MODUL PINTAS TINGKATAN 4

Peperiksaan Akhir Tahun 2018

Skema Jawapan Kimia

Kertas 2 4541/2
 KERTAS 2 T4

Question No. Mark scheme Mark

Sub Total
1 (a) (i) Nucleon number 1 1
(ii) 1. Proton 1
2. Neutron 1 2
(iii)
+

1. Correct number of shell and number of electron 1

2. Has a nucleus and correct charges 1 2
(b) (i) T2 1 1
(ii) 1. Packed closely in orderly manner 1
2. Vibrate, rotate at fix position 1 2
(iii) The heat loss to the surrounding is balanced by the heat produced when
particles are attracted each others 1 1
Total 9
2 (a) (i) Formula that shows the simplest ratio atom of elements in a compound 1 1
(ii) 1. Molecular formula = C4H10 1
2. Empirical formula = C2H5 1 2
(iii) Molecular formula shows the actual number of atoms but empirical formula
shows the simplest ratio of atoms 1 1
(b) (i) 1. Copper = 2.56 g 1
2. Oxygen = 0.64g 1 2
*with correct unit
(ii) 1. Oxygen = 0.04 1
2. Copper = 0.04 1 2
(iii) CuO 1 1
Total 9
3 (a) (i) Salt X : Lead(II) nitrate 1
Solid Y : Lead(II) oxide 1
Gas V : nitrogen dioxide 1 3
(ii) 2Pb(NO3)2 → 2PbO + 4NO2 + O2
1. correct reactants and products formulae 1
2. Balance equation 1 2
(b) 1. Cation : Pb2+ 1
2. anion : NO3- 1 2
(c) 1. mol of X = 6.62/331 // 0.02 1
2. ratio of mol
2 mol of X produced 1 mol of W
0.02 mol X produced 0.01 mol W 1
3. Volume W = 0.01 x 24 dm3 // 0.24 dm3 // 240 cm3 1 3
Total 10
4 (a) Acid is a substances that ionize to H+ when dissolve in water 1 1
(b) (i) 1. Acid X : HCl// HNO3// H2SO4 1
2. Acid Y : CH3COOH 1 2
(ii) 1. Acid X is strong acid, acid Y is weak acid 1
2. Acid X ionize completely in water, acid Y ionize partially in water 1
 3. Concentration of H+ ion of acid X higher than acid Y 1 3
(c) (i) Dilution 1 1
(ii) Volumetric flask 1 1
(iii) 1. (1.0)V1 = (250)(0.01)
V2 = 25 cm3 1
2. Volume of distilled water = 250 – 25
= 225 cm3 1 2
Total 10
5 (a) Electric energy to chemical energy 1 1
(b) Pb2+, Br─ 1 1
(c) (i) Cathode : Pb2+ + 2e → Pb 1
Anode : 2Br─ → Br2 + 2e 1 2
(ii) 1. Brown gas is released 1
2. Because Br- ion is selective discharge 1 2
(d) (i) Blue 1 1
(ii) Intensity of blue colour decrease 1 1
(e) (i) Chlorine gas 1 1
(ii) 1. Put a moist blue litmus paper to the mouth of test tube 1
2. Blue litmus paper turn to red and bleached 1 2
Total 11
6 (a) 1. Group 16 1
2. Because it has 6 electrovalens 1 2
(b) Ionic compound 1 1
(c) 1. High melting and boiling point 1
2. Can conduct electricity in molten or aqueous solution 1 Max.
3. Soluble in water but insoluble in organic compound 1 2
(d) (i)
2+ 2─

Mg O

1. correct number of shell and have a nucleus 1

2. Correct the electron arrangement and charges. 1 2
(ii) 1. Magnesium atom donate two electron to form Mg2+ ion 1
2. Oxygen atom receive two electron to form O2─ ion 1 2
(e) 1. P : Solid 1
2. Q : Liquid 1 2
Total 11
7 (a) (i) 1. Atom Y : 2.8.1 1
2. Ion Z : 2.8.8 1 2
(ii) YZ 1 1
(iii) 1. Lower boiling and melting point 1
2. insoluble in water but soluble in organic solvent 1
3. Cannot conduct electricity in any state 1 3
(b) 1. Carbon/ Sulphur 1
2. Covalent bond 1
C + O2 → CO2 / S + O2 → SO2
3. correct reactants and products formulae 1
4. Balance equation 1 4
(c) 1. K and M // L and M 1
 Sample answer between K and M
2. Electron arrangement for atom K is 2.6 1
3. Electron arrangement for atom M is 2.8.8.2 1
4. M atom donate two electronvalent to form M2+ ion 1
5. K atom receives two electrons to form K2- ion. 1
6. M2+ ion combine K2- ion to form compound with formula MK 1
7. Both ions achieve stable octet electron arrangement 1
8. M2+ ion combine K2- ion attracted together by strong electrostatic forces 1

Diagram 1
9. Correct number of shell and has a nucleus 1
10. Correct arrangement of electrons and has a label for each ion.

2+ 2-

M K

10

Total 20
8 (a) (i) Contact process 1 1
(ii)1. Catalyst : Vanadium(V) oxide / vanadium pentoxide 1
2. Temperature : 450-550 oC 1
3. Pressure : 1 atm 1 3
(iii) 1. SO2 is a poisonous gas. 1
2. Dissolve in rain water to produce acid rain. 1
3. Acid rain can corrode the buildings // reduce the water pH. 1
4. Use CaO to neutralize the SO2 gas 1 4
(b) (i) Name Specific properties
P 1. Stainless steel 2. Shiny and strong 1+1
Q 3. Brass 4. Hard to corrode and beauty 1+1
R 5. Bronze 6. Shiny and beauty 1+1
S 7. Steel 8. Strong and hard 1+1 8

(ii) 1. Pure metal is made up from same size of atoms and arranged in orderly 1
manner.
2. the layer of atoms easily to slide each others 1
3. Different size of foreign atoms disturb the orderly arrangement of pure
metal 1
4. Prevent the layer of atoms from sliding. 1 4
Total 20
9 (a) (i) 1. add distilled water to the beaker 1
2. Stir well 1
3. filter the mixture 1
4. The residue is M carbonate salt, the product is M nitrate salt 1 4
(ii) 1. M nitrate turn from blue solid to black solid and produced colorless gas and 1
brown gas.
Balanced equation:
Cu(NO3)2 → 2CuO + 4NO2 + O2
2. correct reactants and products formulae 1
3. Balanced equation 1
 4. M carbonate turn from green solid to black solid and colorless gas 1
Balanced equation:
CuCO3 → CuO + CO2
5. correct reactants and products formulae 1
6. Balanced equation 1 6
(b) Materials and apparatus:
1. Lead(II) nitrate solution [0.1 – 1.0 moldm-3], sodium sulphate solution [0.1 – 1.0
moldm-3], beaker, filter paper, filter funnel, glass rod and distilled water. 1
1
Procedure:
2.Measured out [20-100 cm3] lead(II) nitrate solution and put in the beaker
3. Measured out [20-100 cm3] sodium/potassium sulphate solution and put in a 1
another beaker. 1
4. Mix the both solution in the beaker 1
5. stir the mixture by using glass rod 1
6. Filter the mixture by using filter funnel and filter paper 1
7. Rinse the residue using distilled water

Balanced equation:
Pb(NO3)2 + Na2SO4 → PbSO4 + 2NaNO3
8. Correct formulae of reactants. 1
9. Correct formulae of products. 1
10. Balanced equation 1 10
Total 20
10 (a) (i) 1. Position of ions in electrochemical series 1
2. Concentration of electrolyte 1
3. Type of electrodes 1 3
(ii) 1. Cathode : Hydrogen ion 1
2. Because its position lower than sodium ion in Electrochemical series 1
3. Anode : Chloride ion 1
4. Because its more concentrated than hydroxide ion 1 4
(b) 1. W, Y, X, Z 1
2. Negative terminal : Z 1
3. Because Z is more electropositive 1
4. 0.2 v 1 4
(c) Materials and apparatus:
1. Metal J, metal K, metal L, metal M, J nitrate solution 1.0 moldm-3 , K nitrate
solution 1.0 moldm-3, L nitrate solution 1.0 moldm-3, M nitrate solution 1.0 moldm-3, 1
test tubes.

Procedure:
2. Pour [2-10 cm3] of , J nitrate solution 1.0 moldm-3 , K nitrate solution 1.0 moldm-
3
, L nitrate solution 1.0 moldm-3, M nitrate solution 1.0 moldm-3 in separate test
tubes.
3. For each test tube, insert the metal J into every solution. 1
4. Record the observation after 5 minutes. 1
5. Repeat step 2 – 4 using K, L and M metal. 1

Observation:
J nitrate K nitrate L nitrate M nitrate
solution solution solution solution
Metal J √ √ √
Metal K X √ √
Metal L X X √
Metal M X X X
6. correct each rows and columns with label 1
7. Correct tick for each columns 1

Conclusion:
9. The more electropositive metal will displace the less electropositive metal from its
salt solution. 1
10. The arrangement of metal in ascending order: M, L, K,J 1 9
Total 20