J
NUMBER T·M.P, RECOVERY SECTION (2200 MTP
STREAM ~.
31 32 33
O)
. 34
NAME MP Dec. Sol. Oullet 35 36
Van. from MP Dec. Condo toMP Abs . 37
10 COMPONENTS MP Abs. Sol. Oullet liP Carb.Pump Flush. 38
M.W . ko/h wt% Van. from MP Abs.
1 NH3 kglh wt% kglh Nliii iOm Condo Vap. from ·NH3 Condo
17 wt% kglh wt% kglh
. 9155 6.33% 48887 wt% kg/h
-_._2 -- rc02
_.
68.42% 58168
61.~~ 34149 47.62%
wt% kgl!i wi"% kglh wt%
---44 2473
- .c3.. _
UREA _ _ • _ _ _ _ . __
__ 60._.
---
91592 63~
1.71% 12529 17.5a.~ h-
!.~ r-' 16.04% 152 n ~.!.3o.l:1 _._ - "..
1-.2.2.iJ1.<> 100.00% 30092
r--_. 100.0~~ 1918 100.00%
4
f-.2...
WATER
C''''3i)~
FOR MA LDE HYD E--
18 ~:@21 1-. 28 .59 % l--.
I-
l0~9. !--. .!.4.05'k 21791 22.88% 2228 7 ~:oa% 1500
"--
--
_. . __ _
- . - - - - -
..•
. -r--'
r- '- -1 - - -
--
rJl.. ~~PHURIC ACI D" -:.-=.~. 1-- ."
100.0Q~
1- - .-1- -- - /-- .
7 AMM. SULPHATE
'-" r-- - 132 r-'-~" - . - -1- --- -
- -1- --- . - - - 1- '-' - !-. _- -
-----~ ~.--.-
"
._S --, --, --_ ._ --_ .- - - - -- '-- ' - - -- -- --- -'-- C" .._ -
~- --
9 --.- " .~
.-
10 + '- -' - -........-.- -- -- '--
..1"
.. 11• ---=-.= .----=r:.~. -- __. - -- -.- - ...
.
~-,---
1- -- ---- -.-1-- --- - - -1 - - - - _ _. ....
-- 1-- -'-- '
..- - . "-'-- -'-_ .- - - - -_ - .. ._- -_..
- ' - ' - - --- --
12 i(INE RTS ) -'.- -- -_. C - - . _ -
TOTAL FLO W RATE
f.) (Nm3lh) 494 (Nm3/h) 494 tNm3lh)
-_.
(Nm3/h)
. --. --- - ._-_.. _- .- - - -
(kglh) 144541 100.00% 71455 (Nm3/h) 494 (Nm31h)
VOLUMETRIC FLO W RATE 100.00% 95236 100.00% (Nm3/h) 494 (Nm31h)
(m3/h) 71713 . .100E.o'l:' 1500 100.00% 32010
131.40 5292.96 100.00% 30092 100.00%
TEMPERATURE 75.49 1918 100.00%
(deg 0c) 165 1.52 2134.00
I----- 145 85 - 52.0 6 147.54
PRESSURE (bar abs.) 20.50
I-- 79 50 48 '-
20.50 19.90 42 42
PHYSICAL STATE 19.90 27.00
DENSITY I-- LIQUID GAS MIXED I- . 19.90 . __ __1,9.70 _ _ ... 19 .70 '-
LIQUID
AV. MOLECULAR WEI GHT
(kg/m3) 1100 .__ .Ihi..<';- .j-- .
r- --LIQU
--ID-- " / - - - -GAS
- - _ . _ .I- LIQUID
. GAS
(kglkmol) 32.72 19.22 - 950 . 990 1-_'_..1~_ 578
19.13 13
19.95
._ --- 18.00 17,00 17.00 -- -
.- / - - _ . _ . _ - _. _. _.._- --- -_ ._ ._ --_ . -'
17.00
«) FIGURES INDICATED IN THE MAT

ERIA L BALANCE ARE THOSE EXPECT
ED AND MAY BE ALTERATED IN
f.) NOT CONSIDERED FOR ORDER TO ACHIEVE THE REQ
UIRED PLANT PERFORMANCE
MATERIAL BAL ANCE OF THE STREAM
This document is the property of Snam

progettJ who WIll safeguard Its lights
according
~:~''''Ti'l!t))~'or;
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SnamprogeHI CO~i'f,H~
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ENTI
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PETROVIETNAM
JOB:
810 312
UNIT No.
20
4)
.._:E~:~",.,;,,~~,.J__~:~.:::~/ PROJECT
PHU.MY, VIETNAM
SPC. No • ZA· E-6 010
FERTILIZER PRO JEC T
MA TER IAL BAL ANC E -UR EA Sh5 0f 10 Rev. I
UNIT·M.P. RECOVERY SECTIO
STREAM
NUMBER 39 40
N (2200 MTPD)
41 42
NAME Ammonia from B.l. . 43
ID COMPONENTS
NH3 10 Boost. Pump NH3 I~ HP pum p' NH3 Refl.to MP Abs.
44
. 45
46
M.W . kgJh Ammonia and Inerts MP Inerts Wash.Co
wt% kgJh wt% nd. NH3 Sol. to M.P.Abs. NH3
.. 1 NH3 kgJh wt% kaJh wt%
Loss. and (narts
17 51792 99.BO% kgJh wt% kgJh
83091 wt%
2
3
--=:=
CO2
..._ . . - .... 44. _
99.87% 75~ 99.87% f-.
--- 7295
-- --99.88% 711.
C'._ .-:.: 100.00%
kg/h
.c- _ 696
wt%
58.83%
kg/h wt%
URE
-~~--~
A
-- ' - - - 60 ..--.. -- _... - _ . - " _.......11 --
100.00%
--
4 WATER
.-----
-.
...- ~
.--"-~
-- --... , , - - - - f - - - -..
.. _-
5 FORMALDEHYDE
- ....- - - - - - .._-
30
-
104 0.20%
1-. __.
18
104 0.13% 95 0.13%
.
-- -'- -" c- --' - -- -- --- --
9 O.l2.!o. f.-.~
. 487
~.-.
100.00% 487 41.17%

1- -'- - -- _ ...
-- -- -_._.
6 SULPHU RIC ACID --~.-
•..
98
.. - . •. -
7
..... .. _- -- -_
AMM. SULPHATE
132
f-- --- -- _. --'-- -~--,.-~
,..._- - ~-- -- -. - ---- -._- - . - - -
8
..
..- -_...- ._ ....
-' .-- .
-- -- -- -.... r ' - - .
,'-~ --~.
.- ._ --- ,
'rei ._ -- -- -- - 1--- ....... --- --- -- _. 1- --
9 .
-.-"-,--
--.--."-
--~- ._ -- - - -..- - - -_ .-- --
---"
11
r'
~--"
--- -,--
. - - - ' - - ' f- -- - ..
j....
__ . ' -J--
1- --- - - - _ .1- - .... "-"-'
-~,-,-
--- 1 - - - - -- -- - - - - -
---
-
f-----
--"-- - ~-~---
'
__ --_._-- r'- --
.f. .-. --
f......- .._ . . .-
.- ' - ---_.
._ --- ._ -- __ /-. _ -
12
.--~,-
-
f---- --- -." - .. _ - ' - . - - - -
(INERTS) (!) -- --- _- -"~--
-,,~
130 (Nm3lh) (Nm3/h)

.
. 1-- -"- " . .-
OTA LFL OWR ATE (Nm3Jh) (Nm3Jh) .. f - - . - -.
(kgJh) 1-.51896 100.00% 624 (Nm3/h)
(Nm3Jh)
83195 100.00% 75891 100.00% (Nm3/h) 624 (Nm3 /h)
OLUMETRIC FLO W RATE 7.~ ..J,0O.OO%
(m3Jh)
-- --86.21
-- _. - 142.21 ~,o .o! o ..21.!......
.. _4.8 7 ._ . .J<lO.OO% 1183 100.00%
,MPE RAT URE (deg "C) 25 35
._ -- _ 129.07
..'- 1-- ._. 12.~ _ _ ~._.~.88..
_. _ I--_.Jl:~.fl... __ _
15 100.00%
.1.5 4... ..._ ._
,ESS URE (bar abs.) 25.00
. - .. 35 35 .... 30 50
0.88
- "..- - - ' - -
-
19..80 50
iYSI CAL STA TE -- 23.50 23.50 19.50
50
"-~-
LIQUID LIQUID LIQUID

27.00
-- -- _.
19.50 19 .5O _ . _
,NSI TY (kg/m3)
..... 602 585
.
-'
LIQUID GAS .. LIQUID ._ /- LIQU --
ID. ' -
L _... _
_. GAS
588
._ - _ _ .£5 _.__ .. -,,~--
-"
I. MOLECULAR WEI GHT (kglkmol) 588
_ ._ -- --
17.00 _ _ 17.QC!.._ _ 17.00
c--- .. 990 . - 770
--"'---'-- _ . 17
17.00
_._ - 0. , - - ._......JIl:ClO"""'._
17.0 17.40 _ ........E!8 __
~.
. 1--"" ,,-,,--
c........... __ __ __
~ FIGURES INDICATED IN THE MAT
f.-.----.--. ... .-- _..._ -
ERIAL BALANCE ARE THOSE
EXPECTED AND MAY BE AL TER
ATED IN ORDER TO ACHIEVE
~ NOT CONSIDERED FOR MATERIA
L BALANCE OF THE STREAM
THE REQUIRED PLANT PERFOR
MANCE
This dOcument Is the propetty of Snam

progetti who Wfll safeguard Its rights
acc;ordfng to the eM and penal provfslons ofthe law.
Fils: BILM ATac id220 0Jsv1 XLS

i __
-~-
"~·"
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_"_
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.
1"-----:~=-~::..:...:.~-~.'.
. CUSTOMER
I._C--O--NFIDENTIAL
JOB : UNIT No_
Snamprogetti PETROVIETNAM
810 312 20
PLANT LOCATION
- - -
-'-r PHU-MY, VIETNAM
0
l t:::'' ''-'l"'" 'j
... ,,,...,,,'-" ....
9,"
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' I U1':;;:EA
MA TER IAL BAL ANC E .. URE A
PROJECT
FERTILIZER PROJECT_
SPC . No. ZA-E-6010
Sh6 0f 10 Rev_ I
NUMBER UNIT-L.P. RECOVERY SECTIO
STREAM 51 N (2200 MTPD)
52 53
NAME LP Dec. SOl. Oullel 54 1-:-:_
Preconcentr. Outlet Vap. from LP Dec. 55 56 57
ID COMPONENTS Vap. from Pr.'; '-';;; :- Vap .lo NH3 Preheat. Carb 58
M.W . kolh wl'% o from LP Condo lP_lner. Wash. Cond
1 NH3
17 2560 1.99%
wJ% ""Ih wJ% kalh i<g/h wJ% kg/h wJ% kglh
o Carb.Sol.from LP Sec.
2 CO2 f---- 508 41.0 0.47% ,---. 659 5 wJ% kolh wJ%
44 5% 2052 9.69% 9983 kolh wJ%
__ 91.6. ~71% 39.41%
3 UREA 105 0.10% 1557 .9~ ---39.41%
e-
_._- -. 60 91592 71.29%
9.69% 811 3.83% 2956 11.67% -- ~-
9983 39.03%
"-~-
I..i... WATER
18
-- 9151J~ _!l5.~~
~--- 1-- ---
2956 11.67%
2956 11.56%
33408 26.00~ _.J. --
5 FORMALDEHYDE 50.9~ f..- 14.06% 7913 49.26% 18318
- -- --- --- - /-- ---
30 - 86.48% 12392 48.92% 12392
--
,~
6
7
SULPHURIC ACID
AMM. SULPHATE
98
132__
- .- - - -1- --- - - - - -
1- -- - -
-- -- - -- ---- --~-
--- --- -
48.92% 250 ~OO.OO% ~642 1--49 .42%
-- -- --
-- - - - -- --
- _.. +- -- --
9
--- - -- -- -- -- -- - --- --- -- --
~----
-- r - - - - -- -- -- -- - -- 1- -- - - - -
- - - -- -- -- -- - f - - - - - - - -- -- --- ---
-- f-- --- - --- --- - - - - - -- --- .- --
10
-'-- - -- -- -- '"- --
-- ---- --"" -- -- - -- -- \---
11
.. _- -
",-_
--- --- - - - - --- ; - - - - -- --
- -- -- --- --- - -- -- - -"- --- - f - - - -
12 (INERTS) @ '- -- 1-- --- -
~,--
-
TOTAL FLOW RATE

(Nm3lh) (Nm31h) (Nm3lh)
-- -- -- --1- --- -- -- -- .
(kglh ) 128476 (Nm3/h)

100.00% 107295 (Nm3 -- f-- --- 1h) (Nm3/h)
'VOLUMETRIC FLOW RATE 100.00% 16065 100.00% 21181 (Nm3/h) (Nm31h)
(m31h) 113.70 - 100.00% 25331 100.00% _~1i-3_3Lc.1()O.
-- -- 0~~ .' 250
TEMPERATURE (deg ·C) 151
89-19
104 .
-- 5950.00 132381.25 1---__ 9381 -I!L__ _._ 2ti 81
· 0.25
100.00% 25581 100.00%
PRESSURE (bar abs.) 5.00 I- -- 130 100
~-
130 ."-- 27.07

PHYSICAL STATE 1--- 0.33 -- I-'- 5.00 0_33 5_00
--- -.£ --- --- 50 42
4.50 4. 80
DENSITY
LIQUID LIQUID GAS GAS GAS
e-- --- 27.00 -
--- --- ---
(kg/m3) \-- ---LIQU ID
AV. MOLECULAR WEIGHT
1130 1195 2.7 0.16 2.7
-- --- --- -- I--- -
945
LIQU ID LIQUID
(kglkmol) 36.18 - __ 990
44.82 18.62 945
18.31 18.86 18-86
1--- - - 18.00 18.85
1-------
-- -- -- -- -- --
4» FIGURES INDICATED IN THE MAT
-- .-- -- -- -
ECTED AND MAYBE ALTERATED
@ NOT CONSIDERED FOR MATERIA IN ORDER TO ACHIEVE THE REQ
L BALANCE OF THE STREAM UIRED PLANT PERFORMANCE
This dOCumenf Is the property of Snam proge ttl Who WIll safeg uard its rights 8CCf)J
tilng to the c/vU and penal provls fons of tM Jaw.
'--....... ~.....-."'".,.'.......,.,.,..,....,'~-.~--~..
"'i""",., l'1"ii;"'l1'iOJ«ll®·Itt~ sIn 11
,--.
-- ~""'"t-4-:"'li~lt,:l>
-- -.
.
_. CUSTOMER JOB: UNIT No.
CONnbENti/~l
Snamprogettl PLANTLOCATION
---~.-¥-~----
.... .-;;- !"~k·;

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PROJECT
PHU-MY. VIETNAM SpC. No. ZA·E·6010
¥.,. ,.--, ,'"~,.,, .-""-~,,,, "." ""'~"""-=--""'~''''''''-'-'''''''''''''''''''''''''''''=-'~'''-''---- FERTILIZER PROJECT Sh70f 10 Rev. I
0 MATERIAL BALANCE - UREA UNIT·L.P. RECOVERY SECTION (2200 MTPD)
STREAM
NUMBER 59 60 61 62 63
-'
64 I --,--,--~.
65 66 .~
NAME Carbo Ree. to MP Sec. Inerts from LP Sect. Reflux to T·1002

ID COMPONENTS M.W. kg/h wt% kg/h wt% ko/h wt% ko/h wt% kg/h wt% kg/h wt% kg/h wt% ko/h wt%
1 NH3 -'~-.
17 9281 39.03% ..
702 39.00% .. _-_. - - '.. ~ .... _. f...._- f....-"
2 ~~. ~i....... 2748 11.56% --- 208 11.56% _- - - " - - _._.....
3 UREA
~~- .....- ..~.-. -
60
----
...
--~ '-'-"
,,~~
-
... .......- .
. -~ ...... _ .... . . ---~,- ...-..--- .. _ ..
--_.
-_.-._._.
4 WATER
~. 11752 49.42% .. 890 49.44% - •.... ~ ~.--~ -"-- _.- -~,.- ..- - _...... .. ... "
5 .. FORMALDEHYDE 30._ .......- ._-_. 1----..- ..

---,
6
-7'
SULPHURIC ACID
AMM. SULPHATE
98
132
-. __ . ._-
.. i - . - - ._-,""._.
. - . - ...... _. .. _-'--'
-.-~
._....
~"--
~~-
--
..
•.- C---. . -._" f--.- ..- ~-- 1------ f-.. - -

6 -_..... f------. ......
_ .._ ... 1----.-
.. . - - -... f--- .. -.
--_. _--_
9 .•
.
.. 1-"'-"
__
.--~ ~.--
__
1 - - ' - " .. _ - ... f.... ---
~ +~
.. --~-.-
~ ~ "-'
..-------_._... _ ... _..",-"._.- " - - " ..._-"------

f------
_ .. " - - _ . _ " " " , ,
10
"""------
•. .... . . 1----....... 1-----.... - ~--'-"
...-.... ...- _ . . - ----'--
11 -_. .... f.... _ _ _ .L.........._ ._. ..- _._ .... ....._ _ .. L..._..•_ _._-----
12 (INERTS) e (Nm3/h) (Nm3/h) (Nm3/h) (Nm3/h) (Nm3/h) (Nm3/h) (Nm3/h) (Nm3/h)
(kg/h) _.2 3781 100.00% 1800.J:.1Q~ _ ..1 __ I .
TOTAL FLOW RATE
VOLUMETRIC FLOW RATE (m3/h) -_.25.17 1.90 . _._,---_..
. - -_.
--_._-_ .. _- _ . _.... __ .f-----.
f---...
.
..- ~--
.
TEMPERATURE (deg ·C) . _ - _ . 42_ - - ' - 1-...- 4..

2 ..._ . _ 1----_..._ . . . . - 1-. "-----,-,-----."'~
- _ . _ -.... _ .. -------,,---,,-
!PRESSURE (bar abs.) 26.00 26.00 .... 1--._..._ .... . ..- . .-
I-'~-''''---'' I-
-~
PHYSICAL STATE _...J,I£~_ f--..- - . _ . LIQUID - - f-----. . ' .. _-"

DENSITY (kg/m3) _. 945 .
945 1-----.-..- .... .... - •. --'-"--
- - _ - - - _ . _ . - .._-"""'--,,--_. ... - -.
~-."
_._--_.
--.~
AV. MOLECULAR WEIGHT (kglkmol) _ _ .~6_5_. 18.65 ...- ..-
---' _.__ ..... _-

....
_. f----.-..-.~.. C'....- -......- . -.. ----~---- ..
0 FIGURES INDICATED IN THE MATERIAL BALANCE ARE THOSE EXPECTED AND MAY BE ALTERATED IN ORDER TO ACHiEVE THE REQUIRED PLANT PERFORMANCE
e NOT CONSIDERED FOR MATERIAL BALANCE OF THE STREAM
File: BILMATacId2200J~JV1,XLS
This document /8 the property of Snllmprogettr whO Wl11 sareguarri its lights acco«ilng to the civil and penal previsions of/he law.
r C::::~". .-: ''''''~"-;1t;&~'
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.
S n am p ro g et tl
C~.O·'N~'''ii''JDE NTI,Al. CUSTOMER
PLANT LOCATIO
PETROVIETNAM JOB:
810312
UNIT No.
--:-' :~
N
.,_:=
20
':;:~.-;--~1-1-~'~" e-
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">-~,"..,... ~,.-
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PROJECT
PHU-MY VIETNA
M
SPC. No. ZA·E-6010
.
NUMBER MATERIAL BALA FERTILIZER PRO
STREAM 71 NCE· UREA UNIT JECT
72 NACUIJM CONCENTRATION SE Sh 8 of 10
NAME Urea 80lulloo 73 CTION 12200MTP Rev. I
10 COMPONEN 14
TS
M .W .
Vap. from ls I Evap
. D\ 75
i
1 NH3 kglh Urea Melt ,
wt% . kglh Urea Me~ to Pro To 76
17 wI% wer Steam to Va 77
2
- - ' . CO2 1_ _·!06 0.11% kglh wI% kalh
.;:5Yst. Van. from 2nd Ev
an. 78
44 402 3.69% wt% ka Urea Product
lh
- --3 .--- UREA
-- -- -- -- -- -- - 10 0.01%
95
87 0.10% 23
wt% kgih wt%
H2 S0 4 sol. Injec
tion
4 WATER ~o.. 91467 0.87% 0.03%
1 -- -- - ka ih wt%
18
94.88%
............1.~ 1.15% 91217
- - - .- ;.... 19 0.39% kglh wt%
5 FORMALDEHY 4817 5.00% 99.66%
DE
30 10273 94.29% 91217
99:~.
t- - - - I-~" 0.2 1%
6 SULPHURIC ACID ..- 225 0.25% 229 -- 250 5.13%
7 AMM. SULPHATE
98
132
f-. - -- _.. f- -- - ..-- . - 0.25% 9800 100.00% ;...........
.4592 ~4.27%
91190
229
99.48%
.... _-- 1- -
8
i-- - -- 0.25% 4 "2 .1 3%
_ - __. _-
-.~
9 ..•... -. ...-
- - J- -- - --
~.~
.
... .. - - - J- - 248 0.27% - - ---

1 -- -- -
10 ---- - . ._ - - -
- - _.. f--. - - - - " - - - - - - - f- .. _ - t - - - - -
-.
--
184
-,
-- -- .- -- ~ ~,
!l.~
-
~--~
11
,,-~
248 0.27%
t- - - - - - - - i- -- -- ._ -_ . ',,-
-.--~
12 I (INERTS)
rO TA l FLOW RA 49 -" --c-t--- ..- 1 - - - - t- --
TE (Nm3lh) -- . -- j - _..
(Nm31h)
'OLUMETRIC FL
OW RATE
(kglh) 98400 100.00% 10895 100.00%
I (Nm31h) (Nm3lh) ---
EMPERATURE (m3lh) 79.67 91529 (Nm3lh)
100.00% 91717 (Nm31h1
(deg "C) 84088.24 100.00% 9800 (Nm3Ih)
RE8SURE 1--_ _12 8 74.72 100.00% 4871 100.00% (Nm31h)
(bar abo.) 128 . 74.87 91667
HYSICAL STATE 0.33 136 _ _ _ 4152.54 100.00% 188
0.33 136 304437.50 100.00"10
~NSITY LIQUID 0.03 147 0.10
GAS 15.50 136
(kg/m3) LIQUID 4.41 60
I. MOLECULAR W 1210 0.03 35
EIGHT (kgikmol)
53.80
0.17
1225
.. LIQUID
GAS
GAS
ATM
3.00
----
18.20 1225 SOLID
59.52 2.36 LIQUID
59.70
18.00
0.016
780 (bulk) ._ ----"
) FIGURES INDICA 16.69 _ _ 1840
TED IN THE MATERIAL 59.74
, BALANCE ARE TH 1- -- -- . - -..
89.53
NOT CONSIDER OSE EXPECTED
ED FOR MATERIAL AND MAY BE ALTE
BALANCE OF TH RATED IN ORDE
E STREAM R TO ACHIEVE TH
E REQUIRED PLANT PERFOR
. MANCE
Tills dOctJment /s the

property of Snam
progotll who Willsa
((lguan1 its rights scco«JIng to
ttut cMI and pella/ provlsJ
On s of the faw.
File: B(LMAr~cId22
00J ev1.xLS
CUSTOMER
Snamprogettl PETROVIETNAM JOB : UNIT No.
81 03 12
PLA NT LOCAT!ON 20
PHU·MY. VIETNAM
SPC. No. ZA-E-S010
MA TE RI AL BA LA NC
ST RE AM E· UREA UNIT-
PROCESS CONDEN
NUMBER 1- , SATE TREATMENT SE Sh 9 of 10
81 Rev, I
82 CTION 2200 MTPO)
NAME Process Conde 83
nsate VaD, from WWT 84
Sect. PrQC,Cond, to T-t
002 Vap, from T-1002 Pro
85 +--::__ _86 __ __ 87
c,Cond, from T-100 88
Proe, Cond, to S,L
W,W. to Hv dro l.,e r
Hydrol. or Fo ed '-
TOTAL FLOW RATE

(kglh)
VOLUMETRIC FLOW
RATE (mJIh)
TEMPERATURE
(dog 'C)
'RESSURE
(bar abs,)
'HYSICAL STATE
lENSITY
(kglm3)
,V, MOLECULAR WEIGH
T (kglkmoi)
I) FIGURES INDICATED
IN TH
E MATERIAL BALANCE
ARE THOSE EXPECT
9 NOT CONSIDERED FO
R MATERIAL BALANCE
ED AND MAY BE AlTE
RATED IN ORDER TO
OF THE STREAM ACHIEVE THE REQUIRE
D PLANT PERFORMANCE
This document is the prop

erty of sn.mprogattJ who
wPI safeguard Its rights 8(:C(
)n1lng to the C/VU and pen
al provisions of the Jaw.
File: BILMATacJd220
0jCv 1.Xts
CUSTOMER JOB: UNIT No.
Icoff!.--ffTENTIAr--
Snamprogettl PLANTLOCATION
-iT',C; : 1 , l' C.:(EA

"---"--'_ .. _ - - , - - - - - - - - _ S N ZA-E-6010
I:P:-RO::-J=EC:::T:----.!.P.!.H~U:::;.M~Y'-.V~I!::E.!.T~NA=M_ _ _ _ _-+__..:::!.P.:::c~.:.:;:::0:..
• .------1
--~ ..... " ..... ., " .....--_•••_. __~._ ..""--- FERTILIZER PROJECT Sh 10 of 10 Rev_ I
MATERIAL BALANCE - UREA UNIT-PROCESS CONDENSATE TREATMENT SECTION 2200 MTPD)
NUMBER B9 90 92 93
STREAM
91
--1------=-
94
95:-=~-+~~~9~6~.____ _
NAME Vap. from Hydrolyzer Hvdrol. "" Outlet Process Condensate Steam to Stripp. T. Steam to Hvdrolvzer Atm. Air to Pr.Tower Air from Pro Tower
10 COMPONENTS M.W. kglh wt% kalh wt% kglh wt% kglh wt% kglh wt% kg/h wt% kglh wt% ko/h wt%
23 46.00%
-- .-. ---.--.--j-------l--~-..- ---+·---+-----+--~1----'""""~1
C~-'+----t--- 1------1·---·--f---+------+--------t--------l--·-2- 7 -"54:00%
---+---+-------f-- --"C-:-:c:-::+--~-:"C"C::+--+---~I----------- ---.--- - . - ------1----.-- .---.---
_="'-'--j----'==+-~10~500 100.00% 3200 100.00%
-.-=::'+--==t----,-+-- t---+---/----+-----I
-_._----+-----------+- ~---+-------------- _.----------- ---_··_··---!-------+---------------I
.. FIGURES INDICATED IN THE MATERIAL BALANCE ARE THOSE EXPECTED AND MAY BE ALTERATED IN ORDER TO ACHIEVE THE REQUIRED PLANT PERFORMANCE
@ NOT CONSIDERED FOR MATERIAL BALANCE OF THE STREAM
File: BILMATacki2200_f8V1XU;
This docum&nt is the properly of SnamprogottJ who will safeguard its rights according to the c/IIY and psnsl provIsions of/he law.
Rev. Description
Prepared Checked
0 ISSUE App rov ed Dal e
Revised where mark RICCARDI RICCARDI CUSTOMER
<1 > 09/08/01
Za~eo M Ho AltHO 05/02/02 PETROVIETNAM JOB :
fit '<A!" I 'Y'I'" PLA NT LOCATION UNJT No.
810312
20
PHU-MY, FERTILIZE
R PROJECT
PROJECT SPC.No. ZA-E-6011
MA TE RI AL BA LA NC 2200 MTPD UREA PL
E - UREA UN IT- C0 2 ANT 8h 10 (10
NUMBER COMPRESSION SECT Rev. 1
STREAM _- '2' --_ __ __ __ __ __ ION (2385 MTPD)
NAME _ ~_ _ +________4__________ +- _________5______
ID ICOMPONENTS M_ W
C02 to S nt Se ct __ + _____ 6____T ______~____ ______8 ___ _
kglh wl'% kg/h wt% kglh wt% kgl h wt% kg/b wt% kglh wt% kg/h wt% kglh
--10-- -- -- -- -- -- --
-- -- - --- --- --- - - - -
- - --- --- -- -- -- -- -
-~-- -- -- -- -- -- 1- -- -- -- -- -- -- - --
12 (lNERTS)
-- - -- -- -- --------- -- -- -- - -- -- -- -- -- - -- -- -- --- ---
--- --- --- --1 --- --- --- --
C9 -- 1- -- - -- -- -- - --- --- --- --- --- - -- -- -- - -- -- -- -
-- -- - 1- -- -- -- -- --
(Nm 3/h ) --- --- --- - 1- -- -- -
(~!;~; 1'__---__--_-__-___---_~-----------+-----=____==~- -~2O:~
TOTAL FL OW RA
TE
(Nm 3/h ) 505 (Nm -- 3/h ) (Nm 3/h )
35 :4;(),()O~ -------'--____+________
VOLUMETRIC FLOW (Nm 3/h )
RATE (Nm 3/h )
(Nm 3/h )
~====~==~==~~== '-_-_ - _- -_-_-__L_-_--_==--_-_-+__--_-____---__-_'__- --=_

(Nm 3/h )
TEMPERATURE
(deg 0c) II__ __ __ ~-- L_ __ _ _
PRESSURE --- ----+---------~------
(ba r ab s) II__ __ __~- --l - __ _J_:?D________1_ _ -_-_-_--_'
----+--------- __ _ -- _ -----+-- -------- --- --- -J- --- ---
PHYSICAL STATE +------I-- _J 58, 00_ ___ _+ ___ ---- --- ---
11 __ __ _-'- -______ + ______
____L _____________ +_____
__ ___ __________ +____________ - --- --- --- --- --- ---
DENSITY
-----'"------".,-"'-l
___ ___ -I- _ _ -'Gp,,,______-f-___
_ --- --- --- -- -- -- -- -- -- - -------------
AV_ MOLECULAR WE
(kg /m3 )
----,~-,,------- ---""~ --- \- --------------
~ -- ------ -- -- --- -- -----
IGH T (kglkmol) __ __ __ ~~'"--,,----j-------- }- -- -- -- -- -- -- -- --
__ _ 1-- ___. ______ ---- -.- - -j- - -.- --- --- -- -- -- -- -
. __ __ _ _______44.00_ --- -- t ~~-.--------
_ ·_·1___·_· _ --- --- ---
--- +- --- --- .- --- -.- -- --, ,~- , . -- - ,-, -,, -,- ----.'"----,-.-."~
--- --. --- --- --- --- -- -- f- -- -- - --- --- --- )--
-- -- -- -- -1 -- -- -- --- --- --- -- - - - --
-- -- -- -- -- --- --- --
o FIGURES INDICATE
D IN THE MATERIAL
- -- -- - +---- - --- ---
- -----+ -- -- -- -- -
BALANCE ARE THOS
C9 NO T CONSIDERED
E EXPECTED AND MA
FOR MATERIAL BALAN Y BE ALTERATED IN
CE OF THE STREAM ORDER TO ACHIEVE
; THE REQUIRED PLA
NT PERFORMANC E
ThiS document is the prop

erty of Sna mpr oge ttl
who will safeguard Jls right
s according to ttle civil and
penal
CUSTOMER
JOB; UNIT No.
PETROVIETNAM
810312 20
PLANT LOCA nON
PHU-MY, FERTILIZER PROJEC

T SPC.No. ZA-E-6011
PROJECT
MATERIAL BAL ANC E - UR EA Sh 2 of 10 Rev. 1
UNIT-H.P. SYNTHESYS SECTIO
STREAM NUMBER . __ _
. _1.:'_~_~_ .. ___ ~_12___ N (2385 MTPD)
NAME C02 to Reactor
___ ~_. ___ .1.3..______ 14 15
Reactor Outle t Stripper Sot Outlet 16 17
ID COMPONENTS Stripper Vapours 18
M. W. kg/h HP Carbonate Rec.
wt% kg/h WI% ko/h I wt% kg/h WI% kglh wt% kg/h wt% kg/h wt% kg/h wt%
TOTAL FLO W RATE

(kg/h)
VOLUMETRIC FLO W RATE
(m3/h)
TEMPERATURE
(deg 'C)
PRESSURE (bar abs.)
PHYSICAL STATE
DENSITY (kg/m3)
AV. MOL ECU LAR WEI GHT
(kg/k mol)
.-~~~- ~---- - ---- ..- ---- --.- ._. -_ .- ---- - --_.

«II FIGURES INDICATED IN THE
MAT ERIA L BALANCE ARE THO
.•/ -
-~-'-'--- --. --- .- .• -..
.. - __
.~ .. ~.---- . ._. --- - .. ---~---4 ..... - --- -.-
SE EXPECTED AND MAY BE ALTE
~ NOT CON SIDE RED FOR MAT RATED IN ORDER TO ACHIEVE
ERIAL BAL ANC E OF THE STR THE REQUIRED PLA NT PERFOR
EAM; MANCE
This document is the property of

$nam proge tti who will safeguard
ils rights according 10 the civil 8n(J
penal provisions of/he l
CUSTOMER
JOB: UNIT No.
PETROVIETNAM
810312 20
PLANT LOCATION
PHU-MY, FERTILIZER PRO JEC SPC.No. ZA-E-B011

T
PRO JECT

MATERIAL BAL ANC E - UREA Sh3 0f10 Rev. 1
UNIT-H.P. SYNTHESYS SECT/O
NUMBER ___ ~_1il. ___ __ 1----
__ ~ ___ ___ ___ ___ 21
N (2385 MTPD)
STREAM
22
ID COMPONENTS
NAME NH3 and Carbamate Pass
.Air to Stripper 23 ________24. _ _ J __ __:15_~__ +_ --- -26 --- -
M. W. kg/h wt% kg/h wt% kg/h
NH3 __ __ _ ___ _~1Z._ _ 14 7456 wt% kg/h wt%
wt% kg/h kg/h
_:1 __CO'3. __ __ __ ___ __.i4_ __ .4~O 1-__~ll:3"lo ______________
E;! ___ 19,S.~o/, ____ _
-1 ________ +__________ +___ _ -1_____ - j
wt% kg/h
-------+------ _,1 _____ --- ----- ----- --- -- --- --1
wt% kg/h wt%
}-~1~~R---------- - - --~~-- -29457 --- -+ --- -_ 1- --

----- - ---- -- 13,39% -- --- --- --- --1 --- --- 1-- --- --- 1-
--- --- - --- --- - --- - -I--- --·-- ·--c -·--- ---- ··L- -·--
- -5 - FORMALDEHYDE ---30 ---- -+- ---- -- -+------+------
-~ ----- --f- ---- --.. jl-- -1-- -··
----~--,
,-,,-.--
--- - ---"
-----.
--"- - ----., ---,- -- --- -",,- --'- ---- -f -- -- -+--- -- -+ --- ---
__"-_ SULPHURIC AC-'~_______
_.Jlll... ___ ___ ___
___ ___ ___ ___
+- -
7 AMM_ SULPHATE ___ __ _
+--------------------
--- --- ---- --- --- --- --- ---
132
--- --- -- ---- --- --
--- --- --1 --- --- --- --- - --- --- f--
---- -f--- -- ---+-----------1--- -----
- - - ---- ---1 ---- ---- -1- ----
--- --- l-- --- - ----------- .--- -. -+- --- -- -/- --- ---
--j- -
-- --1----------- --- - --- - --1 ---- ---- 1-- ---- --1 ---- -1
-- ----- ----- --- --- - --------
_..2 _1----- __________ --- --- --- -1- ---
0 --- -----+~----+--- ---- 1--- -- - -j -1- --- -1-- ---- -- -1------·--1---
-- - - - - --- --- - -- -- - 1--- -- - --j- - --- -1 - -- - -~- --- --1- ---- ---- '1-- --- --)-
-~~r;;ERTS) - - - - - - - ---$------------ - --------- -- --- -- -- -
-(N;;:;;,jL----- 30 (Nm3/h) (Nm3/h) (Nm3/h)
--
TOTAL FLOW RATE
(kg/h) _:?l~?_4.. 100,00% (Nm3/h) - (Nm3/h) __1._IN-m---3/h--)I--------L(-N-m--3-/h
(m3/h) ___ ___ ___ ___ ___
_______ ____ ___ L __________ ..1 __________________1 --)-1
TEMPERATURE
(deg"C)
___ ___ ___ _ ________________
f--- _ ..___125___.__._. . ____"-/,IB.'t=.I\fT___ ~ ___.___ ___ ___ ___ ___ ___
___ , ___ ___ ___ __. __ _ .___
________I ____ + _________L ___ _ -I
________.________ ______ _________ ~ ___ ___ ___ ___ .__________ ._
:~~~~C~:ESTATE ____________ -______ . __ . _____._______ .__ ____ -
--~~~6-----------~:~-------------
DENSITY
(bar abs.)
---- ---- ---- ---.
(kg/m3) ___ ___ ___ ___ ___
---·--···-·---- -------------------- -.--------- ---- -----.. ---.---------- --.-.----.--
---- ---- ---- --- --- --- --- ---
-- - -- --- --- --- --
-.. ----. -- ------
AV. MOLECULAR WEIGHT __ ..____ ._ _ _._____ ___ ___ -- ._- --- --- --- - ---
___ ___ ___ ______________.___ --
___ ___ ___ __. ___ ___ ___ .--- --- - --- --- --- --- - -
(kg/kmol) ______ l!JCI!J. . __.--- t-- --- --- --- -- ____________ ___ ___ ___ ___ ___ ___ __
__ ._____________ ______ ____ ___ _________ _ _ ~
--- --- -- _.- ---.- --- --- --- --- --- - --- --- --- --- -_. ---- ---- ----
---- _._ ---
o FIGURES INDICATED IN THE MAT
ECTED AND MAY BE ALTERATED
@ NOT CONSIDERED FOR MATERIA IN ORDER TO ACHIEVE THE REQ
This document is the prope rty of

snam proge tti who will safeguard
its tights accoming to tho dlli{ and
penal p
CU STO ME R
Sll1amprogetti PETROVIETNAM JO B:
UNIT No.
PLA NT LOC A nO N
81 03 12 20
PHU-MY, FERTILIZE
R PR OJ EC T SPC.No. ZA-E-6011
PROJECT
MA TE RI AL BA LA NC 2200 MTPD UREA PL

~M~R E - UREA UNIT-M.P. ANT Sh 40 f 10
STREAM 31
-- -- -- -- -- -- -- - RECOVERY SECTIO Rev. 1
~
n N (23 85 MTPD)
NAME MP Dec. $01. Outlet ----
---~
-- --- --- --- --- --- - - M
10 COMPONENTS Vap. from MP Dec. -- - - - - - - -~-
M_ W. Concf. to MP Abs. -- %
HP Ca rbP um p Flush.- - - - - - - - - - -~
kglh MP Abs. Sol. Outlet
1 _~_3________ ~ __ __ __ wt% kg/h wt% Vap -- 38
-- -- -- --
__ _I~ _______ Q924 ___ kg/h wt% I . from MP Abs. NH3 from Cond, -- -- --
_~ _~02 _ _ _
~ ___
~,33~ __ _~~1----~8 ,42% __ _6<l0~ ___ ~1 ,06
kg/h wt% kg/h wt% Vap. from NH3 Cone
__________4~ __ __ kg/h wt%
___ 3____tJ_~~A______________________ _ 368 1_ __ ~,_71% __~3?~_2 _____ 120(;3% ____ ')(, _3 ?O £l __<f7,62~ kg/h wt%
__ __ __ __ __ __ __ kgfll
_ _~()__ _ _llB2~~ __165(lO_
16,04o/~ __ _16_5f)() __ _3~~7Zr_1()~()0',\ __ wt%
__L 6_3,'c3__7_o~:4>t___--_+--- _}~2()~ __ __ 3~6()()1_0(),()O%, _____ 202
_Vil~TER__________
__ __~3___ --- ____ __ __ __ __ __ __ _ __ __ ~~OO,()()_1
__ __ 4~?fl5 _ 28,59%, ~_6<l__J~,()
_ __________ _______
__________ ___ ___ ___
__ __ __ __ __ __ __
__ __ __ __ __ __
_~_ ~~~~:~~I~H:~~
_---- !~-- -------------------- ------------ 5',\ ___ 3364lll__--~2,BO',\
_____ ~418X __31-,-OBo~
___ ___ ___ _ __ __ __
_____11l0il _~()O,()()'10
__ _____ ____ __ _
__ __ __ ___ ___ __ _
__ _ __
- - --------
----
__ ~ __ !I_NlNI- SULPHAT,,_ _ --- --- -- f- -- -- --
------+--------
-- -- ------------------- - - - - - - - - - __ __
__ _ --- --- --- 1_ _- --- -
- -- --
-- -- -- -t- -- -- -- -- --
___~ __ __ __ __ ~___
~~--
____ __ __ __ _
----------
__ __ _ _________ __
-- -- -- t-- -- ----------
-- -- __ __ __ __ __
-
----~-
--- - - - - - - - -------------
~-- --
_ \--- _____ --- --- --- --
1- -- -- -- -- -- -- -- -- -- -- --
--- --- --- - -- -- -- --
;~-I----------------- __ __ __ _ -- -- -- - --- --- --- --- -- -- --- --1 --- --- ---
----- --- --- --- -- -- --- --- --- - --- --- --- - -- -- -- - ------ --
11 - - - - - - -- - -- -- -- --- --- --- - - - --- --- --- - --- --- -- -- -- - ---1--------+----------- ---
- - - - - - - - -- - - - - - --- --- - -----~
-I---- --- --- - --- --- --
-- -- -- - -- -- -- -- 1-
-- -- -- -- -- -- - --- ---
--- --
-~-- -- -- --
-- -- ---- --- --- -j- ---
-- -- -- - ----------- - - --- -- --- --- --+ ---
--- -\- --- --- --- --- --- --- -- -- -- -- -- -- -- - -
--- -- --- --- - --- - --
--- --- --- -
12 (lNERTS) - 1----------- ----I--------- - --- --- --- --- --- - ---
------- --- --- --- --- ---
-- -- -- - - -- -- -- --
-- -- -- --
@ --I---~--- --
TOTAL FLOW RATE (Nm3/h) -- -- --- --- -- -- -- -- -- -- -- -- -- -- -
535 (Nm3/h)
535 (Nm3/h) -- - -- -- -- - --- --- --- - ---- -- -- -- -
VOLUMETRIC FLOW (Nm3/h) (Nm3/h)
RATE 535 (Nm3/h) (Nm3/h) 535 (Nm3/h)
TEMPERATURE
PRESSURE
PHYSICAL STATE
DENSITY
AV. MOLECULAR WE
IGHT
-- -- -- -- -- -- -- - -- -- -- -
-- -- - -- -- - -- -+ ----- ---
o FIGURES INDICATED
IN THE MATERIAL BA
--- --- --- --- --- -- ----
-- -- -- -- --
---------
--~---------
LANCE ARE THOSE EX ----I-------
--~-------
@ NOT CONSIDERED FO PECTED AND MAY BE
R MATERIAL BALANCE ALTERATED IN ORDE
OF THE STREAM R TO ACHIEVE THE RE
QUIRED PLANT PERF
ORMANCE
This document is the

prop erly of $na mpr oge
tti who will safeguard
its nghts ac&J!l1ingfo the Civil
anri oM;o1
CUSTOMER JOB; UNIT No.
PLANT LOCATION
PHU-MY, FERTILIZER PROJECT SPC.No. ZA-E-6011

PROJECT
2200 MTPD UREA PLANT Sh50f 10 Rev. 1
MATERIAL BALANCE - UREA UNIT-M.P. RECOVERY SECTION (2385 MTPD)
NUMBER _ 39_~_ 41 ~_~~_~2_~___ 43 __ ___~__+___~___ __4<l_~_ ~_
STREAM
NAME Ammonia from B.L. NH3 to Boost. Pump NH3 to HP Pump NH3 RefUo MP Abs. Ammonia and Inerts MP lnerts Wash.Cond. NH3 Sol. to M.P.Abs. NH3 Loss. and Inerts
ID I COMPONENTS M_ W_ kg/h wt% kg/h wt% kg/h wt% kg/h wt% kg/h wt% kg/h I wl% kg/h wt% kg/h wt%
2 ~~~_=~~~ :;~__ _ 5~~~9,80%_90052-~8'7!' 82144 99,~ 7909!l9,87%:-=~100,0~~=4--=-.

__ .__ .•.- 75558,800/0 .____1.6 ~o,OO%
3 URE ~-~-I~----------~----r-----
LWAT~R~==--=----1--:~ 113~~0,20'<=_~~ _~.o, 13% 103 .Jl,13%-~- 1o~-O:T:io/; ==-~53:!Jr106,oo~ ___529141~20%1______+ ______1
--i- ~32~~~I~H:~~--- --~i-
-- --------- ----
.--- -~----------~ -----
- ---
-----.------~.--~-
----- -~-- ---~-- --------~
,..~--------.----~---.--~----- ~------f___-~--~-
----- ~--- ----- ~--~- ~-
1---
..... j - - - -
~-..
I
~_ !'~r;tSULf'flI\T_'=__ __ ~~2.._ _ _ __ _~~ _______________ +---~----------~- _~ ___ . . ____ ~+-----I~---
- - ------~- --~- ---~- j--- ... ~ - -.. -~- --~---- ~--.- -~--~ --- - - - r----- -~--- ----- -~--- ------~+--~------I
if~==-~--- -----C-~-_=--- ~-_=____-~~~~~~ --I~~~-~+~~-~=>==~~=~ --.=--~=;~---~ ~=--~-_

12 (INERTS) @ 140 (Nm3/h) (Nm3/h) (Nm3/h)t-(Nm3/h) 675 (Nm3/h) (Nm3/h) (Nm3/h) 675 (Nm3/h)
TOTAL FLOW RATE (kg/h) _562_59......1.00,00% _90165 ___100,00% ~~2£..._ 100,()0~ _.2919Ll00,00'Y~_77L __ .J.O.O,OO'Y~...-?29_L.1()O,_01J':i, _~.12!l4__ .~... 100,00%_~16 __ ~_00,00%
VOLUMETRIC FLOW RATE (m3/h) 93,45 154,13 139,86 13,47 61,68 0,53 1,67 0,94
TEMPERATURE (deg "C) ~~--- 25------ --~--- ·---35-----=-=35~=_~ :::=~~3.o.=-------50-=____..s0_~. ___ === 50=~~--
PRESSURE (bar abs.)_~!QCl....____ _19,80 ___ r--~__ 23,5o.... __ __ ~5.o~__ ... ___ __..1.9,50_ .E.!.OO~ ___ ____ .1~50_ ... ____ _.___ 19,50~_~_
PHYSICAL STATE __ .~LI9.\JID___ ~._ LlQUI[)__ ~ _ _ _
LlQUI[) __ ~_ .. _~....LIQUID . _______ GAS LIQUID ._~ ____ .t:'QtJl[)__ ~ ____ ~_ GAS.___ __
DENSITY (kg/m3) 602 585 588 588 12,5 990 770 17
AV_ MOLECULAR WEIGHT (kg/kmol) - - J7.00-=--b---=:~7,00-= "===17,00==~ ==j7:O:0~~- ~-17,OO _18~Oo.--~ ~==-17:4()_=~f----;i2,78-=
__
-~---- f-~--------~ ---~----- ~~---~. -------- ---~-~----------- ----~-~ -~------~~-~---~-~~~----
o FIGURES INDICATED IN THE MATERIAL BALANCE ARE THOSE EXPECTED AND MAY BE ALTERATED IN ORDER TO ACHIEVE THE REQUIRED PLANT PERFORMANCE
@ NOT CONSIDERED FOR MATERIAL BALANCE OF THE STREAM
File: BILMATadd2385Jev1,XLS
This document is the properly of Snamprogetti who will safeguard Irs n'ghls according /0 the clv{/ and penal provisions of the Jaw.
CUSTOMER
JOB: UNIT No.
PETROVIETNAM
810312 20
PLANT LOCATION
PHU-MY, FERTILIZER PRO JEC

T SPC.No. ZA-E-6011
PROJECT

MA TER IAL BAL ANC E - UREA Sh6 of10 Rev. 1
UN IT-L P. RECOVERY SECTIO
N (2385 MTPD)
4) FIGURES INDICATED IN THE MAT

ERIAL BALANCE ARE THOSE EXPECT
ED AND MAY BE ALTERATED IN
fJ NOT CONSIDERED FOR MATERIA ORDER TO ACHIEVE THE REQUIRE
L BALANCE OF THE STREAM D PLANT PERFORMANCE
This docom enl is the prope rty of

Snam proge tti who wl1! safeguard
Hs rights according to the civil and penal
provisi
CUST OME R
JOB : UNIT No.
Snlllmprogetti PETROVIETNAM
810312 20
PLAN T LOCA TION
PHU-MY, FERTILIZER PRO JEC SPC.No. ZA-E-6011

T
PRO JECT

MA TER IAL BAL ANC E - UREA Sh 7 of 10 Rev. 1
UNIT-L.P. RECOVERY SECTIO
N (2385 MTPD)
STREAM
10 I COMPONENTS M. W. kg/h wt% kg/h wt% kglh wt% kg/h WI% kg/h wt% kg/h wt% kg/h wt% kg/h wt%
TOTAL FLOW RATE

(kg/h) ~:15~03~~~~()(),O~% _ _ _ ~L~~.. ~.. ~~ ~~.!
(m3/h)
.95.Q..l.1oo,OO% _~ __ ~T~~ (Nm3/h) (Nm3/h)
27,30 I I
TEMPERATURE
PRESSURE
.
(deg "C) II:-~~-_-':~-.~:4,=2~~~~~~~~··. ~~~
+~_~~~+~ __~+~_~_....4!'.2._~
_ ~+~~__ ~__ ~~"'~'~I~ ~~-~~_~
PHYSICAL STATE
(bar abs.) _ _ ~.::2.6'C,.0,,0~ __ _
__ ~+~~ __-+_._~~,2":6.."O",0_~_~
+~~.
__ .. ~~. ~ ~~~~~~~_~
LIQUID ~~ ~.~~~.~~ .. ~..'~ .... ~~.+.~.~
DENSITY LlQUI[)~~~~.~ .~_.~~~~. ~~
(kg/m3) _~ ~~J4S~ ~~~~~ .. ~.~~~:,~ ~~~~··.. ~~.~~·~~~.·~~~I~
~~_.~~~~~ ~~_~ ~._ 94§,0 ·~_~~ .~~~.~~~~~~ I-~~~-~~·
AV. MOLECULAR WEIGHT iJ... _~ j... ~~ __ ~~.~.~~ ..~ ... I~.~~~ -~~~ ~I'-··-··~~~ ~~..~~-...~~
(kg/kmol) _.~...~~~~8.'~~~~~.. ~
. . ~_~~_~~~~~~~
I
~~ ~__~1(!,~5_~~~ ._ . . ~~~_. __ ~~~
-~-~~.
~~~- ~
C'-.-.~ .. -~--~-
~~~~.-
~-.---
~ ~~.-.~~~-
.
+~~~~~.~_.~~~.~ +.~~.~~
.
~.~.~~ ~+~~~~-.- ~~.- ..
~~~~+ ---~ . . . ~-~ ~~~I
-.--~

E9 NOT CONSIDERED FOR MATERIA IN ORDER TO ACHIEVE THE REQ
This document il> the prope rly of

Snam proge tO who Wi" safeg
SnamprogeUu PLANT LOCATION

PROJECT
2200 MTPD UREA PLANT Sh8af 10 Rev. 1
MATERIAL BALANCE - UREA UNIT-VACUUM CONCENTRATION SECTION (2385 MTPD)
NUMBER 71 72 73
STREAM ~~=------+-- - - 74 ------~~--I~~-
75 76 77 78
NAME Urea Solution Vap. from 1st Evap. Urea Melt Urea Melt to Pr.Tower Steam to Vac. Syst. Vap. from 2nd Evap. Urea Product H2S04 sol. Injection
ID I COMPONENTS M. W. kg/h wt% kg/h wt% kg/h wt% kg/h wt% kg/h wt% kg/h wt% kg/h wt% kg/h I wt%
TOTAL FLOW RATE (kg/h) __104503____100.00% _ 11785__ 100.0()"Io _ 992:2.5 ___ .1DO,O()"lo _.9B429__100,00°;., __J0600____100,00o/oL,s,278 __ _1.00,00% __ JJ!j372.., _100,00%f----20~_L 100,00%
~~~~~!:~~CR~LOW RATE
PRESSURE
PHYSICAL STATE
DENSITY
(d~:3:~~
(bar abs_) =__
c-- 8~~r----- 69~~i53
0,3'3'-
_____ -8;~~0 ----~~6"/--
_=:=0~3 -----=r-----O,03-==~-=_1M() ==-I_::-=4,41=t
c-_~U~_~_ ___2."-S ____ ~ ___Ll(llJIEl__ __ _ ___ LlQUID____c--___G!'S___ l---__~GAS _____ t-- __ SO~____
c-- __ -44~;~53-_- T...E9{;:,0~_= --'60------ _~_-:--_o~~===
___ Jl,():J.
LlQUI[)",, __
(kg/m3) ___ ~ ______1_21Il,_______ 0,H _____ r--__ ..E25 _~~ ~_ .J.2.2s.....__ f--- _____ ~36 ____ f_--..Jl,-0-1-6______.160 (buII<L _ _ ~~1840 ____ _
_____ ~_AT~_______ ,,3,(JO___ _
AV_ MOLECULAR WEIGHT (kg/kmol) _ _ .Ji3,60~___ ~~18,20_ _ _ _ ~~59,1j2 ________59,70____ ___18,OO_~ __ ___ J.8c~~ _______ ~_5!l_,_"/4....___rJ9~ ____ _
- ____________ ________________________ ___________ ----- ------------ --------- l - - - - ------- - - - - - - - - - -
o FIGURES INDICATED IN THE MATERIAL BALANCE ARE THOSE EXPECTED AND MAY BE AI.TERATED IN ORDER TO ACHIEVE THE REQUlr,ED PLANT PERFORMANCE
f!I NOT CONSIDERED FOR MATERIAL BALANCE OF THE STREAM
File: BILMATacid2385_fev1XLS
This document (s the property of snamprogetti who will safeguard ils rights accoming to the civil and penal provisions of (he law.
CUSTOMER
JOB : UNIT No.
PETROVIETNAM
810312 20
PLANTLOCATION
PHU-MY, FERTILIZER PROJEC SPC.No. ZA-E-6011

T
PROJECT
MATERIAL BALANCE - UREA 2200 MTPD UREA PLANT

UNIT-PROCESS CONDENSATE Sh9 0f10 . Rev. 1
NUMBER 81
TRE ATMENT SECTION (2385 MTP
STREAM 82 D)
NAME Proce~s C~;d--;~-;~; V~p:f;~m\NWTs;~t~ ';-':;Z
83 84
C;;nd. t~ T~1-002 85 86 87
con~d··.~t~O·~8-.L·.·.I·w~-.w-.·t·O··-:'H:"Yd··r·~o·,y~z·e··r···-l-··H-yd-
10COMPONENTS Vap. from T-1002 Proc, Condo 88
M. W. from T-100 ProC.
.._~NH3~_~.~._~ _ _.
kg/h wt% kg/h wt% kg/h wt% kglh wt%
;;~;~'F·e-e~d
_.12_~ ~. __
_~_ ~~fA 2()~ _. ~30% kg/h wt%
~~~-..--- c--~-.~~.~~~~ ---!d~~ __'5'5 _15,o.9% 3671 36.56% kg/h wt% kg/h
2.68! ,-...s.30\(, __ }~41!J_41.,( wt% kg/h wt%
)7.% ~.~._~
_._ . _ ·~b~ ~_~:~1_····1203 .. ~~77,/o. __ __._ ~_.~ j-. ... _ .. _._
. r.~.~.. ~.~._._.·.I·
288 050 %
·~.· ..·I_. ···· ...~5.8"l_ . i.1.D'Yo r-.::::~5~ ~:::.·ct,,~O
_ ''' _____ ''' __________ ,, __ .~_ f-~, __ 288
~--- __ ""_"'~_"'_ __ 50% 0
.. 4_~ ~TER _. __ _ . . . . ~
..~.J8_._ . _.46.5.45 _ ..~!~<lI'0
..... .41l54 ~2~\(, .
__,, _______ ~ __ ~,, ___,_______,_" ''' __,_____ ,___
_.<\6~45~ !l.1..94'Y~ _ ..~3524 . ~.!3.
,_,___ ""_," __ ''' __ "' _______ "--. ,___
.. ·.
405 ____ ~,_:c9% , __ .____ ~Q? _____~,
i\
~~·6·sFORMALDEHYDE
ui.PHuRiCAc,D·-·- 1-- 30 '.2(l')\~ .~5?384 j--'(}O.()O%._ 5738 ?9~
-9s-.~....... . 4 ,no no" ......s.tl7~9 _91l,.0l%
_._... ~~_...~.__ __ _. - - . - - - . ..... ....5.67Z!l ....98c 69 %
......- ..--~~~~-.-...~-.--.- ... .--~ ..._ _.. - .... ~.----.-.. . .. -.~ - - -... ,··- ··-· +-· ····
7
.--~AMM
.. -~. .. ~.....-.... ..-. - ... --- ···- 1-· ···· · + -- . -~ ... ~.-...
8
SUL PHATE
·-·-·-·· 132 ·
·---·i·-··-~ -.-. ..- - . - - ..- -..-
.. -~..-~ ...-~-~- f-- ---
--f -.-..... ~.... . ---.~.... -.f---
-~-+..~~ ...... ~. c·· ......
-+. -- _. - ...... -
.~- t-~---
-- ..--. ... ~.~.... ..- .-- -.. -.- ..... . t--.. ~~
...fl ..... _...._. __...._..__ .~ __._ _..-.- .-..-. ...._ - r-- --· ·
__ ~...~_. _._._ .. ~_~.. __. _.. ~......... -- ....-.
-.-~.-
..-...-... ~-
__-..~~- ...- --. -- .. ~ .... .... . -.-. . ..- .--.-~

.-.-.-.~
. ~ ............ -.-~~ ...-.-..-- -~-- - - - ... ~..... ~ ...

-~ ~-.-
.--
..--~t-.... .. ~.. .-~ ..- - f - . - - - - -... ....
--~. .~.~
.-'.0.. . ._ _ _ _ _ _ _ •.•..
~_ _ _~~.. ~ _ - - . ..~-.- - ..~ ..~ .. -~... ~ .... - .... ~. - . - ~~ .
12 (lNERTS) ~
. -• .- .. - • •--.--~~.
---.~ • . . . . • - ...•.
~. --.~
. . - - •.....
. .... ..-~--.. -.- .. _.- .-- .- - ..~.-
(Nm3/h) (Nm3/h) ~- . • . . - . -... - .-. ~.-. .
TOTAL FLOW RATE (Nm3/h) .~ .... ~ ••. - . - . - ••- - • . • .-
. 50El.2.4... .. ~OO'O~r-.1004q __ (Nm3/h) ~
---.-~.-
(kg/h) (Nm3/h) (Nm3/h)
~.

(m3/h)
'()OcD.o.:Yo. 50624 100.00% . _8.1.46_~Oo.QO~ ... (Nm3/h) (Nm3/h)
50.98 5ZJ 8!. ..10(J,Oo.:Yo_57.'3.84.JJ.Q
···~·-··45----·c-·-"13o:::'_ ~==i.i.D-~==
6477.42 53.86 (},OO% _5753(}...._'qo,o.o.% r
TEMPERATURE 5091.25 5753 .Q. ... .1.00.00%
~=:===-13(i=~:=. :=·.:::15i~~·~:
(deg °C) 63.06 59,78
::':~~ . .:4:5 :::~-":==J4~<J;=:=:~:=:==2.20·
61.40
PRESSURE
PHYSICAL STATE
(bar abs.) __ ._._.~~o. ~._._ .. ..__ ~c20 _ _ ~ __ ~_.5c4o._.._...... ._.~
~_5.20__ ..... _ .... ..5ZQ.. _ _
68.49
===
.~ ... 4(}O.:">_.~...
~~N~:7ECULAR
LIQUID GAS
(k~/~:; ~~~~~~~~~~~~= =~~_.,~~, ~~~ =:~~,~~i:·= ~~--_~~~~-::==~

LIQUID GAS '.4U •• _..:J6.,tJO__ ~_ .
LIQUID LIQUID
·-~·~~f;:=~=~~ .~~'~~O~-=~ =:::...;1\~~===~~~~=-

WEIGHT LIQUID LIQUID

.
~ NOT CONSIDERED FOR MATERIA IN ORDER TO ACHIEVE THE REQ
L BALANCE OF THE STRFAM UIRED PLANT PERFORMANCE
This document is the propefty of

Snilmprogstti who will safeguard
its rights accorrfing to 1M civil an
PETROVIETNAM 810312 I 20
PLANT lOCATION

PROJECT
4)
MATERIAL BALANCE - UREA UNIT-PROCESS CONDENSATE TREATMENT SECTION (2385 MTPD)
Sh100f 10
I Rev. 1
ID I COMPONENTS M. W. kg/h wt% kg/h wt% kg/h wt% kg/h wt% I kg/h wt% kg/h wt% kg/h wt% kg/h wt%
4) FIGURES INDICATED IN THE MATERIAL BALANCE ARE THOSE EXPECTED AND MAY BE ALTERATED IN ORDER TO ACHIEVE THE REQUIRED PLANT PERFORMANCE
6 NOT CONSIDERED FOR MATERIAL BALANCE OF THE STREAM
This document is the property of Snamprogetti who wJ1l safeguard ils dghfs according to the civil and penal provisions of the law. File: BILMATacid2385JevlXLS
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
sh130f22 oI I I I
I I I I
2.3 Steam Balances
Please see SPC. W GO-0-6008 rev.1 hereafter attached.

Please see SPC. W GO-0-6009 rev. 1 hereafter attached.
Form code: MDT.GG,QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc
c:>'__ ~~~S~T(~~~~~.~OC~.~P~.~3.~~~~~(~.H2Ll~T~.~3~~T~~----------------,----------------------------~~-L-----------------
--~~~I--D
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E R-1002
..(,,""" ) CII
(
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i T-1002
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E-I002 BI J-I00 2
1 ==-M D
f
LD
'--_ _. _ _..- L_ I
_ _.-L.. E-100 I 2A
:::......::.=.;:..::...
c
C
VACWH sYSTEM
PK-l003/tOO<4
umJ
E-1005B
•
B
T ., "'SOC COND£NSATt a
10B.l. ..,
10 bAr' (ASS) ctJtOCNSArE ... 8 B
I --e
~I!
1_ _ _ _ _ _- -
III I~
~l
,1 ~ r·~-'--,
23.5 bo.r' (A8S.) C~DENSATE
l.-6 ~ f • 176 bal' CABS) CONDENSATE ... 8

T-IOOG ,
V-lOlO E-102 3
C[)MMESSA
•
J Job ---~"-'-=--
810312
~
DISJSPC. :.:.N·_-=G=D_-=D_-G=0~O::..::8=_:___._
d.g./sp c. Fa- 1 c5 I
sn.-o '-
I.. I P-!OI3 A/B P-IOIOA/B P-IOll

PETROVIETNAM
PHU-MY FERTILIZER PROJECT
DoCUMe"to eft proprie to.· SNAHPROGETTI. L4 Societe .·
tuteler n* i propr"i dir-itti in sede civile e penale Q
STEAM AND CONDENSATE BALANCE
This dOCUMent is the proper ty of Snanpr'ogetti. who .at terl"llni c:fi legge.
scf'egucrd its rights o.ccOt"ding to the ciri Qnd penal
Pi"'ovisiDT's of the '0.•. FOR PLANT CAPACITY 2200 MTPD
C\I
MP STEAM HEADER P"c4.5 bGr(ABS) h32S·C
T -1002
(III) TO B£ CONtIRM£D BY VAClJII,JM SYSTEM HF"'R.
D
LPM ST(AM p. 5.9 bcr(ABSl r. t58 "C
D
c
C
• T • ",SOC CClolOCNSAT(
10 Bol.,
a
10 bv' (ABS) C{J\ID(NSATt "'8 B
23.5 ba" (ABS) CONDENSATE ... 8

176 b1J'" (ASS) CONDENSATE "'8
• COMMESSA
Job
810312
----- ----- ----- --
REV.
a
/' v
08/08/01 RICCARDI
DIS./SPC. N~·_....:::G=:D_-.:::.D_-6::::0:.:0:..::9:..,---: A
c1wg./spc.
.... - ...-
rg. J di 1
I ! PETROVIETNAM
~
P-IOIl
PHU-MY VIET NAM
FER TILIZ ER PROJECT
Docl.H"IE'nto di propri eto' SNAMPROGETTJ. La Societo

' tuteler o: j p"'opri diritti in sede civile e penole
STEAM AND CONDENSATE BALANCE
ThiS dOCUMent is tn.e proper ty oF' Sr'lCnpt'ogetti. ","0 terMini eli legge.
.in sofeguQr"d its rights accordi ng to the Civil and penal QprOvisio ns oF' the ICllf. FOR PLANT CAPACITY 2385 MTPD
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
Sh 140f22 0 I
I I I
2.4 Cooling Water Balances
Please see SPC. W GO-0-6006 rev.O hereafter attached.

Please see SPC. N° GO-0-6007 rev.O hereafter attached.
Form code: MDT,GG.QUA0005 Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ur~aunitprocessbook.doc
FRESH RIVER
COOLING WATER COOLING WATER
CIRCUIT CIRCUIT
47°C 46~C 47"C 42"C 42"C
E-1006
OIL
lUBRIF.
COOLERS
AND PK-1004
OTHERS
E-1023 E-1010 E-1012 E-1011 E-1008 E-1009 E-1024
300 m3/h
34-C
E-1023 PK-1003/4 E-1010 E-1012 E-1011 E-1008 E-1009 E-1006 E-1024

r=:':":'':::'::.:...j-l STEAM CONO.
VACUUM FLUSHING LP.AMMONIA M.P. AMMONIA LP. CONDENSER AMMONIA M.P. CONDENSER PURIFIED CONDENSATE
COOLER SYSTEMS CONDENSATE ABSORBER ABSORBER CONDENSER COOLER
COOLER
o 09108101 mwt I CAROl ICCARDI

Slon OATA """",''0
NOTE: 0 TO BE CONFIRMED BY MANUFACTURER

SPC. N' GD - 0 - 6006
PETROVIETNAM COMM.-Job 810312

PHU MY - VIETNAM
FERTILIZER PROJECT
SCALA· Scale
COOLING WATER BALANCE
~um€nto di proprieto' SNAMPROGEITL La Socielo' !utelero' i pfapr! cliriai in sede civile e penale (J lennini di legge. AT2200MTPD
This document IS ihe proper! of SnomproQelli, who '10'111 sol uord its ri his accordi 10 the civil and penol provisions of the low
FRESH RIVER
COOLING WATER COOLING WATER
CIRCUIT CIRCUIT
46"C 42"C 62"e 42"C
E-1006
Oil
lUBRIE
PK-1003
COOlER$
AND' PK·1004
OTHERS'
E-1023 E-1010 E-1012 E-1011 E-1008 E-1024
E-1023 PK-1003/4 E-1010 E-1012 E-1011 E-1008 E-1009 E-1006 E-1024

f-'-=":'::'':::'''+-J STEAM CONO. VACUUM FLUSHING LP.AMMONIA M.P. AMMONIA LP. CONDENSER AMMONIA M.P. CONDENSER PURIFIED CONDENSATE
COOLER SYSTEMS CONDENSATE ABSORBER ABSORBER CONDENSER COOLER
COOLER
09/0810 1 Issue Dj Ie AI
RfNlSt?N DATA LAT APl'ROV.
NOTE: 0 TO BE CONFIRMED BY MANUFACTURER SPC. N" GO - 0 - 601
PETROVIETNAM COMM.-Job 810312

PHU MY - VIETNAM
FERTILIZER PROJECT ~" H+-H+-HH
SCALA - Scale
COOLING WATER BALANCE SOSllTUtSCE IL
In"'~tof
DOpJmeflio di ~f()prieta' SNAlJPRCCEITl. La So~ielo' \u~elera' i propr; dirilti in sede ci~-jie e pennie 0 termini di Iegge. AT2385MTPD
ThiS dowmen! IS the proper[ of Srnlm r ell!, who will sale uord lIs nont, occordin 10 the civil and penai provision,> 01 file low -~
Ropf.ctldby
JOB UNIT No.
810312 20
SPC No. ZA-E-6019

Rev.
8h150122 oI I I I
t t t
Piping and Instrument Diagrams
Please see the following P&IDs hereafter attached:

P-41 Spc. GO-3C-6510 rev. 1
P-42 Spc. GO-3C-6511 rev. 1
P-43 Spc. GO-3C-6512 rev. 1
P-44 Spc. GO-3C-6513 rev. 1
P-45 Spc. GO-3C-6514 rev. 1
P-46 Spc. GO-3C-6515 rev. 1
P-47 Spc. GO-3C-6516 rev. 1
P-48 Spc. GO-3C-6517 rev. 1
P-49 Spc. GO-3C-6518 rev. 1
P-50 Spc. GO-3C-6519 rev. 1
P-51 Spc. GO-3C-6520 rev. 1
P-52 Spc. GO-3C-6521 rev. 1
P-53 Spc. GO-3C-6522 rev. 1
P-54 Spc. GO-3C-6523 rev. 1
P-55 Spc. GO-3C-6524 rev. 1
P-56 Spc. GO-3C-6525 rev. 1
_ _ P-57 Spc. GO-3C-6526 rev. 1
P-58 Spc. GO-3C-6527 rev. 1
Form code: MDT.GG.QUAGGOS Sh. 01/Rev. 3.96 File codespcjobve.dot Data file: ureaunitprocessbook.doc

Urea Unit Process Book

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PETRO VIETNAM

. PHU MY - FERTILIZER PROJECT

, .' ::\,,:. ;:::,,:,:>2/' ~

en"";; ',.: " 't"

SPC No. ZA-E·6019

3. Piping & Instrument Diagrams

SPC No. ZA-E-6019

1.1 Design Basis

Please see SPC. W RA-E-6000 rev. 1 hereafter attached.

;/J .nI 1 I .. k»I

SPC No. RA - E - 6000

1. Design Basis for Urea Plant

1.2 Climatic Conditions

Temperature dry bulb avg. 26.9°C

1.3 Raw Materials Characteristics

Carbon Dioxide from Ammonia Unit to Urea Unit

Composition (on a dry basis): C02 99 %vol min.

Pressure at discharge of C02 Compressor 157 bar g

Composition: NH3 99.8 %wt min.

SPC No. RA - E - 6000

Oil 5 ppm wt max.

1.4 Utilities and Chemicals Characteristics

Pressure (bar Q) Temperature ('C)

Fouling Factor for steam 0.000086 m 2,CIW

A) RIVER COOLING WATER

Pressure operating supply 4 bar g

SPC No. RA - E· 6000

B) FRESH COOLING WATER

Pressure operating supply 5 bar g

Pressure bar g) Temperature eC)

Demi Water from B. L.

Pressure normal 9 bar g

Pressure operating 7 bar g

SPC No. RA· E· 6000

Pressure operating 7.5 bar g

Pressure operating 8 bar g

Composition: H2S04 98 %wl min.

1.5 Product and Recoveries

Nitrogen content 46.3 %wl min.

Process Condensate from Urea Unit to B.L.

SPC No. RA· E· 6000

Composition: NH3 3 ppm

Steam Condensate from Urea Unit to B.L.

Pressure normal 5 bar g

SPC No. ZA-E-6019

1.2 Process Description

Please see SPC. N"ZA-E-6003 rev.O hereafter attached.

SPC No. ZA-E-6003

The Urea Unit is characterized by the following main process steps:

a) Urea synthesis and NH 3, CO 2 recovery at high pressure;

b) Urea purification and NH 3, CO 2 recovery at medium and low pressures;

e) Waste water treatment.

The urea production unit is also provided with the following:

a) Urea synthesis and NH 3, CO2 recovery at high pressure

2 NH3 + CO 2 ++ NH2 COONH 4

NH2 COONH 4 ++ NH CONH + H 0

SPC No. ZA-E-6003

SPC No. ZA-E-6003

b) Urea purification and NH 3, CO, recovery at medium and low pressures

1st stage at 19.5 bar g. pressure;

1ST PURIFICATION AND RECOVERY STAGE AT 19.5 BAR G. PRESSURE

SPC No. ZA-E-6003

2ND PURIFICA TlON AND RECOVERY STAGE A T 4. 0 BAR G.

SPC No. ZA-E-6003