SKOR A KIMIA 2014

TAJUK: SEBATIAN KARBON

SET 1
Diagram 7 shows a flow chart for a series of changes of organic compounds from one
homologous series to another homologous series.
Rajah 7 menunjukkan carta alir satu siri penukaran sebatian organic daripada suatu siri
homologus kepada suatu siri homologus yang lain.

Process I
Butane + H2 But-1-ene Proses I C4H10O
Butana But-1-ena + H2O

+ Ethanoic acid
Asidetanoik

Compound Q
Sebatian Q

Diagram 7 / Rajah 7

(a) Both but-1-ene and butane are hydrocarbons. Which hydrocarbon burn with
sootier flames. Explain your answer.
Kedua-dua but-1-ena dan butana adalah hidrokarbon. Hidrokarbon manakah
terbakar dengan nyalaan lebih berjelaga? Terangkan jawapan anda.
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[4 marks] (b)
b) Butane undergoes complete combustion to produce carbon dioxide and water.
Write the chemical equation for the combustion of butane and calculate the
volume of carbon dioxide produce when 600 cm3 of butane is burnt at room
condition. [1 mole of gas occupies 24dm3at room condition]
Butana menjalani pembakaran lengkap menghasilkan karbon dioksida dan air.
Tuliskan persamaan kimia bagi pembakaran butane dan hitung isipadu karbon
dioksida yang dihasilkan apabila 600 cm3 butana dibakarpada keadaanbilik.
[1 mol gas menempati 24 dm3pada keadaan bilik

[5 marks]
(c) In Process I,
Dalam Proses I,

(i) state the name of Process I and what is the condition needed for but-1-
ene to form C4H10O?
Nyatakan nama Proses I dan apakah keadaan yang diperlukan bagi but-1-ena
membentuk C4H10O?
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[4 marks]
(ii) C4H10O can form isomers. Draw two of the isomers in C4H10O and
state the name of the isomer.
C4H10O boleh membentuk isomer.Lukiskan dua isomer dalam C4H10O dan nyatakan
nama bagi isomer itu.

[4 marks]
(d) Compound Q has sweet fruity smell. What are the homologous series and
the name of compound Q? Draw the structural formula of compound Q.
Sebatian Q mempunyai bau manis buah-buahan. Apakah siri homologus dan
nama bagi sebatian Q? Lukiskan formula strukturbagisebatian Q.

[3 marks]
SKOR A KIMIA 2014
TAJUK: SEBATIAN KARBON
SET 2
Diagram 6.1 shows a series of reactions involving compound P, C2H6O.

Diagram 6.1 /Rajah 6.1

(a) (i) State the name of compound P.
Nyatakan nama bagi sebatian P.
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[1 mark]
(ii) Draw the structural formula for compound P.
Lukis formula struktur bagi sebatian P.

[1 mark]

(b) Write a chemical equation for the complete combustion of compound P.

Tulis persamaan kimia bagi pembakaran lengkap sebatian P.
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[2 marks]
(c) (i) State the name of gas T that produced in reaction III.
Nyatakan nama gas T yang terhasil dalam tindak balas III.

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[1 mark]
 (ii) Draw the diagram of set-up of apparatus to carry out reaction III in the
laboratory.
Lukis gambarajah susunan radas untuk menjalankan tindak balas III di dalam
makmal.

[2 marks]
(d) State the change of colour of acidified potassium manganate(VII) solution in
reaction IV.
Nyatakan perubahan warna larutan kalium manganat(VII) berasid di dalam
tindak balas IV.
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[1 mark]
(e) Diagram 6.2 shows the environment pollution from the manufactured substance
of polymer R.
Rajah 6.2 menunjukkan pencemaran alam sekitar daripada bahan buatan
polimer R.
Uses
Polymer R
Kegunaan
Polimer R

Throw
Buang
Acidic gas
Gas berasid
Burning Toxic gas
Pembakaran Gas beracun

Diagram 6.2 / Rajah 6.2

Based on diagram 6.2, describe the effect of pollution from the
manufactured substance of polymer R on the environment. State one way
to overcome the problem.
Berdasarkan rajah 6.2, huraikan kesan pencemaran bahan buatan daripada
polimer R ke atas alam sekitar. Nyatakan satu cara mengatasi masalah ini.
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[3 marks]
SKOR A KIMIA 2014
TAJUK: SEBATIAN KARBON
SET 3
Table 4 shows the molecular formulae and observations for three compounds when they react
with bromine water.
Jadual 4 menunjukkan formula molekul dan pemerhatian bagi tiga sebatian apabila
bertindakbals dengan air bromin.

Compound Molecular Formula Observation

Sebatian Formula Molekul Pemerhatian
P C2H4 Brown colour is decolourised
Warna perang menjadi tidak berwarna

Q C2H6 Brown colour remains

Warna perang tidak berubah

R C4H10

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Table 4
Jadual 4
a) i) Name the homologous series for these compounds.
Namakan siri homolog bagi sebatian-sebatian ini.

P : ......................................................

Q : ......................................................
ii) Write the general formula for the homologous series of compounds Q and R?
Apakah formula am bagi siri homolog sebatian Q dan R?

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[ 1 mark ]
iii) In Table 4, complete the observation when compound R reacts with bromine water.
Dalam Jadual 4, lengkapkan pemerhatian yang berlaku apabila sebatian R
bertindakbalas dengan air bromin.
[ 1 mark ]

iv) Name another substance that can replace bromine water.

Namakan bahan lain yang boleh menggantikan air bromin.

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[ 1 mark]
v) Explain why compound P is chemically more reactive than compound Q.
Jelaskan mengapa sebatian P lebih reaktif secara kimia berbanding sebatian Q.

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[ 1 mark ]
b) One mole of compound P and Q undergo complete combustion to form gas X and
water.
Satu mol sebatian P dan Q mengalami pembakaran lengkap untuk menghasilkan gas X
dan air.
i) Name gas X.
Namakan gas X.

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[ 1 mark ]
ii) Write a balanced chemical equation when compound P or Q reacts with oxygen.
Tulis persamaan kimia yang seimbang apabila sebatian P atau Q bertindak balas
dengan oksigen.

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[ 1 mark ]
iii) Explain why the compound P burns with more soot compared to compound Q.
Jelaskan mengapa sebatian P terbakar dengan penghasilan jelaga yang lebih
banyak daripada sebatian Q.

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[2 marks ]
SKOR A KIMIA 2014
TAJUK: SEBATIAN KARBON
SET 4
The flow chart in Diagram 6 shows the relationship between four organic compounds.
Carta alir pada Rajah 6 menunjukkan perkaitan antara empat sebatian organik.

Diagram 6 /
Rajah 6
(a) Alcohol Q can be changed into an alkene C4H8, through process I. Draw the
apparatus setup for the process.
Alkohol Q boleh ditukar kepada suatu alkena C4H8, melalui Proses 1. Lukiskan
susunan alat radas untuk melakukan proses tersebut.

[2 marks / 2 markah]

(b) (i) Name the alcohol Q.

Namakan alkohol Q.

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1mrk
(ii) Name the Process I
Namakan Proses 1

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(c) (i) What is meant by isomerism?.
Apakah maksud isomerism
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(ii) Draw and name two isomers of alcohol Q
Lukis dan namakan dua isomer bagi alkohol Q.
(d) Through oxidation process, alcohol Q is changed to butanoic acid.
Explain a chemical test to differentiate between alkane,C4H10 and butanoic
acid.
In the description, you should include : apparatus and materials used, procedures
and
observati
ons
Melalui proses pengoksidaan, alcohol Q ditukarkan kepada asid butanoik.
Terangkan satu ujian kimia untuk membezakan antara alkana, C4H10 dan asid butanoik. Di
dalam penerangan, anda mesti menyatakan : susunan alat radas dan bahan, prosedur dan
pemerhatian.
[10 markah]

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SKOR A KIMIA 2014
TAJUK: SEBATIAN KARBON
SET 5
Table 5 shows the formulae of three organic compounds.
Jadual 5 menunjukkan formula bagi tiga sebatian organik

Organic compound Formula

Sebatian organik Formula
Butan-1-ol
C4H10O
Butan-1-ol
Butanoic acid
C4H8O2
Asid Butanoik
But-1-ene
C4 H 8
But-1-ena

TABLE / JADUAL 5

Use the information in Table 5 to answer the following questions.

Gunakan maklumat dalam Jadual 5 untuk menjawab soalan berikut.

(a) Name the homologous series for butan-1-ol.

Namakan siri homolog bagi butan-1-ol

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[ 1 mark ]

(b) (i) Draw the structural formula of butan-1-ol

Lukiskan formula struktur bagi butan-1-ol

[ 1 mark ]

(ii) The following structural formula is isomer of butanol.

Formula struktur berikut ialah isomer bagi butanol

CH3

CH3 - C - CH3

OH

Name the isomer.

Namakan isomer itu.
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1 mrk
(c ) Butan-1-ol can react with butanoic acid to form compound X and water.
Butan-1-ol boleh bertindak balas dengan asid butanoik untuk menghasilkan
sebatian X dan air.

(i) What is the name of this reaction?

Apakah nama tindak balas ini.

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[ 1 mark ]
(ii) Write the chemical equation for the reaction.
Tuliskan persamaan kimia bagi tindak balas itu.

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[ 1 mark ]

(iii) State one physical property of compound X.

Nyatakan satu sifat fizik bagi sebatian X.

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[ 1 mark ]

(d) Dehydration of butan-1-ol using porous pot chips produce but-1-ene.

Draw the set up of apparatus used in the dehydration.
Pengdehidratan butan-1-ol menggunakan serpihan pasu berliang menghasilkan
but-1-ena. Lukiskan susunan radas yang digunakan dalam pengdehidratan itu.

2 mrk
SKOR A KIMIA 2014
TAJUK: SEBATIAN KARBON
SET 6
(a) Diagram 10.1 shows the structural formulae of compound A and compound B.
Rajah 10.1 menunjukkan formula struktur bagi sebatian A dan sebatian B.

Compound A Compound B
Sebatian A Sebatian B
Diagram 10.1
Rajah 10.1

Compound A and compound B are burnt completely in oxygen to produce

carbon dioxide gas and water.
Sebatian A dan sebatian B terbakar lengkap dalam oksigen menghasilkan gas
karbon dioksida dan air.

(i) Name compound B.

Namakan sebatian B.
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(ii) Compound B produced more soot than compound A when burnt in oxygen.
Explain why.
Sebatian B menghasilkan lebih jelaga daripada sebatian A apabila terbakar
dalam oksigen. Terangkan mengapa.
[Relative molecular mass of: A = 86, B = 84]
[Jisim molekul relatif: A = 86, B = 84]
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4 mrk.
(b) Diagram 10.2 shows the structural formulae of compound J and compound K.
Rajah 10.2 menunjukkan formula struktur bagi sebatian J dan sebatian K.

Compound J Compound K
Sebatian J Sebatian K
Diagram 10.2
Rajah 10.2

State one physical property of compound K . Describe briefly a chemical

test to differentiate between compound J and compound K.
Nyatakan satu sifat fizik Sebatian K. Huraikan secara ringkas satu ujian kimia
untuk membezakan antara sebatian J dan sebatian K.
[6 marks]
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(c) Alcohols undergo dehydration reaction to produce alkenes and water.
Describe how to prepare an alkene from a named alcohol through dehydration
process. In your description, include the diagram of the apparatus set-up and
balanced chemical equation for the reaction.
Alkohol mengalami tindak balas pendehidratan untuk menghasilkan alkena dan air.
Huraikan bagaimana satu alkena disediakan daripada alkohol yang dinamakan melalui
proses pendehidratan. Dalam huraian anda, sertakan gambar rajah bagi susunan radas dan
persamaan kimia seimbang bagi tindak balas itu.
[10 marks]

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